Selfstudys Com File
Selfstudys Com File
Selfstudys Com File
Subject - Chemistry
Sample Question Paper - 7
General Instructions:
Section A
1. A halogen used in potential blood substitutes in surgery is: [1]
a) Fluorine b) Bromine
c) Iodine d) Chlorine
2. In disaccharides, if the reducing groups of monosaccharides i.e. aldehydic or ketonic groups are bonded, these [1]
are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
a) b)
c) d)
a) benzaldehyde b) benzophenone
a) 2, 3 – Hexanedione b) 2, 5 – Hexanedione
c) 2, 4 – Hexanedione d) 3 – Hexanone
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5. Consider the reaction [1]
N2 (g) + 3H2 (g) → 2N H3 (g)
d[N H3 ] −d[H2 ]
The equality relation between dt
and dt
is:
a) b)
d[N H3 ] d[H2 ] d[N H3 ] d[H2 ]
1 2
= − = −
dt 3 dt dt 3 dt
c) d[N H3 ]
= −
3 d[H2 ]
d) d[N H3 ]
= −
d[H2 ]
dt 2 dt dt dt
6. Match the items of column I with appropriate entries of column II. [1]
Column I Column II
a) (a) - (iv), (b) - (i), (c) - (ii), (d) - (iii). b) (a) - (i), (b) - (ii), (c) - (iii), (d) - (iv).
c) (a) - (iii), (b) - (ii), (c) - (iv), (d) - (i). d) (a) - (ii), (b) - (iv), (c) - (i), (d) - (iii).
7. Decomposition of benzene diozonium chloride by using Cu2Cl2/HCl to form chlorobenzene is: [1]
a) 1
2
b) 2
c) 1 d) 0
10. Methyl ketones are usually characterized by: [1]
c) 2,4-dihydroxytoluene d) m-cresol
12. In order to prepare a 1o amine from an alkyl halide with simultaneous addition of one CH2 group in the carbon [1]
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13. Assertion: Fructose can reduce Tollen’s reagent. [1]
Reason: Fructose is a ketone.
a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
Rate = k [N2O5]
Find out the order of reaction with respect to N2O5.
20. Calculate the volume of water which could be added to 20 ml of 0.65 m HCl to dilute the solution to 0.2 m? [2]
OR
What factors are responsible for deviations for Raoult's law?
21. How are the following conversions carried out? [2]
i. Ethanol to 1, 2-Ethanediol
ii. Phenol to Acetophenone
Section C
22. What do you understand by the term 'conductance'? What are its units? [3]
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23. For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate [3]
the average rate of reaction using units of time both in minutes and seconds.
24. Write the equation of the reaction of hydrogen iodide with: [3]
i. 1-propoxypropane
ii. Methoxybenzene
iii. Benzyl ethyl ether
OR
How would you account for the following:
i. Phenols are much more acidic than alcohols.
ii. The boiling point of ethers are much lower than those of the alcohols of comparable molar masses.
25. Write the products formed when (CH3)3 C – CHO reacts with the following reagents : [3]
ii. HCN
iii. Conc. NaOH
26. Depict the galvanic cell in which the reaction: [3]
+ 2+
Zn(s) + 2Ag (aq) → Z n (aq) + 2Ag(s)
28. Conductivity of saturated solution of BaSO4 at 315 K is 3.648 × 10-6 ohm-1 cm-1 and that of water is 1.25 × [3]
4
are 110 and 136.6 ohm-1 cm2 mol-1 respectively.
Calculate the solubility of BaSO4 in g/L.
