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Process Design Basic

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Process Design Basic

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Block 5 - AL SHAHEEN FIELD

Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

GLF - WHP01 – EPCI2

FC, DC & EG Wellhead

Platform Process Design
Basis

Is the document generated from an existing As-Built? YES NO X

Originator Document Number WHP01-RCE1-ASYYY-04-260001 Last ASB Rev. :

Remarks:

02 13-Jun-2019 AFC Accepted for Construction L.M.P V.Kumar R.K.A/B.X.L

01 16-Apr-2019 IFA Issued for Acceptance L.M.P V.Kumar R.K.A/B.X.L

00 8-Jan-2019 IFR Issued for Review L.M.P V.Kumar R.K.A/B.X.L

Rev. Rev. date Status Description Issued by Reviewed by Approved by

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any
purpose not authorized by North Oil Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-

Page 1 of
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

REVISION HISTORY

Rev. Rev. Date Status History Issuer Reviewer Approver

00 8-Jan-2019 IFR Issued for Review L.M.P V.Kumar R.K.A/B.X.L

01 16-Apr-2019 IFA Issued for Acceptance L.M.P V.Kumar R.K.A/B.X.L
02 13-Jun-2019 AFC Accepted for Construction L.M.P V.Kumar R.K.A/B.X.L

Page 2 of
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

TABLE OF CONTENTS

1.0 INTRODUCTION...........................................................................................................................................................6

1.1 BACKGROUND...................................................................................................................................................................................... 6
1.2 SCOPE….................................................................................................................................................................................................. 8

2.0 DEFINITIONS AND ABBREVIATIONS...............................................................................................................8

2.1 ABBREVIATIONS................................................................................................................................................................................... 9
2.2 SYSTEM OF UNITS.............................................................................................................................................................................11
2.3 STANDARD CONDITIONS...............................................................................................................................................................12

3.0 REFERENCES..............................................................................................................................................................13

3.1 PROJECT DOCUMENTS....................................................................................................................................................................13

3.2 CODES AND STANDARDS..............................................................................................................................................................13

4.0 SUMMARY OF PHASE 2, BATCH - 1 DEVELOPMENTS........................................................................14

4.1 NEW WELLHEAD FACILITIES.........................................................................................................................................................14

4.1.1 DC WHP – Key Facilities and Features.....................................................................................................................14
4.1.2 FC WHP – Key Facilities and Features......................................................................................................................16
4.1.3 EG WHP – Key Facilities and Features.....................................................................................................................18
4.1.4 Existing Well Operational issues................................................................................................................................20

5.0 GENERAL DESIGN CONSIDERATION.............................................................................................................22

5.1 DESIGN LIFE........................................................................................................................................................................................ 22

5.2 PLATFORM ORIENTATION..............................................................................................................................................................22
5.3 DESIGN MARGINS............................................................................................................................................................................. 22
5.4 TURNDOWN ON PRODUCTION CAPACITY................................................................................................................................22

6.0 RESERVOIR PROPERTIES AND WELL FLUID COMPOSITION...........................................................23

6.1 WELL EFFLUENT CHARACTERISTICS..........................................................................................................................................23

6.2 RESERVOIR PROPERTIES AND WELL DESIGN PARAMETERS OF FIELD KHARAIB B / SHUAIBA /MAUDDUD....24
6.3 WELL FLUID COMPOSITION OF FIELD KHARAIB B / SHUAIBA /MAUDDUD...................................................................26
6.4 LIFT GAS COMPOSITION.................................................................................................................................................................27
6.5 FLUID VISCOSITY DATA..................................................................................................................................................................28
6.6 PRODUCED SOLIDS LOADING......................................................................................................................................................29

7.0 BASIS OF DESIGN FOR DC / FC / EG PLATFORMS................................................................................29

7.1 SLOT ALLOCATION FOR WELLHEAD PLATFORMS – DC / FC / EG....................................................................................29

7.2 WELLHEAD CONFIGURATION - PRODUCERS..........................................................................................................................30
7.3 WELLHEAD CONFIGURATION – SEA WATER INJECTORS....................................................................................................31
7.4 DESIGN BASIS OF PRODUCTION WELL FLOW LINES – DC.................................................................................................31
7.5 DESIGN BASIS OF PRODUCTION WELL FLOW LINES – FC..................................................................................................32
7.6 DESIGN BASIS OF PRODUCTION WELL FLOW LINES – EG.................................................................................................33

Page 3 of
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

7.7 DESIGN CAPACITY OF FLOWLINES AND MANIFOLDS...........................................................................................................33

8.0 PROCESS AND UTILITIES INTERFACE..........................................................................................................36

8.1 CHEMICAL INJECTION SYSTEM.....................................................................................................................................................43

9.0 PROCESS AND EQUIPMENT DESIGN CRITERIA......................................................................................44

9.1 MAXIMUM DESIGN TEMPERATURE.............................................................................................................................................44

9.2 MINIMUM DESIGN TEMPERATURE...............................................................................................................................................44
9.3 MAXIMUM DESIGN PRESSURE......................................................................................................................................................44
9.4 MINIMUM DESIGN PRESSURE.......................................................................................................................................................45
9.5 EQUIPMENT SIZING CRITERIA......................................................................................................................................................46
9.5.1 2 - Phase and 3 - Phase Separator Sizing...............................................................................................................46
9.5.2 Closed Drain Drum..........................................................................................................................................................48
9.5.3 Flare Knock-out Drum Sizing Criteria.......................................................................................................................48
9.5.4 Vessel Nozzle Sizing Criteria.......................................................................................................................................49
9.5.5 Pumps.................................................................................................................................................................................. 50
9.5.6 Drain Caisson Sizing.......................................................................................................................................................51
9.6 LINE SIZING CRITERIA.....................................................................................................................................................................51
9.6.1 Liquid Line Sizing.............................................................................................................................................................52
9.6.2 Gas Line Sizing.................................................................................................................................................................52
9.6.3 Multiphase Line Sizing...................................................................................................................................................52
9.6.4 Pipe Roughness................................................................................................................................................................55
9.6.5 Sizing PSV and Blowdown Line...................................................................................................................................55
9.6.6 Drain Line Sizing..............................................................................................................................................................56

10.0 SOFTWARES.............................................................................................................................................................57

11.0 ASSAY SPECIFICATIONS....................................................................................................................................57

12.0 SITE AND ENVIRONMENTAL DATA................................................................................................................59

12.1 ENVIRONMENTAL REQUIREMENTS.............................................................................................................................................59

13.0 NEW FACILITIES DESIGN PHILOSOPHY....................................................................................................60

14.0 APPENDICES.............................................................................................................................................................60

Appendix 01 : Carbonate Solids Loading.............................................................................................................................................61

Appendix 02 : MSDS for Production Chemicals.................................................................................................................................62

Page 4 of
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

HOLDS LIST:

HOLD NO. SECTION DESCRIPTION BY

HOLD 1 7.7 Number of WAG wells in operation at a time NOC
4.1.1
Requirement of N2 Bottle Rack (Flare Purge Back-up)
HOLD 2 4.1.2 Contractor
pending CFD Deflagration Study
4.1.3
HOLD 3 8 Deleted Contractor

Page 5 of
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

1.0 INTRODUCTION

1.1 BACKGROUND

The Al-Shaheen field is QATAR’s largest oil field. It is a conventional oil field (of approximately 60m water
depth) situated offshore in QATAR approximately 70km north-north-east of Ras Laffan. The field overlays
the giant pre-Khuff gas field known as North Field.
33 platforms, including five production hubs, are installed in Al-Shaheen field. These are spread over nine
different areas across the field - Locations A to I. Crude is exported by tanker via tandem offloading from
two FSOs which are permanently moored in the field to two (of three) SPMs. Gas is gathered in a gas grid
pipeline system and exported via North Field Alpha. Cleaned-up produced water is currently injected into
the Umm Er-Radhuma (UER) formation with some limited disposal to sea due to current capacity
constraints. Al-Shaheen reached a production plateau of 300kbd in 2007 and is still producing at this rate
today. In December 2016, the total oil produced from Al-Shaheen was 1.7Gbbl.

The field has been developed through several phases and further development phases are envisaged by
North Oil Company (NOC), the new operator of the Al-Shaheen concession.

Page 6 of
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

NOC in an effort to improve the field production capacity, has initiated Al-Shaheen Phase 2 project. Phase 2
project is planned to be developed in 3 batches:

One first batch (Batch 1) of 3 wellhead platforms bridge-linked to existing platforms (EG,

FC and DC). A second batch of 2 wellhead platforms CE, EH bridges linked to existing

facilities

Third batch of 3-4 WHPs remote connected to existing facilities

EH
EG

FC
Batch 1
Batch 2 Batch 3

G-West

G-East

BATCH 1 Main facilities include the following, for each location:

- Jacket and piles.

- Topside.

Page 7 of
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Development

Page 8 of
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

- Bridge.
- Integration works (process tie-ins, electrical, ICSS, Telecom, interfaces).

New development shall enable use of the full design envelope of existing facilities; best possible use shall
be made of existing installations to maintain the production plateau. The methodology applied consisted
of identifying key constraints in surface, well and subsurface areas. The optimal number, size and location
of WHPs was obtained by considering subsurface stakes and a set of identified constraints.

Three (3) new BATCH 1 Wellhead Platforms (WHPs) bridge-linked to existing of Al-Shaheen assets are
selected to be executed on EPCIC basis. Incremental well potential shall be used to fill ullage within the
existing process capacity. Maximum use shall be made of utility / service infrastructure from host
facilities, including; power supply, lift gas supply, instrument air, breathing air, fire water, service water,
flare and vent, diesel, LP fuel gas, control command, etc.

As a base case, platforms shall be designed for full 24 well-slot access and operation using 60-foot drilling
jack-ups on one defined footprint.

1.2 SCOPE

The scope of this document is to present process design basis including basic design data, design criteria
and guidelines required to carry out the Detail Engineering for the development of new WHPs (DC / FC /
EG) and detail design of Tie-in integration of new WHPs with existing host platform (DA / FA / ED), to be
implemented under Phase 2, Batch 1 development in Al Shaheen Field. This document shall be the basis
for the Detail process activities and deliverables to be generated and consolidates the codes and
standards to be used in process design activities during Detail stage.

2.0 DEFINITIONS AND ABBREVIATIONS

NORTH OIL COMPANY (NOC); Business Partnership between QP (70%

CPY (or) COMPANY
shareholder) & TOTAL E & P Golfe (30% shareholder);

Asset number for new WHP (Phase 2, Batch - 1) bridge-linking to existing

DC WHP DA
process facility at D-Location
Asset number for new WHP (Phase 2, Batch - 1) bridge-linking to existing
EG WHP ED
process facility at E-Location
Asset number for future WHP (Phase 2, Batch - 2) bridge-linking to new EG
EH WHP WHP
facility at E-Location
Asset number for new WHP (Phase 2, Batch - 1) bridge-linking to existing
FC WHP FA
The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any
purpose not authorized by North Oil Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-

Page 9 of
Block 5 - AL SHAHEEN FIELD
Development
process facility at F-Location

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Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Full Control of Wells; Intelligent optimizer control platform acting on

existing SCADA-level controllers, to effect auto-pilot management of wells
FCW
/ WHPs in order that production remains stable, within field constraints &
makes optimum return for
available lift gas.
CONTRACTOR EPCI Contractors (PTSCMC)

2.1 ABBREVIATIONS

AIV - Acoustic Induced Vibration

ANSI - American National Standards Institute
API - American Petroleum Institute
ASME - American Society of Mechanical
Engineers ASTM - American Standard for Testing
Materials Bara - Bar absolute
Barg - Bar gauge
bbl - Barrel, volumetric measure equal to 42 US
gallons BOD - Basis of Design
CITHP - Closed-in Tubing Head Pressure
BSW - Base Sediment and Water
bpd - barrels per day
CA - Corrosion Allowance
CD - Closed Drains
CI - Corrosion Injection
CITHP - Closed-in Tubing Head Pressure
CITHT - Closed-in Tubing Head
Temperature CRA - Corrosion Resistance Alloy
CS - Carbon Steel
dBA - Decibel (A-weighted)
DCS - Distributed Control System
DHCI - Downhole Corrosion Inhibitor
EDP - Emergency Depressurisation
EIA - Environmental Impact Assessment
EOR - Enhanced Oil Recovery
ESD - Emergency Shut Down
ESDV - Emergency Shut Down Valve
FCV - Flow Control Valve
FEED - Front End Engineering Design

Page 11
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

F&G - Fire and Gas

FTHP - Flowing Tubing Head Pressure
FTHT - Flowing Tubing Head Temperature
FPSO - Floating Production Storage and Offloading
Vessel GOR - Gas Oil Ratio, scf/bbl
GRE - Glass Fibre Reinforced Epoxy
GRP - Glass Fibre Reinforced Plastics
HAZID - HAZard IDentification review
HAZOP - HAZard OPerability review
HAT - Highest Astronomical Tide
HSE - Health, Safety, Environmental
HP - High Pressure
HPU - Hydraulic Power Unit
HLSD - High Liquid Shut Down
HVAC - Heating, Ventilation and Air
Conditioning INLL - Interface Normal Liquid Level
JT - Joule Thompson
KO - Knock Out
KOM - Kick-Off Meeting
kbopd - Thousand barrels of oil per
day kbwpd - Thousand barrels of water per
day kblpd - Thousand barrels of liquid per
day
LLL - Low Liquid Level
LAH - Level Alarm High
LAL - Level Alarm Low
LAHH - Level Alarm High High
LALL - Level Alarm Low Low
LAT - Lowest Astronomical Tide
LEC - Liquid Erosion-Corrosion
LOPA - Layer of Protection Analysis
MAC - Manual Call Point
MCV - Master Control Valve
MMScfd - Million Standard cubic feet
per day MOT - Maximum Operating
Temperature
MSDS - Material Safety Data Sheet
MSL - Mean Sea Level

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Development

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Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

NFA - North Field Alpha

NA - Not Applicable
NNE - North North-East
NFPA - National Fire Protection Association
NBP - Normal Boiling Point
NLL - Normal Liquid Level
NUI - Normally Unmanned Installation
OT - Operating Temperature
PCS - Process Control System
POB - Persons On Board
PSD - Process Shutdown
System ppm (v) - parts per million by
volume PVC - Polyvinyl Chloride
PWRI - Produced Water Reinjection
RVP - Reid Vapour Pressure
Scf - Standard cubic feet
SSSV - Sub Surface Safety Valve
SEC - Solid Erosion-Corrosion
SS - Stainless Steel
SWI - Seawater Injection
TBC - To Be Confirmed
TDS - Total Dissolved Solids
TEG - Tri-ethylene Glycol
TVD - True Vertical Depth
TVP - True Vapour Pressure
WD - Water Depth
WC - Water Cut
WAG - Water Alternating Gas (EOR
Mechanism) WHP - Wellhead Platform
WHCP - Wellhead Control Panel
WI - Water Injection
WCV - Wing Control Valve

2.2 SYSTEM OF UNITS

The following system of units shall be used throughout the design.

Page 14
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Parameter Unit Unit Abbreviation

Area square meter m2
Length meter (m) or millimeter (mm) m, mm
Liquid Volumetric barrel per day, cubic meter per hour, bpd, m3/h
Flow
Gas Volumetric Million standard cubic feet per day MMscfd
Flow
Mass Kilogram, tonne Kg, t
Mass Concentration parts per million (weight) ppmw
Mass Flow kilogram per hour kg/h
Molar Flow kilogram mole per hour kgmole/h
Velocity meter per second m/s
Density kilogram per cubic meter kg/m3
Viscosity (dynamic) centi Poise cP
Viscosity centi Stokes cSt
(kinematic)
Pressure bar absolute or bar gauge bara or barg
Temperature Degree Celcius °C
Power kilo Watt kW
Heat/Energy kilo Watt or kilo Joule kW or kJ
Mass Enthalpy kilo Joule per kilogram kJ/kg
Mass Heat Capacity (Specific
kilo Joule per kilogram.oCelcius kJ/kg.°C
Heat)
Molar Heat Capacity (Specific
kilo Joule per kilomol.oCelcius kJ/kmol.°C
Heat)
Heat Flow kilo Joule per hour kJ/h
Heat transfer rate kilo Joule per square meter.hour kJ/m2.h
Thermal o W.m.°C
Watt.meter. Celcius
Conductivity
Surface Tension Dyne per centimetre dyne/cm
Gas-to-Oil Ratio Standard cubic feet per standard Scf/stb
barrel

2.3 STANDARD CONDITIONS

Standard conditions: 15.56˚C and 1.01325 barA (absolute)

1. Liquid flowrates in Barrels of liquid per day (blpd) at standard

conditions Liquid flowrates in Barrels of liquid per day (blpd) at
operating conditions
2. Oil flowrates in Barrels per day (bopd) at standard conditions
Oil flowrates in Barrels of liquid per day (bopd) at operating conditions
3. Water flowrates in Barrels of water per day (bwpd) at standard conditions

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Development
4. Gas flowrates in Million standard cubic feet per day (MMScfd) at standard
conditions The designator “MM” refers to Million and “k” refers to
thousand

Page 16
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

3.0 REFERENCES

3.1 PROJECT DOCUMENTS

Contract No. GLF-WHP01-EPCIC2 Rev EXHIBIT A – Scope of Work and services to Company
00
WHP01-MPEN-ASYYY-00-200003 Rev GLF-WHP01-EPCIC2 Punch List
01
WHP01-RCE1-ASYYY-04-260001 Rev 02 FC, DC & EG Wellhead Platform Process Design Basis (FEED)

3.2 CODES AND STANDARDS

The process design shall be in accordance with the following SD-NOC Standards and International Codes
and Standards:

Reference Title
CPY Standards
SD-NOC-ECP-103 Rev.00 Process Design Criteria
SD-NOC-ECP-105 Rev.00 Process and Flow Assurance - Contractor Engineering Phase
Deliverables
SD-NOC-COR-004 Rev.00 Limiting Flow Velocities Calculations for Erosion Corrosion purpose
SD-NOC-COR-005 Rev.00 Material selection for oil and gas production systems
Materials for upstream sour service application, Specification for
SD-NOC-COR-170 Rev.00
selection and design

SD-NOC-INS-125 Rev.00 Safety Relief Valves and Rupture Discs

SD-NOC-SAF-007 Rev.00 Liquid Drainage
SD-NOC-SAF-010 Rev.00 Emergency Shutdown and Emergency Depressurization (ESD & EDP)
SD-NOC-SAF-011 Rev.00 Pressure protection relief and hydrocarbon disposal systems
SD-NOC-PVV-107 Rev.00 Piping Stress Analysis
SD-NOC-PVV-111 Rev.00 Piping Design Standard
SD-NOC-PVV-112 Rev.00 Piping Material Classes
SD-NOC-PVV-813 Rev.00 Skid mounted units for Static Equipment
SD-NOC-PVV-814 Rev.00 Skid mounted units for Chemical Products Injection Systems
International Codes and Standards
Recommended Practice for Analysis, Design, Installation and Testing
API RP 14C, 8th Edition, Feb-2017
of Basic Surface Safety Systems for Offshore Production Platforms
th Recommended Practice for Design and Installation of Offshore
API RP 14E, 5 Edition, Jan-2013
Production Platform Piping Systems
Recommended Practice for Design and Hazards Analysis for Offshore
API RP 14J, 2nd edition
Production Facilities
API RP 520, 6th Edition, Mar-2015 Sizing, Selection, and Installation of Pressure - relieving Devices
(Part I)
API RP 520, 9th Edition, Jul-2014 Sizing, Selection, and Installation of Pressure - relieving Devices
(Part II)
API RP 521- ISO 23251, 6th
Pressure Relieving and Depressuring Systems
Edition, Jan-2014
ASME B31.3, 2016 Process Piping
ASME B31.4, 2016 Pipeline Transportation Systems for Liquid Hydrocarbons and other

Page 17
Block 5 - AL SHAHEEN FIELD
Development Liquids
API 610, 11th edition Centrifugal Pumps for Petroleum, Petrochemical and Natural Gas
Industries

Page 18
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Reference Title
API 676, 3rd edition Positive Displacement Pumps
DNVGL-RP-O501, Edition August Managing sand production and erosion
2015
GPSA, 13th edition Gas Processors Suppliers Association

4.0 SUMMARY OF PHASE 2, BATCH - 1 DEVELOPMENTS

The Phase - 2, Batch -1 development covers three (3) new wellhead platforms DC WHP, FC WHP and EG
WHP and each WHP will have 24 well slots. The new Wellhead platforms DC, FC & EG shall be tied to the
existing host platforms DA, FA and ED respectively. All three (3) new WHPs (DC / FC / EG) developments
shall be considered as “Greenfield”. Similarly, detail of design of Tie-in integration activities with existing
host platforms (DA / FA / ED) shall be considered as “Brownfield”.
Refer to below new well head facilities schematics of DC WHP, FC WHP and EG WHP:

 DC WHP Overall Process Block Diagram, Doc. No.: WHP01-PMC1-ASDCA-03-020001-0001,

 FC WHP Overall Process Block Diagram, Doc. No.: WHP01-PMC1-ASFCA-03-020001-0001,
 EG WHP Overall Process Block Diagram, Doc. No.: WHP01-PMC1-ASEGA-03-020001-0001.

4.1 NEW WELLHEAD FACILITIES

The key process facilities & features for new wellhead platforms (each comprising 24 well-slots) fixed
during FEED study & post-survey definitions remain unchanged for Detail, are presented in below
sections:

For detailed description of Process & Utility facilities, refer to “DC Wellhead Platform Process &
Utilities System” Description, Doc. No.: WHP01-PMC1-ASDCA-04-260001-0001.

4.1.1 DC WHP – Key Facilities and Features

1. Christmas Trees (equipped with 41/16” API 5,000 Xmas trees) - Production / SWI Wells (Refer section
7.1 for Well allocation details).
2. Production & Test Manifolds (900#) equipped with 20‐slots apiece (2 x 10‐slot sections at East &
West of well‐bay). Driven by a philosophy that SWI wells shall initially function (gas‐lifted) as
production wells to effect well clean‐up in the early phase.
3. Production capacity (aligned at 90,000blpd / 100MMScfd).
4. Lift gas distribution manifolds (900#) equipped with 16‐slots apiece (2 x 8‐slot sections at East &
West of well‐bay). Each lift gas flowline shall be capable of supplying a nominal 3MMScfd per
producing well.
5. SWI Manifold (aligned at 1500#) equipped for 14‐slots (2 x 7‐slot sections at East & West of well‐
bay) & catering for up to 120,000bwpd.
6. 24‐Slot electro‐hydraulic Well Head Control Panel (WHCP) including HPUs.

