Std : Long Term Max. Marks: 180 Test Date : 14.12.2023 CHEMISTRY Time : 1 Hr. Note : For every correct answer four marks will be awarded. For every wrong answer one mark will be reduced. For unanswered questions zero mark. Choose the correct answer : 45 x 4 = 180 1. The metal that has highest melting point and 8. Zn and Cd metals do not show variable used in making hard steel is oxidation states because 1) Cu 2) Mn 1) They have only two electrons in the 3) Zn 4) W outermost subshells 2. Which one of the following ions has same 2) Their d-subshells are completely filled number of unpaired electrons as those present in V+3 ion 3) Their d-subshells are partially filled 1) Fe+3 2) Ni+2 4) They are soft metals +2 +3 3) Mn 4) Cr 9. Match the following 3. Which of the following set of elements does Set – I Set – II not belong to transition elements? A) Ferromagnetism 1) 9.273 x 10–24 J T–1 1) Fe, Co, Ni 2) Cu, Ag, Au B) Paramagnetism 2) Fe, Co, Ni 3) Zr, Ti, Hf 4) Ga, In, Tl 4. In which pair, both ions are coloured in C) Diamagnetism 3) Cr+2, Fe+3, Mn+2 aqueous medium D) Bohr magneton 4) Zn+2, Cu+1, Sc+3 1) Sc+3, Zn+2 2) Cu+1, Ti+4 The correct match is +3 +3 3) Ti , Co 4) Cd+2, Hg+2 1) A-4, B-2, C-3, D-1 +3 5. The magnetic moment of the complex Ti is 2) A-2, B-3, C-4, D-1 1) 3.87 BM 2) 1.73 BM 3) A-1, B-2, C-3, D-4 3) 2.84 BM 4) 5.87 BM 6. Which oxide of Mn is more acidic in nature? 4) A-3, B-1, C-2, D-4 1) MnO 2) Mn2O7 10. Atomic number of a transition metal is 25 then 3) Mn2O3 4) MnO2 its magnetic moment in its +3 oxidation state is 7. Zinc gives H2 gas with H2SO4 and conc. HCl 1) 1.73 BM 2) 2.84 BM but not with conc. HNO3 because 3) 4.9 BM 4) 5.9 BM − 1) NO3 is reduced in preference to hydronium 11. In the following elements, the first member is ion. a liquid at room temperature and the second 2) Conc. HNO3 is a weaker acid than conc. member is mostly available metal in the H2SO4 and conc. HCl earth’s crust the pair is 3) Conc. HNO3 acts as a reducing agent 1) Hg, Fe 2) Hg, Tc 4) Zinc is more reactive than H2 3) Cd, Zn 4) Cd, Au 2 Test ID : 745 12. The ratio of magnetic moments of Fe(III) and 18. The characteristics of interstitial compounds Co(II) is are 1) 5: 7 2) 35 : 15 I) They have low melting points II) They are very hard 3) 7 : 3 4) 24 : 15 III) They retain metallic conductivity 13. The compound in which Ni has the lower IV) They are chemically more reactive than oxidation state is pure metals 1) Ni(CO)4 1) II, III are only correct 2) (CH3COO)2Ni 2) I, III only correct 3) NiO 3) II, IV only correct 4) NiCl2 4) IV only correct 14. The correct statement(s) in the following are 19. Which one of the following pairs of elements I) O.S of iron is (+6) in K2FeO4 is called chemical twins because of their very II) Iron shows (+2) O.S. with 6 electrons in similar chemical properties. the 3d orbitals 1) Mn, W 2) Ti, Tc III) The common O.S of iron is (+3) with five 3) Fe, Re 4) Hf, Zr unpaired electrons in the 3d-orbital 20. Oxide of metal ion which is not amphoteric is 1) I, II, III 2) I, II only 1) Al3+ 2) Cr3+ 3) II, III only 4) I only 3) Fe3+ 4) Zn2+ 21. Which metal in the first transition series 15. Which one of the following may be expected exhibits (+1) O.S most frequently? to have the highest second ionization enthalpy? 1) Mn 2) Cu 1) Ti 2) Cr 3) Co 4) Ni 3) V 4) Mn 22. Match the following 16. Transition metals have higher enthalpies of Column – I Column – II atomization due to i) An element which can a) Mn 1) Their ability to show variable O.S show (+8) O.S 2) The presence of incompletely filled d-sub- ii) 3d series element that b) Cr shell can show (+7) O.S 3) Their ability to exist in solid state with iii) 3d series element with c) Os unpaired electrons highest melting point 4) Strong inter atomic interactions arises d) Fe because of having large number of unpaired 1) i-a, ii-b, iii-d 2) i-c, ii-a, iii-d electrons in their atoms 3) i-c, ii-a, iii-b 4) i-a, ii-b, iii-c 17. In the coinage metals group, the I.E decreases 23. Pt, Pd and Ir are called noble metals because from Cu to Ag and then increases from Ag to 1) Alfred noble discovered them Au this is attributed to 2) They are inert towards many common 1) Increased atomic size reagents 2) Increased ionic radius 3) They are lustrous pleasing to look 3) Increased nuclear density 4) They are found in active state. 4) Lanthanide contraction A 3 Test ID : 745 24. In which of the following elements the 31. The catalyst used in polymerization of configuration is against to Auf-bau rule? ethylene is 1) Ni, Pt, Pd 2) Sc, Ti, Zr 1) R3Al + TiCl4 2) SnCl4 3) Cu, Pt, Pd 4) Fe, Cr, Mn 3) Ni 4) Pt 25. An element ‘M’ has the electronic 32. In the dichromate dianion configuration [Ar]3d54s2. Which one of its 1) 4 Cr – O bonds are equivalent oxide is unlikely to exist? 