MasterBrace ADH 2200 PART B - SDS

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MasterBrace ADH 2200 PART B

Product code : 000000000051993784

Manufacturer or supplier's details


Company : Master Builders Solutions Saudi Arabia
for Manufacturing LLC.

Address : Dammam 2nd Industrial Area


AL Khobar 31952

Telephone : +966966138121140

Emergency telephone : ChemTel: +1-813-248-0585

Telefax : +966966138121822

Recommended use of the chemical and restrictions on use


Recommended use : Product for construction chemicals

2. HAZARDS IDENTIFICATION

GHS Classification
Skin corrosion/irritation : Category 2

Serious eye damage/eye irri- : Category 1


tation

Skin sensitization : Category 1

Specific target organ toxicity - : Category 1 (Lung)


repeated exposure
(Inhalation)

Hazardous to the aquatic : Category 3


environment - chronic hazard

GHS label elements


Hazard pictograms :

Signal Word : Danger

Hazard Statements : H318 Causes serious eye damage.


H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H372 Causes damage to organs (Lung) through prolonged or
repeated exposure if inhaled.

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements :
Prevention:
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
P260 Do not breathe dusts or mists.
P273 Avoid release to the environment.
P270 Do not eat, drink or smoke when using this product.
P264 Wash face, hands and any exposed skin thoroughly after
handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
P310 Immediately call a POISON CENTER or doctor/ physi-
cian.
Disposal:
P501 Dispose of contents/container to appropriate hazardous
waste collection point.

Other hazards which do not result in classification


If applicable information is provided in this section on other hazards which do not result in classi-
fication but which may contribute to the overall hazards of the substance or mixture.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Preparation based on:


polyamidoamine
silicates
Components
Chemical name CAS-No. Concentration (%
w/w)
Quartz (SiO2) 14808-60-7 >= 1 - < 75
Fatty acids, tall-oil, reaction products with tetra- 68953-36-6 >= 15 - < 20
ethylenepentamine
3,6,9-triazaundecamethylene-1,11-diamine 112-57-2 >= 3 - < 5
Hydrocarbons, C9-unsatd., polymd. 71302-83-5 >= 3 - < 5

4. FIRST AID MEASURES

General advice : First aid personnel should pay attention to their own safety.
Immediately remove contaminated clothing.

If inhaled : Keep patient calm, remove to fresh air.


If symptoms persist, seek medical advice.
In case of skin contact : After contact with skin, wash immediately with plenty of water

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

and soap.
Under no circumstances should organic solvent be used.
If irritation develops, seek medical attention.
In case of eye contact : Wash affected eyes for at least 15 minutes under running
water with eyelids held open, consult an eye specialist.
If swallowed : Immediately rinse mouth and then drink 200-300 ml of water,
seek medical attention.
Do not induce vomiting unless told to by a poison control cen-
ter or doctor.
Most important symptoms : Causes skin irritation.
and effects, both acute and Causes serious eye damage.
delayed May cause an allergic skin reaction.
Causes damage to organs through prolonged or repeated
exposure if inhaled.
Notes to physician : Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam


Water spray
Dry powder
Carbon dioxide (CO2)
Unsuitable extinguishing : water jet
media
Hazardous combustion prod- : harmful vapours
ucts carbon oxides
nitrogen oxides
fumes/smoke
carbon black

Specific extinguishing meth- : The degree of risk is governed by the burning substance and
ods the fire conditions.
If exposed to fire, keep containers cool by spraying with water.
Collect contaminated extinguishing water separately, do not
allow to reach sewage or effluent systems.
Contaminated extinguishing water must be disposed of in
accordance with official regulations.
Special protective equipment : Wear a self-contained breathing apparatus.
for fire-fighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
tive equipment and emer- Wear eye/face protection.
gency procedures Use personal protective clothing.
Handle in accordance with good building materials hygiene
and safety practice.

Environmental precautions : Contain contaminated water/firefighting water.


Do not discharge into drains/surface waters/groundwater.

Methods and materials for : Pick up with suitable appliance and dispose of.
containment and cleaning up Dispose of absorbed material in accordance with regulations.

7. HANDLING AND STORAGE

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

Advice on protection against : The product is neither self-ignitable, nor an explosion hazard,
fire and explosion nor does it promote fires.

Advice on safe handling : Avoid inhalation of dusts/mists/vapours.


Avoid skin contact.
Ensure adequate ventilation.
No special measures necessary provided product is used
correctly.
Further information on stor- : Keep only in the original container in a cool, dry, well-
age conditions ventilated place away from ignition sources, heat or flame.
Protect from direct sunlight.

