Some Basic Concept NEET Questions

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Class 11th NEET


Some Basic Concepts of Chemistry
Nature of Matter and Uncertainty in Measurement

1. The unit of intensity is 9. Convert 25365 mg to S.I unit


(1) Mole (2) kg (1) 253.65g
(3) Candela (4) Ampere (2) 25.365  10–3 kg
(3) 25.365kg
2. Name the particles which make up matter? (4) 253.65kg
(1) Non-metals (2) Metals
(3) Metalloids (4) Atoms 10. Convert 15.15 pm to basic unit
(1) 15.15×10–13m
3. What is matter? (2) 1.515×10–12m
(1) Anything which has mass but does not occupies (3) 15.15×10–12m
space
(4) 1.515×10–13m
(2) Anything which has mass and occupies space
(3) Anything which neither has mass nor occupies
11. Purity of a solid substance can be checked by its
space
(1) Boiling point
(4) Anything which does not have mass but it
(2) melting point
occupies space
(3) solubility in water
(4) solubility in alcohol
4. Which of the following statement is correct?
(1) Liquids have definite volume but not the definite
shape 12. Which one of the following cannot be separated by
(2) Gases have neither definite volume nor definite the process of sublimation?
shape (1) camphor
(3) Both A and B (2) Iodine
(4) None of the above (3) Ammonium chloride
(4) Copper sulphate
5. A measured temperature on Fahrenheit scale is 300°.
What will this reading be on Celsius scale? 13. Blood is
(1) 40°C (2) 94°C (1) Homogeneous Mixture
(3) 148.8°C (4) 30°C (2) Heterogeneous Mixture
(3) Both A & B
6. At what temperature are Celsius and Fahrenheit the (4) None of these
same?
(1) –30 (2) 30 14. If the speed of light is 3.0  10 ms–1, calculate the
8

(3) –40 (4) 40 distance covered by light in 2.00 ns.


(1) 0.060m (2) 6.00m
7. Convert 30 cm3 to dm3. (3) 0.600m (4) 0.006m
(1) 0.03 (2) 0.003
(3) 0.30 (4) 30 15. Which of the following conditions is most favorable
for converting a gas into liquid?
8. Vanadium metal is added to steel to impart strength.
(1) High pressure, low temperature
The density of vanadium is 5.96 g/cm3. Express this in
(2) Low pressure, low temperature
the SI unit.
(3) Low pressure, high temperature
(1) 5.96 × 103 (2) 59.6 × 103
3
(4) High pressure, high temperature
(3) 596 × 10 (4) 0.596 × 103
2

16. Pressure is determined as force per unit area of the 24. 1mole of atom X has mass, 0.444 times the mass of 1
surface. The SI unit of pressure, pascal is as shown mole of atom Y. Atomic mass of X is 2.96 times the
below: mass of one atom of C- 12. What is the atomic weight
1Pa = 1N m–2 of Y.
If mass of air at sea level is 1034 g cm–2, calculate the (1) 15.77 amu (2) 80 amu
pressure in pascal. (3) 46.66 amu (4) 40 amu
(1) 1.01332 104 Pa
25. 16 g of oxygen has same number of molecules as in
(2) 1.01332 105 Pa (1) 16 g of CO (2) 28 g of N2
(3) 10.01332 105 Pa (3) 24g of C2 (4) 1.0 g of H2
(4) 1.01332 106 Pa .
26. Calculate the mass of 6.022×1023 molecules of
Calcium Carbonate.
17. How many significant figures are in 0.0008?
(1) 50 g (2) 100 g
(1) 1 (2) 2
(3) 200 g (4) None of these
(3) 3 (4) 4

18. Round off 0.1525 upto three significant figures 27. The number of molecules in 89.6 liters of a gas at NTP
(1) 0.153 (2) 0.152 are
(3) 0.16 (4) 0.15 (1) 6.02 × 1023 (2) 2 × 6.02 × 1023
23
(3) 3 × 6.02 × 10 (4) 4 × 6.02 × 1023
19. The multiple 5× 0.2 after rounding off will be
28. Aspirin has the formula C9H8O4. How many atoms of
(1) 1 (2) 1.0
oxygen are there in a tablet weighing 360 mg?
(3) 1.00 (4) 1.000
(1) 1.204 × 1023 (2) 1.08 × 1022
(3) 1.204 × 1024 (4) 4.81 × 1021
20. Add (0.001 + 0.02) upto correct number of significant
figures
29. If Avogadro number NA, is changed from
(1) 0.021 (2) 0.02 6.022 × 1023 mol–1 to 6.022 × 1020 mol–1, this would
(3) 0.003 (4) 0.001 change
(1) the mass of one mole of carbon
21. When 200 g of lime stone is strongly heated, it (2) the ratio of chemical species to each other
undergoes thermal decomposition to form 112 g of in a balanced equation
lime an unknown mass of carbon dioxide gas as (3) the ratio of elements to each other in a
CaCO3 → CaO+ CO2 compound
200g 112g
(4) the definition of mass in units of grams
What will be the mass of CO2 formed?
(1) 88 g (2) 24 g 30. How many grams of calcium oxide is obtained on
(3) 64 g (4) 40 g heating 100 g of CaCO3(s)?
(1) 50 g (2) 40 g
22. Number of gm of oxygen in 32.2 g Na2SO4. 10H2O is (3) 56 g (4) 44 g
(1) 20.8 (2) 22.4
(3) 2.24 (4) 2.08 31. What is the maximum amount of nitrogen dioxide
that can be produced by mixing 4.2 gm of NO(g) and
23. The volume occupied by 4.4 g of CO2 at STP is 3.2 gm of O2(g)?
(1) 22.4 L (2) 2.24 L (1) 4.60 gm (2) 2.30 gm
(3) 0.224 L (4) 0.1 L (3) 3.22 gm (4) 6.44 gm
3

32. The volume CO2 evolved at STP on heating 50 g 40. According to the following reaction the minimum
CaCO3 quantity in gm of H2S needed to precipitate 63.5 gm of
(1) 11.2 litre (2) 22.4 litre Cu2+ ions will be nearly
(3) 5.6 litre (4) 24.4 litre Cu+2 + H2S → CuS + 2H+
(1) 63.5 g (2) 31.75 gm
33. What is the mass of glucose required to produce 44 g (3) 34 gm (4) 20 gm
of CO2 on complete combustion?
(1) 30 g (2) 45 g 41. A quantity of 2.76 g of silver carbonate on being
(3) 60 g (4) 22 g strongly heated yields a residue weighing (Ag = 108)
(1) 2.16 g (2) 2.48 g
34. 10g of MnO2 on reaction with HCl forms 2.24 L of (3) 2.32 g (4) 2.64 g
Cl2(g) at NTP, the percentage impurity of MnO2 is
MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O 42. How many grams of H2 are required to consume 2 mol
(1) 87% (2) 25% of CO?
(3) 33.3% (4) 13% CO(g) + 2H2(g) → CH3OH(g)
(1) 2 g (2) 4 g
35. 12 moles of each A & B are allowed to react as given: (3) 8 g (4) 16 g
1
3A + 2B → C + D. If 60g of D is produced then 43. Equal masses of iron and sulphur are heated together
2
to form FeS. What fraction of the original mass of
calculate the atomic mass of D.
excess reactant is left unreacted? (Fe = 56, S = 32)
(1) 30 (2) 45
(1) 0.22 (2) 0.43
(3) 60 (4) 15
(3) 0.86 (4) 0.57

36. The volume of O2 at STP required for the complete


44. The minimum mass of sulphuric acid needed for
combustion of 4g CH4 is
dissolving 3g of magnesium carbonate is
(1) 5.6 litre (2) 2.88 litre
(1) 3.5 g (2) 7.0 g
(3) 22.4 litre (4) 11.2 litre
(3) 1.7 g (4) 17.0 g

37. What is the weight of oxygen required for the complete


45. When a certain amount of octane, C8H18, is burnt
combustion of 2.8 kg of ethylene? completely, 7.04 g CO2 is formed. What is the mass of
(1) 2.8 kg (2) 6.4 kg H2O formed simultaneously?
(3) 9.6 kg (4) 96 kg (1) 1.62 g (2) 6.48 g
(3) 3.24 g (4) 2.28 g
38. The weight of AgCl precipitated when a solution
containing 5.85 g of NaCl is added to a solution 46. The minimum mass of water needed to slake 1 kg of
containing 3.4 g of AgNO3 is quicklime, assuming no loss by evaporation, is
(1) 28 g (2) 9.25 g (1) 243.2 g (2) 642.8 g
(3) 2.87 g (4) 58 g (3) 160.7 g (4) 321.4 g

39. 1.0 g magnesium is burnt with 0.56 g O2 in a closed 47. One fermi is
vessel. Which reactant is left in excess and how much? (1) 10–13 cm (2) 10–15 cm
(At. wt. Mg = 24, O = 16) (3) 10–10 cm (4) 10–12 cm
(1) Mg, 0.16 g (2) O2, 0.16 g
(3) Mg, 0.44 g (4) O2, 0.28 g 48. A picometre is written as
(1) 10–9 m (2) 10–10 m
(3) 10–11 m (4) 10–12 m
4

49. Significant figures in 0.00051 are 58. In gaseous state, molecules can move
(1) 5 (2) 3 (1) Only in one direction
(3) 2 (4) 4 (2) Only in fixed path
(3) Randomly in all directions
50. Hydrogen combines with oxygen to form H2O in (4) Upward and downward only
which 16 g of oxygen combine with 2g of hydrogen.
Hydrogen also combines with carbon to form CH4 in 59. The gases are highly compressible
which 2g of hydrogen combine with 6g of carbon. If because
carbon and oxygen combine together then they will
(1) the molecules move randomly
do show in the ratio of
(2) the molecular force of attraction is very weak
(1) 6 : 16 (2) 6 : 18
(3) The separation between molecules is very large
(3) 1 : 2 (4) 12 : 24
(4) The separating force is strong
51. 1m3 in equal to
(1) 100 litre (2) 10000 litre 60. The state of matter can be changed by varying
(3) 10 litre (4) 1000 litre (1) pressure (2) volume
(3) mass (4) temperature
52. Which of the following is/are in pure elemental form?
(1) CuSO4  5H2O (2) Brass 61. 44.8 L of SO2(g) weigh how much gram at STP?
(3) Diamond (4) All of these (1) 128 g (2) 95 g
(3) 24 g (4) 50 g
53. Mass of one atom of an element is
8 10g–24 . This is equal to 62. 11.2 L of O3(g) contains how many numbers of
molecules?
(1) 4.8 u (2) 48 u (1) NA molecules
(3) 0.048 u (4) 0.48 u (2) NA/2 molecules
(3) 2NA molecules
54. 1u is equal to
(4) 3NA molecules
–24
(1) 1.66  10 g (2) 1.66  10 –27 kg
1 63. Number of atoms present in 49 g of H2SO4?
(3) g (4) All of these
NA (1) NA/7 (2) 7NA
55. The weight of a molecule of the compound C6H12O6, is (3) 7NA/2 (4) 14NA
about:
(1) 180 g (2) 3 × 10–22g 64. Calculate number of oxygen atoms in 126 g of
(3) 22 × 10–22g (4) 132 g HNO3?
(1) 6NA (2) 12NA
56. What is the charge of 96 amu of S2– ? (3) 3NA (4) 14NA
(1) 2c
(2) 3.2 × 10–19C 65. Calculate total number of electrons in 88g of CO2?
(3) 9.6 × 10–19C (1) NA (2) 32U
(4) 6C (3) 44NA (4) 22 NA

