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MSDS Epon Finish 103

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0% found this document useful (0 votes)
71 views9 pages

MSDS Epon Finish 103

Uploaded by

vuquoctrung57.it
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 9

DATAFETY DATA SHEET

SAFETY DATA SHEET


ZOTA EPON FINISH 103
Section 1. Identification
GHS product identifier : ZOTA EPON FINISH 103
Product code : EPO103
Product description : Paint.
Other means of : Not available.
identification
Product type : Liquid.

Identified uses : Uses in Coatings – Industrial use

Supplier's details : BA BA TRADING CO., LTD.


709 Bui Dinh Tuy Ward 12, Binh Thanh District, HCMC, VN
Telephone: (8428) 38725535
[email protected]

Emergency telephone : (8428)38725535


number

Section 2. Hazards identification of the product


OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Fertility) - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 2

GHS label elements

Danger.

Hazard statements Flammable liquid and vapor.


May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Suspected of causing cancer.
May cause drowsiness and dizziness.
Causes damage to organs through prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.

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Precautionary statements
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear
protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking
tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a
well-ventilated area. Avoid release to the environment. Do not breathe vapor or spray. Do not eat, drink or smoke when
using this product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the
workplace.
Response
Collect spillage. Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF
INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you
feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF
ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash
occurs: Get medical attention. In case of fire Use dry chemical, CO2, water spray or foam to extinguish.
Storage
Store locked up. Store in a well-ventilated place. Keep cool.
Disposal
Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
None known.

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers


CAS number : Not applicable.
Product code : EPO103
Ingredient name % CAS number

Dimethylbenzene ≥5 - <20 1330-20-7


1-Hydroxybutane ≥1 - <5 71-36-3
Epoxy resin (MW 700-1200) ≥40 - ≤60 25036-25-3
Calcium Magnesium Carbonate ≥20 - ≤30 16398-88-1

Any concentration shown as a range is to protect confidentiality or is due to batch variation.


There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

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Section 4. First aid measures
Description of necessary first aid measures
Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Get medical
attention immediately.
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected
that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a
fire, symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Skin contact Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for
at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further
exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in
a position comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting
may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If
vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical
attention. If necessary, call a poison center or physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact No known significant effects or critical hazards.
Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness.
Skin contact May cause an allergic skin reaction.
Ingestion Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact No specific data.
Inhalation Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue
dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations
Skin contact Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal
deaths skeletal malformations
Ingestion Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal
malformations

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Specific treatments: No specific treatment.
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus.
It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)

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Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Use dry chemical, CO₂, water spray (fog) or foam.
Unsuitable extinguishing media: Do not use water jet.
Specific hazards arising from the chemical: Flammable liquid and vapor. In a fire or if heated, a pressure increase
will occur and the container may burst with the risk of a subsequent explosion. Run off to sewer may create fire or
explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal decomposition products: Decomposition products may include the following materials:
carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides
Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the
incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers
from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-
contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through
spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".
Environmental precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up


Small spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in
an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Large spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into
an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g.
sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section
13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures: Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin
sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special
instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and
understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the
environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter
storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take
precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous.
Do not reuse container.

4|Page
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information
on hygiene measures.

Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in a
segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources.
Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits

Ingredient name Exposure limits

Dimethylbenzene ACGIH TLV


TWA: 434 mg/m³ 8 hours. TWA: 100 ppm 8 hours.
OSHA PEL
TWA: 434 mg/m³ 8 hours. TWA: 100 ppm 8 hours.

1-Hydroxybutane ACGIH TLV


TWA: 300 mg/m³ 8 hours. TWA: 100 ppm 8 hours.
OSHA PEL
TWA: 300 mg/m³ 8 hours. TWA: 100 ppm 8 hours.