Packaging material : Suitable material: tinned carbon steel (Tinplate)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters


Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : Wear respiratory protection if ventilation is inadequate.
Combination filter for gases/vapours of organic, inorganic,
acid inorganic and alkaline compounds (e.g. EN 14387 Type
ABEK).
Hand protection

Remarks : impermeable gloves Synthetic rubber gloves Manufacturer's


directions for use should be observed because of great di-
versity of types.
Eye protection : Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Skin and body protection : Body protection must be chosen based on level of activity and
exposure.
Protective measures : Do not inhale dust/fumes/aerosols.
Avoid contact with the skin, eyes and clothing.
Avoid exposure - obtain special instructions before use.
Handle in accordance with good building materials hygiene
and safety practice.
Wearing of closed work clothing is recommended.
Hygiene measures : When using, do not eat, drink or smoke.
Hands and/or face should be washed before breaks and at the
end of the shift.
At the end of the shift the skin should be cleaned and skin-
care agents applied.
Gloves must be inspected regularly and prior to each use.
Replace if necessary (e.g. pinhole leaks).

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : pasty

Color : gray

Odor : amine-like

Odor Threshold : not determined

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

pH : neutral to slightly alkaline

Melting temperature : No data available

boiling temperature : No data available

Flash point : > 90 °C

Evaporation rate : The product is a non-volatile solid.

Flammability (solid, gas) : not determined

Self-ignition : not self-igniting

Lower explosion limit / Lower : dropped


flammability limit

Vapor pressure : No data available

Relative vapor density : The product is a non-volatile solid.

Solubility(ies)
Water solubility : of very low solubility

Partition coefficient: n- : not applicable for mixtures


octanol/water
Decomposition temperature : No decomposition if stored and handled as pre-
scribed/indicated.

Viscosity
Viscosity, dynamic : Not applicable

Explosive properties : Not explosive

Oxidizing properties : not fire-propagating

Self-heating substances : No data available

10. STABILITY AND REACTIVITY

Reactivity : No hazardous reactions if stored and handled as pre-


scribed/indicated.
Chemical stability : The product is stable if stored and handled as pre-
scribed/indicated.
Possibility of hazardous reac- : The product is stable if stored and handled as pre-
tions scribed/indicated.

Conditions to avoid : See SDS section 7 - Handling and storage.


Incompatible materials : Strong acids
Strong bases
Strong oxidizing agents

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

Strong reducing agents


Hazardous decomposition : No hazardous decomposition products if stored and handled
products as prescribed/indicated.

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization

Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Causes damage to organs (Lung) through prolonged or repeated exposure if inhaled.
Aspiration toxicity
Not classified based on available information.
Product:
No aspiration hazard expected.

Further information

Product:
Remarks : Health injuries are not known or expected under normal use.
The product has not been tested. The statements on toxicolo-
gy have been derived from the properties of the individual
components.

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:

Ecotoxicology Assessment
Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.

Persistence and degradability

Product:
Biodegradability : Remarks: Taking into consideration the properties of several
ingredients, the product is estimated not to be readily biode-
gradable according to OECD classification.

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: Discharge into the environment must be avoided.

Mobility in soil
No data available
Other adverse effects

Product:
Results of PBT and vPvB : Remarks: The product does not contain a substance fulfilling
assessment the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB
(very persistent/very bioaccumulative) criteria.

Ozone-Depletion Potential : Remarks: The product does not contain substances that are
listed in Regulation (EC) 1005/2009 on substances that de-
plete the ozone layer.

Additional ecological infor- : Do not discharge product into the environment without control.
mation The product has not been tested. The statements on ecotoxi-
cology have been derived from the properties of the individual
components.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Observe national and local legal requirements.
Residues should be disposed of in the same manner as the
substance/product.
Contaminated packaging : Contaminated packaging should be emptied as far as possi-
ble; then it can be passed on for recycling after being thor-
oughly cleaned.
Packs that cannot be cleaned should be disposed of in the
same manner as the contents.

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

14. TRANSPORT INFORMATION

International Regulations

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

16. OTHER INFORMATION

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No

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SAFETY DATA SHEET

MasterBrace ADH 2200 PART B

Version Revision Date: SDS Number: Date of last issue: 02.02.2021


1.1 16.07.2021 000000314223 Date of first issue: 02.02.2021

1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - Unit-
ed Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials In-
formation System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

UN / EN

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