Battery Analysis
Battery Analysis
Battery Analysis
Research papers
A R T I C L E I N F O A B S T R A C T
Keywords: The demand for electric cars continues to grow every day due to their benefits, such as zero emissions, and the
Battery thermal management system (BTMS) downsides of traditional internal combustion engines, such as toxic pollutants. There are some complications in
Li-ion batteries the practical use of batteries, like thermal runaway and decreased battery life cycles and usage. Hence, this
Cell holders
research introduced an innovative method to achieve uniform temperature distribution in the battery module
Computational fluid dynamics
and decrease the maximum temperature obtained in the battery cells. The new battery module has been designed
Battery module
by considering the cell holders at different cell heights. These cell holders are like a tray to hold the battery cells
and act as fins, enhancing the uniform temperature distribution within the battery module. Base and new battery
modules are analyzed at different discharge conditions with the same boundary conditions and physical pa
rameters. The significance of cell holders acting as fins has been evaluated by analyzing the temperature contours
and profiles for every cell of the battery module. The analysis of numerical results found that at 1, 2 and 3C rate,
the maximum temperatures of 301.5, 303.9 and 308.8 K for base model and whereas for new model these are
300.6, 302.1, and 304 K, respectively. At 1C rate discharge, the temperature gradient among the cells (Tcell4-
Tcell6) in the flow directions has been observed as 0.26 ◦ C and 0.04 ◦ C for the base and novel battery model,
respectively.
https://doi.org/10.1016/j.est.2022.106474
Received 19 April 2022; Received in revised form 24 October 2022; Accepted 17 December 2022
Available online 23 December 2022
2352-152X/© 2022 Elsevier Ltd. All rights reserved.
O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
dispersed at least at the same rate as it is created in the batteries, the ECM and LSTM models are more precise than the ESPM model.
resulting in the degradation of materials and components [15] or From the available literature review, it is understood that battery
possibly the thermal runaway of the batteries [16]. A thermal runaway pack operating temperature plays a significant role in the efficient
is an event that causes a fast temperature increase, gas production, and operation of electric vehicles. Many researchers discussed different
potentially a battery explosion [17], putting the vehicle's and its occu cooling techniques like passive, active, and combinations (hybrid). In
pants' safety in jeopardy [18]. this research, an innovative battery module has been designed and
Quasi temperature distribution within a single cell causes a varied studied its performance at different C rate discharge conditions. The C
rate of electrochemical reactions in different cell regions, resulting in Rate defines the measurement of current at charging and discharging
partial energy usage and shorter battery life [19]. According to studies, a conditions. The cooling performance of the battery module is analyzed
temperature differential of >5 degrees Celsius within a battery cell by assessing the maximum temperature and temperature gradient in the
causes a 25 % increase in thermal aging and a 10 % drop in power ca battery module.
pacity [20–22]. At the battery pack level, cell discrepancies in capacity,
voltage, and internal resistance are typical and expected [23]. These 2. Method for geometrical modeling of battery module
differences result in different thermal behaviors, resulting in a temper
ature gradient throughout the battery pack [24]. A 5 ◦ C temperature The Li-ion battery pack consists of 207 Li-ion cylindrical cells
differential may result in a 1.5–2 % capacity drop in the battery pack (IFR32700); hence, the whole pack is divided into 23 battery modules,
[25], as well as a 10 % reduction in power capability [26]. each consisting of 9 cells. In this research, the nine cells are initially
Aditya et al. [27] studied a phase change material-based passive heat arranged in a matrix form of 3*3 sizes, as shown in Fig. 1. The diameter
management solution for Li-ion cylindrical cells (PCM). The scientists and height of the cell is 32 mm and 70 mm, respectively. All the cylin
examined battery temperatures for various PCM material thicknesses drical cells are designed with separate cathode and anode parts and
and determined that a minimum thickness of 4 mm is required to keep separate busbars connecting all the positive terminals and negative
the battery's maximum temperature within the range. Jeevan Jaidi et al. terminals, respectively. With these arrangements, the battery module is
[28] have investigated the notion of BTMS for a prismatic cell with a considered in parallel connection. For efficient thermal cooling of bat
mini-channel cooling flow channel around the cell and distinct coolant teries and uniform temperature distribution, a novel approach is
inlet circumstances. The primary contribution of this study was to considered by designing cell holders' jacket fins, as shown in Fig. 1.
