Selfstudys Com File
Selfstudys Com File
Subject - Chemistry
Sample Question Paper - 3
General Instructions:
Section A
1. The IUPAC name of the compound shown below is: [1]
a) 6-bromo-2-chlorocyclohexene b) 3-bromo-1-chlorocyclohexene
c) 2-bromo-6-chlorocyclohex-1-ene d) 1-bromo-3-chlorocyclohexene
2. Cheilosis is caused by deficiency of [1]
a) Vitamin B6 b) Vitamin B2
|
3
[1]
3. The correct IUPAC name of C H 3 − C − C H2 C H3 is
|
OH
a) 2-Methylbutan-2-ol b) 3-Methylbutan-3-ol
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The structure of A and type of isomerism in the above reaction are respectively.
a) 5 × 105 b) 3 × 10-5
6. Match the items of column I with appropriate entries of column II. [1]
Column I Column II
a) (a) - (i), (b) - (ii), (c) - (iii), (d) - (iv) b) (a) - (ii), (b) - (i), (c) - (iii), (d) - (iv)
c) (a) - (iii), (b) - (iv), (c) - (i), (d) - (ii) d) (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i)
7. Ethylidene chloride is a/an ________. [1]
a) Fe and Mg b) Fe and Mn
c) Fe and Co d) Mg and Fe
a) +1 d[B]
b) +2 d[B]
3 dt 3 dt
c) +1 d[B]
d) +3 d[B]
2 dt 2 dt
10. Which of the following reagents would one choose to transform CH3COCl into acetone? [1]
a) CH3MgBr b) (CH3)2Cd
c) (CH3O)2Mg d) CH3Cl
c) anhydrous CaC2 and conc. HCl. d) anhydrous ZnCl2 and conc. HCl.
a) Pentanamide b) Hexanamide
c) Butanamine d) Propanamine
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13. Assertion (A): Vitamin C cannot be stored in our body. [1]
Reason (R): Vitamin C is fat soluble and is excreted from the body in urine.
a) Both Assertion (A) and Reason (R) are true b) Both Assertion (A) and Reason (R) are true,
and Reason (R) is the correct explanation of but Reason (R) is not the correct
the Assertion (A). explanation of the Assertion (A).
c) Assertion (A) is true, but Reason (R) is d) Assertion (A) is false, but Reason (R) is
false. true.
14. Assertion (A): Oximes are less acidic than hydroxyl amine. [1]
Reason (R): Oximes of aldehydes and ketones show geometrical isomerism.
a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
20. If the density of some lake water is 1.25 g mL-1 and contains 92 g of Na+ ions per kg of water, calculate the [2]
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b. 30 g of urea is dissolved in 846 g of water. Calculate the vapour pressure of water for this solution if vapour
pressure of pure water at 298 K is 23.8 mm Hg.
21. Convert Toluene to m-Nitrobenzoic acid. [2]
Section C
22. Write the chemistry of recharging the lead storage battery, highlighting all the materials that are involved during [3]
recharging.
23. The first order rate constant for the decomposition of ethyl iodide by the reaction [3]
C2H5I(g) → C2H4(g) + HI(g)
at 600 K is 1.60 × 10-2 s-1. Its energy of activation is 209 kJ/mol. Calculate the rate constant of the reaction at
700 K.
24. Write the mechanism of hydration of ethene to yield ethanol. [3]
OR
Give the major products that are formed by heating each of the following ethers with HI.
C H3
i. C H 3 − C H2 − C H − C H2 − O − C H2 − C H3
C H3
ii. C H 3 − C H2 − C H2 − O − C − C H2 − C H3
|
C H3
iii.
25. An organic compound A, which has a characteristic odour, on treatment with con.NaOH forms two compounds [3]
B and C. Compound B has molecular formula C7H8O which on oxidation gives back A. Compound C is the
sodium salt of an acid. C, when heated with soda lime yields an aromatic hydrocarbon D. Deduce the structures
of A, B, C and D.
26. How much copper is deposited on the cathode of an electrolytic cell if a current of 5 ampere is passed through a [3]
solution of copper sulphate for 45 minutes?
27. How the following conversions can be carried out? [3]
i. 2-Bromopropane to 1-bromopropane
ii. Chloroethane to butane
iii. Benzene to diphenyl
28. Silver is deposited on a metallic vessel by passing a current of 0.2 amps. for 3 hrs. Calculate the weight of silver [3]
deposited. (At mass of silver = 108 amu,1 F = 96500 C)?
