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APPENDIX F
NUMBER OF FREE POSITIVE
ELECTRONS IN THE NUCLEUS OF AN
ATOM BY RUTHERFORD’S METHOD
If represents the number of free positive electrons in the
nucleus, the electronic charge, the known charge on the -
particle, namely , and the known kinetic energy of the -
particle, then, since the inertias of the negative electrons are quite
negligible in comparison with that of the -particle, if the latter
suffers an appreciable change in direction in passing through an
atom it will be due to the action of the nuclear charge. If
represents the closest possible approach of the -particle to the
center of the nucleus, namely, that occurring when the collision is
“head on,” and the -particle is thrown straight back upon its
course, then the original kinetic energy must equal the
work done against the electric field in approaching to the distance ,
i.e.,
Suppose, however, that the collision is not “head on,” but that the
original direction of the -particle is such that, if its direction were
maintained, its nearest distance of approach to the nucleus would be
(Fig. 41). The deflection of the a particle will now be, not 180°, as
before, but some other angle . If follows simply from the
geometrical properties of the hyperbola and the elementary
principles of mechanics that
Fig. 41
in which
where
Elements, the atomic numbers of which are not in the order of atomic weights, are in italics. The
numbers corresponding to missing elements are in bold-faced type.
[1] Mem. of the Manchester Lit. and Phil. Soc., (1851; 2d series),
107; Phil. Mag. XIV (1857), 211.
[2] Phil. Mag., XIX (1860; 4th series), 28. Clausius had discussed
some of the relations of this quantity in 1858 (Pogg. Ann. CV
[1858], 239), but Maxwell’s magnificent work on the viscosity of
gases first made possible its evaluation.
[3] I, 375-36.
[4] See Werke, IV, 281.
[5] Op. cit., p. 294.
[6] Phil. Mag., XI (1881; 5th series), 384.
[7] Wissenschaftliche Abhandlungen, III, 69.
[8] Kelvin, “Contact Electricity and Electrolysis,” Nature, LVI
(1897), 84.
[9] Scientific Transactions of the Royal Dublin Society, IV (1891;
11th series), 563.
[10] See particularly Rutherford’s presidential address at the
recent Liverpool meeting of the British Association, Science, LVIII
(1923), 213.
[11] J. J. Thomson and E. Rutherford, Phil. Mag., XLII (1896),
392.
[12] Phil. Mag., XLIV (1898), 422.
[13] Proc. Camb. Phil. Soc., IX, 401.
[14] Phil. Trans., A 195, p. 193.
[15] Annale de Chimie et de Physique, XXVIII, 289.
[16] Phil. Trans., A 193, p. 129.
[17] Leonard B. Loeb, Proc. Nat. Acad., II (1916), 345, and Phys.
Rev., 1917.
[18] Wellish, Amer. Jour. of Science, XXXIX (1915), 583.
[19] L. B. Loeb, Jour. Franklin Inst., CXCVII (1924), 45.
[20] H. A. Erikson, Phys. Rev., XX (1922), 118.
[21] H. B. Wahlin, ibid., p. 267.
[22] Verb. der deutsch. phys. Ges., XI (1909), 146 and 276.
[23] Proc. Roy. Soc., LXXX (1908), 207.
[24] Fournier d’Albe, Life of Sir William Crookes, 1924.
[25] Proc. Roy. Soc., XL (1890), 526.
[26] Phil. Mag., XLIV (1897), 298.
[27] W. Wien, Wied. Ann., LXV (1898), 440.
[28] Rays of Positive Electricity. London: Longmans, 1913.
[29] Proceedings, IX (1897), 244.
[30] Phil. Mag., XXIX (1890; 5th series), 56.
[31] Ibid., p. 292; Nature, XXXVI, 412.
[32] Proc. Camb. Phil. Soc., IX (1897), 333.
[33] Ibid., p. 345.
[34] Phil. Mag., XLVI (1898), 528.
[35] Verh. der deutsch. phys. Ges., XVI (1914), 422.
[36] Phil. Mag., V (1903; 6th series), 354.
[37] Op. cit., p. 429.
[38] Phys. Rev., XXVI (1908), 198.
[39] Phil. Mag., XIX (1910), 209.