57. Which state has maximum intermolecular force? 66. Calculate total number of valence electrons in 2.8 g
(1) Solid (2) Liquid of N3– ion
(3) Gas (4) Plasma
(1) 2.6 NA (2) 1.6 NA
(3) 7.8 NA (4) 0.8 NA
5

67. Calculate weight occupied by 12.04 × 1024 74. In Haber’s process 30 litre of dihydrogen and 30 L of
molecules of N2(g)? dinitrogen were taken for reaction which yielded only
(1) 280 g (2) 560 g 50% of expected product. What will be the
(3) 112 g (4) 200 g composition of gaseous mixture under the aforesaid
condition in the end.
68. What is the weight of oxygen required for the (1) N2(g) = 20 L; H2(g) = 0; NH3(g) = 20 L
complete combustion of 2.8 kg of ethylene? (2) N2(g) = 25 L; H2(g) = 30 L; NH3(g) = 10 L
(1) 2.8 kg (2) 6.4 kg (3) N2(g) = 25 L; H2(g) = 15 L; NH3(g) = 10 L
(3) 9.6 kg (4) 96 kg (4) N2(g) = 10 L; H2(g) = 25 L; NH3(g) = 15 L

75. Calculate charge on 1.6 g of O2– ion?


69. The amount of zinc required to produce 224 mL of
(1) 3.2 × 10–19C × NA
H2 at STP on treatment with dilute H2SO4 will be (2) 3.2 × 10–20C × NA
(1) 65 g (2) 0.065 g (3) 3.2 × 10–18C × NA
(3) 0.65 g (4) 6.5 g (4) 0.032 × 10–19C × NA

70. The mass of Mg3N2 produced if 48 gm of Mg metal 76. The mass of CO2(g) sample containing 16 g of carbon
is reacted with 34 gm NH3 gas is atoms?
Mg + NH3 ⎯→ Mg3N2 + H2 (1) 50 g (2) 58.6 g
200 100 (3) 42 g (4) 15 g
(1) gm (2) gm
3 3
400 150 77. What volume at STP of CO is required to reduce one
(3) gm (4) gm
3 3 mole of Fe2O3 in the following reaction
Fe2O3 + CO → Fe + CO2
71. What weight of CaCO3 must be decomposed to (1) 11200 cm3 (2) 22400 cm3
3
produce the sufficient quantity of carbon dioxide to (3) 67200 cm (4) 33600 cm3
convert 21.2 kg of Na2CO3 completely in to NaHCO3.
[Atomic mass Na = 23, Ca = 40] 78. A gas is found to contain 2.34 grams of nitrogen and
CaCO3 ⎯→ CaO + CO2 5.34 grams of oxygen. Simplest formula of the
compound is:
Na2CO3 + CO2 + H2O ⎯→ 2NaHCO3
(1) N2O (2) NO
(1) 100 kg (2) 20 kg
(3) N2O3 (4) NO2
(3) 120 kg (4) 30 kg

79. The molality of a sulphuric acid solution is 0.2


72. NX is produced by the following step of reactions:
mol/kg. Calculate the total weight of the solution:
M + X2 ⎯→ MX2
(1) 1098.6 g (2) 1098.6 g
3MX2 + X2 ⎯→ M3X8 (3) 980.4 g (4) 1019.6 g
M3X8 + N2CO3 ⎯→ NX + CO2 + M2O4
How much M (metal) is consumed to produce 206 g 80. What volume of a 0.8 M solution contains 100
of NX. (Take at wt. of M = 56, N = 23, X = 80) millimoles of the solute
(1) 42 g (2) 56 g (1) 100 mL (2) 125 mL
14 7 (3) 500 mL (4) 62.5 mL
(3) g (4) g
3 4
81. What volume of 0.4-M FeCl3.6H2O will contain 600
73. The mass of P4O10 produced if 440 gm of P4S3 is mg of Fe3+?
mixed with 384 gm of O2 is: (1) 49.85 mL (2) 26.78 mL
P4S3 + O2 ⎯→ P4O10 + SO2 (3) 147.55 mL (4) 87 65 mL
(1) 568 gm (2) 426 gm
(3) 284 gm (4) 369 gm
6

82. A sample of H2SO4 (Density : 1.8 g/mL) is 90% by (1) 18 cm3


weight. What is the volume of the acid that has to be (2) 22400 cm3 .
used to make 1 litre of 0.2 M H2SO4?
(3) 6.023 10−23 cm3
(1) 16 ml (2) 10 mL
(3) 12 mL (4) 18 mL (4) 3.0 10−23 cm3

83. The volume strength of a sample of H2O2 is ‘9.08 91. The number of atoms present in 16 g of oxygen gas
vol". The mass of H2O2 present in 250 ml of this is:
solution is (1) 6.02 1011.5 (2) 3.011023
(1) 0.4 g (2) 27.2 g (3) 3.011011.5 (4) 6.02 1023
(3) 6.8 g (4) 108.8 g
84. How much Ca(NO3)2 in mg. must be present in 50 ml
92. Number of atoms in 560 g of Fe
of a solution with 2.35 ppm of Ca? −1
(1) 0.1175 (2) 770.8 ( atomic mass 56 g mol ) is
(3) 4.7 (4) 0.48 (1) Twice that of 70 g N2
(2) Half that of 20 g H2
85. What volume of 0.8 M-A1Cl3 solution should be (3) Both are correct
mixed with 50 ml of 0.2 M-CaCl2 solution to get a (4) None of these
solution of chloride ion concentration equal to 0.6 M?
(1) 5.56 ml (2) 100 ml 93. How many H-atoms are present in 0.046 g of ethanol?
(3) 50 ml (4) 4.89 ml (1) 6 1020 (2) 1.2 1021
(3) 3  10 (4) 3.6 10
21 21

86. Determine the volume/volume percent solution made


by combining 25 mL of ethanol with enough water to 94. Number of atoms of oxygen present in 10.6 g of
produce 200 mL of the solution:
Na 2 CO 3 will be
(1) 12.5 (2) 20
(1) 6.02 10 (2) 12.04 10
23 22
(3) 40 (4) 25
(3) 1.806 10 (4) 31.80 10
23 28

87. What is the meaning of 10% solution of NaCl?


(1) 10 g NaCl in 100 gram of solution 95. Which has the highest mass?
(2) 58.5 grams of NaCl in 100 grams of solution (1) 1 g-atom of C
(3) 94 grams of NaCl in 100 grams of solution (2) 1/2 mole of CH4
(4) 5.85 grams ofH2O in 100 grams of solution (3) 10 mL of water
(4) 3.01110 atoms of oxygen
23
88. For preparing 0.1 M solution of H2SO4 in one litre,
we need H2SO4
96. The number of water molecules in 1 L of water is
(1) 0.98 g (2) 4.9 g
(1) 18 (2) 18 × 1000
(3) 49.0 g (4) 9.8 g
(3) NA (4) 55.55NA

89. Increasing the temperature of an aqueous solution


97. The least number of molecules are contained in:
will cause
(1) 2 g hydrogen (2) 8 g oxygen
(1) Decrease in molality
(3) 4 g nitrogen (4) 16 g CO2
(2) Decrease in molarity
(3) Decrease in mole fraction
(4) Decrease in % w/w

90. The volume occupied by one molecule of water


(density 1 g cm−3 ) is:
7

98. Arrange the following in the order of increasing mass 105. Find mass of 18.066 × 1023 molecules of NH3? (If
(atomic mass; O = 16, Cu = 63, N = 14) atomic mass of N and H are 14 and 1)
(I) One atom of oxygen (1) 51 g (2) 34 g
(II) One atom of nitrogen (3) 17 g (4) None of these
(III) 110−10 mole of oxygen
106. Find mass of CO2 which have same molecules as
(IV) 110−10 mole of copper
present in 68 g of NH3?
(1) II  I  III  IV
(1) 88 g (2) 176 g
(2) I  II  III  IV
(3) 44 g (4) 132 g
(3) III  II  IV  I
(4) IV  II  III  I 107. Find volume of CO2 (g) at STP if it weighs 88 g?
(Atomic mass of C and O are 12g and 32g)
99. The number of atoms in 4.25 g of NH3 is (1) 44.8 L (2) 67.2 L
approximately (3) 22.4 L (4) 89.6 L
(1) 6 1023 (2) 2 1023
108. Find total number of neutrons in 56 g of CO?
(3) 1.5 1023 (4) 1 10 23
If 12
6 C and 16
8 O if Avogadro’s No. = NA

100. Which sample contains the largest number of atoms? (1) 28 NA (2) 22 NA
(1) 1 mg of C4 H10 (2) 1 mg of N2 (3) 11 NA (4) None of these
(3) 1 mg of Na (4) 1 mL of water
109. Human lungs can absorb 8 gm O2 per hour by
respiration. If all oxygen atoms are converted to
101. 1 amu is equal to
carbohydrates (C6H12O6) how long will it take to
(1) 1.00758 g (2) 0.000549 g
produce 180 gm C6H12O6?
(3) 1.66 × 10–24 g (4) 6.02 × 10–23 g (1) 8 hours (2) 12 hours
(3) 10 hours (4) 6 hours
102. The mass of an atom of carbon –12 is :
(1) 1 g (2) 1.99 × 10–23 g 110. What is the total mass of products formed when 16
(3) 1/12 g (4) 1.99 × 1023 g grams of CH4 is burned with excess oxygen?
(1) 32 g (2) 36 g
103. An element, X has the following isotopic (3) 44 g (4) 80 g
composition,
111. Calculate the mass of hydrogen formed when 27 g of
200X : 90% aluminum reacts with excess hydrochloric acid
199X : 8% according to the balanced
202X : 2% equation below.
2Al + 6HCl → 2AlCl3 + 3H2
the weighted average atomic mass of the naturally-
(1) 1.5 g (2) 2.0 g
occuring element 'X' is closest to (3) 3.0 g (4) 6.0 g
(1) 201 amu (2) 202 amu
(3) 199 amu (4) 200 amu 112. How many grams of nitric acid, HNO3, can be
prepared from the reaction of 138 g of NO2 with 54.0
104. Calculate the mass of 2.5 gram atoms of oxygen. g H2O according to the equation below?
(1) 50.0 g (2) 70.0 g 3NO2 + H2O → 2HNO3 + NO
(3) 20.0 g (4) 40.0 g (1) 126 gm (2) 105 gm
(3) 136 cm (4) 120 gm
8