Page 19
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

7. Automated (remotely operable) 2‐phase ASDCA‐V‐3401 Inlet Separator (aligned at 90,000blpd /

100MMScfd) & equipped with on‐line sand‐jetting facilities and handle slug volume (Ram-up slug
volume is 10 m3, continuous cyclic slug is 2 m3).
8. Wet Crude Export Pumps ASDCA‐P‐3611 / ASDCA‐P‐3621 / ASDCA‐P‐3631 (3 x 50% trains, 3 x
45,000blpd / 3kV electric‐motor drivers) suitable to export DC produced fluids directly to DA crude
export manifold (independently of DA production). Initially, 2-off Wet Crude Export Pumps ASDCA‐P‐
3611 / ASDCA‐P‐3621 shall be installed for operation in 2 x 50% configuration. The third pump
ASDCA-P-3631 shall be installed in future. Space and necessary advance tie-in provisions shall be
considered under Phase 2.1 design to facilitate installation of third pump in future without
shutdown of DC WHP facilities. For dimensioning of DC wet crude export pumps, the DA interface
pressure at DA wet crude export header to be considered as 38 barg.
9. Automated (remotely operable) 3‐Phase well testing via dedicated ASDCA‐V‐3402 Test Separator on
DC (aligned at 20,000blpd / 15MMScfd) & equipped with on‐line sand‐jetting facilities and handle
slug volume (Ram-up slug volume is 5 m3, continuous cyclic slug is 1 m3).
10. Sequence‐controlled ASDCA‐A‐3401 Desanding System, to receive continuous solids‐laden jetting
water streams from Inlet & Test Separators. The discharge effluent to sea via drain caisson shall
not exceed 30mg/l oil-in-water.
11. 2 x 60% (thermal duty) Electric heaters each 125 kWh; Lift gas heating system sufficient in capacity
for DC well requirements alone. Each heater shall be able to handle full flow (35 MMscfd)
hydraulically.
12. The following additional main/auxiliary equipment items:
a) HP Flare KOD (1 x 100%)
b) Flare Purge Gas Coalescer (1 x 100%)
c) Diesel Storage Tank (Within Crane pedestal)
d) Diesel Distribution pump (1 x 100%)
e) Diesel Filter Coalescer (1 x 100%)
f) Closed Drain Drum (1 x 100%)
g) Closed Drain Pumps (2 x 100%, 1 working + 1 standby),
h) Open Drain Tank (1 x 100%)
i) Open Drain pumps (2 x 100%, 1 working + 1 standby),
j) Drain Caisson and a vertical submersible pump,
k) Down-hole corrosion inhibitor tank (1 x 100%)
l) DHCI injection pumps – 5 units Multi-head pumps + 1 warehouse spare (2 pumps per motor)
to cater 10 no. of producer wells,
m) Topsides Corrosion Inhibitor tank (1 x 100%)
n) Topsides Corrosion Inhibitor injection pumps (2x 100%, 1 working + 1 standby),
o) Demulsifier tank (1 x 100%)

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p) Development
Demulsifier injection pumps (2x 100%, 1 working + 1 standby),
q) Antifoam tank (1 x 100%)

Page 21
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

r) Antifoam injection pumps (2x 100%, 1 working + 1 standby),

s) Biocide tank (1 x 100%)
t) Biocide injection pumps (2x 100%, 1 working + 1 standby),
u) Chemical TOTE tanks (each 4 m3 capacity)
v) N2 Bottle rack (Flare purge back-up) (HOLD 2)
w) Breathing Air Bottle rack (Back-up)
x) Platform Crane.

13. A new Fire water jockey pump (1 x 100%) and Anti-fouling package (Cuprion) shall be installed at
DA WHP as part of dry FW system conversion to Wet FW system.
14. Other utilities such as HP Flare, Flare purge gas, Instrument Air / Utility air, Diesel, Firewater,
Service Water (continuous seawater from jockey pump), Potable Water, Inert Gas, Breathing Air,
Electric Power shall be extended from the existing host DA platform via bridge. Control and
monitoring of new Wellhead platform is executed by the new DC platform’s SCADA / ESD / F&G
system (referred as ICSS) and interfaced to the host DA platform for a centralised HMI indication.

Key Features:

 Automated (remotely operable) production well testing (via SCADA / HMI): Wellhead inlet and test
manifolds designed with automated and remotely operated well test change-over valves to divert
the well fluid from any one well to the production manifold or the test manifold, for individual well
testing.
 Lift gas manifold and lift gas lines to production wells with flow meter for measurement of the lift
gas flow rates with flow reading available in the SCADA system.
 Full remote adjustment (via SCADA / HMI) of SWI well chokes and Full remote control of downhole
FCVs (via SCADA / HMI; engineer level).
 The production and water injection manifolds shall be arranged in such a way that any SWI well can
be converted from a production phase to a normal water injection phase (SWI clean-up) with a
minimum piping modification.
 Future WAG module installation provision (comprising TEG injection system, HP SWI pre-charge
pumps & HP SWI
/ GI manifolds) shall be considered with the following pre-investments:
 A 500Te future module capability (to be accommodated in jacket and pile design)
 6 inch, 1500# LTCS bridge line (HP GI) pre-installed on DC-DA bridge
 Cabinet space for future WAG I/O within DC ITR.

4.1.2 FC WHP – Key Facilities and Features

1. Christmas Trees (equipped with 41/16” API 5,000 Xmas trees) - Production / SWI Wells (Refer section
7.1 for Well allocation details).

Page 22
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Development

Page 23
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

2. Production & Test Manifolds (900#) equipped with 20‐slots apiece (2 x 10‐slot sections at East &
West of well‐bay). Driven by a philosophy that SWI wells shall initially function (gas‐lifted) as
production wells to effect well clean‐up in the early phase.
3. Production capacity (aligned at 90,000blpd / 100MMScfd).
4. Lift gas distribution manifolds (900#) equipped with 16‐slots apiece (2 x 8‐slot sections at East &
West of well‐bay). Each lift gas flowline shall be capable of supplying a nominal 3MMScfd per
producing well.
5. SWI Manifold (aligned at 1500#) equipped for 14‐slots (2 x 7‐slot sections at East & West of well‐
bay) & catering for up to 120,000bwpd.
6. Pipeline riser & reception facilities (Designed for Intelligent pigging) for a 20” NB 900# CS SWI
pipeline (to replace corroded / life-expired existing 12”-PL-AS-AB-FA-11). SWI inventory to injection
wells on FA shall be established by a 18” bridge-line on the ‘FC-FA’ bridge.
7. 24‐Slot electro‐hydraulic Well Head Control Panel (WHCP) including HPUs.
8. Automated (remotely operable) 3‐Phase well testing via dedicated ASFCA‐V‐3402 Test Separator on
FC (aligned at 20,000blpd / 15MMScfd) & equipped with sand‐jetting internals and SWI tie-in
provision in order to enable jetting water hook-up in future and handle slug volume (Ram-up slug
volume is 5 m3, continuous cyclic slug is 1 m3).
9. 2 x 60% (thermal duty) Electric heaters each 210kWh; Lift gas heating system sufficient in capacity
for FC well requirements alone. Each heater shall be able to handle full flow (31 MMscfd)
hydraulically.
10. The following additional main/auxiliary equipment items:
a) HP Flare KOD (1 x 100%)
b) Diesel Storage Tank (Within Crane pedestal)
c) Diesel Distribution pump (1 x 100%)
d) Diesel Filter Coalescer (1 x 100%)
e) Closed Drain Drum (1 x 100%)
f) Closed Drain Pumps (2 x 100%, 1 working + 1 standby),
g) Open Drain Tank (1 x 100%)
h) Open Drain pumps (2 x 100%, 1 working + 1 standby),
i) Drain Caisson and a vertical submersible pump,
j) Down-hole corrosion inhibitor tank (1 x 100%)
k) DHCI injection pumps -5 units Multi-head pumps + 1 warehouse spare (2 pumps per
motor) to cater 10 no of producer wells,
l) Topsides Corrosion Inhibitor tank (1 x 100%)
m) Topsides Corrosion Inhibitor injection pumps (2x 100%, 1 working + 1 standby),
n) Demulsifier tank (1 x 100%)
o) Demulsifier injection pumps (2x 100%, 1 working + 1 standby),

Page 24
Block 5 - AL SHAHEEN FIELD
p) Development
Antifoam tank (1 x 100%)

Page 25
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

q) Antifoam injection pumps (2x 100%, 1 working + 1 standby),

r) Biocide tank (1 x 100%)
s) Biocide injection pumps (2x 100%, 1 working + 1 standby),
t) Chemical TOTE tanks (each 4 m3 capacity)
u) N2 Bottle rack (Flare purge back-up) (HOLD 2)
v) Breathing Air Bottle rack (Back-up)
w) Platform Crane.

11. A new Fire water jockey pump (1 x 100%) and Anti-fouling package (Cuprion) shall be installed at
FA WHP as part of dry FW system conversion to Wet FW system.
12. Other utilities such as HP Flare, Flare purge gas, Instrument Air / Utility air, Diesel, Firewater,
Service Water (continuous seawater from jockey pump), Potable Water, Inert Gas, Breathing Air,
Electric Power shall be extended from the existing host FA platform via bridge. Control and
monitoring of new Wellhead platform is executed by the new FC platform’s SCADA / ESD / F&G
system (referred as ICSS) and interfaced to the host FA platform for a centralised HMI indication.
Key Features:

 Automated (remotely operable) production well testing (via SCADA / HMI): Wellhead inlet and test
manifolds designed with automated and remotely operated well test change-over valves to divert
the well fluid from any one well to the production manifold or the test manifold, for individual well
testing.
 Lift gas manifold and lift gas lines to production wells with flow meter for measurement of the lift
gas flow rates with flow reading available in the SCADA system.
 Full remote adjustment (via SCADA / HMI) of SWI well chokes and Full remote control of downhole
FCVs (via SCADA / HMI; engineer level).
 The production and water injection manifolds shall be arranged in such a way that any SWI well can
be converted from a production phase to a normal water injection phase (SWI clean-up) with a
minimum piping modification.
 The following future provisions shall be considered in the design:
a) WAG module installation provision (comprising TEG injection system, HP SWI pre-charge
pumps & HP SWI / GI manifolds) shall be considered with the following pre-investment:
 A 500Te future module capability (to be accommodated in jacket and pile design)
 6 inch, 1500# LTCS bridge line (HP GI) pre-installed on FC-FA bridge
 Cabinet space for future WAG I/O within FC ITR.
b) Desander unit.

4.1.3 EG WHP – Key Facilities and Features

1. Christmas Trees (equipped with 41/16” API 5,000 Xmas trees) - Production / SWI Wells (Refer section

Page 26
Block 5 - AL SHAHEEN FIELD
Development
7.1 for Well allocation details).

Page 27
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

2. Production & Test Manifolds (900#) equipped with 20‐slots apiece (2 x 10‐slot sections at East &
West of well‐bay). Driven by a philosophy that SWI wells shall initially function (gas‐lifted) as
production wells to effect well clean‐up in the early phase. A connection slot on Test Manifold shall
be used to connect the future EH WHP test line to enable more precise well testing of EH WHP
using EG Test Separator.
3. Production capacity (aligned at 90,000blpd / 75MMScfd).
4. Lift gas distribution manifolds (900#) equipped with 16‐slots apiece (2 x 8‐slot sections at East &
West of well‐bay). Each lift gas flowline shall be capable of supplying a nominal 3MMScfd per
producing well.
5. SWI Manifold (aligned at 1500#) equipped for 14‐slots (2 x 7‐slot sections at East & West of well‐
bay) & catering for up to 120,000bwpd.
6. 24‐Slot electro‐hydraulic Well Head Control Panel (WHCP) including HPUs.
7. 3‐Phase well testing via dedicated ASEGA‐V‐3402 Test Separator on EG (aligned at 20,000blpd /
15MMScfd) & equipped with sand‐jetting internals and SWI tie-in provision in order to enable jetting
water hook-up in future and handle slug volume (Ram-up slug volume is 5 m 3, continuous cyclic
slug is 1 m3).
8. The following additional main/auxiliary equipment items:
a) HP Flare KOD (1 x 100%)
b) Diesel Storage Tank (Within Crane pedestal)
c) Diesel Distribution pump (1 x 100%)
d) Diesel Filter Coalescer (1 x 100%)
e) Closed Drain Drum (1 x 100%)
f) Closed Drain Pumps (2 x 100%, 1 working + 1 standby),
g) Open Drain Tank (1 x 100%)
h) Open Drain pumps (2 x 100%, 1 working + 1 standby),
i) Drain Caisson and a vertical submersible pump,
j) Down-hole corrosion inhibitor tank (1 x 100%)
k) DHCI injection pumps - 5 units Multi-head pumps + 1 warehouse spare (2 pumps per
motor) to cater 10 no of producer wells,
l) Topsides Corrosion Inhibitor tank (1 x 100%)
m) Topsides Corrosion Inhibitor injection pumps (2x 100%, 1 working + 1 standby),
n) Demulsifier tank (1 x 100%)
o) Demulsifier injection pumps (2x 100%, 1 working + 1 standby),
p) Antifoam tank (1 x 100%)
q) Antifoam injection pumps (2x 100%, 1 working + 1 standby),
r) Biocide tank (1 x 100%)
s) Biocide injection pumps (2x 100%, 1 working + 1 standby),

Page 28
Block 5 - AL SHAHEEN FIELD
t) Development
Chemical TOTE tanks (each 4 m3 capacity)
u) N2 Bottle rack (Flare purge back-up)

Page 29
Block 5 - AL SHAHEEN FIELD
Document Title:
DevelopmentFC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

v) Breathing Air Bottle rack (Back-up)

w) Platform Crane.

9. Other utilities such as HP Flare, Flare purge gas, Instrument Air / Utility air, Diesel, Firewater,
Service Water (continuous seawater from jockey pump), Potable Water, Inert Gas, Breathing Air,
Electric Power shall be extended from the existing host ED platform via bridge. Control and
monitoring of new Wellhead platform is executed by the new EG platform’s SCADA / ESD / F&G
system (referred as ICSS) and interfaced to the host ED platform for a centralised HMI indication.
Key Features:

 Production well testing: Wellhead inlet and test manifolds designed with manually operated well
test change-over valves (with mechanical interlock) to divert the well fluid from any one well to the
production manifold or the test manifold, for individual well testing.
 Lift gas manifold and lift gas lines to production wells with flow meter for measurement of the lift
gas flow rates with flow reading available in the SCADA system.
 Full remote adjustment (via SCADA / HMI) of SWI well chokes and Full remote control of downhole
FCVs (via SCADA / HMI; engineer level).
 The production and water injection manifolds shall be arranged in such a way that any SWI well can
be converted from a production phase to a normal water injection phase (SWI clean-up) with a
minimum piping modification.
 The following future provisions shall be considered in the design:
a) Provisions for future EH WHP process/utilities tie-ins including bridge landing, supply of all
utilities from existing facilities
b) WAG module installation provision (comprising TEG injection system, HP SWI pre-charge pumps
& HP SWI
/ GI manifolds) shall be considered with the following pre-investment:
 A 500Te future module capability (to be accommodated in jacket and pile design)
 6 inch, 1500# LTCS bridge line (HP GI) pre-installed on EG-ED bridge
 Cabinet space for future WAG I/O within EG ITR.
c) Desander unit
d) Produced water disposal facilities
 Produced water disposal line (10" BM1, 300# 6MO) over the bridge from ED
facility with capacity for 120,000bwpd.
 Produced water disposal manifold, suitable to connect one (1) future disposal well.

4.1.4 Existing Well Operational issues

The following well related operational issues are observed at existing wells in Al Shaheen field and the
similar operational issues are foreseen in new well head facilities (DC, FC & EG) and host platforms (DA,
FA & EA) also. Hence, the solutions proposed for the operational issues were studied & implemented in
design during FEED stage.
The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any
purpose not authorized by North Oil Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-

Page 30
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Development

Page 31
Block 5 - AL SHAHEEN FIELD Development
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

Table 4.1.4.1 Proposed solutions to the current operational issues.

Operation issue Root Causes Solution proposed
Liquid a. Presence of liquid ullage within the production flowlines upstream of the Start-up actuated (motorised) valve (Full bore eccentric ball
hammer choke, due to the pocketed configuration of the line (No low point drains valve, 1500#) downstream of xmas tree Wing Valve.
damage of upstream choke valves).
production b. Choke proximity to xmas tree is not minimal. This is because chokes for
well both production & SWI injection wells are located to offer convenient access
choke valves at common levels and smooth transition during clean‐up phase of WI wells.
on Start-up
1. Minimisation of flowline / surface line pockets wherever
Production a. Insufficient lift gas applied to well, for the prevalent water‐cut / BHP. practicable.
Flowline/ b. Momentum change of fluids, when transitioning from production tubing to 2. Using dual small diameter production headers, as
Bridge Line surface flowline. opposed to a single large diameter production header
Slugging across the bridge.
1. All flowlines / production headers / test liquid return lines
shall be designed with solids loading of 3ppmW.
2. Suction strainers on new DC Crude Export Pumps.
a. Design optimisation of handling solids production. 3. Automatic sand‐jetting System at ASDCA‐V‐
Carbonate b. Solids (limestone 2 – 3mm fragments) have been observed within crude 3401 Inlet Separator & ASDCA‐V‐3402 Test
Solids export pump suction strainers at Al Shaheen locations where Kharaib B non- Separator and
Production selective completions are in service. new Desander Unit, suitable to receive continuous solids‐
laden streams for clean‐up from above equipment’s.
4. Sand jetting manifold and tores are installed inside FC &
EG Test Separator (ASEGA-V-3402 & ASFCA-V-3402) for
provision of
future sand removal.
a. Insufficient DHCI injection due to following leads several corrosion 1. Provision of individual chemical injection pumps per
Corrosion
incidences within upper completions: production well (Multi-volute pumps on a common electric
Within
1. During start‐up / shut‐down wells for operational reasons affects the DHCI drive and individual calibration pots per volute).
Production
system calibration / distribution accuracy.
Well Upper
2. BHPs /chemical injection pressures down‐hole can vary with SWI
Completion
pressure fluctuations.
The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version
Major Projects Template MAJOR-ASY-MPQA-MPQA-FOR-000004_Rev00 Dated 09/06/2018

Page 21 of 62
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

5.0 GENERAL DESIGN CONSIDERATION

5.1 DESIGN LIFE

All the new facilities shall be designed for a service life of 25 years.

5.2 PLATFORM ORIENTATION

The orientation of all new WHPs are furnished as below:

DC WHP FC WHP EG WHP

5.3 DESIGN MARGINS

No additional design margin shall be applied on the design capacities of the major equipment,
manifolds & headers. The design capacities of the above are described in sections 4.1.1, 4.1.2, 4.1.3
and 7.7.
A 10% design margin shall be applied in setting the design flow rate for a pump in general service except
for Crude Export Pumps where no margin is added to pump capacity. No margin shall be added to the
differential head.

5.4 TURNDOWN ON PRODUCTION CAPACITY

Turndown requirement for DC production facilities is 11%; 10,000 blpd driven by minimum pump capacity
of a single Crude Export Pump.
Turndown requirement for EG & FC production facilities is 15%, limiting on slug behaviour across 3-phase
bridge lines.

Page 22
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

6.0 RESERVOIR PROPERTIES AND WELL FLUID COMPOSITION

6.1 WELL EFFLUENT CHARACTERISTICS

BATCH 1 wells are analogues of existing Al Shaheen well-stock. Produced fluids & flowing conditions are
similar to those produced today. Areas targeted produce medium crudes ranging in gravity between 23.5
to 26˚API. Crudes are sour, exhibiting sulphur contents in the range of 2 to 5wt%. Isotope analysis
suggests sulphur content to be from microbial sulphate reduction; SWI stream oxygen content &
biocide/oxygen scavenger loadings are critical parameters to be monitored to prevent exacerbation of
reservoir souring in this regard.
All crudes exhibit moderate alkyl wax contents in the range 4.9 to 7.9%. Wax appearance temperatures
are relatively high (20.1 to 30.9˚C), but when considered in relation to operating conditions, wax
deposition is low risk, having been observed to remain in solution in the crude streams to date:
 Flowing well head & seabed conditions are warm (39 - 50˚C & 20˚C respectively)
 Low pour points are a metric that wax gelling is not an issue.
Crudes exhibit moderate to high (>3.5wt%) asphaltene content (in the 3 - 4wt% range) at the D, E & F
locations & are flagged not so much for asphaltene deposition risk, but for the contributing effect of
asphaltene precipitates to the stability of water-in-oil emulsions. Historically this has been managed with
chemicals & this shall form the basis for BATCH 1 WHPs. Due cognisance shall be paid to propensity for
emulsion formation & fluid residence time for all new Separators.
For all Phase 2, Batch – 1 wells, following shall be considered for material selection and equipment design:
- Sour composition (Dry stream) of 10 mol% of CO2 and 2 mol% of H2S
-
Carbonate Solids Loading: 3 ppmW in production liquids (aqueous and hydrocarbon)

Page 23
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

6.2 RESERVOIR PROPERTIES AND WELL DESIGN PARAMETERS OF FIELD KHARAIB B / SHUAIBA

/MAUDDUD Table 6.2.1 Reservoir Properties & Well design parameters of field Kharaib B /

Shuaiba / Mauddud
50% Water-cut 80% Water-cut 95% Water-cut
Flowing Flowing Flowing
Reservo Reservo CITHP CITHT
GOR, 10,000blpd 10,000blpd 10,000blpd
Reservoir Location ir ir
Scf/Stb Lift Gas Lift Gas Lift Gas
Pressur Temp. FTHP FTHT FTHP FTHT FTHP FTHT
(Note4) (Note4) (Note4)
e
bar ˚C barg ˚C barg ˚C MMScf barg ˚C MMScf barg ˚C MMScf
g d d d
Kharaib DC 250 117 56 51 3 55 3 55 3
B wells
Shuaiba DC 500 111 54 47 3 52 3 52 3
wells
Kharaib FC 600 78 57 55 3 55 3 55 3
B wells
Mauddu FC 200 91 50 55 3 55 3 55 3
190
d wells 0 100 Note1 Note1 Note1
Kharaib EG 300 83 56 (Note2 55 3 55 3 55 3
B wells )
Mauddu EG 120 93 51 55 3 55 3 55 3
d wells 0
EH wells
Shuaiba 350 86 54 55 3 55 3 55 3
(Note 3)
EH wells
Mauddu 120 93 51 55 3 55 3 55 3
The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 24
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

Note
s:
1. All well flowlines downstream choke valve shall be designed for the minimum pressure of 4.0 barg.
Considering a minimum pressure drop of 0.5 bar across choke valve, the flowlines upstream choke valve shall be designed for 4.5 barg.
2. CITHP of 190 barg (2755 psig) is arrived in accordance with updated estimation of maximum closed in tubing head pressure for Al Shaheen
wells.
3. Process simulations of future EH wells (Batch - 2) shall be performed for dimensioning purpose of bridge - linked ‘EH – EG’
Production / Test Headers shall be routed from future EH wells.
4. A nominal lift gas flow rate of 3 MMScfd per production well shall be considered for process simulations and generating
HMBs. Lift gas flow per Production well is 0.5 to 3 MMScfd depending on water cut, GOR, reservoir, position in line-drive
pattern, completion lateral trajectory and efficacy of SWI local to wellbore.