[40] I had changed the constant in Wilson’s equation from 3.1 to
3.422 because of careful measurements on the temperature
existing in the cloud chamber about 10 seconds after expansion
and because of new measurements on the viscosity of the
saturated air.
[41] See Phil. Mag., XXI (1911), 757.
[42] Phys. Rev., Series 1, XXXII (1911), 349; Series 2, II (1913),
109.
[43] Comptes rendus (1911), 1735.
[44] Phys. Rev., XXXV (1912), 227.
[45] Cunningham (Proc. Roy. Soc., LXXXIII [1910], 357) and the
author came independently to the conclusion as to the invalidity
of Stokes’s Law, he from theoretical considerations developed at
about the same time, I from my experimental work.
[46] Phys. Rev., N.S., I, (1913), 124.
[47] Phys. Rev., N.S., II (1913), 363.
[48] Phys. Rev., December, 1916.
[49] Ann. der Phys., XXII (1907), 287; XXIII (1908), 447.
[50] Math. and Phys. Papers, III, 59.
[51] See Phil. Mag., XIX (1910), 216; XXI (1911), 757.
[52] Phys. Rev., II (1913), 117. This paper was read before the
Deutsche physikalische Gesellschaft in Berlin in June, 1912.
[53] Phys. Rev., II (1913), 136.
[54] For full details see Millikan, Phil. Mag., June, 1917.
[55] At. wt. of Ag. = 107.88; electrochem. eq’t. of Ag. = 0.01188.
[56] Phil. Trans., CXCIII (1900), 129.
[57] Proc. Roy. Soc., LXXX (1908), 207.
[58] Verh. deutsch. phys. Ges., March 5, 1909.
[59] Phil. Mag., XXIII (1911), 753.
[60] Le Radium, X (1913), 113, 119.
[61] Sitzungsber. d. k. Bayerischen Akad. d. Wiss. (1913), p. 19.
[62] Ann. d. Phys., XLV, 177; XLVII, 227.
[63] Phys. Rev., X (1918), 283.
[64] Phys. Rev., XVI (1920), 260.
[65] Rays of Positive Electricity (1913), p. 46.
[66] Millikan, Gottschalk, and Kelly, Phys. Rev., XI (1920), 157.
[67] Millikan, Phys. Rev., XVIII (1921), 456. Wilkins, ibid., XXIV
(1922), 210.
[68] Phys. Rev., September or October, 1924.
[69] Rays of Positive Electricity (1913), p. 46.
[70] Phil. Mag., IV (1828), 161.
[71] Revue des questions scientifiques, Louvain, VII (1880), 5.
[72] Ibid., II (1877), 319.
[73] Dinglers polyt. Jour., CCXXXIX (1881), 325.
[74] Jour. de Phys., VII (1888), 561; Comptes rendus, CIX (1889),
102.
[75] Ann. d. Phys. (4), XVII (1905), 549; XIX (1906), 371; XXII
(1907), 569.
[76] Comptes rendus, CXLVI (1908), 530.
[77] Ibid., p. 967; CXLVII (1908), 475, 530, 594; CLII (1911),
1380, 1569; see also Perrin, Brownian Movements and Molecular
Reality, Engl. tr. by Soddy, 1912.
[78] Ann. der Phys., IV (1906), 21, 756.
[79] Wiener Berichte, CXVI (1907), II, 1175.
[80] Comptes rendus, CXLVI (1908), 624, 1010.
[81] Ibid., CXLIV (1907), 1338.
[82] Ibid., CXLVIII (1909), 1316.
[83] Jahrbuch der Radioaktivität und Elektronik, X (1913), 513.
[84] Science, February 17, 1911.
[85] Phys. Zeitschr., XII (1911), 202-8; see also Phys. Rev.,
XXXIII (1911), 81.
[86] Phys. Rev., I, N.S. (1913), 218.
[87] It was read before the Academy on July 6: Wiener Berichte,
CXX (1911), II, 1021, but appeared first in print in the August 1st
number of the Phys. Zeitschr. (1911), p. 63. Fletcher’s article is
found in brief in an earlier number of the same volume of the
Phys. Zeitschr. p. 203, and was printed in full in the July number
of Le Radium, VIII (1911), 279.
[88] No error is introduced here if, as assumed, is small in
comparison with . However for more rigorous equations see
Fletcher, Phys. Rev., IV (1914), 442; also Smoluchowski, Phys.
