MOCK TEST : 2023-24 XII-MT-10-JEE(Main)

PART B — CHEMISTRY

31. Ans. (2)

32. Ans. (3)
(ii) B2O3 is acidic (iv) AlCl3 in acidic aq. soln forms octahedral [Al(H2O)6]3+ ion
33. Ans. (4)
34. Ans. (2)
They retain metallic conductivity.
35. Ans. (4)

N sp3 hybridised
H
(I)

N sp3, basicity decreases due to –I effect of oxygen.

H
(III)

N sp2
(II)

lone pair on nitrogen is not available for donation, delocalised into the ring to gain aromaticity..
N
H
(IV)
I > III > II > IV
36. Ans. (1)
At boiling point the liquid and the pure gas coexist at equilibrium at 1 atm. G = 0
H and S do not change with temperature
H = H° = 30.91 kJ
S = S° = 93.2 J/K = 0.0932 kJ/K
Now, G = H – TS = 0

T  H  30.91  331.6K
S 0.0932
37 Ans. (2)
Anti-Markownikoff addition reaction
BD3/THF
D
H2O2/OH
OH
Hydroboration-oxidation

Pathfinder Educational Centre LLP, 47 Kalidas Patitundi Lane, Kalighat, Kolkata-26  033-2455 1840 / 2454 4817 / 4668 1
XII-MT-10-JEE(Main) MOCK TEST : 2023-24

38. Ans. (3)

2SO2(g) + O2 (g)  2SO3(g)
t=0 5 mole 5 mole
at eqm. 5 – 2x 5–x 2x
60  5
Given, 2x 
100
x = 1.5

pO2  XO2 .Ptotal  3.5  1  0.41 atm

8.5
39. Ans. (4)
O – + O
OMgBr OH
Br MgBr C C
+
NBS Mg O=C=O H /H2O
ether

40. Ans. (3)

If 2s – 2p mixing is not operative, then the energy sequence of molecular orbitals in all the molecules will be

1s  1s  2s  2s  2px  2py  2pz  2py  2pz  2px
C2 is paramagnetic.
41. Ans. (4)
Addition reaction will be faster in H2C(Cl)CHO due to –I effect of Cl atom.
42. Ans. (2)
After mixing HNO3 and H2O, intermolecular force of attraction increases and hence boiling point increases.
43 Ans. (1)
3d 4s 4p
3 0
sp hybridised orbitals of Ni in [Ni(CO)4]

sp 3

2+ 2–
dsp2 hybridised orbitals of Ni in [Ni(CN)4]

dsp 2
44. Ans. (4)

Zn2  2e 


 Zn
 n=2
According to Nernst equation
0.059  Zn
0
Ereduction  Ereduction  log10  
2  Zn2 
 
Now, [Zn] = 1
0.059
0
 Ered  Ered  log10  Zn2 
2  
This equation is satisfying y = c + mx
Correct answer (4) since E0zn2/Zn   0.76 V

2 Pathfinder Educational Centre LLP, 47 Kalidas Patitundi Lane, Kalighat, Kolkata-26  033-2455 1840 / 2454 4817 / 4668
 MOCK TEST : 2023-24 XII-MT-10-JEE(Main)

45. Ans. (3)

A + B  2C + D

d A  d B  1 d C  d D 
       
dt dt 2 dt dt
Incorrect answer (3)

46. Ans. (3)


K2Cr2O7 + 6 H2SO4 + 4 NaCl  2KHSO4 + 4NaHSO4 + 2CrO2Cl2 + 3H2O

CrO2Cl2 + 4NaOH  Na2CrO 4  2 NaCl  2H2O

Compound

Correct answer (3)

47. Ans. (2)

   obs   10º   100   50%

% of excess (–) enantiomer  =
  D   20º 

So, 50% of the mixture contains (–) enantiomer and 50% is the racemate [i.e. 25% (+) form and 25% (–) form]

Total percentage of (–) form = (50% + 25%) = 75%

Total percentage of (+) form = 25%

Correct answer (2)

48. Ans. (4)

W total = W AB + W BC + W CD + W DA

 1  2
  2R  300ln    2  VC  VB     2R400ln    1 VA  VD  
 2  1

2R  300 2R  300
VA   600R VB   300R
1 2

2R  400 2R  400
VC   400R VD   800R
2 1
 W total = 2R × 300 ln 2 – 2R × 400 ln2 – 2 (100 R) + 1 (200 R)
= – 100 × 2R ln 2
= – 200 × 0.693 R
= – 138.6 R
49. Ans. (2)

Cl
OH
CHCl3  C (dichloro carbene)
Cl

Pathfinder Educational Centre LLP, 47 Kalidas Patitundi Lane, Kalighat, Kolkata-26  033-2455 1840 / 2454 4817 / 4668 3
XII-MT-10-JEE(Main) MOCK TEST : 2023-24

50. Ans. (1)

H H
Br
alc.KOH
 +
Me Me Me
minor major

51. Ans. [4]

Br2/CCl4 Br NaNH2/
Br 2eqv

(A) (B)

HgSO4 /H2 SO4

D O NaOD (excess) O
D2O
CD3 CH3
(D) (C)

(4 Deutonium atoms)

52. Ans. [6]

(A), (B), (C), (D), (J), (N) can given +ve iodoform test.
53. Ans. [5]

CH3 CH3

54. Ans. [6]

F
F F
Xe Xe Xe
F F O O
F O
3lp 2lp 1lp

55. Ans. [3]

O O OH OH OH H
NaBH4
H2O +
H H H OH
(Meso) (d + l)

56. Ans. [3]

(a) Zn–Hg / HCl (d) N2H4 / OH– (e) H2C—CH2 , H2 / Ni
| |
SH SH

4 Pathfinder Educational Centre LLP, 47 Kalidas Patitundi Lane, Kalighat, Kolkata-26  033-2455 1840 / 2454 4817 / 4668
 MOCK TEST : 2023-24 XII-MT-10-JEE(Main)

57. Ans. [6]

w 1000 
Tb  Tb0  K b  A  
 MA wB 

 373.104  373   0.52 

X 1000 

 60 500 

X 
 0.104  0.52   2
 60 

0.104  60
 X 6
0.52  2

 Correct answer = 6
58. Ans. [8]

Precipitation Precipitation Precipitation

with NH4OH with H2S in with H2S in
in presence of presence of presence of
NH4Cl HCl NH4OH
Fe3 Bi3 Mn2
Cr 3 Sn4 Ni2
Al3 Y2 Co2
X3 Z3
[X + Y + Z] = (3 + 2 + 3) = 8
 Correct answer = 8
59. Ans. [5]
Tautomerism will not be shown by those compounds, which
(1) donot have -hydrogen
(2) forms very unstable enol-structures
 It will be shown by

O O

C6H5CH2CHO , ,O O , H3CCOC(CH3)2COOEt

 Correct answer = 5
60. Ans. [3]

Hofmann rearrangement reaction is strictly intramolecular no crossover experiment are sucessful and retention
of optical active centre was observed.

Pathfinder Educational Centre LLP, 47 Kalidas Patitundi Lane, Kalighat, Kolkata-26  033-2455 1840 / 2454 4817 / 4668 5