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 25
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

6.3 WELL FLUID COMPOSITION OF FIELD KHARAIB B / SHUAIBA /MAUDDUD

The following composition will be used for convergence of well fluid streams of Kharaib B/Shuaiba/Mauddud.

Table 6.3.1 Well Fluid Composition (Kharaib B/Shuaiba/Mauddud Wells):

Dry Well Fluid Compositions, Mole
fraction
Component
Kharaib B Wells Shuaiba Wells Mauddud Wells
GOR 250 GOR 300 GOR 600 GOR 350 GOR 500 GOR 1200 GOR 2000
Hydrogen sulphide, 0.00140 0.00143 0.00213 0.01018 0.00730 0.00000 0.00000
H2S
Carbon dioxide, CO2 0.00060 0.00059 0.00087 0.04054 0.04830 0.02921 0.03265
Nitrogen, N2 0.00170 0.00176 0.00262 0.00092 0.00100 0.00323 0.00361
Methane, C1 0.18720 0.19336 0.28768 0.31482 0.30790 0.48463 0.54155
Ethane, C2 0.04600 0.04744 0.06959 0.02101 0.04180 0.03226 0.03600
Propane, C3 0.06410 0.06582 0.09189 0.02459 0.05680 0.05557 0.06171
i-Butane, iC4 0.02010 0.02050 0.02634 0.01732 0.01870 0.03086 0.03399
n-Butane, nC4 0.04440 0.04492 0.05355 0.01965 0.04280 0.04797 0.05245
Neo-Pentane, C5 0.00010 0.00011 0.00016 0.00000 0.00000 0.00030 0.00034
i-Pentane, iC5 0.02760 0.02760 0.02834 0.02882 0.02510 0.04518 0.04817
n-Pentane, nC5 0.01400 0.01400 0.01326 0.00287 0.01630 0.00052 0.00052
n-Hexane, C6 0.02830 0.02802 0.02357 0.01729 0.03030 0.01797 0.01788
Methyl-cyclo-Pentane, 0.00810 0.00798 0.00626 0.00000 0.00000 0.00165 0.00149
Benzene, C6 0.00120 0.00115 0.00088 0.00000 0.00000 0.00007 0.00005
Cyclohexane, C6 0.00570 0.00567 0.00457 0.00000 0.00000 0.00462 0.00419
n-Heptane, C7 0.01990 0.01963 0.01469 0.01784 0.02950 0.01119 0.00981
Methyl-cyclo-Hexane, 0.01010 0.00990 0.00735 0.00000 0.00000 0.00676 0.00564
Toluene, C7 0.00080 0.00077 0.00061 0.00000 0.00000 0.00052 0.00052
n-Octane, C8 0.02520 0.02475 0.01797 0.02511 0.03050 0.01194 0.00902
Ethyl-Benzene, C8 0.00220 0.00219 0.00160 0.00000 0.00000 0.00105 0.00075
Para-xylene, C8 0.01100 0.01081 0.00778 0.00000 0.00000 0.00110 0.00074
Ortho-Xylene, C8 0.00380 0.00378 0.00273 0.00000 0.00000 0.00055 0.00035
n-Nonane, C9 0.02110 0.02074 0.01498 0.02494 0.02600 0.00950 0.00684
Tri-Methyl-Benzene, 0.00530 0.00507 0.00363 0.00000 0.00000 0.00087 0.00056
C9
Decanes, C10 0.03800 0.03227 0.02319 0.02726 0.02730 0.01178 0.00796
Undecanes, C11 0.00000 0.00000 0.00000 0.00000 0.00000 0.00023 0.00025
Dodecanes, C12 0.00000 0.00000 0.00000 0.00000 0.00000 0.00008 0.00008
khLC11-19, pseudo 0.20760 0.20906 0.14987 --- --- --- ---
khLC20-35, pseudo 0.13030 0.12795 0.09172 --- --- --- ---
khLC36+, pseudo 0.07410 0.07275 0.05215 --- --- --- ---
shLC11-15, pseudo --- --- --- 0.12012 0.11210 --- ---
shLC16-19, pseudo --- --- --- 0.06904 0.06190 --- ---

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Block 5 - AL SHAHEEN FIELD
shLC20+, pseudo --- --- --- 0.21767 0.11650 --- ---

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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Dry Well Fluid Compositions, Mole

fraction
Component
Kharaib B Wells Shuaiba Wells Mauddud Wells
GOR 250 GOR 300 GOR 600 GOR 350 GOR 500 GOR 1200 GOR 2000
MaLC11-19, pseudo --- --- --- --- --- 0.09425 0.06084
MaLC20-35, pseudo --- --- --- --- --- 0.06299 0.04066
MaLC36+, pseudo --- --- --- --- --- 0.03315 0.02140
Total 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000

The following will be used for the characterization of the heavy fractions in the above well fluid
composition. Table 6.3.2 Characterisation Data for Heavy Fractions (Kharaib
B/Shuaiba/Mauddud Wells)
Molecular
Components Weight Density NBP (°C)
(kg/m3)
(kg/kmole)
KhLC11-19 197.53 825.97 254.44

KhLC20-35 343.42 888.51 397.29

KhLC36+ 681.4 1080.62 488.56

ShLC11-15D 174.01 813.50 223.13

ShLC16-19D 241.16 851.90 305.99

ShLC20+D 612.00 976.00 479.59

MaLC11-19 199.43 827.27 256.87

MaLC20-35 345.49 889.11 398.78

MaLC36+ 696.00 1094.10 488.56

6.4 LIFT GAS COMPOSITION

Lift gas composition facilitated in the simulation is summarized in below

Table 6.4.1. Lift gas water content is 3.5lb/MMScf at the outlet of TEG
dehydration unit.

Table 6.4.1 Lift Gas Composition

Lift Gas Composition,
Component
Mole fraction
Hydrogen sulphide, H2S 0.00120
Carbon dioxide, CO2 0.01350
Nitrogen, N2 0.01160
Methane, C1 0.82560
The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any
purpose not authorized by North Oil Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-

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Block 5 - AL SHAHEEN FIELD
Ethane, C2 0.05720

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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Lift Gas Composition,

Component
Mole fraction
Propane, C3 0.04490
i-Butane, iC4 0.01170
n-Butane, nC4 0.01950
Neo-Pentane, C5 0.00000
i-Pentane, iC5 0.00850
n-Pentane, nC5 0.00380
n-Hexane, C6 0.00250
Methyl-cyclo-Pentane, C6 0.00000
Benzene, C6 0.00000
Cyclohexane, C6 0.00000
n-Heptane, C7 0.00000
Methyl-cyclo-Hexane, C7 0.00000
Toluene, C7 0.00000
n-Octane, C8 0.00000
Ethyl-Benzene, C8 0.00000
Para-Xylene, C8 0.00000
Ortho-Xylene, C8 0.00000
n-Nonane, C9 0.00000
Tri-Methyl-Benzene, C9 0.00000
Decanes, C10 0.00000
Undecanes, C11 0.00000
Dodecanes, C12 0.00000
Total 1.00000

6.5 FLUID VISCOSITY DATA

Dry crude viscosity data for BATCH-1 new drills is summarized in

Table 6.5.1 Table 6.5.1 Dry Crude Viscosity Data

Description Kharaib B Shuaiba Mauddud

Dry oil viscosity, cP 6.442 18.56 14.378

PW viscosity, cP 0.471 0.501 0.544
Temperature, ˚C 58.9 55 50

Al Shaheen produced fluids have tendency to form emulsions due to presence of high salt content water,
asphaltenes, FeS (Iron (II) Sulfide) and carboxylate soaps. Al Shaheen fluid emulsion inversion point is
typically 70-80% water-cut.

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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

For line sizing of topside production/test manifolds & headers, emulsion viscosity effects shall not be
considered. However, for 2-phase (Oil + water) crude export lines, volume-weighted average viscosity
(dead oil: produced water) shall be considered.

6.6 PRODUCED SOLIDS LOADING

For DC WHP, the expected carbonate solids (Density: 2,731 kg/m 3) loading shall be 3ppmW within liquid
(Oil + Water) phases. This is equivalent to circa 45 kg/day continuous production rate.
Sand treatment system comprises:

 Sand jetting headers / sand-jet nozzles / pans / vessel outlet

nozzles (Inside Inlet Separator, ASDCA‐V‐3401 & Test Separator,
ASDCA‐V‐3402)
 Sand slurry drain piping
 Sand cleaning package (ASDCA-A-3401)

Solid deposited on the bottom part of each separator / vessel shall be flushed with jetting water and shall
be routed to sand treatment package through dedicated separator drain valves. The package shall
periodically receive the bottom flushings fluid from the separators / vessel to recover the contaminated oil
and dispose of the sand produced into the open drain caisson (skim pile). The flushed feed to sand
treatment package will contain mainly sand, produced water (reservoir water), jet water (de-aerated
seawater), limited amount of oil and dissolved hydrocarbon gas which is saturated at separator operating
conditions. Separated Solid cleaning system shall be designed to handle the single largest feed rate from
any of the source feed as defined above.

The sand removal, cleaning & disposal system is intermittent operation. The sand removal from each
of the process vessel (Inlet Separator & Test Separator) shall be on one by one basis and the sand
treatment system shall be designed to receive the slurry from one vessel at a time. The solids deposited
in the bottom of the separators shall be periodically flushed to the sand treatment package, which
shall clean the oily sand by means of sand washing cycles (Timer based) to minimise oil contamination
to the acceptable level. The maximum oil content in effluent leaving Sand treatment system prior to
disposal via Caisson shall be <=30 mg/l.

For FC WHP & EG WHP, future sand treatment system shall be considered in design for layout and weight
estimation purpose. The FC & EG Test Separators shall be equipped with sand-jetting internals and SWI
tie-in provision in order to enable jetting water hook-up in future.

7.0 BASIS OF DESIGN FOR DC / FC / EG PLATFORMS

7.1 SLOT ALLOCATION FOR WELLHEAD PLATFORMS – DC / FC / EG

Table 7.1.1 Summary of Producer wells & SWI wells for Phase 2, Batch-1 WHPs:
The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any
purpose not authorized by North Oil Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-

Page 31
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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Post Topside No. Platfor

Pre-Drilled
Installation of m size,
New WHP Reservoir
Spar No. of
Producer SWI Producer SWI
e Slots
slots

Kharaib B (KB) 2 1 4 6

DC Shuaiba (SH) - 2 1 1 6 24

Umm - 1 - -

Kharaib B (KB) 2 2 5 6
FC
2 24
(HOLD3 Upper Mauddud - 3 4
)

Kharaib B (KB)
EG (Note
Upper Producer - 10 5 24
1)
Mauddud SWI – 9
(HOLD3)
(UM)

Note 1. One (1-off Umm Er-Rhaduma) future Produced water disposal well shall be considered in EG
WHP.

7.2 WELLHEAD CONFIGURATION - PRODUCERS

Each Producer well shall be equipped with remote actuated SSSV, MCV, WCV. Xmas tree shall be API 5000

rated & Tree size shall be 41/16”. Start-up actuated (motorised) valve (Full bore eccentric ball valve,
1500#) shall be installed downstream of xmas tree Wing Valve. Topside piping interface for BATCH 1 wells
shall be designed for inadvertent shut- in at production manifold / test manifold / production header
(including bridge lines), by closure of choke / test production switching valve (MOV) / battery limit
interface ESDV respectively. For producer well design parameter details, refer to section 6.2 above.

The CITHP relief case is single WAG well capacity as a worst case and this shall be the basis for sizing the
Production Manifold PSVs. CITHP shall be considered at 2,755 psig (190 barg), consistent with;

 Injection choke wide open & 1,740psig (120barg) SWI pressure at manifolds
 Kharaib B (deepest)
 Open fracture to adjacent producer
 Gas‐filled tubing & gas‐gradient to surface

The LOPA calculations conducted by COMPANY concluded with the level of instrumented protection on the
flowlines, the mitigated frequency of overpressure events for 900# producer flowlines is acceptable.

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Production flowlines (upstream & downstream of choke), production & test manifolds, production headers
& bridge lines shall be 900# rated. The

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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

production manifold shall be protected with PSVs sized for gas flow from a single well. Depressuring of
flow lines (for maintenance access) shall follow the existing practice, which is to depressurize via Test
Separator vent line. A depressurised state not greater than 3.5barG shall be achieved before opening
closed drain connections.
Flexible hose connection shall be used for any well head casing venting as per current Al Shaheen practice.

7.3 WELLHEAD CONFIGURATION – SEA WATER INJECTORS

Each WI well shall be equipped with remote actuated SSSV, MCV and WCV & Xmas tree shall be rated for

API 5000 & Tree size shall be 41/16”. Topside piping interface for BATCH 1 shall be designed for inadvertent
shut-in at choke / SWI manifold / SWI header, by closure of choke / header manual isolation valve / battery
limit interface manual isolation valve respectively.

CITHP of WI well shall be considered at 2,755 psig (190 barg) similar to Producer well. The overpressure
case is due to subsurface gas breakthrough. The FTHP of 110 – 120 barg with FTHT of 20 °C shall be
considered.

SWI flowlines (upstream & downstream of choke), SWI manifold, SWI header shall be 1,500# rated.

7.4 DESIGN BASIS OF PRODUCTION WELL FLOW LINES – DC

The following shall be the basis for sizing of production flowline and choke valve

of DC WHP. Table 7.4.1 Design Basis of Production Well Flowlines - DC Platform:

Case 1 (WC 50%) Case 2 (WC 80%) Case 3 (WC 95%)
Descriptio
n Kharaib Shuaiba Kharaib Shuaiba Kharaib Shuaib
B B B a
Water cut, vol % 50 50 80 80 95 95

Max. Liquid flowrate, blpd 10,000 10,000 10,000 10,000 10,000 10,000

Oil Flow Rate, bopd 5000 5000 2000 2000 500 500

Produced Water Flowrate, bwpd 5000 5000 8000 8000 9500 9500

GOR, scf/stb 250 500 250 50 250 500

0
Associated Gas Flowrate, 1.25 2.5 0.5 1.0 0.125 0.25
MMScfd
Lift Gas Flowrate, MMScfd 3.0 3.0 3.0 3.0 3.0 3.0

DC Inlet Separator Operating

7 7 6 6 5.75 5.75
Pressure, barg (Note 1 & 2)

Notes:
1. Inlet Separator operating varies from 5.75 barg to 7 barg to effect free flow of wet gas through existing

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Block 5 - AL SHAHEEN FIELD
24” wet gas Pipeline (24”PL-AS-DB-ED-51) and ensure 2.8 barg at ED gas compressor’s suction. The
design pressure of DC Inlet

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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

separator and DC Test separator shall be aligned at 13.8 barg based on the above operating pressure and
host reception facilities.
2. All well flowlines downstream choke valve shall be designed for the minimum pressure of 4.0 barg.
Considering a minimum pressure drop of 0.5 bar across choke valve, the flowlines upstream choke valve
shall be designed for 4.5 barg.
For all WHP process simulations, refer to “DC Well head platform Process Simulation Report, Doc. No.:
WHP01-PMC1- ASDCA-04-340001-0001.

7.5 DESIGN BASIS OF PRODUCTION WELL FLOW LINES – FC

The following shall be the basis for sizing of production flowline and choke valve of

FC platform. Table 7.5.1 Design Basis of Production Well Flowlines - FC Platform:

Case 1 (WC 50%) Case 2 (WC 80%) Case 3 (WC 95%)

Descriptio
n Kharaib Mauddu Kharaib Mauddu Kharaib Mauddud
B d B d B
Water cut, vol % 50 50 80 80 95 95
Max. Liquid flowrate, blpd 10,000 10,000 10,000 10,000 10,000 10,000
Oil Flow Rate, bopd 5000 5000 2000 2000 500 500
Produced Water Flowrate, 5000 5000 8000 8000 9500 9500
bwpd
GOR, scf/stb 600 2000 600 2000 600 2000
Associated Gas Flowrate, 3.0 10.0 1.2 4.0 0.3 1.0
MMScfd
Lift Gas Flowrate, MMScfd 3.0 3.0 3.0 3.0 3.0 3.0
FA Inlet Separator Operating
9.5 9.5 8 8 5.5 5.5
Pressure, barg (Note 1)
Notes:
1. FA Inlet Separator operating varies from 5.5 barg to 9.5 barg to effect free flow of wet gas through
existing 18” wet gas Pipeline (18”PL-AS-FB-GA-53) and ensure 2.3 barg at GD gas compressor’s suction.
The design pressure of FC Test separator shall be aligned at 17 barg based on FA Inlet separator
operating pressure.
2. All well flowlines downstream choke valve shall be designed for the minimum pressure of 4.0 barg.
Considering a minimum pressure drop of 0.5 bar across choke valve, the flowlines upstream choke valve
shall be designed for 4.5 barg.
For all WHP process simulations, refer to “FC Well head platform Process Simulation Report, Doc. No.:
WHP01-PMC1- ASFCA-04-340001-0001.

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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

7.6 DESIGN BASIS OF PRODUCTION WELL FLOW LINES – EG

The following shall be the basis for sizing of production flowline and choke valve of

EG platform Table 7.6.1 Design Basis of Production Well Flowlines - EG Platform:

Case 1 (WC 50%) Case 2 (WC 80%) Case 3 (WC 95%)

Descriptio
n Kharaib Mauddu Kharaib Mauddu Kharaib Mauddu
B d B d B d
Water cut, vol % 50 50 80 80 95 95
Max. Liquid flowrate, blpd 10,000 10,000 10,000 10,000 10,000 10,000
Oil Flow Rate, bopd 5000 5000 2000 2000 500 500
Produced Water Flowrate,
5000 5000 8000 8000 9500 9500
bwpd
GOR, scf/stb 300 1200 300 1200 300 1200
Associated Gas Flowrate,
1.5 6.0 0.6 2.4 0.15 0.6
MMScfd
Lift Gas Flowrate, MMScfd 3.0 3.0 3.0 3.0 3.0 3.0
ED Inlet Separator
Operating 2.8 2.8 2.8 2.8 2.8 2.8
Notes:
Pressure, barg (Note 1)
1. Separator operating pressure of 2.8 barg is to ensure free flow of wet gas to ED gas compressor’s
suction. The design pressure of EG Test separator shall be aligned at 13.8 barg based on ED Inlet
separator operating pressure.
2. All well flowlines downstream choke valve shall be designed for the minimum pressure of 4.0 barg.
Considering a minimum pressure drop of 0.5 bar across choke valve, the flowlines upstream choke valve
shall be designed for 4.5 barg.
For all WHP process simulations, refer to “EG Well head platform Process Simulation Report, Doc. No.:
WHP01-PMC1- ASEGA-04-340001-0001.

7.7 DESIGN CAPACITY OF FLOWLINES AND MANIFOLDS

The following Tables summarise the design capacity of manifolds such as production manifold, test
manifold, water injection manifold and lift gas manifold and flowlines such as water injection flow line and
lift gas flowline.

Page 38
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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Table 7.7.1 Design Capacity of Flowlines/Manifolds for DC WHP

No. of manifold / Flange Process
Design
connections Rating Design
Description Conditions Remarks
Capacit
Pressure Temp.
Manifol Connectio ANSI y ,
d ns # , barg
oC
Production 90 kblpd +
2 10 + 10 900# 139.5 93/-15 East & West side
Manifolds 100 manifolds
MMScfd
20 kblpd+
Test Manifolds 2 10 + 10 900# 139.5 93/-15 East & West side
15 MMScfd manifolds
SWI Manifolds 2 7+7 1500# 120 kbwpd 228 93/0 East & West side
manifolds
SWI Flowlines - - 1500# 20 kbwpd 228 93/0

Lift Gas 2 8+8 900# 35 MMScfd 139.5 93/-29 East & West side
Manifolds manifolds
Lift Gas Flowline - - 900# 3 MMscfd 139.5 93/-29
HP GI WAG Future: Layout, weight &
Note 1 Note 1 1500# 50 MMScfd 228 93/-29
Manifold (Note spare I/O allocation only
1)

Note
:
1. The design basis for future WAG is (i) 25MMScfd of HP gas injection per well (ii) Two (2) wells in
sequence for either HP gas injection or HP water injection.

Table 7.7.2 Design Capacity of Flowlines/Manifolds for FC WHP

No. of manifold / Flange
Design
connections Rating Design Conditions
Description Remarks
Capacit Pressure Temp.
Manifol Connectio ANSI ,
d ns # y , barg
oC
Production 90 kblpd +
2 10 + 10 900# 139. 93/-15 East & West side
Manifolds 100 5 manifolds
MMScfd
20 kblpd+
Test Manifolds 2 10 + 10 900# 139. 93/-15 East & West side
15 MMScfd 5 manifolds
SWI Manifolds 2 7+7 1500# 120 kbwpd 228 93/0 East & West side
manifolds
SWI Flowline - - 1500# 20 kbwpd 228 93/0

Lift Gas
2 8+8 900# 31 MMScfd 139. 93/-29 East & West side
Manifolds 5 manifolds

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Block 5 - AL SHAHEEN FIELD
Lift Gas - - 900# 3 MMscfd 139. 93/-29
Flowline 5
HP GI WAG For Layout, weight &
Note 1 Note 1 1500# 50 MMScfd 228 93/-29 spare
Manifold (Note
1) I/O allocation only

Page 40
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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Note:
1. The design basis for future WAG is (i) 25MMScfd of HP gas injection per well (ii) Two (2) wells in sequence for
either HP gas injection or HP water injection.

Table 7.7.3 Design Capacity of Flowlines/Manifolds for EG WHP

No. of manifold Flange

/ Design
Rating Design Conditions
Description connections Remarks
Capacit
Pressure Temp.
Manifol Connectio ANSI y ,
d ns # , barg
oC

Production 90 kblpd +
2 10 + 10 900# 139.5 93/-15 East & West side
Manifolds 75 MMScfd manifolds
20 kblpd+
Test Manifolds 2 10 + 10 900# 139.5 93/-15 East & West side
15 MMScfd manifolds
SWI Manifolds 2 7+7 1500# 120 kbwpd 228 93/0 East & West side
manifolds
SWI Flowline - - 1500# 20 kbwpd 228 93/0
Lift Gas
2 8+8 900# 31 MMScfd 139.5 93/-29 East & West side
Manifolds manifolds
Lift Gas - - 900# 3 MMscfd 139.5 93/-29
Flowline
HP GI WAG For Layout, weight &
Note 1 Note 1 1500# 50 MMScfd 228 93/-29 spare
Manifold (Note

Note:
1. The design basis for future WAG is (i) 25MMScfd of HP gas injection per well (ii) Two (2) wells in sequence for

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either HP gas injection or HP water injection.