Zeitschr., XVI (1915), 321.
[89] Le Radium, VIII (1911), 279; Phys. Rev., XXXIII (1911), 107.
[90] Phys. Rev., I (1913), 218.
[91] Sitzungsber. d. k. Akad. d. Wiss. in Wien, CXX (1911), II,
1021.
[92] Ibid., CXXI (1912), II, 950.
[93] Ztschr. f. Phys. Chem., LXXXVII (1914), 40.
[94] Die Brownsche Bewegung besonders als Mittel zur
Bestimmung der Avogadroschen Konstante, inaugural
dissertation. Upsala: Almquist & Wiksells Boktryckeri, 1915.
[95] Proc. Roy. Soc., A LXXXI (1908), 141, 161.
[96] Sitzungsber. d. k. Preuss. Akad., XXXVIII (1909), 948.
[97] Rutherford and Royds, Phil. Mag., XVII (1909), 281.
[98] Phil. Mag. (6), XXII (1911), 599.
[99] Phil. Mag. (6), V (1903), 429.
[100] Comptes rendus, CXLVI (1908), 624, 1010.
[101] Ibid., CXLIV (1907), 1338.
[102] Ibid., CXLVIII (1909), 1316.
[103] Phys. Zeilschr., X (1909), 308.
[104] Ibid., XI (1910), 619.
[105] This paper was published in abstract in Phys. Rev., XXX
(1909), 360, and Phil. Mag., XIX (1910), 209.
[106] This paper was published in abstract in Phys. Rev., XXXI
(1910), 92; Science, XXXII (1910), 436; Phys. Zeitschr., XI
(1910), 1097.
[107] Wien. Ber., CXIX (1910), II, 809. This publication was
apparently not issued before December, 1910, for it is not noted
in Naturae Novitates before this date.
[108] Proc. Roy. Soc., LXXXIII (1910), 360.
[109] These results were presented and discussed at great length
in the fall of 1910; see Phys. Zeitschr., XI (1910), 619, 940.
[110] Phys. Zeitschr., XII (1911), 161; Phys. Rev., XXXII (1911),
394.
[111] Le Radium, VIII (1911), 279; Phys. Rev., XXXIII (1911),
107.
[112] Phys. Rev., XXXIII (1911), 366, 367.
[113] See R. Pohl, Jahrbuch der Radioaktivität und Elektronik, VII
(1912), 431.
[114] Wien. Sitzungsber., CXXIII (1914), 53-155; Ann. d. Phys.,
XLIV (1914), 657.
[115] Phys. Zeitschr., XVI (1915), 10.
[116] Ann. d. Phys., XLVI (1915), 261.
[117] Phys. Zeitschr., XII (1911), 162.
[118] Ibid., XVI (1915), 316.
[119] Phys. Rev., II (1913), 138.
[120] See Phys. Rev., II (1913), 134-35.
[121] Phys. Rev., XXXII (1911), 389.
[122] See Schidlof et Karpowicz, Comptes rendus, CLVIII (1914),
1912.
[123] E. Schmid, Wien. Akad. Ber., CXXIX (1920), 813, and ZfP, V
(1921), 27.
[124] R. Bär, in a series of articles recently summarized in Die
Naturwissenschaften, Vols. XIV and XV, 1922, has emphasized this
point. His data serve merely as a new check upon the work found
in our preceding tables.
[125] “Die bei grösseren Partikeln unter gewissen Umständen bei
gleicher Art der Erzeugung häufig wiederkehrenden höheren
Quanten waren dann etwa als stabilere räumliche
Gleichgewichtsverteilungen dieser Sub-electron anzusehen, die
sich unter gewissen Umständen ergeben.”—Wien. Ber., CXXIII,
59.
[126] Their whole case is summarized in the tables in Ann. d.
Phys., XLIV (1914), 693, and XLVI (1915), 292, and it is
recommended that all interested in this discussion take the time
to glance at the data on these pages, for the data themselves are
so erratic as to render discussion needless.
[127] “Wie ich in meinen früheren Publikationen erwähnt habe,
zeigen die ultramikroskopischen Metallpartikel, unmittelbar nach
der Erzeugung beobachtet, eine viel lebhaftere Brownsche
Bewegung als nach einer halben Stunde.”—Phys. Zeitschr., XII,
98.