Section D
29. Read the following text carefully and answer the questions that follow: [4]
The actinoids include the fourteen elements from Th to Lr. The actinoids are radioactive elements and the earlier
members have relatively long half-lives, the latter ones have half-life values ranging from a day to 3 minutes for
lawrencium. The latter members could be prepared only in nanogram quantities. Actinoids show a greater range
of oxidation states. The elements, in the first half of the series frequently exhibit higher oxidation states. The
actinoids resemble the lanthanoids in having more compounds in +3 state than in the +4 state. All the actinoids
are believed to have the electronic configuration of 7s2 and variable occupancy of the 5f and 6d subshells. The
magnetic properties of the actinoids are more complex than those of the lanthanoids. The variation in the
magnetic susceptibility of the actinoids with the number of unpaired 5f electrons is roughly parallel to the
corresponding results for the lanthanoid.
i. Actinoid contraction is greater from element to element than lanthanoid contraction. Why? (1)
ii. Actinoids show irregularities in their electronic configuration. Justify? (1)
iii. The actinoid metals are all silvery in appearance but display a variety of structures than lanthanoid give
reason. (2)
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OR
The magnetic properties of the actinoids are more complex than those of the lanthanoids. Why? (2)
30. Read the following text carefully and answer the questions that follow: [4]
The boiling point elevation and the freezing point depression of solutions have a number of practical
applications. Ethylene glycol (CH2OH⋅ CH2OH) is used in automobile radiators as an antifreeze because it
lowers the freezing point of the coolant. The same substance also helps to prevent the radiator coolant from
boiling away by elevating the boiling point. Ethylene glycol has a low vapour pressure. We can also use glycerol
as an antifreeze. In order for boiling point elevation to occur, the solute must be non-volatile, but no such
restriction applies to freezing point depression. For example, methanol (CH3OH), a fairly volatile liquid that
32. [NICl4]2- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why? [5]
OR
CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate but
does not react with BaCl2. Isomer ‘B’ gives a white precipitate with BaCl2 but does not react with AgNO3. Answer
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33. Giving an example for each describe the following reactions : [5]
i. Hofmann bromamide reaction.
ii. Gattermann reaction.
iii. Coupling reaction.
OR
Write the main products of the following reactions:
H NO2
ii.
iii.
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Solution
Section A
1. (a) Fluorine
Explanation: Certain fully fluorinated compounds are being considered as potential blood substitutes in surgery. So fluorine is
the element used in these blood substitutes.
2. (a)
Explanation:
This structure represents sucrose(diasaccharides) in which α -D glucose and β -D-fructose is attached to each other by C1-C2
glycosidic linkage. Since reducing groups of glucose and fructose are involved in glycosidic bond formation, this is considered
as a non-reducing sugar.
3.
(c) benzene
Explanation: Phenol is reduced to benzene when it is distilled with zinc dust or its vapour is passed over granules of zinc at
400oC.
4.
(c) 2, 4 – Hexanedione
Explanation: 2,4-hexanedione will have active methylene group.
The structure of 2,4-hexanedione is
-CH2 group present between the two carbonyl group is active methylene group, these hydrogens are highly acidic as their
conjugate base is highly stable.
5.
d[N H3 ] d[ H2 ]
(b) dt
= −
2
3 dt
6.
(d) (a) - (ii), (b) - (iv), (c) - (i), (d) - (iii).
Explanation: (a) - (ii), (b) - (iv), (c) - (i), (d) - (iii).
7.
(c) Sandmeyer's reaction
Explanation: C H N C l 6 5 2
+ −
+ C u2 C l2 /HC l → C6 H5 C l
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Mixing the solution of the freshly prepared diazonium salt with cuprous chloride or cuprous bromide results in the replacement
of the diazonium group by –Cl or –Br. This is called Sandmeyer's reaction.
8.
(c) Variable oxidation states
Explanation: Variable oxidation states is associated with their catalyst activity.
9. (a) 1
Explanation: X → Y
Rate(r) ∝ [X]n [Where n = order of reaction]
If the concentration X is increased by 4 times
X' = 4X
Then, Rate(r') ∝ [X']n
n
′ [4X]
r
= n
= 2
r [X]
Order of reaction = 1
10.
(b) Iodoform test
Explanation: C H C OR + I + N aOH → C HI + RC O O N a
3 2 3
− +
Iodoform test is a characteristic test given by methyl ketones. CHI formed is yellow precipitate.
11. (a) benzyl alcohol
Explanation: Monochlorination of toluene gives benzylchloride.
C6H5CH3 + Cl2 + hv → C6H5CH2Cl
benzyl chloride on reaction with aq. NaOH will give benzyl alcohol by substitution reaction.
