Safety Data Sheet

Hazardous, Dangerous Goods

1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION

Product name: 403 Auto Enamel Black

Synonyms Product Code
403 Auto Enamel Black IN40370000004
403 Auto Enamel Black IN40370000020

Recommended use: Commercial & Industrial Coating

Supplier: CHILMIX PTY LTD T/A CONCEPT PAINTS

ABN: 28 069 967 362
Street Address: 26 - 30 Charles Street
St Marys NSW 2760
Australia
Telephone: +61 2 9673 2555
Facsimile: +61 2 9623 1918
Email: [email protected]

Emergency Telephone number: +1 703 741 6037 (24 hours)

2. HAZARDS IDENTIFICATION

This material is hazardous according to the criteria of Safe Work Australia GHS 7.

Signal Word
Danger

Hazard Classifications
Flammable Liquids - Category 2
Aspiration Hazard - Category 1

Hazard Statements
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.

Prevention Precautionary Statements

P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical, ventilating, lighting and all other equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P280 Wear protective gloves/protective clothing including eye/face protection and suitable
respirator.

Response Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
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P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P331 Do NOT induce vomiting.
P370+P378 In case of fire: Use Foam, Carbon Dioxide or Dry Chemical Powder to extinguish.

Storage Precautionary Statements

P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Disposal Precautionary Statement

P501 Dispose of contents/container in accordance with local, regional, national and
international regulations.

Poison Schedule: S6. Poison

DANGEROUS GOOD CLASSIFICATION

Classified as Dangerous Goods by the criteria of the "Australian Code for the Transport of Dangerous Goods by
Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".

Dangerous Goods Class: 3

3. COMPOSITION INFORMATION

CHEMICAL ENTITY CAS NO PROPORTION

Naphtha, petroleum, hydrodesulfurized heavy 64742-82-1 10-30 % (w/w)

Solvent naphtha, petroleum, light aromatic 64742-95-6 10-20 % (w/w)
Xylene 1330-20-7 <10 % (w/w)
2-Propanol, 1-methoxy-, acetate 108-65-6 <10 % (w/w)
Ingredients determined to be Non-Hazardous Balance
____________
100%

4. FIRST AID MEASURES

If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New Zealand 0800
764 766).

Inhalation: Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and
loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until
fully recovered. Seek medical advice if effects persist.

Skin Contact: If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running
water. If swelling, redness, blistering or irritation occurs seek medical assistance. For gross contamination,
immediately drench with water and remove clothing. Continue to flush skin and hair with plenty of water (and soap
if material is insoluble). For skin burns, cover with a clean, dry dressing until medical help is available. If
blistering occurs, do NOT break blisters. If swelling, redness, blistering, or irritation occurs seek medical
assistance.

Eye contact: If in eyes wash out immediately with water. In all cases of eye contamination it is a sensible
precaution to seek medical advice.

Ingestion: Immediately rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to
drink. Never give anything by the mouth to an unconscious patient. If vomiting occurs give further water.
Immediately call Poisons Centre or Doctor.

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PPE for First Aiders: Wear rubber boots, overalls, gloves, safety glasses, respirator. Use with adequate
ventilation. If inhalation risk exists wear organic vapour/particulate respirator meeting the requirements of
AS/NZS 1715 and AS/NZS 1716. Available information suggests that gloves made from neoprene, polyvinyl
chloride (PVC) should be suitable for intermittent contact. However, due to variations in glove construction and
local conditions, the user should make a final assessment. Always wash hands before smoking, eating, drinking
or using the toilet. Wash contaminated clothing and other protective equipment before storing or re-using.

Notes to physician: Treat symptomatically.

5. FIRE FIGHTING MEASURES

Hazchem Code: •3YE

Suitable extinguishing media: If material is involved in a fire use alcohol resistant foam or dry agent (carbon
dioxide, dry chemical powder).

Specific hazards: Highly flammable liquid and vapour. May form flammable vapour mixtures with air.
Flameproof equipment necessary in area where this chemical is being used. Nearby equipment must be earthed.
Electrical requirements for work area should be assessed according to AS3000. Vapour may travel a
considerable distance to source of ignition and flash back. Avoid all ignition sources. All potential sources of
ignition (open flames, pilot lights, furnaces, spark producing switches and electrical equipment etc) must be
eliminated both in and near the work area. Do NOT smoke.

Fire fighting further advice: Heating can cause expansion or decomposition leading to violent rupture of
containers. If safe to do so, remove containers from path of fire. Keep containers cool with water spray. On
burning or decomposing may emit toxic fumes. Fire fighters to wear self-contained breathing apparatus and
suitable protective clothing if risk of exposure to vapour or products of combustion or decomposition.

6. ACCIDENTAL RELEASE MEASURES

SMALL SPILLS
Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours or dust. Wipe up
with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal.