[128] In my own opinion this is a conclusion contrary to fact,
since in a recent paper (see Phys. Rev., July, 1923) I have fully
established the “Complete Law of Fall.”
[129] II (1913), 117.
[130] Ibid., CCC (1911), 389-90.
[131] The results shown in Fig. 13 do not lay claim to the
precision reached in those recorded in Table X and Fig. 10. No
elaborate precautions were here taken in the calibration of the
Hipp chronoscope and the voltmeter, and it is due to slight errors
discovered later in these calibrations that the slope of line 1 in
Fig. 13 is not quite in agreement with the slope in Fig. 10.
[132] Zeit. für Phys. Chem., LXXXVII (1914), 40.
[133] Inaugural Dissertation von Arne Westgren, Untersuchungcn
über Brownsche Bewegung, Stockholm, 1915.
[134] R. Bär, “Der Streit um das Elektron,” Die
Naturwissenschaften, 1922.
[135] R. A. Millikan, Phys. Rev., XXXII (1911), 397.
[136] J. J. Thomson, Phil. Mag., XI (1881), 229.
[137] Bucherer, Annalen der Physik, XXVIII (1900), 513.
[138] The inadequacy in this argument arises from the fact that
Einstein’s Theory of Relativity requires that all mass, whether of
electromagnetic origin or not, varies in just this way with speed.
[139] Bragg, Phil. Mag., VIII (1904), 719, 726; X (1905), 318; XI
(1906), 617.
[140] Phil. Mag., XXI (1911), 669.
[141] Phil. Mag., XXI (1911), 669-88.
[142] Ibid., XXV (1913), 604.
[143] Phil. Mag., XXI (1911), 648.
[144] Bragg, X-Rays and Crystal Structure, 1915.
[145] Phil. Mag., XXVI (1912), 1024; XXVII (1914), 703.
[146] Jahrbuch der Radioaktivität u. Elektronik, XIII (1916), 326.
[147] Comptes rendus, CLXV (1916), 87, 352.
[148] Barkla and Sadler, Phil. Mag., XVII (May, 1909), 749.
[149] Soddy, The Chemistry of the Radioelements, Part II, 1914.
[150] Millikan and Bowen, “Extreme Ultra-Violet Spectra,” Phys.
Rev., January, 1924.
[151] Balmer (1885) expressed the formula in wave-lengths. Ritz
(1908) first replaced wave-lengths by wave-numbers, or
frequencies, and thereby saw his “combination-principle,” while
Rydberg discovered the general significance of what is now
known as the Rydberg constant .
[152] Paschen, Ann. d. Phys., XXVII (1908), 565.
[153] Spectroscopy of the Extreme Ultraviolet, p. 78.
[154] N. Bohr, Phil. Mag., XXVI (1913), 1 and 476 and 857; XXIX
(1915), 332; XXX (1915), 394; Sommerfeld, Atomic Structure and
Spectral Lines. New York: Dutton, 1923.
[155] Einstein and De Haas, Verh, der deutsch. phys. Ges., XVII
(1915), 152; also Barnett, Phys. Rev., VI (1915), 239; also
Epstein, Science, LVII (1923), 532.
[156] R. A. Millikan, Phil. Mag., XXXIV (1917), 1.
[157] R. A. Millikan, Phys. Rev., VII (1916), 362.
[158] Blake and Duane, ibid., (1917), 624.
[159] A. Sommerfeld, Ann. d. Phys., III (1916), 1. Also Paschen,
ibid., p. 901.
[160] P. Epstein, ibid., L (1916), 489.
[161] See Phys. Rev., July, 1924.
[162] These appeared in an article by Kramers in
Naturwissenschaften, 1923.
[163] Bohr and Coster, Zeit. f. Physik, XII (1923), 344.
[164] Coster and Hevesy, Nature, III (1923), 79; Ber. d. chem.
Ges., LVI (1923), 1503.
[165] Ann. d. Phys. (4), VIII (1903), 149.
[166] Phys. Rev., I (1913), 73.
[167] Ann. d. Phys. (4), XVII (1905), 132; XX (1906), 199.
[168] Phys. Rev., VII (1916), 362.
[169] Warme Strahlung, 1st. ed.