C6H5CH2Cl + NaOH(aq) → C6H5CH2OH
12.
(d) Ethanolic NaCN
Explanation: KCN is used to increase the number of carbon atoms.
RX + NaCN → RCN + KX
H2 /Raney N i
R − CN + 4H −−−−−−−−→ RCH2 N H2
13.
(b) Both A and R are true but R is not the correct explanation of A.
Explanation: Fructose does not contain an aldehyde group but still reduce Tollen's reagent. In presence of the dilute solution of
alkali, fructose undergoes epimerization to form glucose and mannose.
14.
(c) A is true but R is false.
Explanation: Isobutanal does not give an iodoform test because it does not have the −COCH3 group.
15.
(c) A is true but R is false.
Explanation: A is true but R is false.
16.
(d) A is false but R is true.
Explanation:
Electron withdrawing groups such as -NO2, - CN, - X, increase the acidity. Greater the number of electron-withdrawing groups
more is the acidic character, i.e. 2, 4, 6-trinitrophenol is more acidic than 4-nitrophenol.
Section B
17. i. When one mole of CoCl3.6NH3 is mixed with AgNO3, three moles of AgCl are precipitated which indicates that three
ionisable chloride ions in the complex are present. Hence, its structural formula is [Co(NH3)6]Cl3.
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ii. IUPAC name of the complex [Co(NH3)6]Cl3 is Hexa ammine cobalt (III) chloride.
18. The decrease in atomic and ionic size with increase in atomic number in lanthanoids is called lanthanoid contraction. Its
consequences are
(i) It causes the radii of the members of the third transition series to be very similar to those of the corresponding members of the
second series. The almost identical radii of Zr (160 pm) and Hf (159 pm), have almost similar sizes.
(ii) Difficulty in separation of lanthanoids.
19. Answer the following:
(i) Zero Order reaction
(ii) It is first order with respect to N2O5.
20. For dilution -
M1 V1 = M2 V2
M1 V1 0.65M×20ml
V2 = = = 65ml
M2 0.2M
ii.
Section C
22. The reciprocal of electrical resistance is called conductance. It is usually represented by 'G'.
Thus G = R
1
−0.01 −1 −4 −1
= − M min = 4 × 10 M min
25
−4
4×10 −1 −6 −1
= M s = 6.67 × 10 Ms
60
373K
24. i. C 2 H2 C H2 − O − C H2 C2 H5 + HI −−−→ C H3 C H2 C H2 − OH + C H3 C H2 C H2 − I
l - Proproxypropane Propan - l - ol l - Iodopropane
ii.
iii.
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OR
i. Since the phenoxide ion left after the removal of a proton is stabilized by resonance whereas alkoxide ion left after the
removal of a proton from alcohol is not.
ii. The large difference in boiling points of alcohols and ethers is due to the presence of hydrogen bonding in alcohols.
25. i. The product form when (CH3)3-C-CHO react with CH3COCH3 in the presence of dilute NaOH is:
OH O
N aOH(dil) | ||
(C H3 ) − C − C HO + C H3 − CO − C H3 −−−−−−→ (C H3 ) − C − C H − C H2 − C − C H3
3 3
4−Hydroxy−5,5−dim ethylhexa−2−one
ii. The product form when (CH3)3C-CHO react with HCN is(C H 3 )3 − C − C HO + HC N → (C H3 )3 − C − OH
|
CN
Conc. N aOH
iii. The product form when (CH3)3-C-CHO react with conc. NaOH is:2(C H 3 )3 − C − C HO −−−−−−−−→
− +
(C H3 )3 − C O O Na + (C H3 )3 − C H2 OH
26. We have,
+ 2+
Zn(s) + 2Ag (aq) → Zn (aq) + 2Ag(s)
At Cathode (Reduction):
+ −
2Ag (aq) + 2e → 2Ag(s)
At Anode (Oxidation):
2+ −
Zn(s) → Zn (aq) + 2e
i. From half cell reaction, Zinc acts as Anode, i.e. zinc electrode will be negatively charged.