LARGE SPILLS
If safe to do so, shut off all possible sources of ignition. Clear area of all unprotected personnel. Slippery when
spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination
and the inhalation of vapours. Work up wind or increase ventilation. Contain - prevent run off into drains and
waterways. Use absorbent (soil, sand or other inert material). Use a spark-free shovel. Collect and seal in
properly labelled containers or drums for disposal. If contamination of crops, sewers or waterways has occurred
advise local emergency services.

Dangerous Goods - Initial Emergency Response Guide No: 14

7. HANDLING AND STORAGE

Handling: Avoid eye contact and repeated or prolonged skin contact. Avoid inhalation of vapour, mist or
aerosols.

Storage: Store in a cool, dry, well-ventilated place and out of direct sunlight. Store away from foodstuffs. Store
away from incompatible materials described in Section 10. Store away from sources of heat and/or ignition.
Store locked up. Keep container standing upright. Keep containers closed when not in use - check regularly for
leaks.

This material is classified as a Class 3 Flammable Liquid as per the criteria of the "Australian Code for the
Transport of Dangerous Goods by Road & Rail" and/or the "New Zealand NZS5433: Transport of Dangerous
Goods on Land" and must be stored in accordance with the relevant regulations.
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This material is a Scheduled Poison Schedule 6 (Poison) and must be stored, maintained and used in
accordance with the relevant regulations.

This product is a "Manufactured Product" as defined in the ADG Code.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

National occupational exposure limits:

TWA STEL NOTICES

ppm mg/m3 ppm mg/m3

1-Methoxy-2-propanol acetate 50 274 100 548 Sk

Xylene 80 350 150 655

As published by Safe Work Australia.

TWA - The time-weighted average airborne concentration over an eight-hour working day, for a five-day working
week over an entire working life.

STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should not
be exceeded at any time during a normal eight-hour workday.

‘Sk' Notice - absorption through the skin may be a significant source of exposure. The exposure standard is
invalidated if such contact should occur.

These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These exposure standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative
toxicity.

If the directions for use on the product label are followed, exposure of individuals using the product should not
exceed the above standard. The standard was created for workers who are routinely, potentially exposed during
product manufacture.

Biological Limit Values: As per the "National Model Regulations for the Control of Workplace Hazardous
Substances (Safe Work Australia)" the ingredients in this material do not have a Biological Limit Allocated.

Engineering Measures: Ensure ventilation is adequate to maintain air concentrations below Exposure
Standards. Use only in well ventilated areas. Use with local exhaust ventilation or while wearing appropriate
respirator.

Personal Protection Equipment: RUBBER BOOTS, OVERALLS, GLOVES, SAFETY GLASSES,

RESPIRATOR.

Personal protective equipment (PPE) must be suitable for the nature of the work and any hazard associated with
the work as identified by the risk assessment conducted.

Wear rubber boots, overalls, gloves, safety glasses, respirator. Use with adequate ventilation. If inhalation risk
exists wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
Available information suggests that gloves made from neoprene, polyvinyl chloride (PVC) should be suitable for
intermittent contact. However, due to variations in glove construction and local conditions, the user should make
a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated
clothing and other protective equipment before storing or re-using.

Hygiene measures: Keep away from food, drink and animal feeding stuffs. When using do not eat, drink or
smoke. Wash hands prior to eating, drinking or smoking. Avoid contact with clothing. Avoid eye contact and
repeated or prolonged skin contact. Avoid inhalation of vapour, mist or aerosols. Ensure that eyewash stations
and safety showers are close to the workstation location.
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9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Viscous Liquid

Colour: Black
Odour: Strong Solvent Odour

Specific Gravity: 0.90 – 1.00

Vapour Pressure (20 °C): 4.0 kPa @ 20°C
Flash Point (°C): -15 (Closed Cup)
Flammability Limits (%): 1 (LEL) by volume - 7 (UEL) by volume
Autoignition Temperature (°C): 354
Boiling Point/Range (°C): 95 – 175
Viscosity: <1,000cps
Evaporation Rate (n-Butyl acetate=1): 0.20 – 2.70

(Typical values only - consult specification sheet)

N Av = Not available, N App = Not applicable

10. STABILITY AND REACTIVITY

Chemical stability: This material is thermally stable when stored and used as directed.

Conditions to avoid: Elevated temperatures and sources of ignition.

Incompatible materials: Oxidising agents.

Hazardous decomposition products: Oxides of carbon and nitrogen, smoke and other toxic fumes.

Hazardous reactions: No known hazardous reactions.

11. TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the
product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Acute Effects

Inhalation: Material may be an irritant to mucous membranes and respiratory tract.

Skin contact: Contact with skin may result in irritation.

Ingestion: Swallowing can result in nausea, vomiting and irritation of the gastrointestinal tract. May cause lung
damage if swallowed. Small amounts of liquid aspirated into the respiratory system during ingestion or vomiting
may cause bronchopneumonia or pulmonary oedema.

Eye contact: May be an eye irritant.

Acute toxicity

Inhalation: This material has been classified as not hazardous for acute inhalation exposure. Acute toxicity
estimate (based on ingredients): LC50 > 20.0 mg/L for vapours or LC50 > 5.0 mg/L for dust and mist.

