TSR1
TSR1
SEMINAR REPORT
ON
NANOMATERIALS
Submitted to the Jawaharlal Nehru Technological University Hyderabad in
Bachelor of Technology in
Submitted By
DASARI NITHIN
21R91A0556
Under the Guidance
Of
A.PAVANI
(Assistant Professor)
i
TEEGALA KRISHNA REDDY ENGINEERING COLLEGE
(Sponsored by TKR Educational Society)
Approved by AICTE, Affiliated by JNTUH, Accredited by NBA & NAAC-A)
Medbowli, Meerpet, Saroornagar, Hyderabad – 500 097.
Phone: 040-24092838 Fax: +91-040-24092555
E-mail: [email protected] Website: www.tkrec.ac.in
Department of Computer Science & Engineering
College code: R9
CERTIFICATE
submitted by D.Nithin, bearing Roll no. 21R91A0556 in partial fulfillment for the
The results of investigation enclosed in this report have been verified and found
satisfactory. The result embodied in this thesis have not been submitted to any other
Principal
Dr. K. Venkata Murali Mohan
Professor
ii
TEEGALA KRISHNA REDDY ENGINEERING COLLEGE
(Sponsored by TKR Educational Society)
Approved by AICTE, Affiliated by JNTUH, Accredited by NBA & NAAC-A)
Medbowli, Meerpet, Saroornagar, Hyderabad – 500 097.
Phone: 040-24092838 Fax: +91-040-24092555
E-mail: [email protected] Website: www.tkrec.ac.in
Department of Computer Science & Engineering
College code: R9
DECLARATION
I hereby declare that the work which is being presented in the Seminar Report, entitled
College, is submitted in partial fulfillment of the requirements for the award of the
Engineering College and the results embodied in this project have not been reproduced or
copied from any source. The results embodied in this seminar report have not been
submitted to any other University or Institute for the award of any other degree.
Submitted by
D.Nithin (21R91A0556)
iii
TEEGALA KRISHNA REDDY ENGINEERING COLLEGE
(Sponsored by TKR Educational Society)
Approved by AICTE, Affiliated by JNTUH, Accredited by NBA & NAAC-A)
Medbowli, Meerpet, Saroornagar, Hyderabad – 500 097.
Phone: 040-24092838 Fax: +91-040-24092555
E-mail: [email protected] Website: www.tkrec.ac.in
Department of Computer Science & Engineering
College code: R9
ACKNOWLEDGEMENT
We wish to express our deep sense of gratitude to our Seminar Guide A.Pavani ,
Department of Computer Science, Teegala Krishna Reddy Engineering College, Meerpet, for
guiding from the inception till the completion of the seminar. We sincerely acknowledge for
giving valuable guidance, support for literature survey, critical reviews and comments for
giving the final shape of the seminar report. Words are inadequate in offering our thanks to Dr.
Computer Science Engineering, Teegala Krishna Reddy Engineering College, Meerpet for
consistent encouragement and support for shaping our Seminar in the presentable form. Finally,
we would like to express our heartfelt thanks to all supporting staff members and friends who
have been a constant source of encouragement for successful completion of the Seminar.
by.
D.Nithin(21R91A0556)
iv
ABSTRACT
Over recent years, extensive research on nanomaterials has fueled rapid advancements
in nanotechnology, impacting industries such as electronics, energy, medicine, cosmetics,
food engineering, telecommunications, and agriculture. Nanomaterials are at the core of
this technological progress. Their tiny scale endows them with unique properties—optical,
magnetic, electrical, and physical—that contribute to their reactivity, strength, surface
area, sensitivity, and stability. Remarkably, as materials transition from bulk form to
nanoscale, they undergo phase changes; for instance, non-magnetic materials can exhibit
magnetic properties at this scale. This transformation positions nanoscale matter as a
distinct state alongside solid, liquid, gas, and plasma. The traits of nanomaterials are
primarily influenced by their shapes and dimensions. This paper provides a comprehensive
overview of nanomaterials, discussing their types, key attributes, synthesis methods, and
applications across various domains.
v
CONTENTS
1. INTRODUCTION 01
2. LITERATURE SURVEY 02
3. ARCHITECTURE 03-08
4. WORKING 09-11
5. ADVANTAGES 12-13
6. DISADVANTAGES 14-15
7. APPLICATIONS 15-19
8. FUTURE ENHANCEMENTS 20
9. CONCLUSION 21
10. REFERENCES 22
vi
TABLE OF FIGURES
vii
1. INTRODUCTION
The term "nano" originates from the Greek word "nanos," which means "dwarf," referring to
a very small object or person of diminutive height. In the International System of Units (SI),
"nano" is a metric prefix indicating a factor of one billionth. For example, a nanometer is one
billionth of a meter, while a nanoliter is one billionth of a liter. This prefix has become widely
applicable in recent decades, permeating various scientific disciplines as the label "nano" is
now frequently associated with advancements in modern science.