ii. The current will flow from silver to zinc in the external circuit and inside the solution, ions are responsible as shown in the
half cell reaction. Zn2+ is formed in the anode container and goes to the solution and in the cathode container, Ag+ goes from
solution to the silver metal(cathode) and gets deposited. To maintain the concentration of ions in both the containers, salt
bridge is used which contain an electrolyte i.e. KCl.
iii. At anode : Zn(s) → Zn (aq) + 2e 2+ −
27. Haloarenes: The replacement of hydrogen atoms in a aromatic hydrocarbon by halogen atoms results in the formation of aryl
halide (haloarene). Haloarenes contain halogen atoms attached to sp2 hybridized carbon atoms of an aryl group. They are
classified as:
i. Nuclear halogen derivatives: Halogen derivatives of aromatic hydrocarbons in which the halogen atom (F, Cl , Br, or I) is
directly attached to an aromatic ring are called nuclear halogen derivatives. Some examples are:
ii. Side chain halogen derivatives: Halogen derivatives of aromatic hydrocarbons in which the halogen atom is linked to one of
the carbon atoms of the side chain carrying the aryl group are called aryl halides. For example,
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Preparation: By the direct halogenation of a suitable arenas.
28. Λ∘
m (BaSO4 ) = Λm Ba
∘ 2+
+ Λm SO
∘ 2−
4
= 110 + 136.6 = 246.6ohm
−1
cm
−1
−6 −6
KB,S04 = KB,s04 ( solution ) − Kwatar = 3.648 × 10 − 1.25 × 10
−6 −1
= 2.398 × 10 s cm
−6
c K×1000 2.398× 10 ×1000 −6
Λm = = = 9.72 × 10 mol/L
Solubility 246.6
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32. Though both [NICl4]2- and [Ni(CO)4] are tetrahedral, their magnetic characters are different. This is due to a difference in the
nature of ligands. CN- is a weak field ligand and it does not cause the pairing of unpaired 3d electrons. Hence, [NICl4]2- is
paramagnetic.
In [Ni(CO)4] ,Ni is in the zero oxidation state i.e., it has a configuration of 3d84s2.
But CO is a strong field ligand. Therefore, it causes the pairing of unpaired 3d electrons. Also, it causes the 4s electrons to shift to
the 3d orbital, thereby giving rise to sp3hybridization. Since no unpaired electrons are present in this case, [Ni(CO)4] is
diamagnetic.
OR
CoSO4Cl.5NH3:
i. Isomer A reacts with AgNO3 but not with BaCl2, it shows that it has Cl ion outside the coordination sphere. Hence, A =
[CO(NH3)5SO4]CI
Isomer B reacts with BaCl2 but not with AgNO3, it shows that it has SO4- outside the coordination sphere
Hence, B = [CO(NH3)5Cl]SO4
ii. Type of isomerism - Ionization isomerism.
iii. IUPAC name of, A = Pentaamminesulphatocobalt (III) chloride and B = Pentaamminesulphatocobalt (III) sulphate.
33. i. Hofmann bromamide degradation reaction It is a method for the preparation of primary amines by treating an amide with
bromine in an aqueous or ethanolic solution of sodium hydroxide. The amines so formed contain one carbon less than that
present in the parent amide.
ii. Gattermann reaction When benzene diazonium chloride is treated with Cu/HCl Cu/HBr, chlorobenzene or bromobenzene is
obtained. This reaction is known as Gattermann reaction
iii. Coupllng reaction Arenediazonium salts react with highly reactive (i.e. electron rich) aromatic compounds such as aniline,
phenols to form brightly coloured azo compounds, Ar-N =N-Ar. This reaction is called coupling reaction. e.g. Benzene
diazonium chloride reacts with aniline in faintly acidic medium (pH 4- 5) at 273·278K, in which the molecule at its para-
position is coupled with the diazonium salt to form p-aminoazobenzene. This is an example of coupling reaction.
OR
∘
0 C
CH3 CH2 NH 2 CH3 CH2 OH
i. + HNO2 −−→ + N2 + H2O
Ethylamine Ethyl alcohol
ii.
iii.
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