Section D
29. Read the following text carefully and answer the questions that follow: [4]
The f-block consists of elements in which 4f and 5f orbitals are progressively filled. They are placed in a
separate panel at the bottom of the periodic table. The names transition metals and inner transition metals are
often used to refer to the elements of d-and f-blocks respectively. The d–block occupies the large middle section
of the periodic table flanked between s and p blocks in the periodic table. In general, the electronic configuration
of the outer orbitals of these elements is (n - 1)d1-10ns1-2. The electronic configurations of outer orbitals of Zn,
Cd, Hg and Cn are represented by the general formula (n - 1)d10ns2. The transition metals and their compounds
also exhibit catalytic property and paramagnetic behaviour. Transition metal also forms an alloy. An alloy is a
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blend of metals prepared by mixing the components. Alloys may be homogeneous solid solutions in which the
atoms of one metal are distributed randomly among the atoms of the other.
i. Transition metals form alloys. Justify? (1)
ii. Why do transition elements exhibit higher enthalpies of atomization? (1)
iii. Transition metals and many of their compounds show paramagnetic behaviour. Give reason. (2)
OR
Transition metals and their many compounds act as good catalyst. Give reason. (2)
30. Read the following text carefully and answer the questions that follow: [4]
The solutions which boil at a constant temperature like a pure liquid and possess the same composition in liquid,
as well as vapour state are called azeotropes. The components of azeotropes cannot be separated by fractional
distillation. Only non-ideal solutions form azeotropes. Solutions with negative deviation form maximum boiling
azeotrope and the solutions with positive deviation form minimum boiling azeotrope. The boiling point of
azeotrope is never equal to the boiling points of any of the components of the azeotrope.
i. The azeotropic solutions of two miscible liquids show what type of deviation from Raoult's law? (1)
ii. The azeotropic mixture of water & HCI boils at 108.5 ∘
C . What type of deviation is shown by the solution?
Does this solution behave as ideal or non-ideal? (1)
iii. Do ideal solutions form azeotropes? (2)
OR
Out of pure liquid and azeotrope showing positive deviation, Which one has a higher boiling point? (2)
Section E
31. Attempt any five of the following: [5]
(a) Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids. What is their relative [1]
configuration?
(b) What are the three components of nucleic acids? [1]
(c) Name the sugar present in milk. How many monosaccharide units are present in it? What are such [1]
oligosaccharides called?
(d) Is nucleotide and nucleoside the same? What are their roles? [1]
(e) Why cannot vitamin C be stored in our body? [1]
(f) During curdling of milk, what happens to sugar present in it? [1]
(g) Account for the following: [1]
a. There are 5 -OH groups in glucose.
b. Glucose is a reducing sugar
32. List various types of isomerism possible for coordination compounds, giving an example of each. [5]
OR
Explain with two examples each of the following: Coordination entity, ligand coordination number, coordination
polyhedron, homoleptic and heteroleptic.
33. An organic compound A with molecular formula C7H7NO reacts with Br2/aq. KOH to give compound B, which [5]
upon reaction with NaNO2 and HCl at 0oC gives C. Compound C on heating with CH3CH2OH gives a
hydrocarbon D. Compound B on further reaction with Br2 water gives white precipitate of compound E. Identify
the compound A, B, C, D and E; also justify your answer by giving relevant chemical equations.
OR
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i. Write one chemical reaction for each
a. Carbylamine reaction
b. Acetylation reaction
ii. Write structure of N,N-ethylmethylethanamide
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Solution
Section A
1.
(b) 3-bromo-1-chlorocyclohexene
Explanation:
3. (a) 2-Methylbutan-2-ol
CH
3
4.
(c) Prop-1-en-2-ol, tautomerism
40%H2 S O4 Isomerisation
Pr op−1−en−2−ol Acetone
(A)
5.
(c) 5 × 10-5
d[A] d[B] d[C] d[D]
Explanation: rate = − dt
= −
1
3 dt
= +
1
2 dt
= +
1
2 dt
d[A] 1 d[C]
⇒ = −
dt 2 dt
8. (a) Fe and Mg
Explanation: Haemoglobin contains Fe and Chlorophyll contains Mg.
9.
+3 d[B]
(d) 2 dt
+3 d[B]
Explanation: 2 dt
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10.
(b) (CH3)2Cd
Explanation: (CH3)2Cd
11.