1) MO2 2) M2O3 2) 6 Cr – O bonds are equivalent 3) MO4 4) M2O7 3) All Cr – O bonds are equivalent 26. Identify the order in which the spin only 4) All Cr – O bonds have different lengths magnetic moment increases for the following 33. Which of the following statements is false four ions 1) K2MnO4 is colourless and paramagnetic I) Fe+2 II) Ti+2 2) Both MnO −4 and MnO 24 − are in tetrahedral III) Cu+2 IV) V+2 1) I, II, IV, III 2) IV, I, II, III form 3) III, IV, I, II 4) III, II, IV, I 3) Permanganate ion is diamagnetic in nature 27. Which one of the following does not show 4) Permanganate titration in presence of HCl variable oxidation states are unsatisfactory 1) Cu 2) Sc 34. Number of moles of K2Cr2O7 reduced by one 3) Zn 4) Both (2) and (3) mole of Sn2+ ions is 28. Which one of the following elements have 1 highest 3rd ionization enthalpy? 1) 2) 3 3 1) V 2) Cr 1 3) Mn 4) Fe 3) 4) 6 6 29. Which of the following statement regarding 35. Which is not an interstitial compound? transition elements is false? 1) They show fixed valency 1) TiH 2) Fe2O3 2) They form coloured compounds 3) Mn2C3 4) W2C 3)They form complex compounds 36. Which of the following oxides of chromium is 4) They form alloys amphoteric in nature? 30. Cuprous ion is excepted to be colourless while 1) CrO 2) Cr2O3 cupric ion is coloured because, 3) CrO3 4) CrO5 1) Cuprous ion has completely filled d- 37. The Eo values Cr 3+ / Cr 2+ = −0.4V, orbitals, while cupric ion has incomplete filled d-orbitals Mn 3+ / Mn 2 + = 1.5 V , Fe3+ / Fe 2+ = 0.8 V . 2) Cuprous ion has half-filled d-orbitals, Which acts as a strong reducing agent? cupric ion has completely filled d-orbitals 1) Cr2+ 3) Cupric ion has completely filled d-orbitals, 2) Mn2+ cuprous ion has incompletely filled 3) Fe2+ d-orbitals 4) We can’t predict 4) Cupric ion has half-filled d-orbitals, cuprous ion has incompletely filled d-orbitals
A 4 Test ID : 745 38. Identify the incorrect statement from the 42. Match the following ions (Column-I) with following their colours (Column-II) 1) The high melting points of transition metals Column-I Column-II are due to the involvement of electrons I) Manganate a) Purple from (n-1)d and ns II) Dichromate b) Green III) Permanganate c) Yellow 2) Mn has high melting point in 3d series IV) Chromate d) Orange elements 1) I-b, II-d, III-c, IV-a 3) Enthalpy of atomization is an important 2) I-b, II-d, III-a, IV-c factor in determining the standard electrode 3) I-a, II-c, III-b, IV-d potential of a metal 4) I-a, II-d, III-b, IV-c 4) Melting point of Tc is high when compared 43. Match the following compounds (column – I) to Mn with their uses (column – II) 39. Which of the following statements are correct Column-I Column-II about E 0M3+ /M2+ values? I) TiO a) Ostwald’s process II) MnO2 b) Contact process 1) Low value for Fe is due to extra stability of III) V2O5 c) Pigment industry Fe3+ (d5) IV) Fe d) Dry batteries 2) The highest value for Zn is due to the stable 1) I-a, II-c, III-b, IV-d d10 configuration of Zn2+ 2) I-c, II-d, III-b, IV-a 3) The low value for Sc is due to stability of 3) I-a, II-d, III-b, IV-c Sc3+ 4) I-d, II-c, III-b, IV-a 4) All the above 44. Statement-I : Permanganate titrations in 40. Why E0 value for Ni is more negative than presence of hydrochloric acid are unsatisfactory. Statement-II : Permanganate oxidises expected? hydrochloric acid into chlorine. 1) Stability of half filled d5 configuration 1) Both statements are true, statement-II is a 2) Highest second ionisation enthalpy correct explanation for statement-I 3) Highest negative hydration enthalpy 2) Both statements are true, statement-II is not 4) Least enthalpy of atomization a correct explanation for statement-I 41. Identify the incorrect statement about 3) Statement-I is true, statement-II is false interstitial compounds. 4) Statement-I is false, statement-II is true 45. Identify the incorrect statement from the 1) Interstitial compounds are formed when following large atoms are trapped inside the crystal 1) In transition elements oxidation states lattice of metals normally differ from each other by unity 2) Interstitial compounds are neither typically 2) In non-transition elements oxidation states ionic nor covalent normally differ from each other by a unit of 3) Mn4N is an interstitial compound two 4) They have higher melting points than those 3) Cr(VI) is more stable than Mo(VI) 4) Sc does not exhibit variable oxidation states of pure metals ***All the best *** A