113. Which of the following contains the greatest number 121. 1 mole of atom X has mass, 0.444 times the mass of
of atoms? 1 mole of atom Y. Atomic mass of X is 2.96 times the
(1) 1.0 g of butane (C4H10) mass of one atom of C-12.what is the atomic weight
(2) 1.0 g of nitrogen (N2) of Y
(3) 1.0 g of silver (Ag) (1) 15.77 amu (2) 80 amu
(4) 1.0 g of water (H2O)
(3) 46.66 amu (4) 40 amu
114. A sample of aluminium has a mass of 54.0 g. What is
the mass of the same number of magnesium atoms? 122. What is the meaning of 10% solution of NaCl?
(At. wt. Al = 27, Mg = 24) (1) 10 g NaCl in 100 gram of solution
(1) 12 g (2) 24 g (2) 58.5 grams of NaCl in 100 grams of solution
(3) 48 g (4) 96 g (3) 94 grams of NaCl in 100 grams of solution
(4) 5.85 grams of H2O in 100 grams of solution
115. The weight of a molecule of the compound C6H12O6
is 123. The molality of a sulphuric acid solution is 0.2.
(1) 1.09 × 10–21 g (2) 2.988 × 10–22 g Calculate the total weight of the solution having 1000
(3) 5.025 × 10–23 g (4) 16.023×10–23 g gm of solvent
(1) 1000 g (2) 1098.6 g
116. 5.6 litre of oxygen at STP contains
(3) 980.4 g (4) 1019.6 g
(1) 6.02 × 1023 atoms
(2) 3.01 × 1023 atoms
(3) 1.505 × 1023 atoms 124. Volume of CO2 obtained at STP by the complete
(4) 0.7525 × 1023 atoms decomposition of 9.85 g. BaCO3 is
(1) 2.24 lit (2) 1.12 lit
117. A person adds 1.71 gram of sugar (C12H22O11) in (3) 0.84 lit (4) 0.56 lit
order to sweeten his tea. The number of carbon atoms
added are (mol. mass of sugar = 342) 125. The volume of oxygen required for complete
(1) 3.6 × 1022 (2) 7.2 × 1021 combustion of 20 ml of ethene is
(3) 0.05 (4) 6.6 × 1022 (1) 30 ml (2) 60 ml
(3) 40 ml (4) 50 ml
118. Which one of the following pairs of gases contains
the same number of molecules 126. What weight of CaCO3 must be decomposed to
(1) 16 g of O2 and 14 g of N2 produce the sufficient quantity of carbon dioxide to
(2) 8 g of O2 and 22 g of CO2 convert 21.2 kg of Na2CO3 completely in to NaHCO3.
[Atomic mass Na = 23, Ca = 40]
(3) 28 g of N2 and 22 g of CO2
CaCO3 → CaO + CO2
(4) 32 g of O2 and 32 g of N2
Na2CO3 + CO2 + H2O → 2NaHCO3
(1) 100 kg (2) 20 kg
119. The number of water molecules present in a drop of
(3) 120 kg (4) 30 kg
water (volume 0.0018 ml) at room temperature is
(1) 6.023 × 1019 (2) 1.084 × 1018
17
127. The volume of gas at NTP produced by 100g of CaC2
(3) 4.84 × 10 (4) 6.023 × 1023
with water
(1) 70 litre (2) 35 litre
120. 1 amu is equal to
(3) 17.5 litre (4) 22.4 litre
1 1
(1) of C − 12 (2) of O − 16
12 14 128. How many grams of SO3 are produced from 1 mol of
(3) 1g of H2 (4) 1.66 × 10–23 kg S8?
(1) 1280.0 (2) 640.0
(3) 960.0 (4) 320.0
9

129. If 1/2 moles of oxygen combine with aluminium to 133. The volume of water that must be added to a mixture
form Al2O3 then weight of Aluminium metal used in of 250 ml of 0.6 M HCl and 750 ml of 0.2 M HCl to
the reaction is (Al = 27) obtain 0.25 M solution of HCl is
(1) 27 g (2) 18 g (1) 750 ml (2) 100 ml
(3) 54 g (4) 40.5 g (3) 200 ml (4) 300 ml

130. The mass of carbon anode consumed (giving only 134. Calculate ate the weight of FeO produced from 6.7 g
carbon-dioxide) in the production of 270 Kg of VO & 4.8 g Fe2O3 VO + Fe2O3 → FeO +V2O5
aluminium metal from bauxite by the Hall process is (At. wt. of V = 51, At. wt. of Fe = 56)
(1) 180 kg (2) 270 kg (1) 4.32 (2) 7.755
(3) 240 kg (4) 90 kg (3) 2.585 (4) 0.0718

131. 4 g of hydrogen is ignited with 4 g of oxygen, the 135. The weight of lime obtained by heating 200 kg of
amount of water formed is? 95% pure lime stone is
(1) 2.5 g (2) 0.5 g (1) 98.4 kg (2) 106.4 kg
(3) 4.5 g (4) 8 g (3) 112.8 kg (4) 122.6 kg

132. Calculate the amount of H2 which is left unreacted in 136. 20 volume H2O2 solution has a strength of about
the given reaction: (1) 30% (2) 6%
2H2 + O2 → 2H2O (3) 3% (4) 10%
If 8 g of H2 is mixed with 16 g O2?
(1) 3 g (2) 6 g 137. 1 ml of H2O2 solution gives 10 ml of O2 at NTP. It is
(3) 1 g (4) 4 g (1) 10 vol. H2O2 (2) 20 vol. H2O2
(3) 30 vol. H2O2 (4) 40 vol. H2O2

Law of Conservation of Mass

138. The law of conservation of mass is valid for all the 140. Which of the following is the best example of law
following, except of conservation of mass
(1) All chemical reactions (1) 12 g of carbon combines with 32 g of oxygen
(2) Nuclear reactions to form 44 g of CO2
(3) Endothermic reactions (2) When 12 g of carbon is heated in a vacuum
(4) Exothermic reactions there is no change in mass
(3) A sample of air increases in volume when
139. After a chemical reaction, the total mass of heated at constant pressure but its mass
reactants and products remains unaltered
(1) Is always increased (4) The weight of a piece of platinum is the same
(2) Is always decreased before and after heating in air
(3) Is not changed
(4) Is always less or more 141 A sample of pure carbon dioxide, irrespective of its
source contains 27.27% carbon and 72.73%
oxygen. The data support
(1) Law of constant composition
(2) Law of conservation of mass
(3) Law of reciprocal proportions
(4) Law of multiple proportions
10

142. n g of substance X reacts with m g of substance Y 144. Chemical equation is balanced according to the law
to form p g of substance R and q g of substance S. of
This reaction can be represented as X+Y=R+S. The (1) Multiple proportion
relation which can be established in the amounts of (2) Reciprocal proportion
the reactants and the products will be (3) Conservation of mass
(1) n – m = p – q (4) Definite proportions
(2) n + m = p + q
(3) n = m
(4) p = q

143. 𝑛 g of substance X reacts with 𝑚 g of substance Y to


form 𝑝 g of substance R and 𝑞 g of substance S. This
reaction can be represented as, X + Y = R + S .The
relation which can be established in the amounts of
the reactants and the products will be
(1) n –m = p –q
(2) n + m = p + q
(3) n = m
(4) p=q

Law of Definite Proportions

145. The percentage of hydrogen in water and hydrogen 147. The percentage of copper and oxygen in samples of
peroxide is 11.1 and 5.9 respectively. These figures CuO obtained by different methods were found to be
illustrate the same. This illustrates the law of
(1) Law of multiple proportions (1) Constant proportions
(2) Law of conservation of mass (2) Conservation of mass
(3) Law of constant proportions (3) Multiple proportions
(4) Law of combining volumes (4) Reciprocal proportions

146. The law of definite proportions is not applicable to 148. How A sample of calcium carbonate (CaCO3) has the
nitrogen oxide because following percentage composition: Ca = 40%;
(1) Nitrogen atomic weight is not constant C = 12%; O = 48%
(2) Nitrogen molecular weight is variable If the law of constant proportions is true, then the
(3) Nitrogen equivalent weight is variable weight of calcium in 4 g of a sample of calcium
(4) Oxygen atomic weight is variable carbonate obtained from another source will be
(1) 0.016 g (2) 0.16 g
(3) 1.6 g (4) 16 g
11

Law of Multiple Proportions

149. Cu forms two oxides cuprous and cupric oxides, which 154. Among the following pairs of compounds, the one
law can be proved by the weights of Cu and O? that illustrates the law of multiple proportions is
(1) Constant composition (1) NH3 and NCl3
(2) Multiple proportions (2) H2 S and SO2
(3) Reciprocal proportions (3) CuO and Cu2 O
(4) CS2 and FeSO4
(4) Definite proportions
155. Which of the following pairs of substances
illustrate the law of multiple proportions
150. Which of the following pairs of compound (1) CO and CO2
illustrate law of multiple proportions? (2) H2O and D2O
(1) KOH, CsOH (3) NaCl and NaBr
(4) MgO and Mg(OH)2
(2) H2O, D2O
(3) Ethane, benzene 156. 1.0 g of an oxide of A contained 0.5 g of A. 4.0 g of
(4) KCI, KBr another oxide of A contained 1.6 g of A. The data
indicate the law of
(1) Reciprocal proportions
151. Element X forms five stable oxides with oxygen of (2) Constant proportions
formula X2O, XO, X2O3, X2O4, X2O5. The (3) Conservation of energy
formation of these oxides explains (4) Multiple proportions
(1) Law of definite proportions
157. 2g of hydrogen combine with 16g of oxygen to
(2) Law of partial pressures form water and with 6g of carbon to form methane.
(3) Law of multiple proportions In carbon dioxide 12g of carbon are combined with
(4) Law of reciprocal proportions 32g of oxygen. These figures illustrate the law of
(1) Multiple proportions
(2) Constant proportions
152. Two samples of lead oxide were separately reduced (3) Reciprocal proportions
to metallic lead by heating in a current of hydrogen. (4) Conservation of mass
The weight of lead from one oxide was half the
weight of lead obtained from the other oxide. The 158. A sample of pure carbon dioxide, irrespective of its
source contains 27.27% carbon and 72.73%
data illustrates
oxygen. The data support
(1) Law of reciprocal proportions (1) Law of constant composition
(2) Law of constant proportions (2) Law of conservation of mass
(3) Law of multiple proportions (3) Law of reciprocal proportions
(4) Law of equivalent proportions (4) Law of multiple proportions

159. Which of the following pairs of substances


153. Different proportions of oxygen in the various
illustrate the law of multiple proportions
oxides of nitrogen prove the
(1) CO and CO2
(1) Equivalent proportion (2) H2O and D2O
(2) Multiple proportion (3) NaCl and NaBr
(3) Constant proportion (4) MgO and Mg(OH)2
(4) Conservation of matter
12

160. 1.0 g of an oxide of A contained 0.5 g of A. 4.0 g 162. Two samples of lead oxide were separately reduced
of another oxide of A contained 1.6 g of A. The data to metallic lead by heating in a current of hydrogen.
indicate the law of The weight of lead from one oxide was half the
(1) Reciprocal proportions weight of lead obtained from the other oxide. The
(2) Constant proportions data illustrates
(3) Conservation of energy (1) Law of reciprocal proportions
(4) Multiple proportions (2) Law of constant proportions
(3) Law of multiple proportions
161. Among the following pairs of compounds, the one (4) Law of equivalent proportions
that illustrates the law of multiple proportions is
(1) NH3 and NCl3 (2) H2S and SO2
(3) CuO and Cu2O (4) CS2 and FeSO4