Skin contact: This material has been classified as not hazardous for acute dermal exposure. Acute toxicity
estimate (based on ingredients): LD50 > 2,000 mg/Kg bw

Ingestion: This material has been classified as not hazardous for acute ingestion exposure. Acute toxicity
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estimate (based on ingredients): LD50 > 2,000 mg/Kg bw

Corrosion/Irritancy: Eye: this material has been classified as not corrosive or irritating to eyes. Skin: this
material has been classified as not corrosive or irritating to skin.

Sensitisation: Inhalation: this material has been classified as not a respiratory sensitiser. Skin: this material has
been classified as not a skin sensitiser.

Aspiration hazard: This material has been classified as Aspiration Hazard - Category 1

Specific target organ toxicity (single exposure): This material has been classified as not a specific hazard to
target organs by a single exposure.

Chronic Toxicity

Mutagenicity: This material has been classified as not a mutagen.

Carcinogenicity: This material has been classified as not a carcinogen.

Reproductive toxicity (including via lactation): This material has been classified as not a reproductive
toxicant.

Specific target organ toxicity (repeat exposure): This material has been classified as not a specific hazard to
target organs by repeat exposure.

12. ECOLOGICAL INFORMATION

Avoid contaminating waterways.

Acute aquatic hazard: This material has been classified as not hazardous for acute aquatic exposure. Acute
toxicity estimate (based on ingredients): > 100 mg/L

Long-term aquatic hazard: This material has been classified as not hazardous for chronic aquatic exposure.
Non-rapidly or rapidly degradable substance for which there are adequate chronic toxicity data available OR in
the absence of chronic toxicity data, Acute toxicity estimate (based on ingredients): >100 mg/L, where the
substance is not rapidly degradable and/or BCF < 500 and/or log Kow < 4.

Ecotoxicity: No information available.

Persistence and degradability: No information available.

Bioaccumulative potential: No information available.

Mobility: No information available.

13. DISPOSAL CONSIDERATIONS

Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal
protection equipment is used, see "Section 8. Exposure Controls and Personal Protection" of this SDS.

If possible material and its container should be recycled. If material or container cannot be recycled, dispose in
accordance with local, regional, national and international Regulations.

14. TRANSPORT INFORMATION

ROAD AND RAIL TRANSPORT

Classified as Dangerous Goods by the criteria of the “Australian Code for the Transport of Dangerous Goods by
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Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".

UN No: 1263
Dangerous Goods Class: 3
Packing Group: II
Hazchem Code: •3YE
Emergency Response Guide No: 14
Limited Quantities 5L

Proper Shipping Name: PAINT

Segregation Dangerous Goods: Not to be loaded with explosives (Class 1), flammable gases (Class 2.1), if
both are in bulk, toxic gases (Class 2.3), spontaneously combustible substances (Class 4.2), oxidising agents
(Class 5.1), organic peroxides (Class 5.2), toxic substances (Class 6.1), infectious substances (Class 6.2) or
radioactive substances (Class 7). Exemptions may apply.

This product is a "Manufactured Product" as defined in the ADG Code.

MARINE TRANSPORT
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code)
for transport by sea.

UN No: 1263
Dangerous Goods Class: 3
Packing Group: II

Proper Shipping Name: PAINT

AIR TRANSPORT
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous
Goods Regulations for transport by air.

UN No: 1263
Dangerous Goods Class: 3
Packing Group: II

Proper Shipping Name: PAINT

15. REGULATORY INFORMATION

This material is not subject to the following international agreements:

Montreal Protocol (Ozone depleting substances)
The Stockholm Convention (Persistent Organic Pollutants)
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The Rotterdam Convention (Prior Informed Consent)
International Convention for the Prevention of Pollution from Ships (MARPOL)

This material is subject to the following international agreements:

Basel Convention (Hazardous Waste)
• Wastes from production, formulation and use of inks, dyes, pigments, paints, lacquers, varnish

This material/constituent(s) is covered by the following requirements:

The Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) established under the Therapeutic
Goods Act (Commonwealth): S6. Poison.

AICIS Status: All components of this product are listed on or exempt from the Australian Inventory of Industrial
Chemicals (AIIC).

NZ EPA Status: All components of this product are listed on or exempt from the New Zealand Inventory of
Chemical (NZIoC).

HSNO Approval Code: HSR002662

16. OTHER INFORMATION

Reasons for issue: Revised

Format change

This information was prepared in good faith from the best information available at the time of issue. It is based on
the present level of research and to this extent we believe it is accurate. However, no guarantee of accuracy is
made or implied and since conditions of use are beyond our control, all information relevant to usage is offered
without warranty. The manufacturer will not be held responsible for any unauthorised use of this information or for
any modified or altered versions.

If you are an employer it is your duty to tell your employees, and any others that may be affected, of any hazards
described in this sheet and of any precautions that should be taken.

Safety Data Sheets are updated frequently. Please ensure you have a current copy.

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