Appropriate engineering controls:


Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep
worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to
keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Environmental exposure controls:


Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and
using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially
contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing
before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following
protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Skin protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times
when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the
glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the
time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures,
consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Hand protection There is no one glove material or combination of materials that will give unlimited resistance to any
individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product. The instructions and information
provided by the glove manufacturer on use, storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove material.
Always ensure that gloves are free from defects and that they are stored and used correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical damage and poor maintenance.

5|Page
Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has
occurred.
Wear suitable gloves tested to EN374.
Recommended, gloves(breakthrough time) > 8 hours: nitrile rubber, 4H, Teflon Not recommended,
gloves(breakthrough time) < 1 hour: neoprene, butyl rubber, PVC

Body protection: Personal protective equipment for the body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from
static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should
include anti-static overalls, boots and gloves.
Other skin protection: Appropriate footwear and any additional skin protection measures should be selected based on the
task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection: Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard (NIOSH-
approved P95) if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Section 9. Physical and chemical properties

Physical state : Liquid.


Color : Various colors.
Odor : Characteristic.
Flash point : Closed cup: 25°C (77°F)
Relative density : 1.25 to 1.33 g/cm³ 1 2.52 to 13.32 pounds/gallon
VOC : 0.367 g/ cm³ 3.06 pounds/gallon
Solubility : Insoluble in the following materials: cold water and hot water.
Viscosity : Kinematic (40°C (104°F)): >0.225 cm 2/s (>22.5 mm2/s)

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Incompatible materials : Reactive or incompatible with the following materials:
oxidizing materials
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

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Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Dimethylbenzene LC50 Inhalation Gas. Rat 6700 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
1-Hydroxybutane LD50 Oral Rat 790 mg/kg -

Reproductive toxicity
Not available.
Teratogenicity
Not available.

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness.
Skin contact : May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics


Contains epoxy resin (MW 700-1200). May produce an allergic reaction
Eye contact: No specific data
Inhalation: Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue
dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations
Skin contact: Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths
skeletal malformations
Ingestion: Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects: Not available.
General : Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.

Developmental effects : No known significant effects or critical hazards.

Fertility effects :
Suspected of damaging fertility
.

7|Page
Section 12. Ecological information
Toxicity
Product/ingredient name Result Species Exposure
Dimethylbenzene Acute EC50 8.5 mg/l Daphnia 48 hours
Acute IC50 >3.2 mg/l Algae 72 hours
Acute LC50 2 mg/l Fish 96 hours

1-Hydroxybutane Acute EC50 1983 mg/l Daphnia 48 hours


Acute IC50 >500 mg/l Algae 96 hours
Acute LC50 72 mg/l Fish 30 days

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods:
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with
jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from
product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used
containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.

Section 14. Transport information

DOT TDG Mexico ADR/RID IMDG IATA


Classification Classification Classification
UN number 1263 1263 1263 1263 1263 1263

UN proper Paint. Paint. Paint. Paint. Paint. Paint.


shipping name
Transport 3 3 3 3 3 3
hazard class(es)

Packing group III III III III III III


Environmental Yes. Yes. No. Yes. Yes. No.
hazards

Additional information
TDG Classification: Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3), 2.7 (Marine pollutant mark).
The marine pollutant mark is not required when transported by road or rail.

8|Page
ADR/RID: Tunnel restriction code: (D/E) Hazard identification number: 30
Special provisions: 640E

IMDG: Emergency schedules (EmS): F-E, S-E Marine pollutant: Yes.

IATA: The environmentally hazardous substance mark may appear if required by other transportation regulations.

Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright
and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not available.

Section 15. Regulatory information


This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS
contains all the information required by the Controlled Products Regulations

Risk phrases: R10- Flammable.


R20/21- Harmful by inhalation and in contact with skin.
R36/38- Irritating to eyes and skin.
R43- May cause sensitization by skin contact.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases: S23- Do not breathe vapor / spray.


S36/37- Wear suitable protective clothing and gloves.
S38- In case of insufficient ventilation, wear suitable respiratory equipment.

Section 16. Other information


Date of issue: 22.06.2020
Version: 1.03
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

9|Page

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