The following facilities (future) shall be considered in design for layout & weight allocation purpose. These will
facilitate conversion of Water Injection well to WAG (Water Alternating Gas) in near future. Future WAG well
operation shall be designed in such a way that maximum two (2) WAG wells in operation at a time (HOLD 1):
 HP GI Manifold
 WAG Service Water Booster Reciprocating Pump Skids
 TEG Injection Skid

The following design capacities of EH wells shall be used for dimensioning purpose of bridge - linked EH – EG
Production / Test Headers routed from future EH wells.

Page 42
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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Table 7.7.4 Design Capacity of Manifolds / Headers for future EH WHP:

No. of Design Capacity Design Conditions
Description Manifold Remarks
Pressure, Temp.,
Connections barg o
C
East & West
Production 2 90 kblpd + 100 143.6 82/-46 side
Manifolds MMScfd
manifolds
East & West
Test Manifolds 2 20 kblpd+ 15 143.6 82/-46 side
MMScfd
manifolds

8.0 PROCESS AND UTILITIES INTERFACE

Process and Utilities of new WHPs (DC, FC & EG) shall be integrated with host platforms DA, FA & ED
respectively. The interface details of process & utilities including design / operating details are indicated in
the below Tables:

Page 43
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Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

Table 8.1 Process and Utility interface details across ‘DC – DA’ bridge
DA Exist. Line DC New Line Process Design
Operating Conditions Remarks
Size /Spec. Size / Spec Rating Conditio
Description
(Existing/Ne ns
w) Press Tem Press Tem
in in Flow
. p . p
(barg (˚C) (barg (˚C)
) )
Existing 300#crude
900#/600# export header at the DA
Crude export Header 14” / ED 14” / DD1 90,000 blpd 38 55 46.6 -15/93
(Note 3) crude export pumps to
be replaced by 600#.
300#/150# At low points, the wet
Inlet Sep. Gas Header 24” / BD 24” / AD1 100 MMScfd 4- 7 27 - 45 13.8 -20/93
(Note 2) gas pipe is AM1 (6Mo
Water Injection 18” / ED 12” / ED1 900#/ 900# 120,000 bwpd 120 19 - 45 139.5 0/93 material)
Header
Lift Gas 10” / B 10” / ED1 900#/ 900# 35 MMScfd 120 19 139.5 -29/93
31.8XX
Purge for Flare
Flare Purge gas 2” / AD 2” / AD1 150#/ 150# 80 Nm3/h 2 45 13.8 -10/93
headers Drilling
Diesel 2” / AB 2” / AD1 150#/ 150# 5.24 m3/h 5 35 10 0/93
contingency
Inert Gas 1” / IT 2” / AS1 Tubing / 150# 15.2 Nm3/h 7 40 14.8 0/93 OD Caisson
blanket/pump seal pots
Utility Air 2” / AG 2” / AS1 150#/ 150# 50 Nm3/h 5.5 - 8.5 40 10.3 0/93
Instrument Air 2” / AG 2” / AS1 150#/ 150# 108 Nm3/h 5.5 - 8.5 40 10.3 0/93
Bridge IA line
Breathing Air 1” / IT 2” / BS1 Tubing / 300# 72 Nm3/h 5.5 - 8.5 40 33 5/93
18” For 30 POB
Potable Water 2” / AK 2” / AD1 150#/ 150# 4.5 m3/h 5 35 15.9 0/60 Safety shower/eye wash

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 44
Block 5 - AL SHAHEEN FIELD
HP Flare Header 28” / AD 20” / AD1 150#/ 150# 40.35 MMScfd 1.8 – 2.5 21 - 54 10.3 -46/130 stations
Note 1 (DC WHP+ ‘DC-
Service Water 2” / AK 2” / AR1 150#/ 150# 30 m3/h 9 23 15.9 0/60 DA’
bridge fire load)
2 Utility hoses ex.
FW system

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 45
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

DA Exist. Line DC New Line Process Design

Operating Conditions Remarks
Size /Spec. Size / Spec Rating Conditio
Description
(Existing/Ne ns
w) Press Tem Press Tem
in in Flow
. p . p
(barg (˚C) (barg (˚C)
) )
Wet Gas ½” / IT & 2” / Tubing /
½” / IT 4.2 lph 6- 9 48 350 5/93
Corrosion GX1 2500#
Inhibitor
Fire Water 16” / AR 12” / AR1 150# / 150# 60 – 475 m3/h 9 - 9.7 5-50 16 0/60

Note 1. DC WHP HP Flare System & Closed Drain System are designed for 10.3 barg in line with host HP Flare System. Therefore, the
vapour outlet line from Closed Drain Drum is interconnected with HP Flare header at DC WHP. CFD analysis for the HP Flare KO
Drum/Closed Drain Drum system shall be performed to establish that the deflagration over-pressure is <= 10.3 barg (HOLD 2)
Note 2. Refer WHP01-00267-RCE1-MPEN-TQR-000037 for interconnection 150#/300# tie-in.
Note 3. Crude export pump line is 600# piping and is protected by PSV set @300#. The line is connected to existing pipeline @900#.
Therefore, connection 600# to 900# will not impact on existing and new WHPs.

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 46
Block 5 - AL SHAHEEN FIELD

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 47
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

Table 8.2 Process and Utility Interface details across ‘FC – FA’ bridge
FA Exist. FC New Line Process
Operating Conditions Remarks
Line Size Size / Spec Rating
Description
/Spec. (Existing/Ne Design
w) Conditions
Press Tem Press Tem
in in Flow
. p . p
(barg (˚C) (barg (˚C)
) )
Test FC Sep. Gas 300#/ 150#
18” / BD 10” / AD1 15 MMScfd 6.5 - 10 28 - 54 17 -20/93
Header (Note 2)
90kblpd, 2 x 18” 900# bridge
Production Header 32” / AB 26” / AD1 150#/ 150# 6.5 - 10 40 - 52 17 -20/93
100 lines from East/West
MMScfd manifolds Tie-in to
Test FC Liquid (see Remarks) 8” / AD1 150#/ 150# 20,000 blpd 6.5 - 10 28 - 54 17 -20/93 new
26”/AD1
FC Closed production header.
Drain Liquid
(see Remarks) 4” / AM1 150#/ 150# 30 m3/h ~11.1 5 - 50 17.7 -20/93 Connect to Test FC liquid
bridge line.
SWI Header 10” / ED 18” / ED1 900#/ 900# 120,000 bwpd 120 20 - 35 139.5 0/93 Normally no flow.

Lift Gas 10” / ED 6” / ED1 900#/ 900# 31 MMScfd 120 19 139.5 -29/93
Flare Purge gas 2” / AD 2” / AD1 150#/ 150# 190 Nm3/h 2 45 13.8 -10/93
Diesel 2” / AB 2” / AD1 150#/ 150# 5 m3/h 5 35 10 0/93 Purge for Flare

Inert Gas 1” / IT 2” / AS1 Tubing / 150# 15.2 Nm3/h 7 40 14.8 0/93 headers Drilling
contingency
Utility Air 2” / AG 2” / AS1 150#/ 150# 50 Nm3/h 5.5 - 8.5 40 10.3 0/93 OD Caisson
Instrument Air 2” / AG 2” / AS1 150#/ 150# 96.5 Nm3/h 5.5 - 8.5 40 10.3 0/93 blanket/pump seal
pots
Breathing Air 1” / IT 2” / BS1 Tubing / 300# 72 Nm3/h 5.5 - 8.5 40 33 5/93

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 48
Block 5 - AL SHAHEEN FIELD
Potable Water 2” / AK 2” / AD1 150#/ 150# 4.5 m3/h 4 35 15.9 0/60

HP Flare Header 28” / AD 16” / AD1 150#/ 150# 43 MMScfd 1.8 – 2.5 21 - 54 10.3 -46/130 Bridge IA line
16” For 30 POB
Safety shower/eye
wash stations
Note 1 (FC WHP+ ‘FC-FA’
bridge fire load)

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 49
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

FA Exist. FC New Line Process

Operating Conditions Remarks
Line Size Size / Spec Rating
Description
/Spec. (Existing/Ne Design
w) Conditions
Press Tem Press Tem
in in Flow
. p . p
(barg (˚C) (barg (˚C)
) )
2 Utility hoses ex.
Service Water 2” / AK 2” / AR1 150#/ 150# 30 m3/h 9 23 15.9 0/60

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 50
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

Table 8.3 Process and Utility Interface details across ‘EG – ED’ bridge
ED Exist. Line EG New Line Process
Operating Conditions Remarks
Size /Spec. Size / Spec Rating
Description
(Existing/Ne Design
w) Conditions
Press Tem Press Tem
in in Flow
. p . p
(barg (˚C) (barg (˚C)
) )
Test Sep. Gas 34” / AD 10” / AD1 150#/ 150# 15 MMScfd 3.8 – 4 54 - 55 13.8 -20/93
Header 4 x 18” 900# bridge
headers, EG & EH East/West
32 & 36” / 270,000 blpd manifolds. Combined
Production Header 36 & 42” / AD 150#/ 150# 2.8 46 - 51 13.8 -20/93
AD 175 MMscfd capacity of EG, EH & D
1 location liquid
Tie-in to new
Test EG Liquid (see 8” / AD1 150#/ 150# 20,000 blpd 3.8 – 4 54 - 55 13.8 -20/93 32”/AD1 production
Remarks) header.
Connect to EG
EG & EH Closed Production
Drain Liquid
(see 4” / AM1 150#/ 150# 30 m3/h 7.6 - 10 5 - 50 13.8 -20/93
Manifold West bridge line.
Remarks)
Normally no flow.
Water Injection For both EG & EH, split into
24” / ED 16” / ED1 900#/ 900# 240,000 bwpd 120 20 - 35 139.5 0/93
Heade two 12” individual lines on
r EG
Lift Gas 10” / FD 8” / ED1 1500#/ 900# 62 MMScfd 119 70 139.5 -29/93 For both EG & EH, split into
two 6” individual lines on EG
Flare Purge gas 6” / AS 3” / AD1 150#/ 150# 180 Nm3/h 2 38 7 -10/93 Purge for Flare headers for
EG & EH
Diesel 2” / AD 2” / AD1 150#/ 150# 5 m3/h 5 35 10 0/93
Drilling contingency
Inert Gas 3” / AG 2” / AS1 150 / 150# 13 Nm3/h 7 40 14.8 0/93 OD Caisson blanket/pump

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 51
Block 5 - AL SHAHEEN FIELD
seal pots for EG & EH
Utility Air 4” / AG 2” / AS1 150#/ 150# 50 Nm3/h 5.5 - 8.5 40 10.3 0/93
Intermittent Operation
Instrument Air 4” / AG 2” / AS1 150#/ 150# 62.2 Nm3/h 5.5 - 8.5 40 10.3 0/93 (HOLD 4) Bridge IA line 12”
3
Per WHP (EG or EH)
Breathing Air 1-1/2” / AS 2” / AS1 Tubing / 150# 72 Nm /h 5.5 - 8.5 40 13.3 5/93
Per WHP (EG or EH)

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 52
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class 01
:

ED Exist. EG New Line Process

Operating Conditions Remarks
Line Size Size / Spec Rating
Description
/Spec. (Existing/Ne Design
w) Conditions
Press Tem Press Tem
in in Flow
. p . p
(barg (˚C) (barg (˚C)
) )
Potable Water 2” / AR 2” / AR1 150# 150# 4.5 m3/h 5 35 15.9 0/60 Safety shower/eye wash
/ stations
Note 1 (EG WHP+ ‘EG-ED’
HP Flare Header 28” / AD 18” / AD1 150# 150# 53.38 MMScfd 1.8 – 2.5 1 - 54 10.3 -46/130
bridg fire
/ 9

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose not authorized by North Oil
Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS for the updated version

Page 53
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

8.1 CHEMICAL INJECTION SYSTEM

Inventory per chemical shall be 2 weeks, to be stored/dispensed on the platform. The sizing of chemical
storage tanks and dosing pumps shall be based on the current dosing levels by Al Shaheen Operations
and MSDS data (Refer to Appendix 02). All TOTE tanks/portable containers shall be manageable by
platform crane & stored on a designated lay-down area in readiness for quick connection/gravity transfer
to fixed chemical tanks. Provision in wellhead flowlines shall be made for Methanol injection during well
start-up.
The details of production chemicals for Al Shaheen field are tabulated
below: Table 8.1.1 Details of Production Chemicals for Dosing
Loading,
Chemical Name Service Injection Points Phase
ppmv
Down-hole
CECA NORUST 753 corrosion Individual production 30 Water
wells
inhibitor (DHCI)
Topside corrosion Test manifolds &
CECA NORUST 170 Production 20 Water
inhibitor
manifolds
Test separator /Inlet
separator
MiSWACO EPT-3296 Biocide 300 Water
sand-jet headers, Diesel
storage Tank & Closed
drain drum
Test manifolds &
NALCO CHAMPION X- Demulsifier Production 15 Total
8672 liquid
manifolds
Test manifolds &
NALCO CHAMPION AF- Antifoam Production 5 Total
340 liquid
manifolds
Wet Gas Corrosion 1
NORUS IG 57 QAT Inlet Separator gas Gas
Inhibitor (WGCI) outlet litre/
MMScf

Injection of each chemical (Except DHCI) shall be via dual (2x100%) redundant electric motor driven
reciprocating dosing pumps (one operating + one standby) are provided for each service, equipped with
stroke adjustment/full flow over-pressure protection/ calibration pots per pump. Six (5 Working + 1
warehouse spare) DHCI multi-head pumps shall be installed and can cater the injection requirements of
10 producer wells individually i.e. each producer well will have a dedicated DHCI pump. Each pump head
shall have a dedicated stroke adjustment, pulsation dampener, self- actuating pressure control (pump
min. flow line), pressure relief valve and Coriolis flow meter. One warehouse pump unit shall be kept
as a spare unit.

Page 54
Block 5 - AL SHAHEEN FIELD
The storage areas of both tote tanks and compartmentalized chemical storage tanks shall be provided
with bund/drip tray to contain any spillage/leak of chemicals during unloading operation. To prevent cross
contamination of chemicals while unloading from the tote tanks different colour coding shall be used for
different chemicals in-line with current Al Shaheen practice.

Page 55
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

As DC WHP will have dedicated Inlet Separator, Wet gas corrosion inhibitor injection (WGCI) is done in DC
Inlet separator wet gas outlet before being sent to export ‘E’ location. Wet gas corrosion inhibitor is
tapped from DA platform & routed via 2” DC – DA bridge piping.

All production chemicals foreseen for DC, FC & EG WHPs are identical to those already in use at host
facilities.

9.0 PROCESS AND EQUIPMENT DESIGN CRITERIA

9.1 MAXIMUM DESIGN TEMPERATURE

Maximum design temperature to be greater than of the below:

- Normal OT + 15 °C
- Maximum surface temperature due to solar radiation
The maximum design temperature of the first equipment downstream of a cooler (other than air cooler) to
be at least the cooler upstream MOT. The exceptional temperature generated by fire is not considered to
specify the maximum design temperature.
Design temperature may have to be increased to take into account the transient operating modes (e.g.
pigging, shutdown, restart, steam-out, defrost), cyclic operation (e.g. regeneration, backwash), turndown
conditions, equipment ageing/fouling and upsets.

9.2 MINIMUM DESIGN TEMPERATURE

The Minimum design temperature shall be the more stringent of the following

- Minimum OT (obtained during normal operation, start-up, shutdown or process upsets) with the
margin of (-)5
°C.
- Minimum temperature occurring during depressurising.
- Minimum ambient temperature. Lowest temperature shall be based on available environmental data.

9.3 MAXIMUM DESIGN PRESSURE

Systems and components shall be protected according to the relevant international recommended
practices such as API RP 14C and API STD 520/521.
The main production system is designed to withstand 900# (139.5 barg) @ 93 degC. Process and utility
lines are adopted to design condition of host systems which already have design pressure/design
temperature set in order to minimize the HP/LP and HT/LT interfaces. The following criteria are in
accordance with SD-NOC-ECP-103.
Table 9.3.1 Maximum design pressure of equipment with positive operating pressure:

Page 56
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Maximum Design Pressure, barg

Normal OP, barg PSV Discharging to PSV Discharging to a
Atmosphere Flare
<1 2
3.5
1 < normOP < 2.5 normOP + 1 bar
2.5 < normOP < 10 normOP + 1 bar
10 < normOP < 150 normOP + 10%
> 150 normOP + 15 bar
Centrifugal pump Maximum pump shut-off pressure (Note 1)
Positive
normOP + 2 bar
displacement pump
discharge
normOP < 10 barg
Positive
normOP + 20%

displacement pump
discharge

Note 1: The maximum shut-off pressure is the discharge pressure of the pump at no flow with the
maximum suction pressure (suction drum at design pressure + static head at maximum specific gravity
and LAH) and maximum driver speed (in case of variable speed drive).
When the centrifugal pump curve is not yet known, the maximum shut-off pressure should be estimated
using the following formula:
Pd = Psmax + (1.2 * head * dmax) /
10.2 Where,
Pd – Design pressure at pump discharge (barg)
Psmax – Design pressure of suction drum + static head at dmax and at
LAH (barg) Head - Head of the pump at rated flow rate (m)
dmax – Maximum possible specific gravity of pumped liquid

9.4 MINIMUM DESIGN PRESSURE

When a minimum design pressure is specified, the coincident design temperature shall be defined and
specified on the equipment datasheet.
Table 9.4.1 Min. Design pressure criteria (Reference: SD-NOC-
ECP-103)
normOP (bara) Lower design pressure (bara)

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Block 5 - AL SHAHEEN FIELD
< 0.35 Full vacuum
0.35 < normOP < 0.6 normOP - 0.1 bar
> 0.6 0.5

Page 58
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

9.5 EQUIPMENT SIZING CRITERIA

The sizing criteria for all new equipment items in WHPs shall be generally in accordance with COMPANY
standard “Process Design Criteria, SD-NOC-ECP-103”. The process design criteria and design guidelines
specific to WHP equipment items are given in the following sections.

9.5.1 2 - Phase and 3 - Phase Separator Sizing

The Test Separator shall operate as 3-phase separator for testing of wells individually. The pressure in the
test separator shall be controlled by means of a control valve in the gas outlet. Oil and water shall flow
under level control to the Inlet Separator. The Test Separator shall operate at a sufficiently higher
pressure than the Inlet Separator to allow fluids to be routed to the inlet separator (at host) under
level control. The Test Separator shall be designed for a maximum pressure (13.8 barg for DC & EG and
17 barg for FC WHP) at a maximum temperature of 93 ˚C.
Separator sizing should be in accordance with COMPANY standards.
The basis for sizing the vapour area is the Souders and Brown coefficient K.

Table 9.5.1.1 K factor for separator sizing (m/s)

With Demisting Internals (m/s)
Vessel Position Without Demisting
Internals Wire Mesh Vanes or Cyclones
Horizontal 0.08 0.10 0.16

The minimum hold-up time and minimum distances requirement specified in Table 9.5.1.2 & 9.5.1.3 shall be
applied.
Table 9.5.1.2 Liquid Levels and Residence Time Criteria
Minimum Hold-up Time (Minutes) between LAL and
Services
LAH or ILAL and ILAH
Production Separator/Test
3
Separator (excluding slugs) –
without pump
Production Separator/Test
5 of the pumping rated flow rate
Separator (excluding slugs) –
with pump
3-Phase Vessel (mm)
LAL – LAH 200
ILAL - ILAH 200
2-Phase Vessel (mm)
LAL – LAH 300
ILAL - ILAH ----
Horizontal Vessel
Between LAH and LSHH 1 minute of the draw-off capacity/100 mm minimum
Between LAL and LSLL 1 minute of the draw-off capacity/100 mm minimum

Page 59
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Production separators designed to receive liquid slugs (slug catcher service) should minimise surges to
the downstream systems. The determination of the type and volume of the sizing liquid slug should
normally be based on a hydrodynamic study of the upstream pipeline, flowline or network. The
minimum liquid slug volume shall be added to the holdup volume and retention time requirement of
production separators.
It shall be noted that the hold-up volume equivalent to 5 minutes of pumping rated flow as per rule 27 of
SD-NOC- ECP-103 is a highly conservative approach. As a standard industry practice, this value is
typically 2 to 3 minutes. For this project, DC inlet separator's volume from LAH to LAHH shall be
sufficient for ramp up slug of 10 m3, also its liquid hold-up volume shall be considered for 5 minutes
of pumping rated flow plus 2 m3 of cyclic slug.
Table 9.5.1.3 Slug catcher separators surge capacity

Minimum additional capacity

accommodates continuous intermittent slugs (cyclic hydrodynamic or
between LAL and LAH
severe slugs)
accommodates transient slugs (induced by variations in the operating
between NLL and LAH conditions of the upstream system, such as well or flowline
start-up/restart, flow ramp-up,
flowline pigging)

Liquid retention time for each phase depends on the effluent’s characteristics, the operating
temperature, etc. and fixed on a case-by-case basis:
The NLL shall be defined based on the following criteria:
- 50% of LAH to LAL range for all vessels except for slug catchers
For slug catchers: minimum hold-up between NLL and LSLL to be as per below
table 9.5.1.4 Table 9.5.1.4 Slug catcher separators surge capacity

Minimum NLL to LSLL Hold time for Slug Catchers

Slug catcher without pump 1.5 minutes of normal operating flow rate
Slug catcher with pump 2.5 minutes of pumping rated flow rate

For a 2-phase separator, the retention time to be used as given below:

- Retention time to be taken between the liquid outlet and NLL

For a 3-phase separator, the retention time to be used is in the primary separating section:
- For the heavy phase: between the liquid outlet and INLL
- For the light phase: between INLL and the
NLL Table 9.5.1.5 Typical Retention
Timeseparator (Liquid-gas)
2-phase
Oil Gravities Retention Time (Minutes)
>30˚ API 1
20˚ - 30 ˚ API 1 to 2
10˚ -in20
The information contained this˚document
API is the proprietary to North Oil Company. It must
2 tonot4be reproduced, stored, disclosed to any third party or used for any
purpose not authorized by North Oil Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-

Page 60
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

3-phase separator (gas-oil-water)- Equal retention times for oil and water
Oil Gravities Retention Time (Minutes)
>35˚ API 3 to 5
<35˚ API min OT 38˚C 5 to 10
<35˚ API min OT 27˚C 10 to 20
<35˚ API min OT 16˚C 20 to 30

Due to production fluids having emulsion-forming tendency, the 3-phase Test Separator design shall cater
to oil and water residence time of not less than 5 minutes each at normal oil and water levels.
Surge/Slug volume shall also be considered in the design of Test Separator.