Gay Lussac’s Law of Gaseous Volumes, & Avogadro’s Law

163. Equal volume of different gases at any definite 166. Which one of the following pairs of gases contains
temperature and pressure have the same number of molecules?
(1) Equal atoms (1) 16 g of O2 and 14 g of N2
(2) Equal masses (2) 8 g of O2 and 22 g of CO2
(3) Equal densities (3) 28 g of N2 and 22 g of CO2
(4) Equal molecules (4) 32 g of O2 and 32 g of N2

164. Gay Lussac’s law is not valid in the chemical 167. Volume occupied by one molecule of water
reaction: (density = 1g cm–3) is
(1) H2(g) + Cl2(g) → 2HCl(g) (1) 9.0 × 10–23 cm3
(2) 3H2(g) + N2(g) → 2NH3(g) (2) 6.023 × 10–23 cm3
(3) 2SO2(g) + O2(g) → 2SO3(g) (3) 3.0 × 10–23 cm3

(4) CaCO3(s)→CaO(s) + CO2(g) (4) 5.5 × 10–23 cm3

168. How many years it would take to spend one


165. Which of the following represents Avogadro’s
Avogadro’s number of rupees at a rate of 10 lakh of
hypothesis?
rupees in one second?
(1) Gases react together in volumes which bear a
(1) 1.90 × 109 (2) 1.90 × 1010
simple ratio to one another
(3) 1.90 × 1011 (4) 1.90 × 1012
(2) Equal volumes of all gases under same
conditions of temperature and pressure contain 169. A sample of calcium carbonate (CaCO3) has the
equal number of molecules following percentage composition: Ca = 40%; C =
(3) Equal volumes of all gases under same 12%; O = 48%. If the law of constant proportions is
conditions of temperature and pressure contain true, then the weight of calcium in 4 g of a sample of
calcium carbonate obtained from another source will
equal number of atoms be
(4) The rates of diffusion of gases are inversely (1) 0.016 g (2) 0.16 g
proportional to the square root of their densities (3) 1.6 g (4) 16 g
13

170. An atoms has 26 electrons and its atomic weight is 171. An element X has the following isotopic composition
56. The number of neutrons in the nucleus of the atom :
200
will be X : 90%
199
(1) 26 (2) 30 X : 8.0%
202
(3) 36 (4) 56 X : 2.0%
The weighted average atomic mass of the naturally
occurring element X is closest to
(1) 199 amu (2) 202 amu
(3) 201 amu (4) 200 amu

Dalton’s Atomic Theory, Atomic Mass,Gram Atomic Mass, Average Atomic Mass,
Molecular Mass,Gram Molecular Mass, Molar Mass,Formula Mass

172. The modern atomic weight scale is based on 178. Which of the following atom has more electrons than
(1) 12C (2) 16O neutrons?
1
(3) H (4) 13C (1) C (2) F–
(3) O2− (4) Al3+
173. One ‘u’ stands for the mass of
(1) An atom of carbon-12 179. The molecular weight of SO 24− is
(2) 1/12th of carbon-12
(1) 192 u (2) 48 u
(3) 1/12th of hydrogen atom
(3) 96 u (4) 24 u
(4) One atom of any of the elements

180. The molar mass of ferrus sulphate (FeSO4.7H2O) is


174. Mass of 1 amu in g
(1) 152gm (2) 278gm
(1) 1.66×1024 (2) 1.66×10–24
(3) 137gm (4) None of these
(3) 1.008 (4) 9.1×10–28

181. Atomic weight of chlorine is 35.5. It has two isotopes


175. Which property of an element is always a whole
of atomic weight 35 and 37. What is the percentage
number?
of the heavier isotope in the sample?
(1) Atomic weight
(1) 5 (2) 10
(2) Equivalent weight
(3) 25 (4) 20
(3) Atomic number
(4) Atomic volume 10 11
182. B has two isotopes B (19%) and B (81%). The
atomic mass of B is
176. The number of particles present in 1 mol of nitrogen
(1) 10.81 (2) 11.5
atom are
(3) 11 (4) 10.5
(1) 6.022×1025
(2) 6.022×1024
183. If an element Z exist in two isotopic form Z50 and Z52.
(3) 6.022×1023
The average atomic mass of Z is 51.7. Calculate the
(4) 6.022×1022
abundance of each isotopic forms
(1) Z50 (15%), Z52 (85%)
177. The ratio between the neutrons in C and Si with
(2) Z50 (85%), Z52 (15%)
respect to atomic masses 12 and 28 is
(3) Z50 (5%), Z52 (95%)
(1) 2:3 (2) 3:2
(4) Z50 (95%), Z52 (5%)
(3) 3:7 (4) 7:3
14

184. Number of atoms in 4.25 g of NH3 is 192. Which of the following statement is correct?
(1) 6.023 × 1023 (1) 28g CO contains 12 g carbon and 16 g
(2) 4 × 6.023 × 1023 oxygen
(3) 1.7 × 1024 (2) One mole of CO reacts completely with
(4) 4.5 × 6.023 × 1023 half mole of O2 to form CO2
(3) N2 and CO have same molar mass
185. The number of water molecules is maximum in (4) All of these
(1) 1.8 gram of water
(2) 18 gram of water 193. 0.9 g Al reacts with dil. HCl to give H2. The volume
(3) 18 moles of water of H2 evolved at STP is (Atomic weight of Al = 27)
(4) 18 molecules of water (1) 1.12 litre (2) 2.24 litre
(3) 3.33 litre (4) 4.44 litre
186. If mass of one atom is 3.32 × 10–23 g, then calculate
number of nucleons (neutrons and protons) present in 194. In metal oxide, metal is 53% & vapour density of
2 atoms of the element M(Cl)x is 66. Then find atomic mass of metal.
(1) 40 (2) 20 (1) 9 (2) 3
(3) 10 (4) 40 NA (3) 18 (4) 27

187. The number of water molecules present in a drop of 195. Same as repeated Q. No. 189
water weighing 0.018 g is
(1) 6.022 × 1026 (2) 6.022 × 1019 196. Which is not a basic postulate of Dalton’s atomic
(3) 6.022 × 1023 (4) 6.022 × 1020 theory ?
(1) Atoms are neither created nor destroyed in a
188. Percentage of Se in peroxidase anhydrous enzyme is chemical reaction.
0.5% by weight (At. Wt. = 78.4) then minimum (2) Different elements have different types of
molecular weight of peroxidase anhydrous enzyme is atoms.
(1) 1.568 × 104 (2) 1.568 × 103 (3) Atoms of an element may be different due to
(3) 15.68 (4) 2.136 × 104 presence of isotopes.
(4) Each element is composed of extremely small
189. If mass % of oxygen in monovalent metal ‘M’
particles called atoms
carbonate (M2CO3) is 48%. Find atomic mass of
metal?
197. Gram molecular mass of H2S is
(1) 20 (2) 40
(1) 34 g (2) 32g
(3) 30 (4) 10
(3) 34 u (4) 32 u
190. What is the meaning of 10% solution of NaCl?
(1) 10 g NaCl in 100 grams of solution 198. 3.011 × 1022 atoms of an element weighs 1.15 gm.
(2) 58.5 grams of NaCl in 100 grams of solution The atomic mass of the element is:
(3) 94 grams of NaCl in 100 grams of solution (1) 10 amu (2) 2.3 amu
(4) 5.85 grams of H2O in 100 grams of solution (3) 35.5 amu (4) 23 amu

191. What is the concentration of solution in ppm when 199. It is known that atom contain protons, neutrons and
5.0 × 10-5 gm CO2 is dissolved in 100 ml solution? electrons. If the mass of neutron is assumed to half of
(1) 0.5 (2) 5 its original value whereas that of proton is assumed
(3) 500 (4) 5 × 10-5 to be twice of its original value then the atomic mass
of 146C will be:
(1) Same (2) 14.28% less
(3) 14.28% more (4) 28.56% less
15

200. Unit of intensity is 207. Atomic mass of boron is 10.81. It has two isotopes
(1) Mole (2) Candela with 80% and 20% abundance respectively. The
(3) Kg (4) Ampere atomic mass of the isotope having 80% abundance is
11.01. The atomic mass of the other isotope is:
201. An atom of an element weigh 6.4 × 10–23 g. Number (1) 10.80 (2) 11.01
of gram atoms present in 30 Kg of it? (3) 10.01 (4) 21.82
(1) 650 (2) 700
(3) 778 (4) 540 208. Naturally occuring chlorine is 75% Cl35 which has
an atomic mass of 35 amu and 25% Cl37 which has
202. Myoglobin stores oxygen for metabolic process in a mass of 37 amu. Calculate the average atomic mass
muscle. Chemical analysis shows that it contains of chlorine –
0.32% Fe by mass. If there is one Fe atom per (1) 35.5 amu (2) 36.5 amu
molecule of myoglobin, what is the molar mass of (3) 71 amu (4) 72 amu
myoglobin? [At. Mass of Fe = 56 u]
(1) 1.75 × 104 g/mol 209. Carbon occur in nature as a mixture of C12 and C13.
(2) 3.5 × 105 g/mol Average atomic mass of carbon is 12.011 what is the
(3) 1 × 104 g/mol % aboundance of C12 in nature?
(4) 2.5 × 105 g/mol (1) 99.8% (2) 98.9%
(3) 97.6% (4) 98.5%
203. The nucleus of the element having atomic number 25
and atomic weight 55 will contain 210. Boron has two isotopes boron-10 and boron-11
(1) 25 protons and 30 neutrons whose percentage abundances are 19.6% and 80.4%
(2) 25 neutrons and 30 protons respectively. What is the average atomic mass of
(3) 55 protons boron?
(4) 55 neutrons (1) 10.8 (2) 10.6
(3) 9.6 (4) None of these
204. Choose the wrong statement.
(1) 1 mole means 6.023× 1023 particles 211. If the atomic mass of Sodium is 23, the number of
(2) Molar mass is mass of one molecule moles in 46 g of sodium is
(3) Molar mass is mass of one mole of a substance (1) 1 (2) 2
(4) Molar mass is molecular mass expressed in (3) 2.3 (4) 4.6
grams
212. The total number of g-molecules of SO2Cl2 in 13.5 g
205. Number of atoms of He in 100 u of He (atomic weight of sulphuryl chloride is
of He is 4) are (1) 0.1 (2) 0.2
(1) 25 (2) 100 (3) 0.3 (4) 0.5
(3) 50 (4) 100 × 6 × 10–23
213. Number of atoms in 560g of Fe (atomic mass 56 g
206. Atomic mass of chlorine is 35.5. It has two isotopes mol–1) is
of atomic mass 35 and 37. The percentage of heavier (1) Twice that of 70g N
isotope is: (2) Half that of 20g H
(1) 10 (2) 15 (3) Both (1) and (2)
(3) 20 (4) 25 (4) None of these