Nanomaterials are also recognized for their potential contributions to global sustainability
efforts, as green technologies based on nanomaterials may prove more efficient than those
relying on conventional bulk materials. Additionally, nanomaterials have become invaluable
in healthcare, aiding in the diagnosis and management of epidemics such as COVID-19, and
they are even instrumental in current efforts to control diseases like monkeypox.
In the future, nanomaterials, nanoscience, and nanotechnology are expected to lead global
advancements, underscoring the importance of broad public and professional understanding of
these fields. While the past two decades have seen extensive research on nanomaterials, most
recent studies focus on the classification, preparation methods, properties, and specific
applications of each type. However, few studies integrate a comprehensive view of all types,
classifications, and preparation techniques suitable for various fields. Addressing this gap, this
paper provides an in-depth examination of the classification, preparation methods, properties,
and potential uses of nanomaterials across multiple disciplines.
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2. LITERATURE REVIEW
Significant studies have explored key findings, theories, and methodologies related to
nanomaterials. This includes major advancements in synthesis techniques,
characterization methods, and a wide range of applications across fields like electronics,
medicine, and environmental science. Core concepts, such as the unique properties of
nanomaterials due to their small size and high surface area, are highlighted, along with
essential techniques like sol-gel processing, chemical vapor deposition, and
electrospinning.
The exploration of nanomaterials dates back to early work on colloidal gold and other
nanosized particles, which laid the groundwork for understanding nanoscale phenomena.
Richard Feynman's famous 1959 lecture, "There’s Plenty of Room at the Bottom," is often
credited with sparking interest in nanotechnology, paving the way for more advanced
studies and applications in the field.
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3. ARCHITECTURE
3
3.1.1. Classification by Origin:
▪ Nanomaterials can also be grouped based on their structural makeup into organic,
inorganic, carbon-based, and composite categories.
▪ Organic Nanomaterials are derived from organic compounds and include liposomes,
micelles, and dendrimers, which are biodegradable and commonly used in drug delivery
due to their sensitivity to stimuli like heat and radiation.
▪ Inorganic Nanomaterials lack carbon and include metal-based (e.g., silver, gold) and
metal oxide nanoparticles (e.g., titanium oxide, zinc oxide) that are valued for their
unique optical, catalytic, and antibacterial properties.
▪ Carbon-Based Nanomaterials are made of carbon and include fullerenes, carbon
nanotubes, graphene, and carbon black. These materials are widely used for
reinforcement due to their strength and thermal conductivity.
▪ Composite Nanomaterials combine nanoparticles with other materials for enhanced
properties and are used in fields such as automotive manufacturing and packaging.
4
Fig 3.1.2 : Classification of nanomaterials according to dimension:
A, zero-dimensional; B, one-dimensional; C, two-dimensional; D,three-dimensional.
3.1.3.Classification by Dimensions:
The density of states (DOS) describes the distribution of electronic states and varies
according to dimensional classification:
▪ 3D Nanomaterials (bulk) exhibit a DOS that is proportional to the square root of energy,
providing numerous continuous states.
▪ 2D Nanomaterials (quantum wells) have a DOS that remains constant with energy.
▪ 1D Nanomaterials (quantum wires) have a DOS inversely proportional to the square
root of energy, leading to discrete energy bands.
5
▪ 0D Nanomaterials (quantum dots) confine electrons in all dimensions, resulting in
discrete energy levels where states are available only at specific energies.
The diverse classifications of nanomaterials emphasize their versatility and the tailored
properties that different types of nanostructures bring to scientific and industrial applications.
Each classification aspect—from origin and structure to dimensional confinement—sheds light
on the suitability of nanomaterials for advanced functions in medicine, electronics,
environmental remediation, and material science.
6
3.2.3. Hierarchical and Multi-Shell Nanostructures:
These complex structures feature multiple layers, which boost catalytic activity and ion
transport, making them suitable for energy storage and drug delivery with sequenced release.
Example: Multi-shell structures in lithium-ion batteries improve both charge capacity and
stability.
7
3.3.1. Top-Down Methods:
▪ The top-Down approach involves breaking down bulk materials into nanoscale
particles.
▪ Mechanical Milling: Widely used for oxide and carbide-strengthened alloys and
composite materials.
▪ Nanolithography: Uses light sensitive material to etch precise nanostructures. Though
effective, it requires costly equipment.