At the design flow conditions, the performance of the Inlet/Test separator shall meet the
specifications below: Maximum 0.1 USgal/MMScf liquid carryover in gas outlet.
Minimum 99% separation efficiency of droplets larger than 10
microns in gas For 3-phase test separation, the following shall apply:
 Less than 5% (max.) volume water in oil outlet.
 Less than 1000ppm (max.) oil in water outlet

9.5.2 Closed Drain Drum

The following table describes the design criteria for sizing the closed
drain drum: Table 9.5.2.1 Closed Drain Drum Recommended
Minimum Hold-up Capacity
Case Minimum Hold-up Capacity
Drum collecting operation drain and /or
Largest volume below LAH of any one vessel
maintenance drains with no positive
of the installation
isolation (e.g spectacle blinds)
Drum collecting maintenance drain from
Largest volume below LSLL of any one
connections that are normally positively
vessel of the installation
isolated (e.g spectacle blinds)

The Closed Drain Drum shall be sized to hold maximum inventory volume from Test Manifolds, Production
Manifolds/Headers including bridge lines drains, Test Separator Liquid Outlet Header and Closed Drains
during any maintenance campaign. The pump-start and pump-stop levels should be set so as to avoid
triggering the low or high- level alarms under normal operation. Since HP Flare KO Drum shall be located
at higher elevation than the Closed Drain drum, it is possible to drain the liquids separated in the KO drum
directly to the Closed Drain drum.

9.5.3 Flare Knock-out Drum Sizing Criteria

Flare KO Drum sizing shall follow the below listed design criteria:

- Only one flare / vent can be connected to a KO drum

Page 61
Block 5 - AL SHAHEEN FIELD
- No internals shall be installed on gas side (e.g. mist eliminators) in the flare drum

Page 62
Block 5 - AL SHAHEEN FIELD
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

The minimum distance and minimum liquid hold-ups between levels shall follow below table 9.5.3.1

Table 9.5.3.1 KO Drum Minimum Distances and Hold-ups

Minimu
Between m Minimum Liquid Hold-up
Distanc
e
(mm)
Liquid inventory expected during
Top to LSHH - emergency depressurisation (between
LSHH and inlet/outlet location,
e.g. inlet elbow)
15 minutes of flow from the largest source involved
in the relief scenario + 90 seconds of full
LAHH to LSHH -
simultaneous flow from all the sources involved in
the relief scenario (wells,
trunklines, utilities, etc.)
LAH to LAHH 150

LAL to LAH 300 To be adapted based on selected pumping rate

LSLL to LAL 100 1 minute of pumping rated flow rate.

Bottom to LSLL 100 -

Dimensioning of HP Flare KO drum shall be based on liquid hold-up equivalent to one production well
under blocked in relief scenario plus 90 seconds of full simultaneous flow from DC production wells, with
liquids contained in both Closed Drain Drum and HP Flare KO Drum. Since HP Flare KO Drum shall be
located at higher elevation than the Closed Drain drum to facilitate draining of liquids separated in the
KO drum directly to the Closed Drain drum, dimensioning of HP Flare KO Drum shall be done taking
credit of hold-up volume available above LAH in the Closed Drain Drum. Liquid level control shall be
based on liquid levels in closed drain drum. ESD2 trip shall be activated on LAHH in HP Flare KO drum.
The Knockout Drum Droplet Size and Gas Velocity criteria specified in below table 9.5.3.2:
Table 9.5.3.2 Knockout Drum Droplet Size and Gas Velocity
Maximum Liquid Droplet
Maximum Gas Velocity inside
Flare/vent Position Size at Flare KO Drum
Flare KO Drum
Outlet Nozzle
Onshore or on not-
normally 600µm 3m/s

manned platforms

Page 63
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Other 600µm 2m/s

9.5.4 Vessel Nozzle Sizing Criteria

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Nozzle sizing for both vertical and horizontal separators shall be according to the following criteria:

Since SD-NOC guidelines do not specify the design criteria for Inlet Nozzle and outlet nozzle, the nozzle
sizing based on momentum criteria has been considered as per standard Engineering Industry
Practice/guidelines.
Nozzle sizing for both vertical and horizontal process vessels which are in continuous operation shall be
according to the following criteria:
Table 9.5.4.1 Nozzle sizing criteria for Process vessels:

Inlet Device Momentum

None ρv2 ≤ 1400 kg/ms2
Half Open Pipe ρv2 ≤ 2100 kg/ms2
Multi-vane / Schoepentoeter ρv2 ≤ 8000 kg/ms2 (Note 1)
Cyclone (conventional) ρv2 ≤ 10,000 kg/ms2 (Note 1)
Multi-cyclone ρv2 ≤ 35,000 kg/ms2 (Note 1)

Where,

ρ : the mean density of mixture in the feed pipe in

kg/m3 V : the velocity of the mixture in the inlet
nozzle in m/s.

Note 1: Vendor to confirm the values.

- For Gas outlet nozzle size for a ρv2 of less than 3750 kg/ms2.
- For Liquid outlet nozzle size for a liquid velocity of less than 2 m/s.

Nozzle sizing criteria for Flare KO drum

The Flare KO drum inlet nozzle is usually equipped with only simple and robust inlet devices such as
deflector baffle, 90° elbow or half-open pipe (ρV 2 <5000 kg/ms2) to direct the incoming stream towards
dished end and make the vessel length available for the liquid droplets to settle. The Gas outlet nozzle
shall not be fitted with any devices.

For half open pipe inlet device, a maximum allowable momentum criterion of 5000 kg/ms2 based on
industry standard guideline is considered for inlet nozzle sizing.

9.5.5 Pumps

No design margin shall be applied for Crude export pumps and Intermittent service pumps.
 Static head used in calculating the NPSHA to be taken from the LSLL of the vessel or tank upstream
of the pump to one of the following:
- The centreline for a horizontal pump
- The suction impeller for a vertical centrifugal pump

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 Pump suction lines should be sized so as the net positive suction head available (NPSH A) at the rated
point and at

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rated impeller exceeds by at least 20% the net positive suction head required (NPSH R).
 Over the full allowable operating range of the pump, the minimum difference between NPSHA and
NPSHR should be 0.5 m.
 The design pressure of the pump suction lines downstream of their inlet block valves (block valve or
shutdown valve included) to be identical to the discharge line design pressure.

9.5.6 Drain Caisson Sizing

An overflow line from open drain tank is routed to drain caisson. In case of overflow of washdown water
from open drain tank, liquid will be directed to drain caisson and that will be considered as the sizing
basis. As per SD-NOC-SAF- 007, where the deck washdown facility is provided, the design capacity of one
washdown hose shall be taken into account. Typical capacity of a washdown hose reel is 50 USgpm (11.4
m3/h). As advised by NOC, a flow rate of 15 m 3/h per hose connection with use of two seawater hose
connections at a time has been considered in the design. This is also in line with SD-NOC-SAF-007 which
says, "In the absence of any specific figure, a value of 30 m 3/h (Company requirement) may be used".

9.6 LINE SIZING CRITERIA

In general, all line sizing shall comply with the SD-NOC-ECP-103, SD-NOC-COR-004, DNVGL-RP-O501 and
API RP 14E. The minimum piping size shall be 2” for process lines and utility lines on pipe rack except for
stainless steel tubing for services such as breathing air, instrument air supply , hydraulic lines, and some
chemical lines. In performing line sizing, the following constraints shall be addressed, as applicable:
 Required capacity/available driving pressure
 Flow induced forces
 Noise/vibration
 Pressure surges
 Erosion/Corrosion/ Cavitation
 Liquid accumulation/Slug flow
 Sand accumulation and
 Scaling
Lines shall be sized based on the worst case flowing condition. Pressure drop due to piping components
are to be accounted for in terms of equivalent length.
Lines with calculated ρv2 exceeding the limit specified in Table 19 (Reference: SD-NOC-ECP-103) to avoid
excessive FIV (all fluids – Liquid, Gas & Multiphase) shall be classified as being subject to flow induced
turbulence. The following correlations shall be used for determination of maximum allowable ρv 2 with
respect to pipe support arrangement of Stiff and Medium stiff (standard).

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Table 9.6.1 Determination of maximum allowable ρv2

Pipe NPS OD Maximum
α β
Support (inch) (mm) ρv2 (Pa)
Arrangeme
nt
60 to α = 446187.1 +
Sti 2 to 30 β =0.1xln(OD)- 0.3*α/FVF*(OD/
ff 762 645.51xOD+(9.166/104) x 1.3739 Ɛ)β
OD3

Medium 60 to β
2 to 30 α = 283921 + 370.24 x OD 0.3*α/FVF*(OD/
stiff 762 =0.1106xl Ɛ)β
(standard n(OD)-
) 1.501

Where,
OD is the pipe outside diameter (mm)
Ɛ is the piping wall thickness without corrosion allowance (mm, end-of-life
conditions) FVF = 1 for liquid and multiphase (> 5% of liquid volume
fraction)
FVF = √µ for gases (< 5% of liquid volume fraction), with µ the dynamic viscosity (cP)

9.6.1 Liquid Line Sizing

Liquid line sizing shall be in accordance with API RP 14E. The velocities shall be kept as such to prevent
problems like erosion, water hammer, pressure surges, and vibration and reaction forces. API 14E
requires that the flow velocity should not exceed 4.6 m/s at maximum flow rates. For sea water service,
the velocity shall not be less than 2m/s.
The maximum allowable limit of ρv 2 value shall be estimated using the correlations listed in table 9.6.1
with respect to pipe support arrangement of Stiff and Medium stiff standard, as applicable.
The following velocity criteria shall be used in special service conditions:

 Liquid with sand: 0.8 m/s as min. velocity; 3 m/s max.

 Solid-liquid mixture lines: 1 to 2.75 m/s max.

9.6.2 Gas Line Sizing

Line sizing for Gas lines shall be performed based on ρv 2 criteria which are in accordance with NOC
standard, ‘Process Sizing Criteria, SD-NOC-ECP-103.
The maximum allowable limit of ρv 2 value shall be estimated using the correlations listed in table 9.6.1
with respect to pipe support arrangement of Stiff and Medium stiff standard, as applicable.

9.6.3 Multiphase Line Sizing

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BATCH 1 incremental wells are to increase the field production potential of known reservoir fluids which
are already produced at Al Shaheen, rather than to add new (& more corrosive) stream compositions. All
systems (including lift gas) exposed to the production streams shall be NACE MR-0175 / ISO 15156 Region
3 (Severe Sour) H2S Service CS.

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Corrosion management / monitoring shall be by combination of the following:

 Corrosion allowance,
 Continuous Corrosion Inhibitor injection,
 Provision of corrosion coupons & probe points at strategic locations; to be retrievable under line
pressure without shutdown
 Beaning in wells to be below erosional limits & limits at which filming corrosion inhibitors are
stripped from pipe walls.

The following criteria shall be used for multiphase line sizing based on the nature of fluid and applicability:

a. Erosional Velocity Criteria

The sizing of multiphase lines shall be based on calculating the erosional velocity ensuring the fluid velocity is
less than the erosional velocity. The velocity above which erosion may occur can be determined by the
following empirical equation:
Ve =
c/√ρm
Where,
Ve is the erosional velocity, expressed
in m/s c is the empirical constant
ρm is the gas/liquid mixture density at flowing pressure and temperature,
expressed in kg/m3 API 14E erosion constant as per below table 9.6.3.1 shall be
used for design.

b. ρv2 Criteria
The maximum allowable limit of ρv2 value shall be estimated using the correlations listed in table 9.6.1 with
respect to pipe support arrangement of Stiff and Medium stiff standard, as applicable.

c. Erosion - Corrosion Criteria

Cmax criteria (and corresponding VAPI) apply to either SE-C (Solids) or LE-C. Vmax criteria apply to LE-C
conditions only, i.e. with a solid-free fluid.
As per SD-NOC-COR-004, solid-free fluid for multiphase fluids is defined as absence of solid particles which is
described as follows:
For Multiphase fluids or liquids considering that all sand is present in the
liquid phase, i.e., Particle size 30 µm (less than 5% mass > 30 µm)
(or)
Sand concentration less than 3 kg/1000 m3 of liquid or 3ppm.
As per the potential corrosivity, the Cmax value, which is considered for line sizing calculation, is taken from
below table

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9.6.3.1. The carbonate solids content in the production fluids is expected to be less than 3ppm, and hence, for
dimensioning

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of all WHPs’ well flowlines and manifolds (CS, inhibited), a C max value of 130 (US units) shall be used
considering LE-C conditions only, i.e. with a solid-free fluid.
d. Erosion rate Criteria as per DNV method
Multiphase liquid handling solids shall consider methodology detailed in DNV standard: “DNVGL-RP-O501,
Managing Sand production and Erosion”.
The C values and the API equation are only applicable to carbon steel. For other materials such as stainless
steel, copper- nickel, titanium, GRP, etc., there is only one criterion, which is the maximal total velocity (Vmax)
given in Table 9.6.3.1.

Table 9.6.3.1 Erosional Constant & Velocity Limitation Criteria:

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9.6.4 Pipe Roughness

For all calculations of pressure drop, the following pipe roughness values shall be used.

Carbon steel (CS) non-corroded : 0.05 mm

Carbon steel (CS) corroded : 0.5 mm
Stainless steel (SS) : 0.05 mm
Titanium and Cu-Ni : 0.05 mm
Glass fibre reinforced polyester (GRP): 0.02 mm
Polyethylene (PVC) : 0.005
mm
Synthetic rubber (Elastopipe) : 0.02 mm

9.6.5 Sizing PSV and Blowdown Line

Peak flowrate of blowdown valves shall be calculated by depressurising the inventories to 6.9 barg or 50% of
design pressure (whichever is more stringent) in 15 minutes. The resultant depressurisation rate will be used
to obtain the minimum design temperature of the piping material.
For depressurization device (blowdown valves + restriction orifice) line size shall be
minimum 2”. For PSVs, inlet and outlet lines design flow rates shall be as follows:
Table 9.6.5.1 PSV design flow rate criteria:

Device Type Inlet/outlet Design Flowrate

Pop-action, pilot-operated PSV PSV rated capacity (Note 1)
Modulating-action, pilot-operated PSV Required relieving rate
Spring-loaded PSV PSV rated capacity (Note 1)
Rupture disc Required relieving rate
Note 1: considering the lowest possible superimposed back-pressure corresponding to a single
relief scenario (typically 0barg).

Pressure drop between the protected equipment and the PSV < 3% of PSV set
pressure. The design criteria for lines upstream of relieving devices (PRD &
BDV) shall be as follows:
- ρV2 < 25 000 Pa for line NPS 2”,
- ρV2 < 30 000 Pa for design pressure < 50 barg,
- ρV2 < 50 000 Pa for design pressure > 50 barg.

For headers, the design basis should be the sum of the required relieving capacities of the pressure safety
valves and possibly blowdown valves.

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The design of lines downstream of relieving devices shall comply for all relief scenarios at rated capacity
with the following:

Table 9.6.5.2: ρV2, Mach and AIV criteria in relief lines and headers (Note 4)

Liquid/Multiphase
Criterion Flow (Note 1) Gas Service
Service (Note 2)
Emergency 0.7 (Note 3)
Mach 0.25
Non-routine 0.35
Emergency 100,000 Pa
ρV2 50,000 Pa
Non-routine 50,000 Pa
Emergency As per the
AIV methodology Not Applicable
Non-routine described in section
15.1.4.3, SD-NOC-ECP-
103.

Notes:
1. Emergency corresponds to safety relief (PRV, BDV). Non-routine corresponds to process
control lined up to the flare (Pressure Control valve).
2. Multiphase: 2-phase flow with > 5 vol% liquid in actual conditions at the inlet of relieving device.
3. 0.8 Mach may be accepted for a long straight line without elbow or connection (e.g. stack, line on bridge).
4. Minimum backpressure (0 barg by default) to be considered for PRD and BDV tail pipe sizing.

9.6.6 Drain Line Sizing

Drain line flow velocity shall be kept within a range that allows self-cleansing, prevents emulsification and
damage to the pipe and fittings (erosion). Generally, the introduction of solids into drain pipes cannot be
avoided and this is prone to produce silting in the pipes. Following line sizing criteria is referred from SD-
NOC-ECP-103, Process Design Criteria.
Table 9.6.6.1 Drain Line Pipe Velocity Criteria:

Drainage System Minimum (m/s) Maximum (m/s)

0.8
Open Drain, Oil-free (OD3) 3.0
1.2 (particle/sand
presence)
Open drains, permanently oil-contaminated
(OD1) 0.8 2.0
Open drains, accidentally oil-contaminated
(OD2)

Horizontal gravity line shall be provided with a slope of 1: 100. For sizing the horizontal gravity line, Pipes
with a diameter below 8 inch shall be designed for 50% full of liquid, while pipes with a diameter of 8 inch
and greater shall be designed for 75% full of liquid. The manning formula shall be used for horizontal line

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sizing calculations.

For sizing the vertical gravity line, the Froude number (Fr) for the down flow service shall be less than 0.3
to avoid air entrainment (self-venting down flow).

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10.0 SOFTWARES

The following software programs shall be used for process simulation activities & generating process
deliverables. In addition, In-house calculation templates (validated) shall also be used, as applicable.
Table 10.1 Software to be used in Process
Software Process activities / Deliverables

AutoCAD Block diagrams/ PFDs / UFDs / PSDs / P&IDs and Brownfield C

& Es
Aspen HYSYS (Version 8.6) Process Simulations and H&MB
generation (Using Peng Robinson
property package)
Aspen HYSYS (V10) BLOWDOWNTM
Tool Emergency blowdown & depressurization calculations
(developed by Imperial College of
London, now as part of AspenTech’s
HYSYS software)
Aspen Flare System Analyser (version Flare model update and flare header sizing calculations
10)
PIPENET latest version 1.8 Surge /Transient analysis of FC WHP WI reception facilities

11.0 ASSAY SPECIFICATIONS

The assay specifications of produced water, sea water and Fuel Oil (Diesel), which shall be basis for selection
of suitable material for vendor package/facilities are presented in the below tables.
Table 11.1 Produced Water Salinity Assay
Kharaib B Shuaiba Mauddud
Components
Level, mg/l Level, mg/l Level, mg/l
Cations
Sodium 19,800 29,617 17,200
Potassium 9,581 1,213 1,340
Calcium 1,936 4,432 70
Magnesium 724 2,713 1.2
Barium 1.0 --- 0.35
Strontium 62.3 188 1.3
Total Iron 0.4 --- ---
Dissolved Iron --- 8 76
TOTAL 32,105 38,171 18,689
Anions
Chloride 42,790 59,930 26,810
Sulphate 1,332 1,095 555
Bicarbona 1,839 337 965
te nil --- 190
Carbonate
Hydroxide nil --- Nil
TOTAL 45,961 61,362 28,520

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General
TDS (Total Dissolve mg/l 78,066 99,533 47,209
d

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Kharaib B Shuaiba Mauddud

Components
Level, mg/l Level, mg/l Level, mg/l
Cations
Solids)
SG (60⁰F) --- 1.0527 1 1.04
H2S mg/l not not nil
pH (25⁰C) --- tested tested 8 9.0
7.6 7

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Resistivity (60⁰F) Ohm.m 0.0937 not tested 0.171

Table 11.2 Sea water analysis

Constituents Unit Results
Total Hardness mg/L 7720
Total Alkalinity mg/L 125

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Total Dissolved Solids (Dried @ mg/L 41026
180⁰C)
Calcium mg/L 449
Magnesium mg/L 1604
Sodium mg/L 12600
Potassium mg/L 810
Carbonate mg/L 30
Bi-Carbonate mg/L 152
Sulphate mg/L 3169
Chloride mg/L 22511
H -
P value @ 25⁰C 8.56
Electrical Conductivity @25⁰C (Micro 56200
ohms/cm)

Table 11.3 Diesel Fuel (Light Gas Oil) Specification

Test Specification Method
Specific Gravity @ 60/60 F 0.820 to 0.850 IP-160
Color 3.0 max. ASTM D-1500
Flash Point PMC⁰F 140 min. IP-34
Sulphur % Wt 0.5 max. IP-336
Copper Corrosion, 3 hrs @ 100⁰C NO. 1 max. IP-154
Viscosity Kin.@100⁰F, Cst 1.6 to 6.0 ASTM D-445
Viscosity S.U @100⁰F, SSU 30 to 45 ASTM-88
Pour Point ⁰F / ⁰C 25 / -4 max. IP-15
Cloud Point ⁰F / ⁰C 32 / 0 max. IP-219
Conradson Carbon on 10% res. 0.20 max. IP-13
%Wt.
Total Acidity mg KOH/g 0.25 max IP-1
Inorganic Acidity mg KOH/g NIL IP-1
Ash % Wt 0.01 max. IP-4
Water % Volume 0.05 max. IP-74

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Test Specification Method

Sediment by Extraction % Wt 0.01 max. IP-53
Gasoil Index 53 min. IP-21
Cetane Index 50 min. IP-380
Distillation:
- 90% Volume Recovery @⁰C 90 min.
- 95% Volume Recovery @⁰C
- F.B.P
- % Volume Recovery @357 ⁰C

12.0 SITE AND ENVIRONMENTAL DATA

The following Site & Environmental data shall be used for process design
of facilities:

Parameters Minimum Maximum

Ambient Air Temperature, °C 5 50
Relative Humidity, % 60 100
For HVAC design
- 45
a. Air Temperature, °C
- 70
a. Relative Humidity, %
Sea Water Temperature,°C 19 35
Max. height, Hmax (m)
Wave data (With return period of 100 years) 10.1 Max. period,
THmax (s) 8.7
Max. crest, Cmax (m) 7.7
HAT (m) 1.85
Bathymetric data MSL (m) 0.97
LAT (m) 0.00
Black bulb Temperature,
93
°C (Temperature of metal
exposed to solar radiation)
Max. Solar radiation
1.045
(Offshore), kW / m2
Wind Speed, m/s
0.5 to 20
(For Flare radiation / dispersion analysis study)
Precipitation 50mm/hr (design figure for open drain rainfall
consideration)

12.1 ENVIRONMENTAL REQUIREMENTS

Any water streams arising from BATCH 1 process operations which can end up being discharged to
sea, shall be treated, so as not to exceed 30mg/l oil-in-water. This shall include open drains effluents /
fire water test streams, washed solids ex ASDCA-A-3401 Desander Package & excess produced water
streams (via dump caisson).

Total weighted noise levels shall be < 85 dBA within the working area.