(d) anhydrous ZnCl2 and conc. HCl.
Explanation: "Lucas' reagent" is a solution of anhydrous zinc chloride in concentrated hydrochloric acid.
12.
(c) Butanamine
Explanation: In the Hoffmann bromamide reaction, the amine formed has one carbon less than that present in the amide.
RCONH2 + Br2 + 4NaOH → RNH2 + Na2CO3 + 2NaBr + 2H2O
13.
(c) Assertion (A) is true, but Reason (R) is false.
Explanation: In a tetrapeptide, there are four amino acids connected by three peptide bonds
14.
(d) A is false but R is true.
Explanation: Oximes are more acidic because, there is a delocalisation of π electrons (i.e. resonance) and it stabilises it and its
conjugate acid. But no such resonance exists in hydroxyl amine base (NH2O-).
15.
(c) A is true but R is false.
Explanation: Alkyl halides give polyalkylation products.
16. (a) Both A and R are true and R is the correct explanation of A.
Explanation: (CH3)3C-O-CH3 gives (CH3)3C-I and CH3OH on treatment with HI. The reaction occurs by SN1 mechanism.
Section B
17. 1. [Pt(NH3)6]Cl4
2. [CoCl2(NH3)4]+
92g
No. of moles of N a +
=
−1
= 4mole
23gmol
Mass
Density =
Volume
Mass 1000
V = = ( g)
density 1.25
V = 800ml
Number of moles
Molarity = × 1000
Volume (ml)
4×1000
Molarity = = 5 moles
800
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OR
The solution obeys Raoult’s law at all concentrations. The solution does not obey Raoult’s law.
W
B
0
P −P M
A
b. A
P
o
=
W
B
W
o B A
A +
M M
B A
30 30
P P
or 1 −
A 60 A 60
1 − = =
23⋅8 846 23⋅8 846 30
+
18 18 60
46.5 47
PA = 47
× 23.8 = 23.5 mm Hg or vapour pressure of the solution PA = 47.5
× 23.8 = 23.5 mm Hg
21.
Section C
22. A lead storage battery consists of a lead anode, a grid of lead packed with lead dioxide (PbO2) as cathode and a 38% solution of
sulphuric acid (H2SO4) as an electrolyte.
When the battery is in use, the following cell reactions take place:
At anode: P b(s) + SO (aq) → P bSO (s) + 2e 2−
4 4
−
4
+ −
4 (s) + 2H2 O(l)
2P bO2 (s) + 2H2 O(l) −−−−−→ P b(s) + P bO2 (s) + 2H2 SO4
T2 = 700K
Ea = 209K J /mol
−1
= 209000J mol
−5 −1
k1 = 1.60 × 10 s
k2 =?
Ea 700−600
log k2 − log k1 = [ ]
2.303R 600×700
−5 209000 100
log k2 − log 1.60 × 10 = [ ]
2.303×8.314 600×700
−5
log k2 = log 1.60 × 10 + 2.599
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= - 2.197
k = anti log (-2.197)
2
−3 −1
= 6.36 × 10 s
24. The mechanism of hydration of ethene to form ethanol involves three steps.
Step 1:
Protonation of ethene to form carbocation by electrophilic attack of H3O+:
Step 2:
Nucleophilic attack of water on carbocation:
Step 3:
Deprotonation to form ethanol:
OR
CH3 CH3
| |
i. C H3 − C H2 − C H − C H2 − O − C H2 − C H3 + HI → C H3 C H2 C H C H2 OH + C H3 C H2 I
CH3 CH3
| |
ii. C H3 − C H2 − C H2 − O − C − C H2 − C H3 + HI → C H3 C H2 C H2 OH + C H3 C H2 − C − I
| |
CH3 CH3
iii.
The molecular formula of (B) and characteristic odour of (A) suggests that (A) is an aromatic aldehyde, C6H5CHO and (B) is
alcohol, C6H5CH2OH. As (C) is a sodium salt of an acid & gives hydrocarbon (D) on heating with soda lime, (C) is sodium
benzoate and (D) is benzene. In this reaction, Benzaldehyde undergoes self oxidation and reduction(disproportionation).