214. Which property of an element is always a whole


number?
(1) Atomic weight (2) Equivalent weight
(3) Atomic number (4) Atomic volume
16

215. The modern atomic weight scale is based on 218. He has two naturally occurring isotopes He –3 and
(1) C12 (2) O16 He –4. The average atomic mass of helium is 3.98
(3) H1 (4) C13 amu which isotope is more abundant in nature
(1) He – 4
216. Boron has two stable isotopes, 10B (19%) and 11B (2) He – 3
(81%). The atomic mass that should appear for boron (3) both are equally abundant
in the periodic table is (4) none of these
(1) 10.8 (2) 10.2
(3) 11.2 (4) 10.0 219. The mass of 70% H2SO4 required for neutralization
of one mole of NaOH is
217. If an element Z exist in two isotopic form Z50 and Z52 (1) 70 g (2) 35 g
The average atomic mass of Z is 51.7. Calculate the (3) 30 g (4) 95 g
abundance of each isotopic forms
(1) Z50 (15%), Z52 (85%)
(2) Z50 (85%), Z52 (15%)
(3) Z50 (5%), Z52 (95%)
(4) Z50 (95%), Z52 (5%)

Moles, Atoms and electrons, Equation based problems


17

220. Chlorine atom differs from chloride ions in the 230. The total number of protons in 10 g of calcium
number of carbonate is (NA = 6.023 ×1023)
(1) Proton (2) Neutron (1) 1.5057 × 1024
(3) Electrons (4) Protons and electrons (2) 2.0478 × 1024
(3) 3.0115 × 1024
221. The nitrogen atom has 7 protons and 7 electrons, (4) 4.0956 × 1024
the nitride ion (N3–) will have
(1) 7 protons and 10 electrons 231. If 1021 molecules are removed from 200 mg of
(2) 4 protons and 7 electrons CO2, then the number of moles of CO2 left are
(3) 4 protons and 10 electrons
(1) 2.85 × 10–3
(4) 10 protons and 7 electrons
(2) 28.8 × 10–3
(3) 0.288 × 10–3
222. The mass of one molecule of water is
(4) 1.68 × 10–2
approximately
(1) 3×10–23 g (2) 18 g
–23 232. The number of atoms in 0.1 mol triatomic gas is
(3) 1.5×10 g (4) 4.5×10–23 g
(NA = 6.02 × 1023 mol–1)
223. 1 mol of CH4 contains (1) 6.026 × 1022 (2) 1.806 × 1023
23
(1) 6.02 ×1023 atoms of H (3) 3.6 × 10 (4) 1.8 × 1022
(2) 4 g atom of Hydrogen
(3) 1.81 × 1023 molecules of CH4 233. One atom of an element x weighs 6.643 × 10–23 g.
(4) 3.0 g of carbon Number of moles of atoms in its 20 kg is
(1) 4 (2) 40
224. The number of moles of sodium oxide in 620 g of (3) 100 (4) 500
it is
(1) 1 mol (2) 10 moles 234. Which one of the following is the lightest?
(3) 18 moles (4) 100 moles (1) 0.2 mole of hydrogen gas
(2) 6.023 × 1022 molecules of nitrogen
225. The number of moles of nitrogen atom in 56 g (3) 0.1 g of silver
nitrogen gas is (4) 0.1 mole of oxygen gas
(1) 2 mol (2) 4 mol
(3) 8 mol (4) 10 mol 235. Arrange the following in the order of their
increasing masses.
226. The number of mole of N-atom in 18.066 × 1023 I. One atom of oxygen
nitrogen atoms is II. One atom of nitrogen
(1) 1 mol (2) 2 mol III. 1 × 10–10 mole of oxygen
(3) 3 mol (4) 4 mol (1) II < I < III (2) I < II < III
(3) III < II < I (4) II < III < I
227. What weight in grams is represented by 1.5 moles
of Sulphur dioxide? 236. How many molecules are there in one drop of water
(1) 60 g (2) 74 g if 1 mL of water contains 20 drops?
(3) 96 g (4) 91 g (1) 4.324 × 1023 (2) 1.673 × 1021
(3) 6.023 × 1023 (4) 6.023 × 1021
228. The number of atoms in 20 g of SO3 is
approximately 237. How many moles of HCl are present in 1 litre of 1
(1) 1 × 1023 (2) 1.5 × 1023 M HCl solution?
(3) 2 × 10 23
(4) 6 × 1023 (1) 2 mole (2) 3 mole
(3) 1 mole (4) 5 mole

229. The number of electrons in 3.1mg NO3− is: 238. A sample of ammonium phosphate (NH4)3PO4
(1) 32 (2) 1.6 × 10–3 contains 3.18 moles of hydrogen atoms. The
(3) 9.6 × 1020 (4) 9.6 × 1023 number of moles of oxygen atoms in the sample is
(1) 0.265 (2) 0.795
18

(3) 1.06 (4) 4.00


247. Calculate total number of electrons and protons in
239. Limiting reagent in a chemical reaction is that 32g of SO2
reactant which (1) 32 NA (2) 64 NA
(1) Left some amount unreacted after the (3) 16 NA (4) 8 NA
completion of reaction
(2) Reacts completely in the reaction 248. The number of moles of Ca(HCO3)2 required to
(3) Does not react in the reaction prepare 1.50 moles of CO2, according to the
(4) All of these equation Ca(HCO3)2 + 2HCl → CaCl2 + 2CO2 +
2H2O is
240. 8 g H2 and 32 g O2 is allowed to react to form water (1) 1.00 mol (2) 2.00 mol
then which of the following statement is correct? (3) 0.750 mol (4) 1.50 mol
(1) O2 is limiting reagent
(2) O2 is reagent in excess 249. The reaction between aluminium metal and dilute
(3) H2 is limiting reagent hydrochloric acid produces H2(g) and Al3+ ions.
(4) 40 g water is formed The molar ratio of aluminium used to hydrogen
produced is
241. The number of moles of ‘B’ required to produce (1) 1 : 2 (2) 2 : 1
2.5 mole of AB4 according to equation: A + 4B → (3) 2 : 3 (4) 3 : 2
AB4
(1) 1 (2) 10 250. The number of moles of oxygen obtained by the
(3) 5 (4) 15 electrolytic decomposition of 90 g water is
elec.
(2H2O → 2H2 + O2)
242. How many moles of lead (II) chloride will be (1) 2.5 (2) 5
formed from a reaction between 6.5 g of PbO and (3) 7.5 (4) 10
3.2 g of HCl?
(1) 0.029 (2) 0.044 251. How many mole of Zn(FeS2) can be made from 2
(3) 0.333 (4) 0.011 mole zinc, 3 mole iron and 5 mole Sulphur.
(1) 2 mole (2) 3 mole
243. Equal volume of N2 and H2 react to form ammonia (3) 4 mole (4) 5 mole
under suitable condition then the limiting reagent
is 252. 0.5 mole of H2SO4 is mixed with 0.2 mole of
(1) H2 Ca(OH)2. The maximum number of moles of
(2) NH3 CaSO4 formed is
(3) N2 (1) 0.2 (2) 0.5
(4) No one reactant is limiting reagent (3) 0.4 (4) 1.5
253. If 1/2 moles of oxygen combine with aluminium to
244. For the reaction: form Al2O3 then weight of aluminium metal used
7A + 13B + 15C → 17P in the reaction is (Al = 27)–
If 15 moles of A, 26 moles of B & 30.5 moles of C (1) 27 g (2) 18 g
are taken initially then limiting reactant is (3) 54 g (4) 40.5 g
(1) A (2) B
(3) C (4) None of these

245. Maximum number of moles are present in


(1) 49 g of H2SO4 (2) 63 g of HNO3
(3) 8.8 g of CO2 (4) 192 g of SO42–
246. Calculate the minimum number of moles in which
option?
(1) 18.06 × 1023 atom of C
(2) 12.04 × 1023 ions of SO42–
(3) 24.08 × 1023 ions of SO42–
(4) 3.01 × 1023 molecules of O3
19

254. 10g H2 reacts with 64g of O2 determine number of 262. Sodium atom differs from sodium ion in the
moles of gaseous product formed. number of
(1) 1 mole (2) 4 mole (1) Electron (2) Protons
(3) 3 mole (4) 5 mole (3) Neutrons (4) Does not differ

255. NH3 contains 12 moles of hydrogen. Calculate 263. The atomic number of an element represents
moles of nitrogen present in it (1) Number of neutrons in the nucleus
(1) 12 moles (2) 3 moles (2) Number of protons in the nucleus
(3) 4 moles (4) 5 moles (3) Atomic weight of element
(4) Valency of element
256. K4[Fe(CN)6] contains 2 moles. Calculate number
of moles of nitrogen in it?
264. Chlorine atom differs from chloride ion in the
(1) 6 mole (2) 12 mole
number of
(3) 3 mole (4) 9 mole
(1) Proton (2) Neutron
257. 10 g of hydrogen reacts with 64 g of oxygen to (3) Electrons (4) Protons and electrons
form ...... moles of water
(1) 2 (2) 4 265. The number of electrons in one molecule of CO2
(3) 6 (4) 8 are
(1) 22 (2) 44
3 (3) 66 (4) 88
258. The equation 2Al(s) + O2 ⎯⎯ → Al2O3 (s) shows
2
that
3 266. Same as repeated Q. No. 221
(1) 2 moles of aluminium react with moles of
2
oxygen to produce one mole of aluminium 267. The number of electrons in the atom which has 20
oxide protons in the nucleus is
3 (1) 20 (2) 10
(2) 2 atoms of aluminium react with atoms of
2 (3) 30 (4) 40
oxygen to produce one atom of aluminium
oxide 268. An atom which has lost one electron would be
3 (1) Negatively charged
(3) 2g of aluminium react with g of oxygen to
2 (2) Positively charged
produce 1 g of aluminium oxide (3) Electrically neutral
3 (4) Carry double positive charge
(4) 2g of aluminium react with litres of
2 269. Positive ions are formed from the neutral atom by
oxygen to the
produce 1 g of aluminium oxide
(1) Increase of nuclear charge
(2) Gain of protons
259. Number of neutrons in 1 molecule of CO2 are
(3) Loss of electrons
(1) 22 (2) 20
(4) Loss of protons
(3) 12 (4) 16

270. The nucleus of the atom consists of


260. Sum of proton, electron and neutron in1molecule
(1) Proton and neutron
of H2S2O8
(2) Proton and electron
(1) 290 (2) 292
(3) Neutron and electron
(3) 294 (4) 296
(4) Proton, neutron and electron
261. The number of electrons in Cl– ion is 271. The number of electrons in [19K40] is
(1) 19 (2) 20 (1) 19 (2) 20
(3) 18 (4) 35 (3) 18 (4) 40
20