[170] Cf. R. Pohl u. P. Pringsheim, Verh. der deutsch. phys. Ges.,
XV (1913), 637; Sommerfeld, Atombau, etc. (3d ed. 1922), p. 47;
also Phys. Rev., VII (1916), 18, 362.
[171] Phys. Rev., IV (1914), 73; VI (1915), 55; and VII (1916),
362.
[172] Phys. Rev., VI (1915), 166; Proc. Nat. Acad., II (1916), 90;
Phys. Rev., VII (1916), 599; IX, 568; X (1917), 93 and 624.
[173] D. L. Webster and H. Clark, Proc. Nat. Acad., III (1917), 18.
Also Webster, ibid., VI (1920), 26 and 639.
[174] Paper read before the Third Solvay Congress, 1921.
[175] Proc. Roy. Soc., XCIX (1921), 261. See also the same,
January, 1924.
[176] Verh. der deutsch. phys. Ges., XV and XVI, 1914.
[177] Millikan and Bowen, Phys. Rev., January, 1924.
[178] Nichols and Tear, ibid., 1923.
[179] J. J. Thomson, Electricity and Matter, p. 9.
[180] Phys. Rev., II (1913), 109.
[181] Ann. d. Phys. (4), VIII (1902), 149.
[182] Drude, Lehrbuch der Optik (1906), p. 472.
[183] Phil. Mag., XXXII (1916), 188.
[184] Radioactive Substances and Their Radiations, p. 288.
[185] Millikan, Phys. Rev., XVIII (1921), 236.
[186] Page, Amer. Jour. Sci., XXXVI (1913), 501; Hennings and
Kadesch, Phys. Rev., VIII (1916), 217.
[187] Zeitschrift für Physik, 4 (1921), 46.
[188] Zeitschrift für Physik, 10 (1922), 185.
[189] This was first called to my attention by Dr. Epstein, of the
California Institute.
[190] A. H. Compton, Phys. Rev., XXI (1923), 483, 715; XXII
(1923), 409.
[191] P. A. Ross, Proc. Nat. Acad., VII (1923), 246.
[192] Duane and Clark, ibid., February and March, 1924.
[193] Becker et al., Proc. Phys. Soc., April 26, 1924; Phys. Rev.,
June, 1924.
[194] Proc. Nat. Acad. Sci., IX (1923), 158; Compton, ibid., p.
359.
[195] Ibid., 1924.
[196] Ibid.
[197] See Proc. Nat. Acad. Sci., III (1917), 236; also Phil. Mag.,
July, 1917.
[198] Lamb, Hydrodynamics, 1895, p. 533.
[199] Comptes Rendus, CXLVI (1908), 530.
INDEX OF AUTHORS
Aepinus, 12, 14
Ampere, 20, 21
Aristotle, 9
Bacon, 8, 9
Barnett, 212
Becker, 259 f.
Begeman, 57
Blake, 214
Boltwood, 160
Boltzmann, 81, 261
Brown, 145
Campbell, 27
Carbonelle, 145
Cario, 256
Clausius, 8
Coulomb, 32
Dalton, 2
Davis, 247
De Haas, 212
Delsaulx, 143
Democritus, 2, 6, 8, 9, 15
Drude, 251
Dufay, 11
Ehrenfest, 260
Ellis, 246
Enright, 46
Epicurus, 6
Erikson, 38
Eyring, 136
Foote, 247
Fowler, 142
Gaertner, 117
Gerlach, 133 f.
Gibson, 94
Gilbert, 11
Gilchrist, 93, 94
Goucher, 247
Gouy, 145 f.
Grindley, 94
Hadamard, 88
Hevesy, 225
Hogg, 94
Hughes, 245
Huygens, 233
Jeans, 276
Joffé, 135
Joule, 7
Karpowicz, 171
Klein, 255
Konstantinowsky, 166
Kossel, 231
Kramers, 221
Lamb, 267
Laue, 197
Lavoisier, 46
Leucippus, 2
Loeb, 37, 38
Lucretius, 2, 6
Lunn, 89
McLennan, 247
Mendeleéff, 202
Nernst, 27
Nichols, 248
Peltier, 20, 21
Pierson, 136
Plato, 9
Prenin, 27
Pringsheim, 245
Pythagoras, 4