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2019
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13.0 NEW FACILITIES DESIGN PHILOSOPHY

Reference shall be made to the following philosophy documents for the design of new WHP and
Bridge facilities: Table 13.1 Philosophy documents for reference
Document title Document Number

FC, DC & EG Wellhead Platform Relief & Blowdown Philosophy WHP01-PMC1-ASYYY-04-260002-0001

FC, DC & EG Wellhead Platform Overpressure Protection WHP01-PMC1-ASYYY-04-260003-0001
Philosophy
FC, DC & EG Wellhead Platform Isolation, Vent & Drain Philosophy WHP01-PMC1-ASYYY-04-260005-0001
DC Wellhead Platform Process Operating, Control & Shutdown WHP01-PMC1-ASDCA-04-260002-
Philosophy 0001
FC Wellhead Platform Process Operating, Control & Shutdown WHP01-PMC1-ASFCA-04-260002-
Philosophy 0001
EG Wellhead Platform Process Operating, Control & Shutdown WHP01-PMC1-ASEGA-04-260002-
Philosophy 0001

14.0 APPENDICES

Appendix 01 Carbonate Solids Loading

Appendix 02 MSDS for Production
Chemicals

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Appendix 01 : Carbonate Solids Loading

(No. of Pages: 4)

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Development
Document Title: FC, DC & EG Wellhead Platform Process Design
Basis
Document Number: WHP01-PMC1-ASYYY-04-262001-0001 Date: 13-Jun- Rev.: 02
2019
Doc Type: PHI System: GENE Phase DE Status: AFC Class: 01

Appendix 02 : MSDS for Production Chemicals

(No. of Pages: 47)

A. CECA NORUST 753 - Down-hole corrosion inhibitor (8 pages)

B. CECA NORUST 170 - Topside corrosion inhibitor (8 pages)
C. MiSWACO EPT-3296 – Biocide (14 pages)
D. NALCO CHAMPION X-8672 – Demulsifier (9 pages)
E. NALCO CHAMPION AF-340 – Antifoam (8 pages)

The information contained in this document is the proprietary to North Oil Company. It must not be reproduced, stored, disclosed to any third party or used for any purpose
not authorized by North Oil Company. Printed documents are uncontrolled and considered as "for information only". Reference should always be made to the on-line EDMS
for the updated version
Major Projects Template MAJOR-ASY-MPQA-MPQA-FOR-000004_Rev00 Dated 09/06/2018

Page 62 of 62
Page
SAFETY DATA SHEET
accordance with Annex II of Regulation (EC) No 1907/2006 and
its amendment(s)

Product: NORUST 753 QAT N Page: 1 / 8

SDS No.: 915891-001 (Version 1.0) Date 30.10.2017

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Identification of the product

Identification of the mixture: NORUST 753 QAT N

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture : Corrosion inhibitors and anti-scaling agents

1.3. Details of the supplier of the safety data sheet

Supplier ARKEMA
Made under ARKEMA FRANCE licence
420 rue d’Estienne d'Orves
92705 Colombes, FRANCE
Telephone: +33 (0)1 49 00 80 80
Telefax: +33 (0)1 49 00 83 96
E-mail address: [email protected]
http://www.arkema.com

1.4. Emergency telephone number

+ 33 1 49 00 77 77
European emergency phone number: 112
þ
2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008):

Corrosive to metals, 1, H290
Oral: Acute toxicity, 4, H302 Skin
corrosion, 1B, H314 Serious eye
damage, 1, H318 Acute aquatic
toxicity, 1, H400 Chronic aquatic
toxicity, 2, H411

Additional information:
For the full text of the H, EUH-phrases mentioned in this Section, see Section 16.

2.2. Label elements

Label elements (REGULATION (EC) No 1272/2008):

Hazardous components which must be listed on the label:

ethanediol; ethylene glycol
Quaternary ammonium salt
sodium hydroxide; caustic soda
Alkylamine derivatives

Hazard
pictograms:

Signal word: Danger

Hazard statements:
H290 : May be corrosive to metals.
H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
H410 : Very toxic to aquatic life with long lasting effects.

ARKE 420 rue d’Estienne d'Orves - 92700 Colombes –

Quick-FDS [18334-53032-00017-015007] - 2018-03-12 -

Product: NORUST 753 QAT N Page: 2 Page
/8
SDS No.: 915891-001 (Version 1.0) Date 30.10.2017

Precautionary statements:
Prevention:
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response:
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON
CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Disposal:
P501 : Dispose of contents/ container to an approved waste disposal plant.

Special labelling:

EUH208 May produce an allergic reaction. Contains: Sodium Thioglycolate; Hexahydro-1,3,5-trimethyl-1,3,5-triazine.

2.3. Other hazards

Physical and chemical hazards:

No special risks of flammability or explosion.

þ
3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

Chemical nature of the mixture1:

Hazardous components (accordance with Annex II of Regulation (EC) No 1907/2006 and its amendment(s)) :

Classification
Chemical name1 & REACH Registration Number2 EC-No. CAS-No. Concentration REGULATION (EC) No 1272/2008
ethyleneglycol (01-3229456816-28) (N° ANNEX: 603-027- Acute Tox. 4 (Oral); H302
00-1) 203-473-3 107-21-1 <= 20 %
Acute Tox. 4 (Oral); H302
Skin Corr. 1B; H314
Eye Dam. 1; H318
Aquatic Acute 1; H400
Quaternary ammonium salt (01-2119970550-39) 270-325-2 68424-85-1 < 20 %
Aquatic Chronic 1; H410

M-Factor Acute = 10
M-Factor Chronic = 1
Met. Corr. 1; H290
Sodium hydroxide (01-2119457892-27) (N° ANNEX: 011- Skin Corr. 1A; H314
215-185-5 1310-73-2 < 10 %
002-00-6) Eye Dam. 1; H318

Acute Tox. 4; H302

Eye Dam. 1; H318
Alkylamine derivatives – 61791-14-8 <5%
Aquatic Chronic 3; H412

1
: See chapter 14 for Proper Shipping Name
2
:See the text of the regulation for applicable exceptions or provisions : The transition time according to REACH Regulation, Article 23, is
still not expired.
þ
4. FIRST AID MEASURES

4.1. Description of necessary first-aid measures:

General advice:
Under the shower: Take off immediately all contaminated clothing (including shoes).

Inhalation:
Move to fresh air. Oxygen or artificial respiration if needed. Hospitalize immediately.

Skin contact:
Wash off immediately with plenty of water. Keep under medical surveillance. Hospitalize immediately.

Eye contact:
Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Consult an ophthalmologist immediately.

Ingestion:
Do not induce vomiting, rinse mouth and lips with plenty of water if the subject is conscious, then hospitalize.

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Protection of first-aiders:
If potential for exposure exists refer to Section 8 for specific personal protective equipment.

4.2. Most important symptoms/effects, acute and delayed: No data available.

4.3. Indication of immediate medical attention and special treatment needed, if necessary

Treatment: Treat symptomatically.

þ
5. FIREFIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media: Foam, carbon dioxide, dry powder extinguishers., Use suitable means to extinguish
neighbouring fires.

Unsuitable extinguishing media: Water jet.

5.2. Special hazards arising from the substance or mixture:

Possible formation of carbon oxides, nitrogen oxides and hazardous organic compounds.

5.3. Advice for firefighters:

Specific methods:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations. Cool closed containers exposed to fire with water spray.

Special protective actions for fire-fighters:

In the event of fire, wear self-contained breathing apparatus. Complete suit protecting against chemicals.
þ
6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures:

Wear suitable protective clothing, gloves and eye/face protection. Ensure adequate ventilation. Evacuate area of all unnecessary personnel.

6.2. Environmental precautions:

Do not release into the environment.
Local authorities should be advised if significant spillages cannot be contained.

6.3. Methods and materials for containment and cleaning up:

Methods for cleaning up:

Keep in suitable, closed containers for disposal.

Recovery:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Sweep up to
prevent slipping hazard.

Elimination:
Dispose of in accordance with local regulations.

6.4. Reference to other sections: None.

þ
7. HANDLING AND STORAGE

7.1. Precautions for safe handling:

Technical measures/Precautions:
Provide water supplies and ocular fountains near the point of use. Provide a catch-tank in a bunded area. Provide waterproof electrical
equipment.

Safe handling advice:

Smoking, eating and drinking should be prohibited in the application area.

Hygiene measures:
See heading 4.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.

7.2. Conditions for safe storage, including any incompatibilities:

Keep container tightly closed in a dry and well-ventilated place. Provide impermeable floor.

Storage temperature: < 50 °C (to maintain the technical properties of the product).

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Packaging material:
Recommended: Original packaging
To be avoided: Metals

7.3. Specific end use(s): None.

þ
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters:

Exposure Limit Values

ethyleneglycol
Source Date Value type Value Value Remarks
(ppm) (mg/m3)
EU ELV 12 2009 STEL 40 104 Indicative value
EU ELV 12 2009 SKIN – – Can be absorbed through the skin.
EU ELV 12 2009 TWA 20 52 Indicative value
ACGIH (US) 02 2012 Ceiling – 100 Aerosol

Sodium hydroxide
Source Date Value type Value Value Remarks
(ppm) (mg/m3)
ACGIH (US) 02 2012 Ceiling – 2 –

2-Phosphonobutane-1,2,4-tricarboxylic acid
Source Date Value type Value Value Remarks
(ppm) (mg/m3)

Derived No Effect Level (DNEL): No data available.

Predicted No Effect Concentration: No data available.

8.2. Exposure controls:

Appropriate engineering controls: Provide appropriate exhaust ventilation at machinery.

Personal protective equipment:

Respiratory protection: Wear a respirator if necessary.
In case of spillage, wear a mask Recommended Filter type: Filter type AK
Avoid breathing dust or vapour., In the case of vapour formation use a respirator with an
approved filter.
Hand protection: Acid resistant gloves (PVC, neoprene)
Eye/face protection: Face-shield, or, Safety glasses with side-shields conforming to EN166, Eye wash bottle with pure
water
Skin and body protection: Acid resistant clothing, anti acid boots

Environmental exposure controls: See chapter 6

þ
9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance:
Physical state (20°C): liquid
Odour: No data available.
Olfactory threshold: No data available.
pH: pH 7,5 - 8
Solidification point : -25 °C
Boiling point/boiling range: No data available.
Flash point: > 100 °C
Evaporation rate: No data available.
Flammability (solid, gas):
Flammability: Not relevant
Vapour pressure: No data available.
Vapour density: No data available.
Density: 1,09 - 1,11 g/cm3 , at 25 °C
Water solubility: soluble

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Partition coefficient: n-octanol/water: QUATERNARY AMMONIUM SALT :

log Kow : < 2
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity, dynamic: 10 - 20 mPa.s
Explosive properties:
Explosivity: Not explosive
Oxidizing properties: The substance or mixture is not classified as oxidizing.

9.2. Other data: None.

þ
10. STABILITY AND REACTIVITY

10.1. Reactivity:
Stable under recommended storage conditions.

10.2. Chemical stability: No data available.

10.3. Possibility of hazardous reactions: No data available.

10.4. Conditions to avoid: No data available.

10.5. Incompatible materials to avoid:

Strong acids and oxidizing agents

10.6. Hazardous decomposition products:

Possible formation of carbon oxides, nitrogen oxides and hazardous organic compounds.
þ
11. TOXICOLOGICAL INFORMATION

All available data on this product and/or the components quoted in section 3 and/or the analogue substances/metabolites have been taken
into account for the hazard assessment.

11.1. Information on toxicological effects:

Acute toxicity:

Inhalation: Based on available data, the classification criteria are not met. Little or not harmful by
inhalation

Ingestion: According to its composition, can be considered as : Harmful if swallowed.

Acute toxicity estimate: ca. 1.100 mg/kg

Dermal: Based on available data, the classification criteria are not met. Slightly or not harmful in
contact with skin

Local effects ( Corrosion / Irritation / Serious eye damage ):

Skin contact: According to its composition, can be considered as : Causes severe skin burns and eye
damage.

Eye contact: According to its composition, can be considered as : Causes serious eye damage.

Respiratory or skin sensitisation:

Inhalation: Based on available data, the classification criteria are not met. not a respiratory sensitizer

Skin contact: Based on available data, the classification criteria are not met. Not a skin sensitizer

CMR effects :

Mutagenicity: Results from tests do not lead to considering the product as genotoxic

Carcinogenicity: Based on the available data, the substance is not suspected of having carcinogenic potential

Reproductive toxicity:

Fertility: Based on the available data, the substance is not suspected of having reprotoxic potential.

Foetal development: Based on the available data, the substance is not suspected of having developmental toxicity
potential.

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Specific target organ toxicity :

Single exposure :

Inhalation: Based on available data, the classification criteria are not met.

Repeated exposure: Based on available data, the classification criteria are not met.

Aspiration hazard:
Not relevant
þ

12. ECOLOGICAL INFORMATION

Ecotoxicology Assessment: According to its composition, can be considered as : Very toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment. Do not dispose large quantities into the natural or
aquatic environment.

12.1. Acute toxicity :

Fish:
QUATERNARY AMMONIUM SALT :
LC50, 96 h : 0,5 - 0,9 mg/l

Aquatic invertebrates:
QUATERNARY AMMONIUM SALT :
EC50, 48 h (Acartia tonsa) : 0,4 mg/l

Aquatic plants:
QUATERNARY AMMONIUM SALT :
72 h (Skeletonema costatum (marine diatom)) : 0,26 mg/l (Method: ISO 10253)

Aquatic toxicity / Long term toxicity:

Fish:
QUATERNARY AMMONIUM SALT :
Through analogy with a comparable product :
NOEC, 34 d (Pimephales promelas (fathead minnow)) : >= 0,0322 mg/l (Method: US EPA)

Aquatic invertebrates:
QUATERNARY AMMONIUM SALT :
Through analogy with a comparable product :
NOEC, 21 d (Daphnia magna (Water flea)) : >= 0,025 mg/l (Method: OECD Test Guideline 211)

Aquatic plants:

QUATERNARY AMMONIUM SALT :

NOEC r, 72 h (Pseudokirchneriella subcapitata (green algae)) : = 0,06 mg/l (Method: OECD Test
Guideline 201, growth rate inhibition)

Non aquatic toxicity / Acute toxicity :

Toxicity to soil dwelling

organisms:
QUATERNARY AMMONIUM SALT :
NOEC, 14 d (Eisenia fetida (earthworms)) : >= 517 mg/kg ( Soil dw ) (Method: OECD Test Guideline
207)
EC50, 28 d : = 130 mg/kg ( Soil dw ) (Method: OECD Test Guideline 216)

Terrestrial plants:

QUATERNARY AMMONIUM SALT :

EC50, 16 d : >= 537 mg/kg (Method: OECD Test Guideline 208, Inhibition of germination)

12.2. Persistence and degradability :

Biodegradation (In water): Based on the available information, it is not possible to conclude on the hasard potential of
this mixture.
QUATERNARY AMMONIUM SALT :
Readily biodegradable: > 60 % after 28 d (Method: OECD Test Guideline 301 D)

12.3. Bioaccumulative potential :

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QUATERNARY AMMONIUM SALT :

Partition coefficient: n-octanol/water: log Kow : < 2

12.4. Mobility in soil - Distribution among environmental compartments: No data available.

12.5. Results of PBT and vPvB assessment : None.

12.6. Other adverse effects:

Global warming potential (GWP): Not relevant (due to the chemical structure)

Ozone depletion potential: Not relevant (due to the chemical structure)

þ
13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment:

Disposal of product: Do not release into the natural environment or aquatic environment the pure or concentrated product.
Incinerate in suitable incineration plant, observing local authority regulations.
According to the European Waste Catalogue, Waste Codes are not product specific, but application
specific. Waste codes should be assigned by the user based on the application for which the product
was used.

Disposal of packaging: Must be dumped or incinerated in accordance with local regulations.

þ
14. TRANSPORT INFORMATION

14.1. UN 14.3.Clas 14.4. 14.5. Environmental 14.6. Special precautions for

Regulation 14.2.UN proper shipping name Label PG*
number s* hazards user
AMINES, LIQUID, CORROSIVE, N.O.S.
ADR 2735 8 8 II yes
(QUATERNARY AMMONIUM SALTS)
AMINES, LIQUID, CORROSIVE, N.O.S.
ADN 2735 8 8 II yes
(QUATERNARY AMMONIUM SALTS)
AMINES, LIQUID, CORROSIVE, N.O.S.
RID 2735 8 8 II yes
(QUATERNARY AMMONIUM SALTS)
Amines, liquid, corrosive, n.o.s. (Quaternary
IATA Cargo 2735 8 8 II yes
ammonium salts)
Amines, liquid, corrosive, n.o.s. (Quaternary
IATA Passenger 2735 8 8 II yes
ammonium salts)
AMINES, LIQUID, CORROSIVE, N.O.S. EmS Number: F-A, S-B
IMDG 2735 8 8 II Marine pollutant
(QUATERNARY AMMONIUM SALTS) Mark: MP
*Description: 14.3. Transport hazard class(es)
14.4. Packing group

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable

þ
15. REGULATORY INFORMATION

Safety data sheets: accordance with Annex II of Regulation (EC) No 1907/2006 and its amendment(s)

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture:

Listed in:

EU. REACH, Annex XVII, Marketing and Use Restrictions (Regulation 1907/2006/EC): ethanol; ethyl alcohol

15.2. Chemical safety assessment: None.

þ
16. OTHER INFORMATION

Full text of H, EUH-phrases referred to under sections 2 and 3

H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

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H412 Harmful to aquatic life with long lasting effects.

Thesaurus:
NOAEL : No Observed Adverse Effect Level (NOAEL)
LOAEL : Lowest Observed Adverse Effect Level (LOAEL)
bw : Body weight
food : oral feed
dw : Dry weight
vPvB : very Persistent and very Bioaccumulative
PBT : Persistent, Bioaccumulative and Toxic

This safety data sheet complies with international standard ISO 11014-1. In case of formulations or mixtures, it is necessary to ascertain
that a new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is
given quite sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not
intended. This sheet shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and
codes of practice documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the
totality of the official documents concerning the use, the possession and the handling of the product. It is also the responsibility of the
handlers of the product to pass on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of
containers, other processes) the totality of the information contained within this safety data sheet and necessary for safety at work, the
protection of health and the protection of environment.
NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is "," (comma).

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A
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Product: NORUST 170 QAT Page: 1 / 8

SDS No.: 926509-001 (Version 1.0 ) Date 05.02.2015

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Identification of the product

Identification of the mixture: NORUST 170 QAT

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture : Corrosion inhibitor

1.3. Details of the supplier of the safety data sheet

Supplier CECA
Adresse postale : 89 Boulevard
National 92250 LA GARENNE-
COLOMBES FRANCE
Téléphone : +33 (0)1 49 00 38 00
Télécopie : +33 (0)1 49 00 38 01 http://
www.cecachemicals.com
[email protected]
E-mail address
1.4. Emergency telephone number

+33 1 49 00 77 77
European emergency phone number : 112 (24/7)
National Chemical Emergency Centre Tel: 01865 407 333 (24/7)

2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008):

Oral: Acute toxicity, 4, H302
Skin corrosion, 1B, H314
Skin sensitisation, 1, H317
Serious eye damage, 1, H318
Acute aquatic toxicity, 1, H400
Chronic aquatic toxicity, 1, H410

Classification according to EU Directives 1999/45/EC :

Xn; R21/22
C; R34
Xi; R43
N; R50/53

Additional information:
For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.

2.2. Label elements

Label elements (REGULATION (EC) No 1272/2008):

Hazardous components which must be listed on the label:

Quaternary ammonium salt

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Heterocyclic derivatives

Hazard pictograms:

Signal word: Danger

Hazard statements:
H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
H317 : May cause an allergic skin reaction.
H410 : Very toxic to aquatic life with long lasting effects.

Precautionary statements:
Prevention:
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P303 + P361 + P353 : IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention.
Disposal:
P501 : Dispose of contents/ container to an approved waste disposal plant.

2.3. Other hazards

Physical and chemical hazards:

No special risks of flammability or explosion.

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

Chemical nature of the mixture1:

Aqueous solution

Hazardous components (according to Regulation (EC) No. 1907/2006) :

Classification Classification
Chemical Name1 & REACH Registration Number2 EC-No. CAS-No. Concentration Directive REGULATION (EC) No
67/548/EEC 1272/2008
Quaternary ammonium salt 270-325-2 68424-85- < 50 % Xn; R21/22 Acute Tox. 4 (Oral); H302
1 C; R34 Skin Corr. 1B; H314
N; R50 Eye Dam. 1; H318
Aquatic Acute 1; H400
Aquatic Chronic 1; H410

M-Factor Acute = 10
M-Factor Chronic = 1
ethyleneglycol (01-3229456816-28) (N° ANNEX: 603- 203-473-3 107-21-1 < 50 % Xn; R22 Acute Tox. 4 (Oral); H302
027-00-1)

Heterocyclic derivatives < 10 % C; R34 Met. Corr. 1; H290

R43 Skin Corr. 1C; H314
N; R50/53 Skin Sens. 1; H317
Aquatic Acute 1; H400
Aquatic Chronic 1; H410

M-Factor Acute = 1
M-Factor Chronic = 1

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4. FIRST AID MEASURES

4.1. & 4.2. Description of necessary first-aid measures & Most important symptoms/effects, acute and delayed:

General advice:
Under the shower: Take off immediately all contaminated clothing (including shoes).

Inhalation:
Move to fresh air. Oxygen or artificial respiration if needed. Hospitalize immediately. Delayed effects possible

Skin contact:
Wash off immediately with plenty of water. Keep under medical surveillance. Hospitalize immediately.

Eye contact:
Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Consult an ophthalmologist immediately.

Ingestion:
Do not induce vomiting, rinse mouth and lips with plenty of water if the subject is conscious, then hospitalize.

4.3.Indication of immediate medical attention and special treatment needed, if necessary

Treatment: Treat symptomatically.

5. FIREFIGHTING MEASURES

5.1.Extinguishing media

Suitable extinguishing media: Foam, carbon dioxide, dry powder extinguishers., Use suitable means to extinguish
neighbouring fires.

Unsuitable extinguishing media: Water jet.

5.2. Special hazards arising from the substance or mixture:

Possible formation of carbon oxides, nitrogen oxides and hazardous organic compounds.

5.3. Advice for firefighters:

Specific methods:
In case of fire nearby, remove exposed containers. Collect contaminated fire extinguishing water separately. This must not be discharged into
drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Cool closed
containers exposed to fire with water spray. Ensure a system for the rapid emptying of containers.

Special protective actions for fire-fighters:

In the event of fire, wear self-contained breathing apparatus. Complete suit protecting against chemicals.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures:

Wear suitable protective clothing, gloves and eye/face protection. Ensure adequate ventilation. Evacuate area of all unnecessary personnel.