272. In the nucleus of 20Ca40 there are produced. Assuming that the product formed can
(1) 40 protons and 20 electrons also be reused. Reactions are:
(2) 20 protons and 40 electrons A + 2Z→ B …(i)
(3) 20 protons and 20 neutrons B + C→ Z + F ...(ii)
(4) 20 protons and 40 neutrons (1) 3 moles (2) 4.5 moles
(3) 5 moles (4) 6 moles
273. Nitrogen atom has an atomic number of 7 and
oxygen has an atomic number 8. The total number 281. Write a balanced equation for the combustion of
of electrons in a nitrate ion (NO3–) will be acetaldehyde, CH3CHO. When properly
(1) 8 (2) 16 balanced, the equation indicates that
(3) 32 (4) 64 mole(s) of O2 are required for each
mole of CH3CHO.
274. One mole electron means: (1) 1 (2) 2
(1) NA electrons (3) 2.5 (4) 3
(2) 6.023 × 1023 electrons
(3) 0.55 mg electrons 282. Write a balanced equation for the combustion of
(4) All of these propane, C3H8. When balanced, the equation
indicates that ___ moles of O2 are required for
275. Mass of 0.1 mole of methane is each mole of C3H8.
(1) 1 g (2) 16 g (1) 1.5 (2) 3
(3) 1.6 g (4) 0.1 g (3) 35 (4) 5

276. Find total number of electrons in 51 g of NH3? If 283. How many moles of magnesium phosphate,
14
7 N and 1 H if Avogadro’s No. = NA
1
Mg3(PO4)2 will contain 0.25 mole of oxygen
(1) 20 NA (2) 30 NA atoms?
(3) 10 NA (4) 5 NA (1) 0.02 (2) 3.125 × 10–2
–2
(3) 1.25 × 10 (4) 2.5 × 10–2
277. According to the equation,
N2O3(g) + 6H2(g)→2NH3(g) + 3H2O(g) how many 284. How many moles of electron weigh one kilogram
moles of NH3(g) could be formed from the reaction 1
(1) 6.023 × 1023 (2) 1031
of 0.22 mol of N2O3 (g) with 0.87 mol of H2(g)? 9.108
(1) 0.29 mol (2) 0.44 mol 6.023 1
(3)  1054 (4) 108
(3) 0.73 mol (4) 1.1 mol 9.108 9.108  6.023

278. The number of moles of C and D produced on 285. The number of electron in 3.1 mg NO3 is
mixing 5 moles of A and 7 moles of B are (1) 32 (2) 1.6 × 10–3
respectively : (3) 9.3 × 1020 (4) 9.6 × 1023
(3A + 5B → 7C + 9D)
(1) 9 moles and 11 moles 286. The total number of protons in 10 g of calcium
(2) 11.66 moles and 15 moles carbonate is (N0 = 6.023 × 1023)
(3) 9.8 moles and 12.6 moles (1) 1.5057 × 1024 (2) 2.0478 × 1024
(4) 1 moles and 13 moles (3) 3.0115 × 1024 (4) 4.0956 × 1024

279. Find maximum moles of CCl4 formed when 10 287. The number of moles of sodium oxide in 620 g of
moles of CH4 undergoes chlorination with excess its is
of chlorine: (1) 1 mol (2) 10 moles
1CH4 + 4Cl2 → 1CCl4 + 4HCl (3) 18 moles (4) 100 moles
(1) 2 moles (2) 5 moles
(3) 8 moles (4) 10 moles

280. 5 moles of A, 6 moles of Z are mixed with


sufficient amount of C to finally produce F. Then
find the maximum moles of F which can be
21

288. 1 mol of CH4 contains 296. For the reaction 2P + Q → R, 8 mol of P and 5 mol
(1) 6.02 × 1023 atoms of H of Q will produce
(2) 4 g atom of Hydrogen (1) 8 mol of R (2) 5 mol of R
(3) 1.81× 1023 molecules of CH4 (3) 4 mol of R (4) 13 mol of R
(4) 3.0 g of carbon
297. 0.5 mole of H2SO4 is mixed with 0.2 mole of
289. Same as repeated Q. No. 220 Ca(OH)2. The maximum number of moles of
CaSO4 formed is
290. Same as repeated Q. No. 221 (1) 0.2 (2) 0.5
(3) 0.4 (4) 1.5
291. The ratio between the neutrons in C and Si with
respect to atomic masses 12 and 28 is 298. For the reaction: A + 2B → C
(1) 2 : 3 (2) 3 : 2 5 mole of A and 8 mole of B will produce
(3) 3 : 7 (4) 7 : 3 (1) 5 mole of C (2) 4 mole of C
(3) 8 mole of C (4) 12 mole of C
292. Which of the following atom has more electrons
than neutrons 299. Zinc and hydrochloric acid react according to the
(1) C (2) F– reaction.
2–
(3) O (4) Al3+ Zn(s) + 2HCl(aq.) → ZnCl2(aq.) + H2(g)
If 0.30 mole of Zn are added to hydrochloric acid
293. 1.2 g of Mg (At mass 24) will produce MgO equal containing 0.52 mole HCl, how many moles of H2
to are produced?
(1) 0.05 mol (2) 40 g (1) 0.26 (2) 1.04
(3) 40 mg (4) 4 g (3) 0.52 (4) 0.13

294. Butane, C4H10, burns with the oxygen in air to give 300. One mole of potassium chlorate (KClO3) is
carbon dioxide and water. thermally decomposed and excess of aluminium is
What is the amount (in moles) of carbon dioxide burnt in the gaseous product. How many mol of
produced from 0.15 mol C4H10? aluminium oxide (Al2O3) are formed?
C4H10(g) + O2(g) → CO2(g) + H2O(g) (1) 1 (2) 1.5
(not balanced) (3) 2 (4) 3
(1) 0.15 mol CO2
(2) 0.30 mol CO2 301. How many moles of lead (II) chloride will be
(3) 0.45 mol CO2 formed from a reaction between 6.5 g of PbO and
(4) 0.60 mol CO2 3.2 g of HCl?
(1) 0.044 (2) 0.333
295. If 0.5 mol of BaCl2 is mixed with 0.1 mole of (3) 0.011 (4) 0.029
Na3PO4, the maximum number of mole of
Ba3(PO4)2 that can be formed is 302. 1021 molecules are removed from 200 mg of CO2.
(1) 0.7 (2) 0.05 The mole of CO2 left are
(3) 0.30 (4) 0.10 (1) 2.88 × 10–2 (2) 28.2 × 10–3
(3) 2.88 × 10–3 (4) 28.8 × 103

303. The number of moles of oxygen obtained by the


electrolytic decomposition of 90 g water is
(1) 2.5 (2) 5
(3) 7.5 (4) 10
22

Percentage Composition ,Empirical formula ,Molecular formula

304. The percentage of nitrogen in urea is about 311. The empirical formula and molecular mass of a
(1) 46 (2) 85 compound are CH2O and 180 g respectively. What
(3) 18 (4) 28 will be the molecular formula of the compound?
(1) C9H18O9 (2) CH2O
305. The empirical formula of a compound is CH2O. (3) C6H12O6 (4) C2H4O2
0.0835 moles of the compound contains 1.0 g of
hydrogen. Molecular formula of the compound is
312. 0.30 g of an organic compound containing C, H
(1) C6H12O6 (2) C5H10O5
and O on combustion yields 0.44 g CO2 and 0.18 g
(3) C4H8O4 (4) C3H6O3
H2O. If one mol of compound weighs 60 g, then
306. A compound (80 g) on analysis gave C = 24 g, H = molecular formula of the compound is
4 g, O = 32 g. Its empirical formula is (1) C3H8O (2) C2H4O2
(1) C2H2O2 (2) C2H2O (3) CH2O (4) C4H6O
(3) CH2O2 (4) CH2O
313. What is the empirical formula of the compound
307. 2.2 g of a compound of phosphorous and Sulphur which has the following percentage composition:
has 1.24 g of ‘P’ in it. Its empirical formula is Carbon 80%, Hydrogen 20%. If the molecular
(1) P2S3 (2) P3S2 mass is 30, then also calculate molecular formula.
(3) P3S4 (4) P4S3 (1) CH3, C2H6 (2) C2H2, CH3
(3) C2H6, CH3 (4) CO3, CH3
308. An organic compound contains carbon, hydrogen
and oxygen. Its elemental analysis gave C, 38.71% 314. 2.2 g of a compound of phosphorous and Sulphur
and H, 9.67%. The empirical formula of the has 1.24 g of ‘P’ in it. Its empirical formula is:
compound would be (1) P2S3 (2) P3S2
(1) CH4O (2) CH3O (3) P3S4 (4) P4S3
(3) CH2O (4) CHO
315. An oxide of metal M has 40% by mass of oxygen.
309. An organic compound containing C, H and N gave
the following analysis C = 40%, H = 13.33%, N = Metal M has atomic mass of 24. The empirical
46.67%. Its empirical formula would be formula of the oxide.
(1) CH4N (1) M2O (2) M2O3
(2) CH5N (3) MO (4) M3O4
(3) C2H7N2
(4) C2H7N 316. Two oxides of a metal contains 50% and 40% of
the metal respectively. The formula of the first
310. An oxide of metal M has 40% by mass of oxygen. oxide is MO. Then the formula of the second oxide
Metal M has atomic mass of 24. The empirical is:
formula of the oxide. (1) MO2 (2) M2O3
(1) M2O (2) M2O3 (3) M2O (4) M2O5
(3) MO (4) M3O4
23

w/w %, w/v % , V/v %, mole fraction, molarity, normality

317. Carbon and oxygen react in ratio of 3:8 by mass to 326. 1.26 g of hydrated oxalic acid was dissolved in
form CO2. What weight of carbon should be used water to prepare 250 ml of solution. Calculate
to react completely with 32 g of oxygen? molarity of solution.
(1) 10 g (2) 15 g (1) 0.04 M (2) 0.02 M
(3) 12 g (4) 7 g (3) 0.01 M (4) 0.50 M

318. Calculate the mole percentage of CH3OH and H2O 327. Concentration of glucose (C6H12O6) in normal
respectively in 60% (by mass) aqueous solution of
blood is approximately 90 mg per 100 mL. What is
CH3OH.
the molarity of the glucose solution in blood?
(1) 45.8, 54.2 (2) 54.2, 45.8
(1) 5 M (2) 0.005 M
(3) 50, 50 (4) 60, 40
(3) 0.05 M (4) 1 M
319. Na2SO4 xH2O has 50% H2O by mass. Hence, x is
(1) 4 (2) 5 328. Mole fraction of solvent in aqueous solution of
(3) 6 (4) 8 NaOH having molality of 3 is
(1) 0.3 (2) 0.05
320. A polystyrene having the formula Br3C6H3 (C8H8)n, (3) 0.7 (4) 0.95
was prepared by heating styrene with tribromo
benzoyl peroxide in the absence of air. If it was 329. A solution contains 10 moles of sucrose in 1 kg of
found to contain 10.45% of bromine by mass. Find solvent. Calculate the molality of solution.
the value of n. (1) 10 mol kg–1 (2) 20 mol kg–1
(1) 15 (2) 20 (3) 4 mol kg–1 (4) 5 mol kg–1
(3) 19 (4) 12