▪ Laser Ablation: A laser beam strikes a target, vaporizing atoms that are solvated to form
nanoparticles in a solution.
▪ Sputtering: Deposits thin layers of nanoparticles on a substrate, followed by annealing
for structure.
▪ Thermal Decomposition: Uses heat to break down compounds into nanoparticles
through an endothermic reaction.
▪ Arc Discharge: Generates carbon-based nanomaterials, such as fullerenes and carbon
nanotubes, using an electric arc.
▪ Sol-Gel Method: Uses metal oxide or chloride precursors to produce nanoparticle films.
▪ Spinning: Employs a rotating disc reactor to create nanoparticles under controlled
conditions.
▪ Chemical Vapor Deposition (CVD): Deposits thin films through a reaction between
gaseous reactants on heated substrates.
▪ Pyrolysis: Efficient for largescale nanoparticle production due to its high yield and cost-
effectiveness.
▪ Solvothermal/Hydrothermal: Produces various nanostructures in closed systems, ideal
for forming specific geometries like nanowires and sheets.
▪ Templating Methods: Uses soft or hard templates to create nanoporous materials,
commonly with surfactants or block copolymers.
▪ Reverse Micelle: Forms nanoparticles within a water-in-oil emulsion with hydrophilic
cores.
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4. WORKING
The Working of Nanomaterials section explains how nanomaterials function and exhibit
their unique properties, enabling a range of applications.
When materials are scaled down to the nanoscale, they exhibit distinct behaviors due
to changes in physical principles.
▪ Quantum Effects: At nanoscale dimensions, electrons are confined to a very small
space, leading to quantum confinement effects. This phenomenon alters the optical
and electronic properties of materials, making them suitable for use in quantum
dots, LEDs, and semiconductors.
▪ Increased Surface Area: Nanoparticles have a high surface-to-volume ratio, which
greatly enhances their reactivity. This makes them ideal for applications that require
increased reactivity, such as catalysis (accelerating chemical reactions) and sensor
applications (detecting trace amounts of substances).
At the nanoscale, surface interactions play a crucial role in how nanomaterials interact
with their environment.
▪ Adsorption and Reactivity: Nanomaterials have a high surface energy, which allows
them to easily bond with other molecules. This property is useful in drug delivery,
where nanocarriers can transport drugs to specific sites, and in environmental cleanup,
where nanoparticles adsorb contaminants.
Nanomaterials often exhibit unique thermal and optical properties that differ significantly
from their bulk forms.
▪ Heat Resistance and Conductivity: Some nanomaterials are engineered for improved
heat resistance and conductivity. This makes them ideal for thermal management in
electronic devices, where heat dissipation is crucial.
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Fig 4.3: Cooling system using nanoparticles
▪ Plasmonic Effects: Metal nanoparticles, such as gold and silver, exhibit surface
plasmon resonance, which is the oscillation of electrons on their surface when exposed
to light. This effect enhances optical properties, making them valuable in sensors and
imaging applications.
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5. ADVANTAGES
▪ Targeted Drug Delivery: Nanotechnology allows for the design of drug delivery
systems that target specific cells or tissues, increasing treatment effectiveness and
reducing side effects.
▪ Diagnostic Tools: Nanomaterials are used to create highly sensitive sensors and
imaging agents, enhancing early disease detection and monitoring.
▪ Tissue Engineering: Nanomaterials contribute to the development of biomimetic
scaffolds that support tissue regeneration and healing.
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5.4. Electronics and Computing:
▪ Stain and Water Resistance: Nano coatings are used to make fabrics water- and stain-
resistant, enhancing the durability of clothing and other textiles.
▪ Antimicrobial Properties: Nano-silver particles are used in products to prevent
bacterial growth and increase hygiene.
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6. DISADVANTAGES
▪ Toxicity Concerns: Nanoparticles can penetrate cells and tissues, potentially causing
harm to biological systems. Their small size allows them to cross biological barriers
and interact with cellular processes in unpredictable ways.
▪ Respiratory Issues: Inhalation of certain nanomaterials, such as carbon nanotubes and
nanofibers, can lead to respiratory problems and potential long-term damage.
▪ Bioaccumulation: Nanoparticles may accumulate in the body over time, leading to
chronic exposure and associated health risks.
14
▪ Ethical Concerns: The implications of using nanomaterials in various sectors,
including medicine and surveillance, raise ethical questions regarding their safe and
responsible application.