6.2. Environmental precautions:

Do not release into the environment.
Local authorities should be advised if significant spillages cannot be contained.

6.3. Methods and materials for containment and cleaning up:

Methods for cleaning up:

Keep in suitable, closed containers for disposal.

Recovery:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Sweep up to
prevent slipping hazard.

Elimination:
Dispose of in accordance with local regulations.

6.4. Reference to other sections: None.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling:

Technical measures/Precautions:

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Provide water supplies and ocular fountains near the point of use. Provide a catch-tank in a bunded area.

Safe handling advice:

Smoking, eating and drinking should be prohibited in the application area.

Hygiene measures:
See heading 4.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.

7.2. Conditions for safe storage, including any incompatibilities:

Keep container tightly closed in a dry and well-ventilated place.

Packaging material:
Recommended: Original packaging

7.3. Specific end use(s): None.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters:

Exposure Limit Values

ethyleneglycol
Source Date Value type Value Value Remarks
(ppm) (mg/m3)
EH40 WEL 12 2011 SKIN – – particulate Can be absorbed through the skin.
EH40 WEL 12 2011 SKIN – – vapour Can be absorbed through the skin.
EH40 WEL 12 2011 STEL 40 104 vapour
EH40 WEL 12 2011 TWA – 10 particulate
EH40 WEL 12 2011 TWA 20 52 vapour
EU ELV 12 2009 STEL 40 104 Indicative value
EU ELV 12 2009 SKIN – – Can be absorbed through the skin.
EU ELV 12 2009 TWA 20 52 Indicative value
ACGIH (US) 02 2012 Ceiling – 100 Aerosol

Derived No Effect Level (DNEL): No data available.

Predicted No Effect Concentration: No data available.

8.2. Exposure controls:

Appropriate engineering controls: Provide appropriate exhaust ventilation at machinery.

Personal protective equipment:

Respiratory protection: Wear a respirator if necessary.
In case of spillage, wear a mask Recommended Filter type: AK
Avoid breathing dust or vapour., In the case of vapour formation use a respirator with an
approved filter.
Hand protection: Impervious gloves

Protective gloves complying with EN 374.

Request information on glove permeation properties from the glove supplier., The suitability for a
specific workplace should be discussed with the producers of the protective gloves.
Eye/face protection: Safety glasses with side-shields conforming to EN166, Eye wash bottle with pure water
Skin and body protection: Protective suit

Environmental exposure controls: See chapter 6

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance:
Physical state (20°C): liquid
Colour: yellow
Odour: No data available.
Olfactory threshold: No data available.
pH: Concentration 10 %, pH 7 - 8, (as aqueous solution)
Melting point/range : < -10 °C (OECD Test Guideline 102)
Boiling point/boiling range: No data available.

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Flash point: ca. 93 °C (Standard ASTM D 93)

Evaporation rate: No data available.
Flammability (solid, gas):
Flammability: Not relevant
Vapour pressure: No data available.
Vapour density: No data available.
Relative density (Water=1): 1,00 - 1,04 at 25 °C (OECD Test Guideline 109)
Water solubility: soluble
Partition coefficient: n-octanol/water: QUATERNARY AMMONIUM SALT : log Kow : < 2
ETHYLENEGLYCOL : log Kow : -1,36 , at 23 °C
HETEROCYCLIC DERIVATIVES : log Kow : < 3
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity, dynamic: < 20 mPa.s , at 25 °C
< 50 mPa.s , at 4 °C
Explosive properties:
Explosivity: Not explosive
Oxidizing properties: The substance or mixture is not classified as oxidizing.
9.2. Other data: None.

10. STABILITY AND REACTIVITY

10.1. & 10.2. Reactivity & Chemical stability:

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions: No data available.

10.4. Conditions to avoid: No data available.

10.5. Incompatible materials to avoid:

Strong oxidizing agents

10.6. Hazardous decomposition products:

Possible formation of carbon oxides, nitrogen oxides and hazardous organic compounds.

11. TOXICOLOGICAL INFORMATION

All available data on this product and/or the components quoted in section 3 and/or the analogue substances/metabolites have been taken
into account for the hazard assessment.
11.1. Information on toxicological effects:

Acute toxicity:

Inhalation: Based on available data, the classification criteria are not met. Slightly or not harmful by
inhalation

Ingestion: According to its composition, can be considered as : Harmful if swallowed.

Acute toxicity estimate: 900

Dermal: Based on available data, the classification criteria are not met. Slightly or not harmful in
contact with skin

Local effects ( Corrosion / Irritation / Serious eye damage ):

Skin contact: According to its composition, can be considered as : Causes severe skin burns and eye
damage.

Eye contact: According to its composition, can be considered as : Causes serious eye damage.

Respiratory or skin sensitisation:

Inhalation: Based on available data, the classification criteria are not met. not a respiratory sensitizer

Skin contact: According to its composition, can be considered as : May cause an allergic skin reaction.

CMR effects :

Mutagenicity: Results from tests do not lead to considering the product as genotoxic

CECA 89 Boulevard National - 92250 LA GARENNE-COLOMBES -

Product: NORUST 170 Page: 6 / 8
SDS No.: 926509-001 (Version

Carcinogenicity: Based on the available data, the substance is not suspected of having carcinogenic potential

Reproductive toxicity:

Fertility: Based on the available data, the substance is not suspected of having reprotoxic potential.

Foetal development: Based on the available data, the substance is not suspected of having developmental toxicity
potential.

Specific target organ toxicity :

Single exposure :

Inhalation: Based on available data, the classification criteria are not met.

Repeated exposure: Based on available data, the classification criteria are not met.

Aspiration hazard: Not relevant

12. ECOLOGICAL INFORMATION

12.1. Toxicity : No data available.

12.2. Persistence and degradability :

Biodegradation (In water): There is no data available for this product.

12.3. Bioaccumulative potential :

Bioaccumulation: No data available.

QUATERNARY AMMONIUM SALT :
Partition coefficient: n-octanol/water: log Kow : < 2
ETHYLENEGLYCOL :
Partition coefficient: n-octanol/water: log Kow : -1,36 , at 23 °C
HETEROCYCLIC DERIVATIVES :
Partition coefficient: n-octanol/water: log Kow : < 3
12.4. Mobility in soil - Distribution among environmental compartments: No data available.

12.5. Results of PBT and vPvB assessment : None.

12.6. Other adverse effects:

Global warming potential (GWP): Not relevant (due to the chemical structure)

Ozone depletion potential: Not relevant (due to the chemical structure)

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment:

Disposal of packaging: Must be dumped or incinerated in accordance with local regulations.

According to the European Waste Catalogue, Waste Codes are not product specific, but application
specific. Waste codes should be assigned by the user based on the application for which the product
was used.

14. TRANSPORT INFORMATION

CECA 89 Boulevard National - 92250 LA GARENNE-COLOMBES -

Product: NORUST 170 Page: 7 / 8
SDS No.: 926509-001 (Version

UN Environmentally
Regulation number Proper shipping name Class Label PG
hazardous
Other information
CORROSIVE LIQUID, N.O.S.(Quaternary yes
ADR 1760 ammonium salts) 8 8 II
ADN 1760 CORROSIVE LIQUID, N.O.S. (Quaternary 8 8 II yes
ammonium salts)
RID 1760 CORROSIVE LIQUID, N.O.S. (Quaternary 8 8 II yes
ammonium salts)
IATA Cargo 1760 Corrosive liquid, n.o.s. (Quaternary ammonium salts 8 8 II yes
IATA Passenger 1760 Corrosive liquid, n.o.s. (Quaternary ammonium 8 8 II yes
salts)
IMDG 1760 CORROSIVE LIQUID, N.O.S. (Quaternary 8 8 II Marine pollutant EmS Number: F-A, S-B
ammonium salts) Mark: MP

15. REGULATORY INFORMATION

Safety data sheets: according to Regulation (EC) No. 1907/2006

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture:

UK REGULATION Chip3: Chemical (Hazard Information and Packaging for Supply) Regulations 2002

15.2. Chemical Safety Assessment: None.

INVENTORIES:
EINECS: Conforms to
TSCA: Does not conform
AICS: Conforms to
DSL: This product contains one or several components that are not on the Canadian DSL nor NDSL lists.
ENCS (JP): Conforms to
KECI (KR): Conforms to
PICCS (PH): Conforms to
IECSC (CN): Conforms to

16. OTHER INFORMATION

Full text of R, H, EUH-phrases referred to under sections 2 and 3

R21/22 Harmful in contact with skin and if swallowed.

R22 Harmful if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
R50 Very toxic to aquatic organisms.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

CECA 89 Boulevard National - 92250 LA GARENNE-COLOMBES -

Product: NORUST 170 Page: 8 / 8
SDS No.: 926509-001 (Version

This safety data sheet complies with international standard ISO 11014-1. In case of formulations or mixtures, it is necessary to ascertain that a
new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is given quite
sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet
shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and codes of practice
documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official
documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product to pass
on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other processes) the totality
of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of
environment.
NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is "," (comma).

CECA 89 Boulevard National - 92250 LA GARENNE-COLOMBES -

SDS no. 141392
Version 1
Revision date 12-Feb-2016
Supersedes date None

Safety Data Sheet

EPT-3296

1. Identification of the substance/preparation and of the Company/undertaking

1.1 Product identifier

Product name EPT-3296

Product code 141392
Country Limitations This SDS is not for use in the European Union (EU).

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Biocide

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
SMI Oilfield Technology & Products FZE
P.O Box 17120
Jebel Ali
Dubai
UAE
+97 14 8833100
+97 14 8837197

[email protected]
1.4 Emergency Telephone Number

Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe
+44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600

2.1 2. Hazards
Classification of the substance or mixture identification
Classification according to (EC) No. 1272/2008

Health hazards
Acute oral toxicity Category 4
Acute inhalation toxicity - dust/mist Category 3
Skin corrosion/irritation Category 1 Subcategory 1B
Serious eye damage/eye irritation Category 1
Skin sensitization Category 1
Reproductive toxicity Category 2

Environmental hazards
Acute aquatic toxicity Category 1
Chronic aquatic toxicity Category 2

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EPT- SDS no. 141392
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_ _

Physical Hazards Not classified

2.2 Label elements

Signal word
DANGER

Hazard statements
H302 - Harmful if swallowed
H331 - Toxic if inhaled
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H361d - Suspected of damaging the unborn child
H400 - Very toxic to aquatic life
H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)

P201 - Obtain special instructions before use
P280 - Wear protective gloves/protective clothing and eye/face protection
P273 - Avoid release to the environment
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician

Supplementary precautionary statements

P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P272 - Contaminated work clothing should not be allowed out of the workplace
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing
P363 - Wash contaminated clothing before reuse
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P501 - Dispose of contents/container in accordance with local regulations.

Contains
Tetrakis(hydroxymethyl)phosphonium sulphate(2:1)

Quaternary ammonium compounds, benzylcoco alkyldimethyl, chlorides

Ethylene Glycol

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EPT- SDS no. 141392
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_ _

2.3 Other data

Not classified as PBT/vPvB by current EU criteria

3.1 Substances 3. Composition/information on ingredients

Not Applicable

3.2 Mixtures

Component EC-No. CAS-No Weight % - Classification Classification (Reg. REACH

range (67/548) 1272/2008) registration
number
Tetrakis(hydroxymethyl 259-709-0 55566-30-8 30-60 T; R23, Acute Tox. No data available
)phosphonium Xn; R22 4(H302) Acute
sulphate(2:1) Xi; R41/43 Tox. 2(H330) Eye
Repr. 3 R63 Dam. 1(H318)
N; R50
Skin Sens. 1(H317)
Repr. Tox. 2(H361D)
Aquatic Acute 1(H400)
Aquatic Chronic
2(H411)
Quaternary ammonium 263-080-8 61789-71-7 5-10 Xn;R21/22 Oral Acute Tox. 4 (H302) No data available
compounds, C; R34 Dermal Acute Tox 4 (H312)
benzylcoco N;R50 Skin Corr. 1B (H314)
alkyldimethyl, chlorides Aquatic Acute 1 (H400)

Ethylene Glycol 203-473-3 107-21-1 <3 Xn; R48/22 Acute Tox. 4 (H302) 01-2119456816-28-x
STOT Rep. Exp. Cat xxx
2
(H373)

Comments
The product contains other ingredients which do not contribute to the overall classification.

4.1 First-Aid Measures 4. First aid measures

Inhalation Move the exposed person to fresh air at once. If breathing is difficult, (trained
personnel should) give oxygen. If not breathing, give artificial respiration. Seek
medical attention at once.

Ingestion Do NOT induce vomiting. Get immediate medical attention. Rinse mouth. Risk of
product entering the lungs on vomiting after ingestion. Never give anything by mouth to
an unconscious person.

Skin contact Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove
clothing if soaked through and wash as above. Burns: Flush with water immediately. While
flushing, remove clothes which do not adhere to affected area. Call an ambulance.
Continue flushing during transport to hospital. Chemical burns must be treated by a
physician.

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EPT- SDS no. 141392
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_ _
Eye contact Remove contact lenses. Immediately flush eyes with water for 15 minutes while
holding eyelids open. Seek medical attention.

4.2 Most important symptoms and effects, both acute and delayed

General advice Seek medical attention for all burns, regardless how minor they may seem. The severity of
the symptoms described will vary dependant of the concentration and the length of
exposure. If adverse symptoms develop, the casualty should be transferred to hospital as
soon as possible.

Main symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5.1 Extinguishing media 5. Fire-fighting measures

Suitable extinguishing media
Water spray, dry chemical, carbon dioxide (CO2), or foam.

Extinguishing media which shall not be used for safety reasons

Do not use water jet.

5.2 Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

None known.

Hazardous combustion products

Fire or high temperatures create:, Oxides of phosphorus, Sulphur oxides, Hydrogen gas, Carbon monoxide, carbon dioxide and
unburned hydrocarbons (smoke), Phosphines, Carbon oxides (COx), Nitrogen oxides (NOx).

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

6.1 6. Accidental
Personal precautions, protective equipment release measures
and emergency procedures

Evacuate personnel to safe areas. Do not get on skin or clothing. Wash thoroughly after handling. Do not breathe vapors or spray

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EPT- SDS no. 141392
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_ _
mist. Use personal protective equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and materials for containment and cleaning up

Methods for containment

Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

Methods for cleaning up

Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and
place in container for disposal according to local/national regulations (see Section 13).

6.4 Reference to other sections

See section 13 for more information.

7.1 Precautions for safe handling 7. Handling and storage

Handling
Handle in accordance with good industrial hygiene and safety practice. Do not get in eyes, on skin or on clothing. Do not breathe
vapors or spray mist. Avoid spills and splashing during use. Persons susceptible to allergic reactions should not handle this
product.

Safe handling instructions

Use good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and face
before breaks and immediately after handling the product Remove contaminated clothing.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Take precautionary measures against static discharges.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid excessive heat
for prolonged periods of time. Avoid contact with: Strong acids. Strong bases Strong
oxidizing agents Strong reducing agents.

Storage class Toxic storage. Corrosive storage.

Packaging material Use specially constructed containers only.

7.3 Specific end uses

See Section 1.2.

8.1 Control parameters 8. Exposure controls/personal protection

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EPT- SDS no. 141392
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_ _

Component EU OEL Austria Australia Denmark

Tetrakis(hydroxymethyl)phosphonium Not determined Not determined Not determined Not determined
sulphate(2:1)
Quaternary ammonium compounds, Not determined Not determined Not determined Not determined
benzylcoco alkyldimethyl, chlorides
Ethylene Glycol 40 ppm STEL 20 ppm STEL 40ppmSTELvapour 10 ppm TWA
104 mg/m3 STEL 52 mg/m3 STEL 104mg/m3STELvapour 26 mg/m3 TWA
20 ppm TWA 10 ppm TWA 10mg/m3TWAparticulate 10 mg/m3 TWA
52 mg/m3 TWA 26 mg/m3 TWA 20ppmTWAvapour Potential for
Possibility of 52mg/m3TWAvapour cutaneous absorption
significant skin notation
uptake through the skin

Component Malaysia France Germany Hungary

Component New Zealand Italy Netherlands Norway

Tetrakis(hydroxymethyl)phosphonium Not Determined Not determined Not determined Not determined
sulphate(2:1)
Quaternary ammonium compounds, Not Determined Not determined Not determined Not determined
benzylcoco alkyldimethyl, chlorides
Ethylene Glycol 50 ppm Ceiling mist and Not determined 104mg/m3STEL 10 mg/m3 TWA dust
vapour 52 mg/m3 20 ppm TWA total
127 mg/m3 Ceiling mist 10 mg/m3 dust and vapor
and vapour 52 mg/m3 TWA
104 mg/m3 STEL dust
40 ppm STEL
25 ppm Ceiling (vapor)
Skin

Component Poland Portugal Romania Russia

Tetrakis(hydroxymethyl)phosphonium Not determined 2 mg/m3 TWA Not determined Not determined
sulphate(2:1)
Quaternary ammonium compounds, Not determined Not determined Not determined Not determined
benzylcoco alkyldimethyl, chlorides
Ethylene Glycol 50 mg/m3 STEL NDSCh Skin 40ppmSTEL 10 mg/m3 STEL aerosol
15 mg/m3 TWA NDS 40 ppm STEL VLE-CD 104mg/m3STEL and vapor
104 mg/m3 STEL 20ppmTWA 5 mg/m3 TWA aerosol
VLE-CD 52mg/m3TWA and vapor
20 ppm TWA indicative
limit value
52 mg/m3 TWA
indicative limit value

Component Spain Switzerland Turkey UK

Tetrakis(hydroxymethyl)phosphonium Not determined Not determined Not determined Not determined
sulphate(2:1)
Quaternary ammonium compounds, Not determined Not determined Not determined Not determined

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EPT- SDS no. 141392
Revision date 12-Feb-
_ _
benzylcoco alkyldimethyl, chlorides
Ethylene Glycol 40 ppm STEL 20 ppm STEL 40 ppm STEL 40 ppm STEL vapour
104 mg/m3 STEL 52 mg/m3 STEL 104 mg/m3 STEL 104 mg/m3 STEL
Skin Skin Skin vapour
20 ppm TWA VLA-ED 10 ppm TWA MAK 20 ppm TWA 30 mg/m3 STEL
3
52 mg/m TWA VLA-ED 26 mg/m3 TWA MAK 52 mg/m3 TWA calculated particulate
Skin
10 mg/m3 TWA
particulates
20 ppm TWA vapour
52 mg/m3 TWA vapour

Derived No Effect Level (DNEL)

Long term exposure local effects

Ethylene Glycol
Inhalation 35 mg/m³
Long term exposure systemic effects

Ethylene Glycol
Dermal 106 mg/kg
Predicted No Effect Concentration (PNEC)
Ethylene Glycol
Fresh water 10 mg/l
Sea water 1 mg/l
Fresh water sediment 37 mg/kg
Sea sediment 3.7 mg/kg
Soil 1.53 mg/kg
Impact on sewage treatment 199.5 mg/l
Intermittent release 10 mg/l

8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the
chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional
hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory
protection will vary from workplace to workplace and should be assessed by the user in each situation.

Engineering measures to reduce exposure

Ensure adequate ventilation. Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into
work environment.

Personal protective equipment

Eye protection Chemical splash goggles and/or face shield.
Hand protection Impervious gloves made of:, PVC, Nitrile, Rubber, Be aware that liquid may penetrate
the gloves. Frequent change is advisable.
Respiratory protection Positive-pressure supplied air respirators may be required for high airborne
contaminant concentrations. Respiratory protection must be provided in accordance
with current local regulations, Type ABEKP, At work in confined or poorly ventilated
spaces, respiratory protection with air supply must be used.

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EPT- SDS no. 141392
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_ _
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available
at the work place.

Safe handling instructions Wash hands before eating, drinking or smoking, Remove and wash contaminated clothing
before re-use.

9.1 Information on basic physical and9.chemical

Physical and chemical
properties properties
Physical state Liquid
Appearance Clear Aqueous solution
Odor Characteristic
Color Colorless
Odor threshold Not applicable

Property Values Remarks

pH No information available
pH @ dilution 3.21 ± 1.00 @ 10% (20°C)
Melting/freezing point No information available
Boiling point/range No information available
Flash point 72 °C / 161.6 °F
Evaporation rate (BuAc =1) No information
available Flammability (solid, gas) Not Applicable
Flammability Limits in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity No information available
Bulk density No information available
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information
available Autoignition temperatureNot Applicable
Decomposition temperature No information
available
Kinematic viscosity 22.2 cPs @ 20 °C
Dynamic viscosity No information available
Log Pow Not determined

Explosive properties Not Applicable

Oxidizing properties None known.

9.2 Other information

Pour point < -21°C/-5.8°F
Molecular weight No information available
VOC content(%) None
Density 1.26 ± 0.03 g/ml @ 20°C

10.1 Reactivity 10. Stability and reactivity

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EPT- SDS no. 141392
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_ _

Corrosive.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Not known.

10.4 Conditions to avoid

Take precautionary measures against static charges. Avoid excessive heat for prolonged periods of time.

10.5 Incompatible materials

Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents.

10.6 Hazardous decomposition products

See Section 5.2.

11.1 Information on toxicological effects11. Toxicological information

Acute toxicity

Inhalation Toxic if inhaled. May cause additional affects as listed under "Ingestion".

Eye contact Causes serious eye damage.

Skin contact Causes severe skin burns. Components of the product may be absorbed into the
body through the skin. May cause an allergic skin reaction.

Ingestion Harmful if swallowed. May cause damage to organs through prolonged or

repeated exposure.

Unknown acute toxicity Not Applicable.

Component LD50 Oral LD50 Dermal LC50 Inhalation

Tetrakis(hydroxymethyl)phosphonium 575 mg/kg ( Rat ) > 2000 mg/kg (Rat) 0.591 mg/l (Rat)
sulphate(2:1)
Quaternary ammonium compounds, benzylcoco 200 - 2000 mg/kg Oral (Rat) No data available No data available
alkyldimethyl, chlorides
Ethylene Glycol 4000 - 10200 mg/kg ( Rat ) = 10600 mg/kg ( Rat ) No data available

Sensitization May cause allergic skin reaction.

Mutagenic effects This product does not contain any known or suspected mutagens.

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_ _

Carcinogenicity This product does not contain any known or suspected carcinogens.

Reproductive toxicity H361d - Suspected of damaging the unborn child.

Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.

Routes of entry Inhalation. Ingestion. Skin contact. Eye contact.

Specific target organ

Not classified
toxicity (single exposure)
Specific target organ
Not classified.
toxicity (repeated exposure)

Aspiration hazard Not Applicable.

12.1 Toxicity 12. Ecological information

Very toxic to aquatic life with long lasting effects
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.

