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    PH Jonathan Belakar

    Uploaded by

    lutfialchemie

    Copyright:

    © All Rights Reserved
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    PH Jonathan Belakar

    Uploaded by

    lutfialchemie
    3 views4 pages

    Copyright

    © © All Rights Reserved

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    DOCX, PDF, TXT or read online from Scribd

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    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    3 views4 pages

    PH Jonathan Belakar

    Uploaded by

    lutfialchemie

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 4

    1.

    Determine pH value :
    a. HNO3 0.01 M
    b. Ba(OH)2 0.02 M
    c. CH3COOH 0.1 M Ka = 10-5
    d. NH3 0.001 M , Kb = 10-5
    a. [H+] = M x a = 0.01 x 1 = 0.01 = 10-2 , pH = - log 10-2 = 2
    b. [OH-] = M x b = 0.02 x 2 = 0.04 = 4 x 10-2 , pOH = - log 4 x 10-2 = 2 – log 4, pH = 14 – (2 – log 4 )
    = 12 + log 4
    c. [H+] = √ Ka x M = √ 10−5 x 0.1 = √ 10−6 = 10-3 , pH = - log [H+] = - log 10-3 = 3
    d. [OH-] = √ K b x M = √ 10−5 x 0. 00 1 = √ 10−8 = 10-4 M , pOH = - log 10-4 = 4 , pH = 14-4 = 10

    2. 0.2 g of HCOOH ( Ar C = 12 , H =1 , O = 16 ) is dissolved in water until the volume of solution


    750 mL. detemine pH value of solution.( Ka HCOOH = 6 x 10-6)
    Answer :
    Mr HCOOH = ( 1 + 12 + 16 + 16 + 1 ) = 46
    mass 0.2
    Mol = = = 0.0435 mol
    Mr 46
    m ol 0.0435
    M= = = 0.0058 = 5.8 x 10-3 M
    Volume 0.75
    [H+] = √ Ka x M = √ 6 x 10−6 x 5.8 x 10−3 = 1.9 x 10-4
    pH = - log 1.9 x 10-4 = 4 – log 1.9

    3. 0.5 g of NH3 ( Ar N =14, H =1 ) is dissloved in water until the volume of solution 600 mL. if
    ionized degree (  ) = 0.01 . detrmine PH value of solution ?
    Answer :
    Mr = 14 + 3 = 17
    mass 0.5
    Mol = = Mol = = 0.03 mol
    Mr 17
    mol 0.03
    M= = = 0.05
    Volume 0.6
    [OH-] = M x  = 0.05 x 0.01 = 5 x 10-4 , pOH = - log 5 x 10-4 = 4 – log 5 , pH = 14 – ( 4 – log 5 ) =
    10 + log 5

    4. Determine acid, base , conjugate base and conjugate acid.


    a. NH3 + H2O → NH4+ + OH-
    Base acid CA CB
    b. HNO3 + NH3 → NO3 + NH4+
    -

    A B CB CA

    c. H2SO4 + NH3 → HSO4- + NH4+


    A B CB CA
    + -
    d. H2O + H2O → H3O + OH
    B A CA CB

    5. Complete reaction below


    a. 3HNO3 + Al(OH)3→ Al(NO3)3 + 3H2O
    b. H3PO4 + Fe(OH)3 → FePO4 +3 H2O
    c. 3H2SO4 + 2Al(OH)3 → Al2(SO4)3 +6 H2O
    d. 2H3PO4 + 3Ca(OH)2 → Ca3(PO4)2 + 6H2O
    e. H2CO3 + Ba(OH)2 → BaCO3 + 2H2O

    Rumus : HxSA + L (OH)y  Lx(SA)y + H2O

    6. 100 mL CH3COOH 0.1 M are mixed with 100 mL CH3COONa 0.1 M. If Ka CH3COOH = 10-5.
    Determine pH of mixture.
    Answer :
    Mmol CH3COOH = M x V = 0.1 x 100 = 10 mmol CH3COOH ( weak acid )
    Mmol CH3COONa = M x V = 0.1 x 100 = 10 mmol ( salt ) Buffer solution
    Because there are weak acid and salt

    weak acid 10 mmol


    [H+] = Ka = 10-5 = 10-5, pH = - log 10-5 = 5
    salt 10 mmol

    7. 100 mL NH4OH 0.1 M are mixed with 100 mL NH4Cl 0.1 M . if Kb NH4OH = 10-5. Determine pH
    of mixture ?
    Mmol NH4OH = M x v = 0.1 x 100 = 10 mmol ( Weak base )
    Mmol NH4Cl = M x v = 0.1 x 100 = 10 mmol ( salt ) buffer solution
    Because there are weak base and salt

    weak base 10
    [OH-] = Kb = 10-5 x = 10-5 , pOH = - log 10-5 = 5 , pH = 14 – 5 = 9
    salt 10

