Yogendra sir
ch 1,2,3,4 Std : Xl Sci. Date : 23/09/23
Total Marks: 70 Full Course Time: 3 hours
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [14]
1. If the molecular weight of H3PO3 is M, its equivalent weight will be
(A) M (B) M/2 (C) M/3 (D) 2M
2. 0.32g of metal gave on treatment with an acid 112 mL of hydrogen at STP. Calculate the equivalent
weight of the metal
(A) 58 (B) 32 (C) 11.2 (D) 24
3. Give no. of energy state orbital and electrons in N orbit.
(A) 4, 12, 32 (B) 4, 16, 30 (C) 4, 16, 32 (D) 4, 32, 64
4. Iso-electronic species are
(A) F–, O–2 (B) F–, O (C) F–, O+ (D) F–, O+2
5. The order of electron gain enthalpy (with negative sign) of F, Cl, Br and I is...
(A) F < Cl < Br < I (B) I < Br < F < Cl (C) F < Br < I < Cl (D) Br < I < Cl < F
6. Which of the following species is not paramagnetic ?
(A) NO (B) CO (C) O2 (D) B2
7. The hydrogen bond is strongest in .......... .
(A) O – H----S (B) O – H----N (C) F – H----F (D) O – H----O
8. What is the molecular type of T-shaped molecule ?
(A) AB4E2 (B) AB2E2 (C) AB3E2 (D) AB4E
9. In which of the following compounds the rule of octet is not obeyed ?
(A) H2O (B) PCl5 (C) NH3 (D) CH4
10. What will be the molecular orbital order of CO molecule ?
(A) p2px = p2py > s2pz (B) p2px = p2py < s2pz
(C) p2px = p*2py > s*2pz (D) (A) and (C) are correct
11. Which element having 4 electronegativity ?
(A) Li (B) F (C) Cl (D) O
12. Which element shown less shield effect ?
(A) Group-12, period-4 (B) Group-12, period-3
(C) Group-12, period-2 (D) Group-12, period-5
13. By which of the following equation, atomic mass can be known ?
(A) Z + n (B) Z + e– (C) N + e– (D) Z + N
14. Give moles of 50 g Al2(SO4)3 ..........
(A) 0.083 (B) 0.952 (C) 0.481 (D) 0.146
Section B
//X
• Write the answer of the following questions. [Each carries 2 Marks] [20]
15. R) Explain Hund’s rule of maximum multiplicity.
16. Explain Law of Multiple Proportions.
17. Explain the “Law of Triads” with examples ?
1.2)
18. A compound contains 4.07% hydrogen, 24.27 % carbon and 71.65% chlorine. Its molar mass is 98.96
g. What are its empirical and molecular formulas ?
1.8)
19. The density of 3 M solution of NaCl is 1.25 g mL–1. Calculate molality of the solution.
20. 3) The mass of an electron is 9.1 ´ 10–31 kg. If its K.E. is 3.0 ´ 10–25 J, calculate its wavelength.
21. 4) Calculate the mass of a photon with wave-length (l) = 3.6 Å.
22. State the contribution of Nyholm & Gillespie in VSEPR theory.
23. What is Bond Angle ? Explain.
24. ) What is bond length ? How it is measured ?
Section C
//X
• Write the answer of the following questions. [Each carries 3 Marks] [21]
25. What is electron gain enthalpy (DegH) ? When its value becomes positive and negative ?
26. Explain : Lewis dots Representation.
27. Write a note on s-block elements of periodic table.
28. Explain photoelectric effect.
29. How many significant figures should be present in the answer of the following calculations ?
0.02856 ´ 298.15 ´ 0.112
(i)
0.5785
(ii) 5 ´ 5.364
(iii) 0.0125 + 0.7864 + 0.0215
30. What is electronegativity ? Explain periodicity in periodic table.
31. ) 50.0 kg of N2(g) and 10.0 kg of H2(g) are mixed to produce NH3(g). Calculate the NH3(g) formed. Identify
the limiting reagent in the production of NH3 in this situation.
Section D
//X
• Write the answer of the following questions. [Each carries 5 Marks] [15]
32. Write down Bohr’s model of hydrogen atom.
33. Write down Heisenberg’s uncertainty principle.
34. How many significant figures are present in the following ?
(i) 0.0025
(ii) 208
(iii) 5005
(iv) 126.000
(v) 500.0
(vi) 2.0034