Toxicity to algae
See component information below.

Toxicity to fish
See component information below.

Toxicity to daphnia and other aquatic invertebrates

See component information below.

Component Toxicity to fish Toxicity to algae Toxicity to daphnia and other

aquatic invertebrates
Tetrakis(hydroxymethyl)phosphoniu < 1 mg/l No information available No information available
m sulphate(2:1)
Quaternary ammonium LC50 96 hours fish 1 – 10 mg/l IC50 72 hours algae <1 mg/l EC50 48 hours Daphnia <1 m g/l
compounds,
benzylcoco alkyldimethyl, chlorides
Ethylene Glycol 40000 - 60000 mg/L LC50 6500 - 13000 mg/L EC50 46300 mg/L EC50 (Daphnia
(Pimephales promelas) = 96 h (Pseudokirchneriella subcapitata) = magna)
96 h = 48 h
40761 mg/L LC50 (Oncorhynchus
mykiss) = 96 h

27540 mg/L LC50 (Lepomis

macrochirus) = 96 h

14 - 18 mL/L LC50 (Oncorhynchus

mykiss) = 96 h

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_ _
16000 mg/L LC50 (Poecilia
reticulata) = 96 h

41000 mg/L LC50 (Oncorhynchus

mykiss) = 96 h

12.2 Persistence and degradability

Product is biodegradable.

12.3 Bioaccumulative potential

The product does not contain any substances expected to be bioaccumulating.

12.4 Mobility in soil

Mobility
Soluble in water.

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

13.1 Waste treatment methods 13. Disposal considerations

Waste from residues /
Dispose of in accordance with local regulations.
unused products

Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.

EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used. The following Waste Codes are only suggestions: EWC
waste disposal No: 07 01 04

14. Transport information

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_ _
14.1 UN Number

UN/ID No. (ADR/RID/ADN/ADG) UN2810

UN No. (IMDG) UN2810
UN No. (ICAO) UN2810

14.2 Proper shipping name

TOXIC LIQUID, ORGANIC, N.O.S. (Tetrakis(hydroxymethyl)phosphonium sulphate(2:1))

14.3 Hazard class(es)

ADR/RID/ADN/ADG Hazard class 6.1
IMDG Hazard class 6.1
ICAO Hazard class/division 6.1

14.4 Packing group

ADR/RID/ADN/ADG Packing group III
IMDG Packing group III
ICAO Packing group III

14.5 Environmental hazard

Yes

14.6 Special precautions

Hazard identification no (ADR) 60

EmS (IMDG) F-A, S-A
Emergency action code 2X
Tunnel restriction code (E)

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Please contact [email protected] for info regarding transport in Bulk.

15.1 15. Regulatory specific

Safety, health and environmental regulations/legislation information
for the substance or mixture

Australian Standard for the Uniform Scheduling of Drugs and Poisons

Quaternary ammonium compounds, benzylcoco alkyldimethyl, chlorides

Schedule 6
Schedule 5
Quaternary ammonium compounds, benzylcoco alkyldimethyl, chlorides

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_ _
Schedule 6
Schedule 5
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European
Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation
(EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC
and 2000/21/EC, including amendments.

This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.

International inventories

USA (TSCA) Complies

European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Does not Comply
New Zealand (NZIoC) Complies

This SDS is not for use in the European Union (EU).

15.2 Chemical Safety Report

No information available

16. Other information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam

Revision date 12-Feb-2016

Version 1

The following sections have

been revised: New issue.

Text of R phrases mentioned in Section 3

R22 - Harmful if swallowed
R23 - Toxic by inhalation
R34 - Causes burns
R41 - Risk of serious damage to eyes
R43 - May cause sensitization by skin contact
R50 - Very toxic to aquatic organisms
R63 - Possible risk of harm to the unborn child

R21/22 - Harmful in contact with skin and if swallowed

R48/22 - Harmful: danger of serious damage to health by prolonged exposure if swallowed

Full text of H-Statements referred to under sections 2 and 3

H302 - Harmful if swallowed

_ _

Page 13 / 14
EPT- SDS no. 141392
Revision date 12-Feb-
_ _
H331 - Toxic if inhaled
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H361d - Suspected of damaging the unborn child
H400 - Very toxic to aquatic life
H411 - Toxic to aquatic life with long lasting effects
H318 - Causes serious eye damage
H312 - Harmful in contact with skin
H330 - Fatal if inhaled
H373 - May cause damage to organs through prolonged or repeated exposure

Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS
information, Supplier makes no express or implied warranties as to the information or product; merchantability or
fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier
assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others.
To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in
separate agreement between the parties.

_ _

Page 14 / 14
SAFETY DATA SHEET

Product name Emulsotron X-8672X-8672

: Emulsotron

Other means of identification : Not applicable.

Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Recommended use : EMULSION BREAKER

Restrictions on use : Reserved for industrial and professional

use. Company : Nalco Champion Company

7705 Highway 90-A
Sugar Land, Texas 77478
USA

Emergency telephone : See section 16, for Emergency Telephone Numbers.

number

Issuing date : 08/25/2016

COMPANY CONTACT TELEPHONE NUMBERS.

Nalco European NALCO EUROPE B.V. 0031 71 5241100

Operations
UAE Nalco Gulf Ltd. Tel. +97148836049
Fax. +97148836050
Jordan Nalco Gulf Ltd. Tel. +962-6-464-7990
Fax. +962-6-464-1029
Saudi Arabia Nalco Saudi Co. Ltd. Tel. +966-3-847-1517
Fax. +966-3-847-2978
Egypt Nalco Egypt Ltd Tel. +20222910740
Fax. +20222910350
Qatar Nalco Ltd, c/o Salam Petroleum Services Tel. +974 483 6911
Nalco Ltd - c/o TEYSEER Trading & Cont. Co. Tel. +974 456 8081
Fax. +974 456 8069
Oman Nalco Ltd, c/o Special Oilfield Services Tel. +968 600450
Fax. +968 600761

Section:
GHS 2. HAZARDS IDENTIFICATION
Classification
Flammable liquids : Category 4
Skin irritation : Category 2
Eye irritation : Category 2A
Carcinogenicity : Category 2
Aspiration hazard : Category 1

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Combustible liquid

May be fatal if swallowed and enters airways.
1/9
SAFETY DATA
SHEET

Causes skin irritation.

Causes serious eye irritation.
Suspected of causing
cancer.

Precautionary Statements : Prevention:

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wash
skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF
ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. IF exposed or concerned: Get medical advice/attention.
Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If
eye irritation persists: Get medical advice/ attention.

Other hazards : Do not mix with bleach or other chlorinated products – will cause chlorine gas.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Concentration: (%)

Heavy Aromatic Naphtha 64742-94-5 30 - 60
Diesel Fuel No. 2 68476-34-6 30 - 60
Naphthalene 91-20-3 1-5
1,2,4-Trimethylbenzene 95-63-6 1-5
Dodecylbenzenesulphonic Acid 27176-87-0 1-5

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild
soap if available. Get medical attention if irritation develops and persists.

If swallowed : Do NOT induce vomiting. Never give anything by mouth to an unconscious

person. Aspiration hazard if swallowed - can enter lungs and cause damage.
Get medical attention immediately.

If inhaled : Get medical attention if symptoms occur.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Foam
Carbon dioxide
Dry powder
Other extinguishing agent suitable for Class B fires

2/
SAFETY DATA
SHEET

For large fires, use water spray or fog, thoroughly drenching the burning
material.

Unsuitable extinguishing : High volume water jet

media

Specific hazards during : Fire Hazard

firefighting Keep away from heat and sources of ignition.
Flash back possible over considerable distance.

Hazardous combustion : Decomposition products may include the following materials: Carbon
products oxides nitrogen oxides (NOx) Sulphur oxides

Special protective : Use personal protective equipment.

equipment for firefighters

Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of
methods in accordance with local regulations. In the event of fire and/or explosion do
not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is
protective equipment and conducted by trained personnel only. Refer to protective measures listed in
emergency procedures sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so.
containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material,
(e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for
disposal according to local / national regulations (see section 13). For large
spills, dike spilled material or otherwise contain material to ensure runoff does
not reach a waterway. Do not flush into surface water or sanitary sewer
system.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin and eyes. Take necessary action to avoid static
electricity discharge (which might cause ignition of organic vapours). Keep away
from fire, sparks and heated surfaces. Wash hands thoroughly after handling.
Use only with adequate ventilation. Do not mix with bleach or other chlorinated
products – will cause chlorine gas.

Conditions for safe storage : Keep away from heat and sources of ignition. Keep away from oxidizing agents.
Keep out of reach of children. Keep container tightly closed. Store in suitable
labelled containers.

Suitable material : Surface fluorinated polyethylene

Unsuitable material : Polyethylene, Mild steel

Section: 8. EXPOSURE
Components CONTROLS/PERSONAL
with workplace control parameters PROTECTION

Components CAS-No. Form of exposure Permissible Basis

concentration
Heavy Aromatic Naphtha 64742-94-5 TWA 500 ppm OSHA Z1

3/
SAFETY DATA
SHEET

2,000 mg/m3
TWA 200 mg/m3 (as ACGIH
total hydrocarbon
vapor)
Diesel Fuel No. 2 68476-34-6 TWA (Inhalable 100 mg/m3 (total ACGIH
fraction and vapor) hydrocarbons)
Naphthalene 91-20-3 TWA 10 ppm ACGIH
TWA 10 ppm NIOSH REL
50 mg/m3
STEL 15 ppm NIOSH REL
75 mg/m3
TWA 10 ppm OSHA Z1
50 mg/m3
1,2,4-Trimethylbenzene 95-63-6 TWA 25 ppm NIOSH REL
125 mg/m3
TWA 25 ppm ACGIH

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.

Personal protective equipment

Eye protection : Safety goggles

Face-shield

Hand protection : Wear the following personal protective equipment:

Standard glove type.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : No personal respiratory protective equipment normally required.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling.

Section: 9. PHYSICAL AND CHEMICAL

Appearance : liquid PROPERTIES
Colour : Clear Brown
Odour : Characteristic
Flash point : 61 °C, Method: PMCC
pH : 2.5 - 4.5
Odour Threshold : no data available
Melting point/freezing point : POUR POINT: -10 °C
Initial boiling point and : 160 °C
boiling range
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available

4/
SAFETY DATA
SHEET

Vapour pressure : no data available

Relative vapour density : no data available
Relative density : 0.898, (20 °C),
Density : no data available
Water solubility : insoluble
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available
Thermal decomposition
: no data available
temperature
Viscosity, dynamic : 15 mPa.s (20 °C)
10 mPa.s (40 °C)
Viscosity, kinematic : no data available
Molecular weight : no data available
VOC : 0.23 %

Section: stability
Chemical 10. STABILITY AND:REACTIVITY
Stable under normal conditions.

Possibility of : Do not mix with bleach or other chlorinated products – will cause chlorine gas.
hazardous reactions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Decomposition products may include the following materials:

products Carbon oxides
nitrogen oxides (NOx)
Sulphur oxides

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact
exposure

Potential Health Effects

Eyes : Causes serious eye irritation.

Skin : Causes skin irritation.

Ingestion : May be fatal if swallowed and enters airways.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Suspected of causing cancer.

Experience with human exposure

5/
SAFETY DATA
SHEET

Eye contact : Redness, Pain, Irritation

Skin contact : Redness, Irritation

Ingestion : Vomiting

Inhalation : No symptoms known or expected.

Toxicity

Product
Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: > 40 mg/l
Exposure time: 4 h
Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : no data available
sensitization
Carcinogenicity
IARC Group 2B: Possibly carcinogenic to humans
Naphthalene 91-20-3

OSHA No component of this product present at levels greater than or equal to 0.1%
is identified as a carcinogen or potential carcinogen by OSHA.

NTP Reasonably anticipated to be a human carcinogen

Naphthalene 91-20-3

Reproductive effects : no data available

Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity

Environmental Effects : Toxic to aquatic life with long lasting effects.

Components
Toxicity to fish : Heavy Aromatic Naphtha
LC50 Oncorhynchus mykiss (rainbow trout): 3.5 mg/l
Exposure time: 96 h

Dodecylbenzenesulphonic Acid
LC50 Fish: 4.3 mg/l
Exposure time: 96 h

6/
SAFETY DATA
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Components
Toxicity to daphnia and other : Diesel Fuel No. 2
aquatic invertebrates EC50 : 5.5 mg/l
Exposure time: 48 h

Persistence and degradability

no data available

Mobility

no data available

Bioaccumulative potential

no data available

Other information

no data available

Section:methods
Disposal 13. DISPOSAL CONSIDERATIONS
: The product should not be allowed to enter drains, water
courses or the soil. Where possible recycling is preferred to
disposal or incineration. If recycling is not practicable, dispose
of in compliance with local regulations. Dispose of wastes in
an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be

taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.

Section:
The 14. TRANSPORT INFORMATION
shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.

Land transport (DOT)

Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Technical name(s) : Heavy Aromatic Naphtha
UN/ID No. : UN 3082
Transport hazard class(es) :9
Packing group : III

Air transport (IATA)

Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Technical name(s) : Heavy Aromatic Naphtha
UN/ID No. : UN 3082
Transport hazard class(es) :9
Packing group : III

Sea transport (IMDG/IMO)

Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Technical name(s) : Heavy Aromatic Naphtha
UN/ID No. : UN 3082

7/
SAFETY DATA
SHEET

Transport hazard class(es) :9

Packing group : III

*Marine pollutant : Heavy Aromatic Naphtha

*Note: This product is regulated as a Marine Pollutant when shipped by Rail, Highway (in bulk
quantities), or Air (if no other hazard class applies), and when shipped by water in all quantities.

Section: 15.
NATIONAL REGULATORY INFORMATION
REGULATIONS
National regulations in the country where this substance is used, should be followed.

Section:
NFPA: 16. OTHER INFORMATION HMIS III:
Flammability
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
2 HEALTH
4 = Extreme, * = Chronic 2*
Instabil

2 0
Hea

FLAMMABILITY 2
PHYSICAL HAZARD 0

Special hazard.

8/
SAFETY DATA
SHEET

Trans-European +32-(0)3-575-5555
Saudi Arabia +966-(3)847-1515
UAE +44-(0)7071-223-738

POISON CONTROL CENTER TELEPHONE NUMBERS

UAE Poison and Drug Information Center- Abu Toll Free Number:800 424
Dhabi
Jordan Jordan National Poison Information Center- Tel.+962 6 53535444
Amman
Saudi Arabia Drug and Poisons Information Center-Riyadh Tel.+966 1 4677354
Fax. 0096614676229
Egypt Alexandria Poisons Center Tel. +20 3 4862244
Fax. +20 3 4873076
Poisons Control Center-Cairo Tel. +20 2 6840902
Fax. +20 2 683 6674
Oman Poison Control Center-Musqat Tel. +968 562898
Fax. +968 563121

Revision Date : 08/25/2016

Version Number : 1.0
Prepared By : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision
is indicated by a bar in the left-hand margin of the SDS.

9/
SAFETY DATA
SHEET

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
For additional copies of an SDS visit www.nalco.com and request access.

10
SAFETY DATA
SHEET

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Defoamer AF340

Other means of identification : Not applicable.

Recommended use : DEFOAMER

Restrictions on use : Reserved for industrial and professional

use. Company : Nalco Champion Company

7705 Highway 90-A
Sugar Land, Texas 77478
USA

Emergency telephone : See section 16, for Emergency Telephone Numbers.

number

Issuing date : 07/21/2016

COMPANY CONTACT TELEPHONE NUMBERS.

Nalco European NALCO EUROPE B.V. 0031 71 5241100

Section:
GHS 2. HAZARDS IDENTIFICATION
Classification
Flammable liquids : Category 4
Aspiration hazard : Category 1

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Combustible liquid

May be fatal if swallowed and enters airways.

Precautionary Statements : Prevention:

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear
1/8
SAFETY DATA
SHEET

protective gloves/ eye protection/ face protection.

Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do
NOT induce vomiting. In case of fire: Use dry sand, dry chemical or alcohol-
resistant foam to extinguish.
Storage:
Store in a well-ventilated place. Keep cool. Store locked up.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Concentration: (%)

Hydrotreated Light Distillate 64742-47-8 60 - 100

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse with plenty of water. Get medical attention if symptoms occur.

In case of skin contact : Wash off with soap and plenty of water. Get medical attention if symptoms
occur.

If swallowed : Do NOT induce vomiting. Never give anything by mouth to an unconscious

person. Aspiration hazard if swallowed - can enter lungs and cause damage.
Get medical attention immediately.

If inhaled : Get medical attention if symptoms occur.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Foam
Carbon dioxide
Dry powder
Other extinguishing agent suitable for Class B fires
For large fires, use water spray or fog, thoroughly drenching the burning
material.

Unsuitable extinguishing : High volume water jet

media

Specific hazards during : Fire Hazard

firefighting Keep away from heat and sources of ignition.
Flash back possible over considerable distance.

Hazardous combustion : Decomposition products may include the following materials: Carbon
products oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus

2/
SAFETY DATA
SHEET

Special protective : Use personal protective equipment.

equipment for firefighters

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Ensure adequate ventilation. Remove all sources of ignition. Refer to
protective equipment and protective measures listed in sections 7 and 8.
emergency procedures

Environmental precautions : Do not allow contact with soil, surface or ground water.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Take necessary action to avoid static electricity discharge (which might cause
ignition of organic vapours). Keep away from fire, sparks and heated surfaces.
Wash hands thoroughly after handling. Use only with adequate ventilation.

Suitable material : Keep in properly labelled containers.

Unsuitable material : not determined

Section: 8. EXPOSURE
Components CONTROLS/PERSONAL
with workplace control parameters PROTECTION

Components CAS-No. Form of exposure Permissible Basis

concentration
Hydrotreated Light Distillate 64742-47-8 TWA 500 ppm OSHA Z1
2,000 mg/m3
TWA 200 mg/m3 (as ACGIH
total hydrocarbon
vapor)
TWA (Mist) 5 mg/m3 OSHA Z1
TWA (Mist) 5 mg/m3 NIOSH REL
STEL (Mist) 10 mg/m3 NIOSH REL

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.

Personal protective equipment

Eye protection : Safety goggles

3/
SAFETY DATA
SHEET

Face-shield

Hand protection : Wear the following personal protective equipment:

Standard glove type.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : No personal respiratory protective equipment normally required.

Section: 9. PHYSICAL AND CHEMICAL

Appearance : liquid PROPERTIES
Colour : clear
Odour : no data available
Flash point : ca. 71 °C, Method: Pensky-Martens closed cup
pH : 6-8
Odour Threshold : no data available
Melting point/freezing point : POUR POINT: < -22 °C
Initial boiling point and : no data available
boiling range
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : 7 V%
Lower explosion limit : < 0.01 V%
Vapour pressure : < 0.1 hPa, (20 °C),
Relative vapour density : 1(Air = 1.0)
Relative density : 0.8 - 0.83, (20 °C),
Density : no data available
Water solubility : insoluble
Solubility in other solvents : no data available
Partition coefficient: n- : log Pow: > 3
octanol/water
Auto-ignition temperature : 230 °C
Thermal decomposition
: no data available
temperature
Viscosity, dynamic : < 25 mPa.s (20 °C)
Viscosity, kinematic : no data available
Molecular weight : no data available
VOC : no data available

Section: 10. STABILITY AND REACTIVITY

4/
SAFETY DATA
SHEET

Chemical stability : Stable under normal conditions.

Possibility of : No dangerous reaction known under conditions of normal use.

hazardous reactions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Decomposition products may include the following materials:

products Carbon oxides
nitrogen oxides (NOx)
Sulphur oxides
Oxides of phosphorus

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact
exposure

Potential Health Effects

Eyes : Health injuries are not known or expected under normal use.

Skin : Health injuries are not known or expected under normal use.

Ingestion : May be fatal if swallowed and enters airways.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact : No symptoms known or expected.

Skin contact : No symptoms known or expected.

Ingestion : Vomiting

Inhalation : No symptoms known or expected.

Toxicity

Product
Acute oral toxicity : no data available
Acute inhalation toxicity : no data available
Acute dermal toxicity : no data available
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : no data available
sensitization
Carcinogenicity : no data available

5/
SAFETY DATA
SHEET

Reproductive effects : no data available

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity

Environmental Effects : This product has no known ecotoxicological effects.

Components
Toxicity to fish : Hydrotreated Light Distillate
LC50 : > 1,000 mg/l
Exposure time: 96 h

Components
Toxicity to daphnia and other : Hydrotreated Light Distillate
aquatic invertebrates EC50 : > 1,000 mg/l
Exposure time: 48 h

Components
Toxicity to algae : Hydrotreated Light Distillate
EC50 : > 1,000 mg/l
Exposure time: 72 h

Components
Toxicity to bacteria : Hydrotreated Light Distillate
> 1,000 mg/l
Exposure time: 48 h

Persistence and degradability

no data available

Mobility

no data available

Bioaccumulative potential

no data available

Other information

no data available

Section: 13. DISPOSAL CONSIDERATIONS

6/
SAFETY DATA
SHEET

Disposal methods : Where possible recycling is preferred to disposal or

incineration. If recycling is not practicable, dispose of in
compliance with local regulations. Dispose of wastes in an
approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be

taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.

Section:
The 14. TRANSPORT INFORMATION
shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.

Land transport (DOT)

For packages less than or equal to 119 Gallons:

Proper shipping name : PRODUCT IS NOT REGULATED DURING

TRANSPORTATION

For packages greater than 119 Gallons:

Proper shipping name : COMBUSTIBLE LIQUID, N.O.S.

Technical name(s) : Hydrotreated Light Distillate
UN/ID No. : NA 1993
Hazard Class - Primary : COMBUSTIBLE LIQUID
Packing group : III

Air transport (IATA)

Proper shipping name : PRODUCT IS NOT REGULATED DURING

TRANSPORTATION

Sea transport (IMDG/IMO)

Proper shipping name : PRODUCT IS NOT REGULATED DURING

TRANSPORTATION

Section: 15.
NATIONAL REGULATORY INFORMATION
REGULATIONS
National regulations in the country where this substance is used, should be followed.

Section: 16. OTHER INFORMATION

7/
SAFETY DATA
SHEET

NFPA: HMIS III:

Flammability
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
2 HEALTH
4 = Extreme, * = Chronic 2

Instabil
2 0
Hea

FLAMMABILITY 2
PHYSICAL HAZARD 0

Special hazard.

Trans-European +32-(0)3-575-5555
Saudi Arabia +966-(3)847-1515
UAE +44-(0)7071-223-738

POISON CONTROL CENTER TELEPHONE NUMBERS

Revision Date : 07/21/2016

Version Number : 1.0
Prepared By : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision
is indicated by a bar in the left-hand margin of the SDS.

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