321. Two oxides of a metal contain 36.4% and 53.4% of 330. Calculate the molality of solution containing 3 g
oxygen by mass respectively. If the formula of the glucose dissolved in 30 g of water. (molar mass of
first oxide is M2O, then that of the second is glucose = 180)
(1) M2O3 (2) MO (1) 0.50 m (2) 0.56 m
(3) MO2 (4) M2O5 (3) 0.091 m (4) 0.05 m

322. Molality is expressed in units of 331. How many grams of NaOH should be added to
(1) mol kg–1 (2) mol L–1 water to prepare 250 ml solution of 2 M NaOH?
(3) mol L–1 s–1 (4) mol1 g–1 s–1 (1) 9.6 × 103 (2) 2.4 × 103
(3) 20 (4) 24
323. Which of the following methods of expressing
concentration varies with temperature? M
(1) Molality (2) Weight percent 332. When 100 ml of H2SO4 is mixed with 500 ml
10
(3) Molarity (4) Mole fraction M
of NaOH then nature of resulting solution and
10
324. Increasing the temperature of an aqueous solution
normality of excess of reactant left is
will cause
N N
(1) Decrease in molality (1) Acidic, (2) Basic,
5 5
(2) Decrease in molarity
N N
(3) Decrease in mole fraction (3) Basic, (4) Acidic,
20 10
(4) Decrease in % w/w
333. 6.025 × 1020 molecules of acetic acid are present in
325. Calculate the volume by volume percentage of a 500 ml of its solution. The concentration of
solution of 15 ml of alcohol in 60 ml of water. solution is
(1) 20 (2) 25 (1) 0.002 M (2) 10.2 M
(3) 30 (4) 50 (3) 0.012 M (4) 0.001 M
24

334. Concentrated aqueous sulphuric acid is 98% 343. Rashida dissolved 40 g of sugar in 600 mL of sugar
H2SO4 (w/v) and has a density of 1.80 g mL–1. solution. Calculate the mass by volume percentage.
Molarity of solution (1) 66.6 (2) 70
(1) 1 M (2) 1.8 M (3) 6.66 (4) 50
(3) 10 M (4) 1.5 M
344. A solution is prepared by dissolving 1.0 g of NaOH
335. Calculate the normality of 0.0521 M H3PO4 in water to get 250 ml of solution. Calculate its
(1) 0.0521 N (2) 0.1042 N molarity.
(3) 0.1563 N (4) 0.0173 N (1) 2.5 (2) 4.5
(3) 5.0 (4) 0.1
336. What is conc. in ppm if 0.025g of KCl is dissolved
in 100 grams of water? 345. A solution is prepared by adding 5 g of a substance
(1) 25 ppm (2) 250 ppm x to 18 g of water. Calculate the mass percentage
(3) 2.5 ppm (4) 0.25 ppm of the solute.
(1) 21.74% (2) 19%
337. Which of the following is correct? (3) 25% (4) 40%
(1) The sum of mole fractions of all the
components in a solution is always 346. What is the molarity of NaOH solution if 250 mL
unity of it contains 1 mg of NaOH?
(2) Mole fraction depends upon temperature (1) 10–1 M (2) 10–2 M
–4
(3) Mole fraction is always negative (3) 10 M (4) 10–3 M
(4) Mole fraction is independent of content of
solute in solution. 347. A given solution of NaOH contains 2.00 g of
NaOH per litre of solution. Calculate the molarity
338. If 1.8 gm glucose is present in 200 ml of solutions. of this solution.
Calculate molarity. (1) 0.05 M (2) 0.09 M
(1) 0.05 M (2) 1.0 M (3) 0.02 M (4) 0.40 M
(3) 2.0 M (4) 0.25 M
348. Determine the volume/volume percent solution
339. A solution is prepared by adding 360 g of glucose made by containing 25 mL of ethanol with enough
to 864 g of water. Calculate mole fraction of water to produce 200 mL of the solution:
glucose (molar mass of glucose = 180) (1) 12.5 (2) 20
(1) 0.02 (2) 0.04 (3) 40 (4) 25
(3) 0.5 (4) 10.2
349. Given, 5 × 10–3 kg of urea of dissolved in 2 × 10–3
340. The molarity of H2SO4 solution, which has a kg of water. Calculate the percent by mass of urea.
density 1.84 g/cc at 35°C and contains 98% by (1) 90% (2) 71.42%
weight is (3) 70% (4) 80%
(1) 1.84 M (2) 18.4 M
(3) 20.6 M (4) 24.5 M 350. 300 gm of 25% w/w solution of solute A is mixed
with 400 gm of 40% (w/w) solution of another
341. What weight of calcium phosphate must be present solute B. What is the w/w percentage of the new
in 250 ml of solution. So that molarity of solution mixture?
becomes 0.2 M? (1) 33.57% (2) 35%
(1) 31.5 g (2) 15.5 g (3) 25% (4)40%
(3) 20 g (4) 40 g
351. A 500gm toothpaste sample has 0.2g fluoride
342. A given solution of NaOH contains 4.00 g of concentration. The conc. Of fluoride ions in terms
NaOH per litre of solution. Calculate the molarity of ppm.
of this solution. (1) 25 (2) 250
(1) 0.1 (2) 0.5 (3) 400 (4) 40
3
(3) 0.9 (4) 1.5 352. 2.5cm of 0.2M H2SO4 solution is diluted to 0.5
dm3. Find normality of diluted solution.
25

(1) 0.2 N (2) 0.04 N (1) 18 L (2) 9L


(3) 0.02 N (4) 0.002 N (3) 0.9 L (4) 1.8 L

353. 3.42g of a substance of molecular weight 342g is 364. Repeated Question as same Q No. 343
present in 250g of water. Molality of this solution
is
365. Calculate the volume by volume percentage of a
(1) 0.04 m (2) 0.4m
(3) 4.0m (4) 0.8m solution of 15 ml of alcohol in 60 ml of water.
(1) 20 (2) 25
354. Repeated Question as same Q No. 320 (3) 30 (4) 50

355. Repeated Question as same Q No. 319 366. Calculate the concentration in terms of mass by
volume percentage of the solution containing, 2.5
356. An oxide (Fe2On) of iron contains 70% iron by g potassium chloride in 50 ml of potassium
mass. Calculate value of n.
chloride (KCl) solution?
(1) 1 (2) 2
(1) 25% (2) 20%
(3) 3 (4) 4
(3) 5% (4) None of these
357. Caffine has a molecular weight of 194. It contains
28.9% by mass of nitrogen number of atoms of 367. What is the volume percentage of a solution
nitrogen in one molecule of it: formed by dissolving 75.0 mL of a solute into
(1) 2 (2) 3 155.0 mL of a solvent?
(3) 4 (4) 5 (1) 4.84% (2) 48.4%
(3) 32.6% (4) 3.26%
358. Repeated Question as same Q No. 318

368. A solution of ethanol in water is 10 % by volume.


359. Mole fraction of A in H2O is 0.2. The molality of
A in H2O is: If the solution and pure ethanol have densities of
(1) 13.8 (2) 15.5 0.9866 g/cc and 0.785 g/cc respectively. The
(3) 14.5 (4) 16.8 percent by weight is nearly?
(1) 7.95% (2) 17%
360. The molarity of the solution containing 2.8% mass- (3) 9.86% (4) 16.2%
volume solution of KOH/(Given atomic mas K –
39) is: 369. Repeated Question as same Q No. 350
(1) 0.1 M (2) 0.5 M
(3) 0.2 M (4) 1 M 370. Repeated Question as same Q No. 349

361. 500 mL of a glucose solution contains 6.02 × 1022 371. 8 g NaOH is dissolved in one litre of solution, its
molecules. The concentration of the solution is: molarity is
(1) 0.1 M (1) 0.8 M (2) 0.4 M
(2) 1.0 M (3) 0.2 M (4) 0.1 M
(3) 0.2 M
372. The molarity of a solution of sodium chloride
(4) 2.0 M
(mole wt. = 58.5) in water contain 5.85 gm of
sodium chloride in 500 ml of solution is
362. The mole fraction of a given sample of I2 in C6H6
(1) 0.25 (2) 2.0
is 0.2. The molality of I2 in C6H6 is-. (3) 1.0 (4) 0.2
(1) 0.32 (2) 3.2
(3) 0.032 (4) 0.48
373. 60 g of solution containing 40% by mass of NaCl
363. An aqueous solution of glucose is 10% (w/v). The are mixed with 100 g of a solution containing 15%
volume in which 1 mole of glucose is dissolved by mass NaCl. Determine the mass percent of
sodium chloride in the final solution.
will be
(1) 24.4% (2) 78%
26

(3) 48.8% (4) 19.68% 384. Repeated Question as same Q No. 324

374. If 500 ml of 1 M solution of glucose is mixed with 385. The number of moles of solute per kg of a solvent
500 ml of 1 M solution of glucose final molarity of is called its
solution will be (1) Molarity (2) Normality
(1) 1 M (2) 0.5 M (3) Molar fraction (4) Molality
(3) 2 M (4) 1.5 M
386. When WB gm solute (molecular mass MB)
375. What volume of 0.10 M H2SO4 must be added to dissolves in WA gm solvent. The molality M of the
50 mL of a 0.10 M NaOH solution to make a solution is
solution in which the molarity of the H2SO4 is WB M B WB 1000
0.050 M ? (1) W  1000 (2) M  W
A B A
(1) 400 mL (2) 50 mL
(3) 100 mL (4) 150 mL WA 1000 WA  M B
(3)  (4)
WB M B WB  1000
376. What approximate volume of 0.40 M Ba(OH)2
must be added to 50.0 mL of 0.30 M NaOH to get 387. Which of the following relations is correct for
a solution in which the molarity of the OH– ions is solutions?
0.50 M? (1) 3 N Al2(SO4)3 = 0.5 M Al2(SO4)3
(1) 33 mL (2) 66 mL (2) 3 M H2SO4 = 6 N H2SO4
(3) 133 mL (4) 100 mL (3) 1 M H3PO4 = 1/3 N H3PO4
(4) 1 M Al2(SO4)3 = 6 N Al2(SO4)3
377. What volume of a 0.8 M solution contains 100
millimoles of the solute?
388. Determine the volume/volume percent solution
(1) 100 mL (2) 125 mL
made by combining 25 mL of ethanol with enough
(3) 500 mL (4) 62.5 mL
water to produce 200 mL of the solution:
378. The molality of a sulphuric acid solution is 0.2. (1) 12.5 (2) 20
Calculate the total weight of the solution having (3) 40 (4) 25
1000 gm of solvent.
(1) 1000 g (2) 1098.6 g 389. Repeated Question as same Q No. 343
(3) 980.4 g (4) 1019.6g
390. Repeated Question as same Q No. 325
379. Repeated Question as same Q No. 340 391. Repeated Question as same Q No. 366

