132/2-Fv Joint Examination 2023

PRESIDENT’S OFFICE
REGIONAL ADMINISTRATION AND LOCAL GOVERNMENT
ADVANCED CERTIFICATE OF SECONDARY EDUCATION EXAMINATION
FORM FIVE JOINT EXAMINATION SOUTHERN ZONE
(MTWARA AND LINDI)

132/2 CHEMISTRY 2
(For Both School and Private Candidates)

Time: 3 Hours May 2023

Instructions

1. This paper consists of six (6) questions.

2. Answer only five (5) questions.
3. Each question carries twenty (20) marks.
4. Mathematical tables and Non programable calculators may be used.
5. Cellular phones and any unauthorized materials are not allowed in the
examination room.
6. Write your Examination Number on every page of your answer booklet(s).
7. For calculations you may use the following constants:
• Universal gas constant,R=
8.314JK−1 mol−1 or 0.0821K−1 atm mol−1 K−1 dm3
• Avogadro’s constant, N6.022 × 1023 mol−1
• Standard pressure =1atm =760mmHg =1.0 × 105 Nm−2
• Atomic masses:H= 1, Cl= 35.5, Cr=52, O=16, C=12, F=19, Na=23, Ca=40,
S=32, N=14

This paper consists of five printed pages

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1. (a) A special type of distillation for temperature sensitive materials having high
boiling point organic compounds, such compound can not be distilled at their
own boiling point
(i) Suggest the best terminology that describe a special type of distillation.
(ii) Explain the meaning of the terminology
(iii) Why high temperature sensitive materials cannot be distilled at their own
boiling point. Give one reason.
(04 marks)
(b) Calculate the percentage by mass of bromobenzene(C6 H5 Br) in the distillate
when the mixture of bromobenzene and water distils in a steam at 95◦ C. The
vapour pressure of bromobenzene and water at 99◦ C are 1.59 × 104 Nm−2 and
8.50 × 104 Nm−2 respectively.
(c) (i) State any four(4) conditions that govern the distribution law. (04 marks)
(ii) given that the solubility of iodine in water is 0.34g/L and the aqueous
solution of iodine containing 0.0516g/L is in equilibrium with carbon tetra
chloride(CCl4 ) solution containing 4.412g/L, calculate the solubility of
iodine in carbontetrachloride. (04 marks)
(d) State the unique properties of immiscible liquids. Give four reasons.
(04 marks)
2. (a) The following chemical reaction was carried out at constant temperature
4A(g) + 3B(g) −→ 2C(g) . The data obtained when A and B were allowed to
react at the same temperature are;
Experiment [A],M [B],M initial rate, Ms−1
1 0.100 0.100 5.00
2 0.300 0.100 45.00
3 0.100 0.200 10.00
4 0.300 0.200 90.00
(i) Calculate the order of reaction with respect to each reactant.
(ii) Calculate the value of rate constant (K). (13 marks)
(b) Show the derivation of Arrhenious equation which gives the relation of T1
and T2
(07 marks)
3. (a) What do you understand by the following terms
(i) Fractional distillation
(ii) Ideal solution
(iii) Azeotropic mixture
(iv) Vapour pressure (04 marks)

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(b) Give a reason to why mixture of liquids deviate

(i) Positively
(ii) Negatively (02 marks)
(c) The nitric acid (B.P 85◦ C) mixture with water form azeotropic mixture with
boiling point of 121◦ C and Nitric acid composition of 68%.
(i) Sketch a temperature-composition curve for water nitric acid mixture
(ii) What type of deviation is this? Explain.
(iii) It is possible to separate water-nitric acid mixture into pure water but not
into pure Nitric acid. (14 marks)
4. (a) Mendeleef is a father of periodic table since was the founder of many feature
present in the current periodic table. Explain the merits and demerits of
Mendeleev’s periodic table. (Give three points in each case). (06 marks)
(b) Halogens react differently with cold and hot sodium hydroxide solution.
Describe this with the aid of chemical reactions. (04 marks)
(c) Beryllium react differently comparing to other group II elements. Give
three(3) reasons to why Beryllium react differently. Give two(2) reactions
that Beryllium differ to other group II elements. (05 marks)
(d) Form five students observed the similarity of reaction shown by magnesium
and lithium. What do we call this phenomenone in the periodic table? Explain
the two causes of this phenomenone. Give example of two reactions in which
Lithium and Magnesium react similar. (05 marks)
5. (a) By using IUPAC system name the following compounds;
OH
(i)
OH

NO2
(ii)

NO2
(iii) HO CH2 CH2 OH
CH3
(iv) CH3 CH2 CH2 CH CH CH2 CH CH3

CH2 CH3 OH
(04 marks)

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(b) (i) Arrange the following molecule according to increasing of acidic

character
OH OH OH OH

NO2 NO2
, , , (02 marks)

NO2 NO2
(ii) By using one chemical test show how you can distinguish phenol from
alcohol. (02 marks)
(c) Explain the following phenomenone
(i) Alcohols have higher boiling point than alkyl halides or alkanes of
comparable molecular weight.
(ii) Ethanol is more soluble in water than alkane.
(iii) Phenol is more acidic than ethanol.
(iv) Why alcohols with large number of carbons are less soluble compared to
the lower one.
(06 marks)
(d) By using not more than two(2) steps show how can carry out the following
conversions
(i) Benzylalcohol into Benzoic acid
(ii) Chlorobenzene into P-nitrophenol
(iii) Toluene into benzylalcohol
(iv) 2-chloropropane into 1-propanol. (06 marks)
6. (a) Give the IUPAC names of the following compounds
O

(i) CH3 C CH3

O

(ii) H C O CH2 CH3

O
C CH3
(iii)
O

(iv) CH3 C H
O

(v) CH3 C OH (05 marks)

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(b) By using one chemical test show, how would you distinguish the following
O O
C H C CH3
(i) from
O
COOH C CH2 CH3
(ii) from
O O

(iii) CH3 CH2 C CH2 CH3 from CH3 CH2 C H (06 marks)
(c) A carbonyl compound A was reduced with LiAlH4 to give compound B.
Compound B was dehydrated with Conc.H2 SO4 to give one product, C
(molecular formula C5 H10 ). Ozonolysis of C gave ethanal and other
compound D with molecular formulae C3 H6 O. Compound D gives a
positive iodoform test
(i) Identify compound A to D
(ii) Give the chemical reactions for the above reaction. (07 marks)
(d) Explain why carboxylic acids has higher boiling point(s) than alcohol.
(02 marks)

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