determine the minimal input temperature and mass flow rate of the These jacket fins are designed to improve the heat removal rate from the
coolant required to achieve the desired battery cell cooling. battery surface and ensure uniform thermal distribution within the
Zhao et al. [29] exhibited both experimental and numerical research battery. The heat removal plate (cell holder's jacket) is considered with
for an ultra-fast charging battery module constructed using pouch cell lightweight aluminum with 1 mm thickness, and 10 mm sleeve height
Li-ion battery cells. The battery moducel was placed between foam and around the cell and 4 mm fin extension from the sleeve surface. The
heat sinks on both sides. Several tests were undertaken to determine the battery nominal voltage and capacity are 3.2 V and 6000 mAh, respec
maximum temperature, surface temperature, and heat flow during ultra- tively. The battery materials and properties are defined in Table 1.
fast charging the battery module at a rate of 5C. At 20 ◦ C inlet coolant
temperature and 5C rate fast charging, the scientists performed further 3. Mathematical modeling and numerical methods
tests to determine the power loss from the battery and determined that it
is 30 % at 20 ◦ C inlet coolant temperature and 5C rate fast charging. The computational flow domains are computed by solving the
Liang et al. [30] did a comparative analysis of the modeling of battery Reynolds-averaged Navier-Stokes (RANS) equations, k-ε turbulence
packs using various voltage techniques. Recurrent neural network model transport equations, and the other governing equations for bat
model, analogous circuit model, and extended single particle model are tery Multi-Scale Multi-Domain (MSMD) modeling. These governing
the three models. These models were evaluated and compared using four equations' spatial derivatives are discretized using the finite volume
distinct standard driving cycles at six distinct ambient conditions method with a second-order upwind discretization scheme. The PISO
ranging from − 20 ◦ C to 40 ◦ C. The comparative analysis determined that (Pressure-Implicit with Splitting of Operators) algorithm for pressure-
2
O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
Fig. 1. Geometrical modeling of battery module a) Base model and b) New model.
3
O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
to zero. The Equivalent Circuit Model (ECM) based on the mimic of an Reynolds number (Re) based on the local properties like dynamic vis
electrical circuit with three resistors, two capacitors, and open-circuit cosity (μf), density of fluid (ρf) and the velocity of fluid (U) as shown
voltage based on Chen [31] has been considered for battery electrical- below. The mass flow rate of air at a velocity of 0.5 m/s corresponds to a
thermal modeling. Reynolds number of 1008.
The relation between the voltage and current for the considered
ρf UD
circuit model is obtained by solving the following set of equations: Re = (28)
μf
V(t) = VOCV (SOC) − V1 − V2 − Rs (SOC)I(t) (10)
4. Grid-independent study and experimental validation
dV1 1 1
= V1 − I(t) (11)
dt R1 (SOC)C1 (SOC) C1 (SOC)
The mesh generation is the crucial step in the CFD problem for ac
curate numerical results; hence, utmost care has been taken for gener
dV2 1 1
= V2 − I(t) (12) ating the mesh. As the computational domain consists of solid battery
dt R2 (SOC)C2 (SOC) C2 (SOC)
and surrounding flow domain, the unstructured mesh has been gener
d(SOC)
/ ated using both the hexahedral and tetrahedral elements, as shown in
= I(t) 3600QAh (13) Fig. 2. Different mesh size elements 0.10 mm, 0.05 mm and 0.01 mm are
dt
considered for the coarser, medium, and fine mesh settings, respectively.
For the considered MSMD battery model and ECM sub-model, the Their impact on the numerical results is analyzed. The meshing was
circuits open voltage, capacitors capacitances, and resistors resistances generated by considering the inflation option to limit the y+ value
are the state of charge (SOC) functions. In ANSYS Fluent, these relations within the acceptable range. For this case, based on the nearest wall
are defined in two ways as follows: distance (y) from the battery cell, the y+ value is considered as 1.0. A
grid independence study has been conducted for the base model with a
Fifth order polynomial form: different number of mesh elements by observing the cell5 temperature at
1C discharge rate as shown in Fig. 2 (b). From the temperature profile
Rs = a0 + a1 (SOC) + a2 (SOC)2 + a3 (SOC)3 + a4 (SOC)4 + a5 (SOC)5 (14)
analysis, it has been identified that the temperature does not vary much
after the medium mesh refinement unless with increased computational
R1 = b0 + b1 (SOC) + b2 (SOC)2 + b3 (SOC)3 + b4 (SOC)4 + b5 (SOC)5 (15)
time and cost. Hence, the complete numerical analysis for the base and
new models are performed with medium mesh elements.
