Chapter 2 Basic Physics of Semiconductors
Chapter 2 Basic Physics of Semiconductors
1
Semiconductor Physics
➢ Eg, or bandgap energy determines how much effort is needed to break off an electron
from its covalent bond.
➢ There exists an exponential relationship between the free-electron density and bandgap
energy.
➢ In the above equation: T is the temperature in K and k is the Boltzmann constant = 1.38 × 10-23
J/K.
➢ Eg unit is eV: The unit eV (electron volt) represents the energy necessary to move one electron across a
potential difference of 1V. Note that 1 eV= 1.6 x10-19J.
➢ A band gap is the distance between the valence band of electrons and the
conduction band. Essentially, the band gap represents the minimum energy
that is required to excite an electron up to a state in the conduction band
where it can participate in conduction.
➢ The lower energy level is the valence band, and thus if a gap exists between
this level and the higher energy conduction band, energy must be input for
electrons to become free. The size and existence of this band gap allows
one to visualize the difference between conductors, semiconductors, and
insulators. These distances can be seen in diagrams known as band
diagrams, shown below.
Source:
https://energyeducation.ca/encyclopedia/Band_gap#:~:text=A%20band%20gap%20is%20the,it%20can%20participate%20in%20conduction.
10
Band Gap Sizes
➢ This figure illustrates the difference in size of the band gap
for insulators, conductors, and semiconductors. The size
of this band gap gives the materials some of their distinct
properties. In insulators, the electrons in the valence band
are separated by a large band gap from the conduction
band. This means that there is a large "forbidden" gap in
energies preventing electrons from the valence band from
jumping up into the conduction band and participating in
conduction. This provides an explanation for why
insulators do not conduct electricity well.
➢ In conductors, the valence band overlaps with the conduction band. This overlap causes the valence
electrons to be essentially free to move into the conduction band and participate in conduction. Since it is not
a full overlap, only a fraction of the valence electrons can move through the material, but this is still enough to
make conductors conductive.
➢ In semiconductors, the gap is small enough that it can be bridged by some sort of excitation - perhaps from
the Sun in the case of photovoltaic cells. The gap is essentially some size "in-between" that of a conductor or
insulator. In this model, a finite number of electrons are able to reach the conduction band and conduct small
amounts of electricity. The excitation of this electron also allows additional conduction processes to occur as
a result of the electron hole left behind. An electron from an atom close by can occupy this space, creating a
chain reaction of holes and electron movement that creates current. A small amount of doping material can
drastically increase the conductivity of this material.
Source: 11
https://energyeducation.ca/encyclopedia/Band_gap#:~:text=A%20band%20gap%20is%20the,it%20can%20participate%20in%20conduction.
Comments on ni Equation
In some textbooks, authors give Diamond different values of Eg such as the following:
Source of Eg table: 12
https://www.chu.berkeley.edu/wp-content/uploads/2020/01/Chenming-Hu_ch1-3.pdf
Example 1
13
Example 1 / Solution
14
Example 1 / Solution
− Eg
ni = 5.2 10 T exp
15 3/ 2
electrons / cm 3
2kT
ni (T = 3000 K ) = 1.08 1010 electrons / cm 3
ni (T = 6000 K ) = 1.54 1015 electrons / cm 3
15
Question Related To Previous Example
16
Question Related To Previous Example 1
17
Why Doping?
➢ Pure or intrinsic silicon is not a good conductor since it has very low
number of free electrons compared to the total no. of our silicon we have in a
crystal.
➢ Based on the previous example, in 1 cm3 Si crystal area, and at room
temperature (300 k), we will have 1010 of free electrons which is equal to the
number of holes created while we have 5x1022 of Silicon atoms. So, Si has a
relatively high resistance and it is not a very useful material in terms of
conductivity.
➢ To overcome the poor conductivity of pure Silicon so perhaps there is a
way to modify and increase the number of free carriers or free electrons in
Silicon, and hence we do Doping by adding impurities to the Silicon crystal.
18
Doping (N type)
➢ Pure Si can be doped with other elements to change its electrical properties.
➢ In this doping process, we replace some of the Si atoms by Phosphorus (P)
atoms.
➢ P is a pentavalent atom since it has 5 electrons in its last orbital and this P
is called impurity, and also called dopant, and also called donor since it
donates free electrons in the Silicon crystal for current conduction and the
material is called n-type semiconductor material.
➢ In other words, if Si is doped with P (phosphorous) (which is a pentavalent
atom since it has 5 electrons in its last orbital), which means P has more
electrons → Si becomes type N (electron).
➢ Si doped with P is called Extrinsic Silicon.
21
Example 2 / Solution
22
Example 2 / Solution
23
Doping (P type)
➢ Pure Si can be doped with other elements to change its electrical properties.
➢ In this doping process, we replace some of the Si atoms by Boron (B)
atoms.
➢ B is a trivalent atom since it has 3 electrons in its last orbital and this B is
called impurity, and also called dopant, and also called acceptor since it
accepts free electrons in the Silicon crystal for current conduction and the
material is called p-type semiconductor material.
➢ In other words, if Si is doped with B (Boron) (which is a trivalent atom since
it has 3 electrons in its last orbital), which means B has less electrons → Si
becomes type P (hole).
➢ Si doped with B is called Extrinsic Silicon.