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7. APPLICATIONS
Nanomaterials have a wide range of applications due to their unique properties, such as high
surface area, quantum effects, and enhanced mechanical, electrical, and optical properties. Here
are some major applications and related technologies:
• Drug Delivery: Nanoparticles can deliver drugs directly to targeted cells, improving
the efficiency and reducing side effects of treatments.
• Diagnostics: Quantum dots and nanoparticle-based biosensors enhance imaging and
early diagnosis of diseases.
• Antimicrobial Coatings: Silver nanoparticles are used for their antimicrobial
properties in medical equipment and wound dressings.
• Cancer Treatment: Nanotechnology enables targeted therapies, such as using gold
nanoparticles to destroy cancer cells with minimal damage to healthy tissue.
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7.4. Environment:
• Water Purification: Nanomaterials like carbon nanotubes and nanofibers are used for
filtering contaminants, improving water purification processes.
• Air Purification: Photocatalytic nanoparticles, such as titanium dioxide (TiO2), help
break down pollutants in the air.
• Waste Treatment: Nanotechnology assists in the decomposition of hazardous waste
and remediation of contaminated environments.
• Food Packaging: Nanomaterials help create packaging that prevents the growth of
bacteria and extends the shelf life of food.
• Crop Protection: Nano pesticides and nano-fertilizers ensure better absorption and
targeted action, reducing environmental impact.
• Sensors for Agriculture: Nano sensors help monitor soil conditions and crop health
for optimized farming.
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7.8. Construction and Infrastructure:
• Enhanced Cement and Concrete: The use of nanomaterials like nano-silica improves
the strength and durability of construction materials.
• Thermal Insulation: Nanostructured materials are used in coatings and paints to
provide better insulation and energy efficiency in buildings.
• Protective Gear: Nanomaterials enhance the strength and weight of body armor and
helmets.
• Stealth Technology: Nano coatings reduce radar cross-sections, aiding in stealth
capabilities for military equipment.
• Sensors: Nano sensors are used for detecting chemical and biological threats.
• Skincare Products: Nanoparticles like titanium dioxide and zinc oxide are commonly
used in sunscreens to provide better UV protection without leaving a white residue.
• Anti-Aging: Nano-encapsulation allows for deeper penetration of active ingredients in
anti-aging creams and treatments.
Super capacitor Very fast charger or discharger, high power storage Lithium, sodium, potassium
Imaging Ability to penetrate cells, good analytical signals Ag and Cu bimetallic nanoparticles
Cancer diagnosis Biomedical Imaging Used for Cancer and tumor Gold and iron-based nanoparticles
detection
Drug delivery and cancer The aim of drug delivery includes precise targeting and Au nanoparticle, silicon nanoparticle,
therapy therapeutic efficacy carbon nanotube, nano graphene
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COVID-19 diagnosis and rSARS-CoV-2 tagging and development of COVID-19 Lipid nanoparticles Au nanoparticle
prevention mRNA vaccines
Against monkey pox Chelating the vires circulating in the blood stream. Iron oxide nanoparticle Ag nano
Block vires host cell binding and penetration particle
Food industry Despite toxicological concerns, detect volatile organic TiO2 and Ag
compounds
Potential vaccine adjuvant Used for the development of robust immune response. Aluminum hydro-oxide, gold
nanoparticle
Anti -bacterial activity Used in treatment of disease caused by bacteria. Gold, silver, copper, titanium, iron
nanoparticle
High sensitivity sensor For detecting varies parameters like electrical resistivity, ZnSe, CdS, ZnS, CdTe
magnetic permeability, thermal conductivity and
capacitance
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8. FUTURE ENHANCEMENT
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9. CONCLUSION
The review classifies nanomaterials into five primary groups from different
perspectives. Based on origin, they are categorized as natural or synthetic nanomaterials.
Structural configuration divides them into organic, inorganic, carbon-based, and composite
materials. Dimensional classification includes 0D, 1D, 2D, and 3D nanomaterials. Their
pore size can classify them into microporous, mesoporous, and macroporous materials.
Additionally, nanomaterials are assessed for potential toxicity, with types such as fiber-
like nanoparticles, persistent granular nanoparticles, and CMAR nanoparticles.
Various synthesis methods for nanomaterials are critically examined. Synthesis is broadly
divided into top-down and bottom-up approaches. The top-down methods, which are
physical, include techniques such as lithography, mechanical or ball milling, laser ablation,
sputtering, arc discharge, and thermal decomposition. In contrast, the bottom-up methods,
which are chemical in nature, include processes like chemical vapor deposition (CVD),
sol-gel processing, spinning, and pyrolysis. Biological synthesis is also part of the bottom-
up category, involving microorganisms like bacteria, algae, and fungi, as well as biological
templates and plant parts.
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10. REFERENCES
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