C1 = c0 + c1 (SOC) + c2 (SOC)2 + c3 (SOC)3 + c4 (SOC)4 + c5 (SOC)5 (16)
R2 = d0 + d1 (SOC) + d2 (SOC)2 + d3 (SOC)3 + d4 (SOC)4 + d5 (SOC)5 (17) 4.1. Experimental validation of the numerical model
C2 = e0 + e1 (SOC) + e2 (SOC)2 + e3 (SOC)3 + e4 (SOC)4 + e5 (SOC)5 (18) The validity of the current numerical model has been verified by
solving the experimental test conditions available in the open literature.
VOCV = f0 + f1 (SOC) + f2 (SOC)2 + f3 (SOC)3 + f4 (SOC)4 + f5 (SOC)5 (19) Wu's [32] conducted experimental research for a prismatic cell at a 5C
discharge rate and observed the cell temperature concerning discharge
Proposed functions based on the Chen [31] model:
time. The same work has been solved with the present CFD model with
Rs = a0 + a1 exp[ − a2 (SOC) ] (20) the same experimental conditions like battery properties, discharge
condition, discharge time etc., predicted the surface temperature of the
R1 = b0 + b1 exp[ − b2 (SOC) ] (21) cell and compared the same with the experimental results as shown in
Fig. 2. c). The comparison results found that the present CFD model
C1 = c0 + c1 exp[ − c2 (SOC) ] (22) results are in good matching with the experimental with a minimum and
maximum error of 0.1 K and 0.32 K, respectively. Therefore, this model
R2 = d0 + d1 exp[ − d2 (SOC) ] (23) has been implemented for this research work and analyzed the flow field
and battery thermal distribution.
C2 = e0 + e1 exp[ − e2 (SOC) ] (24)
5. Results and discussion
VOCV = f0 + f1 (SOC) + f2 (SOC)2 + f3 (SOC)3 + f4 exp[ − f5 (SOC) ] (25)
The source terms for the electrical potential governing equations are Numerical simulation has been performed for the base and new
derived from the following expressions: model battery modules with the ECM battery sub-models at different
discharge conditions. The numerical results are analyzed by evaluating
jECh = I/Vol (26)
the temperature contours and profiles for individual cells and the bat
[ ] tery module. For easy observation of heat generation vs. airflow stream
I dU
q̇ECh = VOCV − (φ+ − φ− ) − T (27) effect on battery cooling, a horizontal plane has been designed on XY
Vol dT
plane at cell middle height. The cell temperatures at different discharge
Proper boundary conditions and initial conditions play a significant conditions are shown in Fig. 3. From observing temperature contours for
role in solving the computational fluid dynamics problem. Hence, the the base and new models at a 1C rate, the temperature has been
battery module airflow computational domain inlet and outlet bound distributed uniformly with significantly less temperature gradient
aries are defined with the mass flow inlet and pressure outlet boundary among the battery module for the new model. If we observe the tem
conditions, respectively. The interface between the battery cell, cell perature of cells in the flow direction, the base model has recorded the
holder and the surrounding flow area is defined with temperature con highest temperature difference of (Tcell4-Tcell6) 0.26 ◦ C, whereas the new
tinuity boundary conditions. The remaining surrounding walls are model with cell holders acting as fins has recorded 0.04 ◦ C, which is a
assigned with adiabatic boundary wall conditions. As the simulations significantly less temperature gradient for the battery module. Therefore
are unsteady, initial battery and flow domain conditions are assigned even if extrapolated for the whole battery pack, it will be less than
with the environmental temperature at the beginning of the solution. desired temperature limits (<5 ◦ C as per standards, but for our model, it
The airflow rate into the battery module is calculated from the local will be <2 ◦ C).