28
Summary of Charge Carriers
2
np = ni
Majority Carriers : p NA
p-type 2
n
semiconductor Minority Carriers : n i
NA
Majority Carriers : n ND
n-type
2
semiconductor n
Minority Carriers : p i
ND
31
Example 3 / Solution
32
Example 4
33
Example 4 / Solution
34
First Charge Transportation Mechanism: Drift
A
Si
➢ mp = 480 cm2/(V.s) ve = − m n E
CH2 Basic Physics of Semiconductors 35
Example 5
36
Example 5 / Solution
37
Current Flow: General Case
J n = mn E n q
J tot = m n E n q + m p E p q
= q( m n n + m p p) E
J n = mn E n q
J tot = m n E n q + m p E p q
= q( m n n + m p p) E
Observation about this equation:
➢ 1) So if we have n-type material, the first part of this equation will be for the
majority free electrons and the second part is for the minority holes carriers and
hence the second part could be ignored.
➢ 2) And if we have p-type material, the first part of this equation will be for the
minority free electrons and the second part is for the majority holes carriers and
hence the first part of this equation could be ignored.
➢ 3) This equation is for drift mechanism where we have a piece of silicon with
some doping or no doping, it doesn’t matter, then we apply a voltage and in
response to this voltage we will have electric field and if we know the amount of
doping or the amount of free electrons per cm3 and the amount of holes per cm3 and
we know other parameters in the above equation we can find the total drift current
per unit cross sectional area.
CH2 Basic Physics of Semiconductors 42
Velocity Saturation
m0
m=
1 + bE
m0
vsat =
b
m0
v = E
m0 E
1+
vsat
➢ A topic treated in more advanced courses is velocity
saturation.
➢ In reality, velocity does not increase linearly with electric
field. It will eventually saturate to a critical value.
44
Example 6 / Solution
45
In-Class Exercise
46
In-Class Exercise/Solution
47
In-Class Exercise/Solution
48
In-Class Exercise/Solution
49
Second Charge Transportation Mechanism:
Diffusion Current
dn dp
I = AqDn J p = − qD p
dx dx
dn dn dp
J n = qDn J tot = q ( Dn − Dp )
dx dx dx
dn N dn − qDn N −x
J n = qDn = −qDn J n = qD = exp
dx L dx Ld Ld
60
Example 7 / Solution
61
Einstein's Relation
D kT
= = Thermal Voltage VT = 26 mV @ 300
m q
63
Example 8 / Answer
Answer:
64
PN Junction (Diode)
69
Example 9 / Solution
70
PN Junction in Equilibrium
➢ Now recall from basic physics that a particle or object carrying a net
(nonzero) charge creates an electric field around it. Thus, with the formation
of the depletion region, an electric field emerges as shown in the figure.
➢ Interestingly, the field tends to force positive charge flow from left to right
whereas the concentration gradients necessitate the flow of holes from right
to left (and electrons from left to right). We therefore surmise that the junction
reaches equilibrium once the electric field is strong enough to completely
stop the diffusion currents. Alternatively, we can say, in equilibrium, the drift
currents resulting from the electric field exactly cancel the diffusion currents
due to the gradients.
CH2 Basic Physics of Semiconductors 74
Electric Field Profile in a PN Junction
➢ In the junction shown in the figure , the depletion region has a width
of b on the n side and a on the p side. Following is how to sketch the
electric field as a function of x.
➢ Beginning at x < b, we note that the absence of net charge yields E =
0. At x > b, each positive donor ion contributes to the electric field,
i.e., the magnitude of E rises as x approaches zero. As we pass x =
0, the negative acceptor atoms begin to contribute negatively to the
field, i.e., E falls. At x = a, the negative and positive charge exactly
cancel each other and E = 0.
75
Current Flow Across Junction: Equilibrium
I drift , p = I diff , p
I drift ,n = I diff ,n
dp dV dp
qm p pE = −qD p − mp p = −Dp
dx dx dx
x 2 p
dp n
Dp p p
m p dV =D p V ( x2 ) − V ( x1 ) = ln
x 1 p p p m p pn
kT p p kT N A N D
V0 = ln ,V0 = ln 2
q pn q ni
➢ Important comments:
– Vo is the Barrier Voltage across the pn junction with no
external voltage applied.
– NA and ND are the doping concentrations of the p side and n
side of the junction, respectively. Thus, Vo depends both on
doping concentrations and on temperature.
– Vo is also known as the junction built-in voltage.
– Typically, for silicon at room temperature, Vo is in the range
of 0.6 V to 0.9 V. Can you prove it?
79
Example 10 / Solution
80
Example 11
81
Example 11 / Solution
82
Diode in Reverse Bias
C j0
Cj =
V
1+ R
V0
si q N A N D 1
C j0 =
2 N A + N D V0
1 1
f res =
2 LC
p p ,e
pn , e =
V0
exp
VT
p p, f
pn , f =
V0 − VF
exp
VT
ND V NA V
n p (exp F − 1) pn (exp F − 1)
V VT V VT
exp 0 exp 0
VT VT
NA V ND V
I tot (exp F − 1) + (exp F − 1)
V0 V V0 VT
exp T exp
VT VT
VF 2 Dn Dp
I tot = I s (exp − 1) I s = Aqni ( + )
VT N A Ln N D L p
VD
I D = I S (exp − 1)
VT
96
Example/Solution
Solution:
97
Example/Solution
Solution:
98
Comments about the Example: Diode Calculations
IX
VX = I X R1 + VD = I X R1 + VT ln
IS
I X = 2.2mA for VX = 3V
I X = 0.2mA for VX = 1V