Therefore:-
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Reaction are:-
m = Z × I × t
63.5
= × 5amp × 45 × 60
2×96500
857250
= = 4.44g
193000
C H3 − C H − C H3 −−−−−−−−−−−−−→ C H3 C H = C H2 −−−−−−−−−→ C H3 C H2 C H2 Br
| 1−Bronopropane
Dehydroha log enation P eroxide ef f ect
Br
2−Bromoprpane
2C H3 C H2 − C l + 2N a −−−−−−−−−→ C H3 C H2 − C H2 C H3 + 2N aC l
Chloroethane W urtz reaction Bu tan e
Page 11 of 14
Section E
31. Attempt any five of the following:
(i) Both the aldopentoses(ribose and 2-deoxyribose) have D-configuration.
(ii) The three components of nucleic acid are base, sugar and phosphate group..
(iii)Lactose is present in milk as sugar. Two monosaccharide units (i.e., glucose and galactose) are present in it. Such
oligosaccharides are called disaccharides.
(iv)The main difference between nucleotide and nucleoside lies in their chemical composition. Nucleotide consists of
phosphate group, a sugar and a nitrogenous base. Nucleoside consists of sugar and a base without the phosphate group.
Nucleotides are the major causes of cancer and nucleosides are same as nucleotides only with the addition of phosphate
groups.
(v) Vitamin C cannot be stored in our body because it is water soluble. As a result, it is readily excreted in the urine.
(vi)The milk sugar lactose is converted into lactic acid by the bacteria during curdling of milk.
(vii) a. Acetylation of glucose with acetic anhydride gives glucose pentaacetate which confirms the presence of five -OH
groups. Since, it exists as a stable compound, five -OH groups should be attached to different carbon atoms.
32.
i. Geometric isomerism: This type of isomerism is common in heteroleptic complexes. It arises due to the different possible
geometric arrangements of the ligands. For example:
ii. Optical isomerism: This type of isomerism arises in chiral molecules. Isomers are mirror images of each other and are non-
superimposable.
iii. Linkage isomerism: This type of isomerism is found in complexes that contain ambidentate ligands. For example: [Co(NH3)5
(NO2)] Cl2 and [Co(NH3)5 (ONO)Cl2
Yellow form Red form
iv. Coordination isomerism:
This type of isomerism arises when the ligands are interchanged between cationic and anionic entities of different metal ions
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present in the complex.
[Co(NH3)5ONO]2+ and [Co(NH3)5NO2]2+
v. Ionization isomerism:
This type of isomerism arises when a counter ion replaces a ligand within the coordination sphere. Thus, complexes that have
the same composition, but furnish different ions when dissolved in water are called ionization isomers. For e.g.,
Co(NH3)5SO4Br, and Co(NH3)5BrSO4
vi. Solvate isomerism:
Solvate isomers differ by whether or not the solvent molecule is directly bonded to the metal ion or merely present as a free
solvent molecule in the crystal lattice.
[Cr(H2O)6] Cl3 [Cr(H2O)5Cl]Cl2.H2O[Cr(H2O)5Cl2 Cl.2H2O
Violet Blue-green Dark green
OR
Coordination entity: This entity usually constitutes a central metal atom or ion, to which are attached a fixed number of other
atoms or ions or groups by coordinate bonds. Examples are [Ni(CO)4], [COCl3(NH3)3], etc.
Ligands: It is an ion having at least one lone pair of electrons and capable of forming a coordinate bond with central atom / ion in
the coordination entity.
Examples are : Cl-, (OH)-, (CN)-etc.
Coordinate number: The total number of coordinate bonds with which central atom/ ion is linked to ligands in the coordination
entity is called coordination number of central atom / ion.
Coordination polyhedron : The spatial arrangement of the ligands which are directly attached to the central atom / ion defines a
coordination polyhedron about the central atom.
Examples are: [Co(NH3)6]3+is octahedral,
[Ni(CO)4]is tetrahedral.
Homoleptic and hedroleptic: Complexes in which a metal is bound to only one kind of donor groups are known as homoleptic.
Example [CO(NH3)6]3+
Complex in which a metal is bound to more than one kind of donor groups are called hetroleptic. Example : [Co(NH3)4Cl2]+
33.
OR
i. Carbylamine reaction: Aliphatic or aromatic primary amines on heating with chloroform and ethanolic potassium hydroxide
form isocyanides or carbylamine which are foul smelling substances. This reaction is known as carbylamine reaction.
Δ
C6 H5 NH 2
+ CHCl3 + 3KOH −
→ C6H5NC + 3KCl + 3H2O
Aniline
This reaction is used as a test for primary aliphatic and aromatic amine.
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ii. Acetylation:
C2 H5 − N − C − C H3
| ||
CH3 O
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