With an increase in discharge current, the heat generation has been
4
O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
Fig. 2. a) Mesh generation and b) Grid independence study and c) Validation [32].
increased, and the same has been observed with the temperature con is observed that comparatively among three cells, cell 5 consists of low
tours, as shown in Fig. 3. At 1C rate, the maximum temperatures of temperature due to better conduction and convection of heat transfer.
301.5 and 300.6 K have been recorded for the base and new models, There is no considerable variation in the temperature gradient as the
respectively. With further increase in discharge current, it is found that discharge current increases unless increased maximum temperature.
at 2C rates 303.9 and 302.1 K and with 3C rates, these are 308.8 and The analysis of these temperature profiles among the multi cells reveals
304.9 K respectively for the base and new models. that the temperature profiles for new models are uniform, i.e., negligible
Two different straight lines are considered; one is horizontal along temperature gradient due to better heat distribution among the cells and
the X-axis, which covers cells 4, 5, and 6, and another straight-line along increased conduction and convection with cell holders acted as baffles
the Y-axis covers cells 2, 5, and 8. These straight lines are considered and fins.
strictly at cell half of the height and used to export the post-processing For efficient analysis of cell holders' impact on better cooling, the
data. The impact of airflow distribution on thermal cooling for the individual cell behavior has been analyzed by observing the cell's core
base model and the new model has been further assessed by observing temperature along its height, as shown in Fig. 5. Initially, cells 6, 5, and
the temperature profiles for the considered straight lines along with the 4, which are in-line with the flow direction, have been monitored, as
cells, as shown in Fig. 4. shown in Fig. 5. As per the given cell arrangement and its numbering,
From the analysis of temperature profiles for cells 4, 5, and 6, it is initially, cell 6 was exposed to the fresh air and then cell 5 and lastly cell
observed that the temperature profile (Fig. 4) increases gradually in the 4 as shown in Fig. 1. Hence, first cell 6 has been plotted and observed
flow direction for the base model, whereas for the new model with fins, that at 1C rate, the temperature is uniform along with its height for the
it is constant along the flow direction (X-axis). As the discharge current new model, whereas slightly increased temperature has been observed
increases, the temperature gradient (dT/dx) also increases in the base at the middle of the cell for the base model.
model's flow direction, whereas it is very less almost negligible for the As the discharge current increased to 2C and 3C rate, the base model
new model. The temperature profiles for another straight-line covering cell temperature and its slope and height also increased due to less heat
cell 2, 5, and 6 reveal that the temperature profiles are uniform for all dissipation. Whereas with new models, it is observed that the cell tem
cells but recorded higher temperature with the base model. And also, it perature is uniform throughout its height, and with increased discharge
5
O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
Fig. 3. Base model and new model battery modules temperature contours on XY plane at the middle height of the cell in the z-direction.
rate, there is no considerable increase in temperature gradient compared same flow conditions of the air. The temperature profiles show that cells
to the base models. Cell 5 is located in the middle of the battery module, 2 and 8 have similar temperature profiles because of their geometrical
as shown in Fig. 1. Its temperature profiles are predicted along with its similarity and are exposed to similar airflow conditions. Whereas cell 5
height at different discharge currents, as shown in Fig. 5. These profiles registers slightly fewer temperatures as its exchanges, its heat with
are almost similar to that of cell 6 except for an increased overall tem surrounding cells in all the directions.
perature as it is subjected to the downstream air of cell6. Similarly, cell 4 As the simulations are performed with transient conditions, the
is also subjected to already used air; hence cell4 temperature profiles temperature development in the cells with discharge time has been
consist of higher temperature gradients at high discharge currents. monitored for almost one hour, as shown in Fig. 6. The transient tem
Similarly, the row of cells 2, 5, and 8 temperatures are also predicted perature profiles for each cell of the battery module reveal that the cells'
at different discharge conditions, as shown in Fig. 5. These three cells are temperature increases with an increase in discharge rate and time. This
arranged on a single straight-line along the Y-axis at the same distance is due to continuous heat generation and accumulation in the battery
from the air inlet position such that all the cells are experienced with the itself. Hence, the cooling of batteries plays a significant role in the
6
O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
Fig. 4. Temperature profiles for a) a horizontal line along 4, 5, 6 cells b) a vertical line along 2, 5, and 8 cells.