    8. 200 mL of HCOOH 0.1 M are mixed with 100 ml ( HCOO)3Al 0.1 M . if Ka HCOOH = 4 x 10-5.
    Determine pH of mixture ?
    mmol HCOOH = 0.1 x 200 = 20 mmol ( weak acid )
    mmol (HCOO)3Al = 0.1 x 100 = 10 mmol ( salt )

    weak acid 20
    [H+] = Ka = 4 x 10-5 x = 2.67 x 10-5, pH = - log 2.67 x 10-5 = 5 – log 2.67
    3 salt 3 x 10

    9. 300 mL of NH3 0.1 M are mixed with 100 mL ( NH4)3PO4 0.1 M. if Kb of NH3 = 10-5. Determine
    pH of mixture ?
    Answer :
    Mmol NH3 =0.1 x 300= 30 mmol ( weak base )
    Mmol (NH4)3PO4 = 0.1 x 100 = 10 mmol ( salt )

    weak base 30
    [OH-] = Kb = 10-5 x = 10-5, pOH = - log 10-5= 5 , pH = 14 – 5 = 9
    3 salt 3 x 10
    Hydolysis
    10. Determine pH :
    a. NaCl 0.1 M
    b. CH3COONa 0.1 M , ka CH3COOH = 10-5
    c. NH4Cl 0.1 M , Kb NH4Cl = 10-5

    It is hydrolysis because only salt

    a. pH = 7

    √ √
    −14
    Kw 10
    b. [OH-] = x M salt = −5
    x 0.1 = 10-5. pOH = - log 10-5 = 5, pH = 14 – 5 = 9
    Ka 10

    √ √
    −14
    Kw 10
    c. [H+] = x M salt = −5
    x 0.1 = 10-5 , pH = - log 10-5 = 5
    Kb 10

    11. 100 mL CH3COOH 0.1 M are mixed with 50 mL NaOH 0.1 M. if Ka of CH3COOH = 10-5 ,
    determine pH of mixture ?
    Answer :
    Mmol CH3COOH = 0.1 x 100 = 10 mmol ( weak acid )
    Mmol NaOH = 0.1 x 50 = 5 mmol ( strong base )

    CH3COOH + NaOH  CH3COONa + H2O


    I 10 mmol 5 mmol - -
    R 5 mmol 5 mmol 5 mml 5 mmol
    --------------------------------------------------------------------------------------------
    E 5 mmol - 5 mmol 5 mmol
    ( weak acid ) ( salt )
    Buffer solutin
    weak acids 5
    [H+] = Ka = 10-5 x = 10-5 , pH = - log 10-5 = 5
    salt 5

    12. 100 mL CH3COOH 0.1 M are mixed with 100 mL NaOH 0.1 M. if Ka of CH3COOH = 10-5 ,
    determine pH of mixture ?
    Answer :
    Mmol CH3COOH = 0.1 x 100 = 10 mmol ( weak acid )
    Mmol NaOH = 0.1 x 100 = 10 mmol ( strong base )

    CH3COOH + NaOH  CH3COONa + H2O


    I 10 mmol 10 mmol - -
    R 10 mmol 10 mmol 10 mml 10 mmol
    --------------------------------------------------------------------------------------------
    E - - 10 mmol 10 mmol
    ( salt )

    Hydrolysis
    mmol 10
    M salt = = = 0.05 = 5 x 10-2
    total volume 100+100
    √ √
    −14
    Kw 10
    [OH-] = x M salt = −5
    x 5 x 10−2 = 7.07 x 10-6
    Ka 10
    pOH = - log 7.07 x 10-6 = 6 – log 7.07
    pH = 14 – ( 6 – log 7.7 ) = 8 + log 7.7

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