380. The density (in g mL–1) of a 3.60 M sulphuric acid 392. Repeated Question as same Q No. 367
solution that is 29% (H2SO4 molar mass = 98 g
mol–1) by mass will be : 393. Repeated Question as same Q No. 368
(1) 1.22 (2) 1.45
(3) 1.64 (4) 1.88 394. Repeated Question as same Q No. 350
395. Repeated Question as same Q No. 349
381. Repeated Question as same Q No. 361
396. Repeated Question as same Q No. 371
382. What is the [OH–] in the final solution prepared by
mixing 20.0 mL of 0.050 M HCl with 30.0 mL of
0.10 M Ba(OH)2 ? 397. Repeated Question as same Q No. 374
(1) 0.10 M (2) 0.40 M 398. Repeated Question as same Q No. 375
(3) 0.0050 M (4) 0.12 M
399. Repeated Question as same Q No. 376
383. The amount of anhydrous Na2CO3 present in 250
ml of 0.25 M solution is 400. Repeated Question as same Q No. 377
(1) 6.225 g (2) 66.25 g
(3) 6.0 g (4) 6.625 g 401. Repeated Question as same Q No. 340
27

402. Repeated Question as same Q No. 380 410. 250 ml of 0.5 M KCl is diluted with water to 500
ml of solution, the number of chloride ions in the
403. Repeated Question as same Q No. 361 resulting solution are
(1) 6.02 × 1023 (2) 7.52 × 1022
24
404. Repeated Question as same Q No. 382 (3) 1 × 10 (4) 3.76 × 1023

411. What is the quantity of water that should be added


405. Repeated Question as same Q No. 383
to 16 g. methanol to make the mole fraction of
methanol as 0.25
406. Repeated Question as same Q No. 324
(1) 27 g (2) 12 g
(3) 18 g (4) 36 g
407. Repeated Question as same Q No. 385
412. Mole fraction of the solute in a 1.00 molal aqueous
408. What is the concentration of nitrate ions if equal solution is
volumes of 0.1 M AgNO3 and 0.1 M NaCl are (1) 0.1770 (2) 0.0177
mixed together (3) 0.0344 (4) 1.7700
(1) 0.1 M (2) 0.2 M
(3) 0.05 M (4) 0.25 M 413. The volume strength of 1.5 N H2O2 solution is
409. The molarity of the solution containing 2.8% mass- (1) 4.8 V (2) 8.4 V
volume solution of KOH is (3) 3 V (4) 8 V
(1) M/10 (2) M/2
(3) M/5 (4) 1 M 414. Find the volume strength of H2O2 solution prepared
by mixing of 250 mL of 3N H2O2 and 750 mL of
1N H2O2 solution
(1) 1.5 V (2) 8.4 V
(3) 5.6 V (4) 11.2 V

Stoichiometry calculation , Limiting Reagent , %age yield

415. How many mole of Zn(FeS2) can be made from 2 418. The number of moles of hydrogen molecules
mole zinc, 3 mole iron and 5 mole sulphur. required to produce 20 moles of ammonia through
(1) 2 mole Haber’s process is
(2) 3 mole (1) 40 (2) 10
(3) 4 mole (3) 20 (4) 30
(4) 5 mole
419. 10 g of hydrogen and 64 g of oxygen were filled in a
416. According to following reaction: steel vessel and exploded. Amount of water produced
A + BO3 → A3O4 + B2O3 in this reaction will be
The number of moles of A3O4 produced if 1 mole of (1) 3 mol
A is mixed with 1 mole of BO3 (2) 4 mol
(1) 3 (2) 1 (3) 1 mol
(3) 1/3 (4) 2/3 (4) 2 mol

417. In a chemical reaction, A + B → AB, if B is acting 420. 10g of MnO2 on reaction with HCl form 2.24L of
as a limiting reagent, then choose the correct option. Cl2(g) at NTP. The percentage purity of MnO2 is
A B
MnO2 + 4HCl ⎯→ MnCl2 + Cl2 + 2H2O.
(1) 50 atoms 100 atoms
(1) 87% (2) 80%
(2) 100 atoms 200 atoms
(3) 27% (4) 15%
(3) 50 atoms 30 atoms
(4) 50 atoms 200 atoms
421. If ‘x’ dm3 of N2 reacts with ‘x’ dm3 of H2 to form NH3
under suitable conditions, then
28

(1) H2 is limiting reagent 2Al (s) + 3Cl2(g) → 2AlCl3(s)


(2) N2 is limiting reagent (1) Which is limiting reagent?
(3) Both reactants are limiting reagents (2) How many moles of AlCl3 are formed
(4) NH3 is limiting reagent (3) Moles of excess reagent left unreacted is
(1) (1) Al, (2) 1.0 (3) 1.5
(2) (1) Cl2, (2) 2.0 (3) 2.0
(3) (1) Al, (2) 0.5 (3) 1.5
(4) (1) Cl2, (2) 1.0 (3) 1.5
422. A mixture of 1.0 mole of Al and 3.0 mole of Cl2 are
allowed to react as :
Equivalent and Molecular Weight

423. 32 g of metal react with 48 g O2. Find EM? 430. If the weight of metal oxide is x g containing y g of
(1) 3.5 (2) 2.5 oxygen, the equivalent weight of metal will be
(3) 5.3 (4) 4.3 (1) E = 8 x (2) E = 8( y − x)
y x
424. Find the equivalent weigh of y 8( x − y )
K2SO4 ∙ Al2(SO4)3 ∙ 24H2O (3) E = (4) E =
8 y
(Molar mass = M)
431. An unknown element forms an oxide. What will be
M M
(1) (2) the equivalent mass of the element if the oxygen
8 6
content is 20% by mass.
M M (1) 8 (2) 16
(3) (4)
12 2 (3) 32 (4) 64

425. Calculate equivalent weight of H3PO4 on the basis of 432. 6g of monobasic acid is dissolved in 100 ml water to
given reaction: form normal solution. What is equivalent mass of the
H3PO4 + NaOH → NaH2PO4 + H2O acid?
(1) 100 (1) 60 (2) 20
(2) 96 (3) 40 (4) 30
(3) 98
(4) 99 433. Mass of metal is increased by 50% when kept in air.
Find EM =?
426. 2.4 g of metal displaces 0.56 L H2 at NTP, then EM? (1) 8 (2) 16
(1) 24 (2) 12 (3) 24 (4) 20
(3) 8 (4) 48
434. If 300 ml of a gas weighs 0.368 g at STP. What is the
427. What is the equivalent weight of hydride of metal if molecular weight?
equivalent weight of its oxide is 20? (1) 30.16 g (2) 37.5 g
(1) 12 (2) 13 (3) 2.55 g (4) 27.5 g
(3) 8 (4) 1
435. The equivalent weight of SnCl2 in the reaction:
428. Find the equivalent weight of CaCO3 SnCl2 + Cl2 → SnCl4 is
(1) 50 (2) 100 (1) 95 (2) 48
(3) 150 (4) 20 (3) 190 (4) 380

429. Calculate equivalent weight of Ca(OH)2 on the basis 436. 2g of metal on reaction with H2SO4 give 5g metal
of given reaction: sulphate. Find equivalent mass of metal?
Ca(OH)2 + HCl → Ca(OH)Cl + H2O (1) 2 (2) 16
(1) 70 (2) 74 (3) 32 (4) 64
(3) 65 (4) 79
29

437. What is the average molecular weight of a gas 446. When HNO3 is converted into NH3, the equivalent
containing 20% of N2 (molecular weight 28) and weight of HNO3 will be
80% of SO2 (molecular weight 64)? (1) M/2 (2) M/1
(1) 51 (2) 53 (3) M/6 (4) M/8
(3) 50 (4) None of these
447. Equivalent weight of carbon in CO and CO2 are in
the ratio of
438. Which one of the following properties of an element
(1) 1 : 1 (2) 1 : 2
is not variable
(3) 2 : 1 (4) 1 : 4
(1) Valency
448. The moles of O2 required for reacting with 6.8 g of
(2) Atomic weight
ammonia
(3) Equivalent weight
(....NH3 + ....... O2 → ..... NO + .... H2O) is
(4) All of these
(1) 5 (2) 2.5
439. When N2 is converted into NH3, the equivalent
weight of nitrogen will be (3) 1 (4) 0.5
(1) 1.67 (2) 2.67
(3) 3.67 (4) 4.67 449. Same as repeated Q. No. 265

440. In the ionic equation, 450. Which has maximum number of atoms?
2K+ + BrO3− + 12H++10e– → Br2 + 6H2O + 2K+ (1) 24 g of C (12) (2) 56 g of Fe (56)
(3) 27 g of Al (27) (4) 108 g of Ag (108)
the equivalent weight of KBrO3 will be
(1) M/5 (2) M/2
451. If ‘VISHAL RAHAL’ is written by graphite pencil,
(3) M/6 (4) M/4
it weighs 3.0  10–10 g. How many carbon atoms are
present in it?
441. If molecular weight of KMnO4 is 'M', then its
equivalent weight in acidic medium would be (NA = 6  1023)
(1) M (2) M/2 (1) 1.5  1013 (2) 5  1012
(3) M/5 (4) M/4 (3) 2  1033 (4) 1.5  1010

442. In the conversion NH2OH → N2O, the equivalent 452. Twenty molecules of SO3 will weigh as much
weight of NH2OH will be as......molecules of oxygen.
(1) M/4 (2) M/2 (1) 100 (2) 50
(3) M/5 (4) M/1 (3) 15 (4) 8

443. The equivalent weight of phosphoric acid (H3PO4) in 453. The largest number of molecules is in
the reaction (1) 36 g of water
NaOH + H3PO4 → NaH2PO4 + H2O (2) 28 g of CO
(1) 59 (2) 49 (3) 46 g of ethyl alcohol
(3) 25 (4) 98 (4) 54 g of nitrogen pentaoxide (N2O5)

444. The equivalent weight of MnSO4 is half its molecular 454. The ratio mass of oxygen and nitrogen of a particular
weight when it is converted into gaseous mixture is 1 : 4. The ratio of number of their
− molecule is
(1) Mn2O3 (2) MnO4 (1) 1: 4 (2) 7: 32
2−
(3) MnO2 (4) MnO4 (3) 1: 8 (4) 3 :16

445. The equivalent weight of Mohr's salt, 455. Which one of the following has maximum number of
FeSO4.(NH4)2SO4.6H2O is equal to atoms?
(1) Its molecular weight (1) 1 g of Ag(s) [Atomic mass of Ag = 108]
(2) Atomic weight (2) 1 g of Mg(s) [Atomic mass of Mg = 24]
(3) half-its molecular weight (3) 1 g of O2(g) [Atomic mass of O = 16]
(4) one-third its molecular weight (4) 1 g of Li(s) [Atomic mass of Li = 7]
30

456. The number of water molecules is maximum 458. Which has the maximum number of molecules
in among the following?
(1) 1.8 gram of water (1) 44 g CO2 (2) 48 g O3
(2) 18 gram of water (3) 8 g H2 (4) 4 g SO2
(3) 18 moles of water
(4) 18 molecules of water.

457. The mass of 3.2  105 atoms of an element is 8.0 


10–18 g. The atomic mass of the element is about (NA
= 6  1023)
(1) 2.5  10–22 (2) 15
–18
(3) 8.0  10 (4) 30

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