efficient operation battery pack. From the comparison of temperature cell holders for the new model. This leads to a decrease in the maximum
profiles for the base and new models at a 1C rate, it is found that the base temperature of the cells and temperature gradient among the battery
model has registered the highest temperature of 301 K and the tem module and maintains within the desirable range.
perature gradient also increases with increases in discharge time. For a
new model at a similar discharge rate (1C), the maximum temperature is 6. Conclusion
300.22 K, and the temperature gradient among the different cells is
negligible. In this research article, a novel technique has been introduced to cool
Similarly, the base and new models are studied at 2C and 3C the battery module and maintain the whole battery pack with a uniform
discharge rates and predicted temperature profiles, as shown in Fig. 6. temperature. Initially, a base model battery module was designed with
The maximum temperatures of 304 K and 309 K are registered for the nine cells, and after concerning this model, a new model was designed
base model at 2C and 3C discharge conditions, respectively. Whereas for by considering baffle cell holders that act like fins and heat conduction
new models, these are 300.9 and 302 K, these temperatures are smaller media. The primary intention of this research is to reduce the battery
compared to the base model due to the presence of baffles, which also operating temperature and temperature gradient among the battery
act like fins and increase the heat dissipation from the battery cells. It is cells. Hence, two models are analyzed at different discharge conditions
also identified that the temperature gradient among different cells in with similar boundary conditions. Temperatures of both models are
creases for the base models with an increase in discharge rate and time. analyzed at different discharge conditions using plane contours and
In contrast, the temperature gradient is negligible for the new model due temperature profiles for each cell of the battery module. The tempera
to the uniform temperature among the battery module with baffle cell ture contours for both models represent that the base model has recor
holders. ded the highest cell temperature and temperature gradient. The
The voltage and depth of discharge profiles are observed for the base numerical analysis finds the following quantitative conclusions:
and new models at different discharge conditions and plotted in Fig. 7.
The analysis of voltage profiles shows that the voltage drop increases • At 1C discharge rate, the temperature gradient among the cells
with an increase in discharge rate and time and found no variation for (Tcell4-Tcell6) in the flow directions was found to be 0.26 ◦ C for the
base and new models voltage profiles. Depth of discharge profiles is standard battery model and 0.04 ◦ C for the innovative battery model.
found that with the increase in discharge rate and time, the depth of • Under various discharge settings (1C, 2C, and 3C rate), the base
discharge also increases but no variation between the base and new model's maximum temperatures are 301.5 K, 303.9 K, and 308.8 K,
models. but the new battery model's maximum temperatures are 300.6 K,
The most critical parameter during battery discharge conditions is 302.1 K, and 304.9 K.
the heat generation source; hence, this parameter has been monitored • Comparatively, under the same discharge condition of 1C, the basic
for the two models at different discharge conditions, as shown in Fig. 8. model (cell 9) reached a maximum temperature of 301 K in 66 min.
The analysis of profiles shows that the heat generation source is signif However, the highest temperature reached by the new battery type
icantly less for 1C and 2C discharge conditions than for the 3C discharge (cell 9) at the same period and 1C rate was only 300.2 K. Identical
condition. In addition, the heat generation rate is higher for the first 500 performance is seen at both 2C and 3C rate.
s of the discharge time, and after that, it is uniform as the cooling per
formance activates the heat dissipation. Comparatively, a little higher CRediT authorship contribution statement
heat generation is observed for the base model with increases in
discharge rate (Fig. 8) due to poor heat dissipation and the cells' accu The author performs the following tasks:
mulation of generated heat energy. Even though heat generation is I am the sole author of this manuscript.
similar in the base and new models, its storage energy is less due to Obula Reddy Kummitha: Problem statement, Introduction and
increased heat dissipation to the surrounding fluid due to the presence of literature, Methodology, Numerical Modeling, and Simulations, Data
7
O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
Fig. 5. Temperature profiles along with cell height for the middle horizontal three cells (cell6, cell5, and cell4) and the middle vertical three cells (cell2, cell5,
and cell8).
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O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
9
O.R. Kummitha Journal of Energy Storage 59 (2023) 106474
Fig. 7. Voltage and depth of discharge for whole battery pack at different discharge conditions.
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