Chemistry Worksheet 11

UDGAM SCIENCE ACADEMY
CHEMISTRY WORKSHEET
Class 11 - Chemistry
Section A
1. Number of significant figure in π . [1]
a) infinite b) 3
c) 1 d) 4
2. Which of the following quantities have no units? [1]
a) Relative atomic mass b) Weight
c) Molar mass d) Density
1
3. The density of 3M solution of NaCl is 1.25 g mL- . The molality of the [1]
solution is:
a) 1.79 m b) 0.79 m
c) 2.79 m d) 2.09 m
4. The molar mass of AgNO3 in g/mol is: [1]
a) 159.9 b) 169.9
c) 179.9 d) 189.9
(3+) (2+) + - (2-) (3-)

5. Al < Mg < Na < F < O <N [1]
The above can be aptly described as:
a) isoelectronic species. b) the same number of

electrons (9 electrons).
c) the same number of d) the same number of

electrons (7 electrons). electrons (8 electrons).
2+
6. Mg is isoelectronic with: [1]
2 2
a) Zn2+ b) Cu2+
c) Ca2+ d) Na+
7. 2 × 108 atoms of carbon are arranged side by side. Find the radius of [1]
carbon atom if the length of this arrangement is 2.4 cm.
a) 3.0 × 10-11 m b) 6.0 × 10-11 m
c) 1.2 × 10-11 m d) 5.7 × −11

10 m
8. Which of the following groups of elements have highly negative [1]

electron gain enthalpy?
a) Group-14 b) Group-17
c) Both Group-16 and 17 d) Group-16
9. According to Pauling, the atomic orbitals combine to form new set of [1]
equivalent atomic orbitals known as
a) pure orbitals b) Atomic orbitals
c) molecular orbitals d) hybrid orbitals
10. VSEPR theory helps in predicting the shape of [1]
a) ionic molecules b) covalent molecules
c) noble gases d) All of these
11. The sp3d2 hybridization of central atom of a molecule would lead to [1]
a) Trigonal bipyramidal b) Octahedral geometry

geometry
c) square planar geometry d) Tetrahedral geometry
12. N2, CO and NO+ are isoelectronic molecules. Their respective bond [1]
order is :
a) 3,3,3 b) 2,3,4
c) 1,1,3 d) 2,3,3
13. Which of the following, is correct when decrease in entropy has been [1]
taken place?
a) △
b) Temperature of a
2NaHCO3(s) −→
crystalline solid is raised
Na2CO3(s) + CO2(g) +
from 0 K to 115 K
H2O(g)
c) A liquid crystallises into a d) H2(g) → 2H(g)

solid
14. For the isothermal reversible free expansion of an ideal gas from Vi, [1]
the initial volume to Vf, the final volume of the work done on the gas
is:
a) w = −nRT ln b) w = −nT ln
Vf Vf
( ) ( )
Vi Vi
c) w = −RT ln d) w = −nRln
Vf Vf
( ) ( )
Vi Vi
15. For the reaction 2A(g) + B(g) → 2D(g) ΔU = - 10.5kJ and ΔS = -

0 0
[1]
-1
44.1J K . Calculate ΔG for the reaction, and predict whether the
0
reaction may occur spontaneously?
a) 0.165 kJ, the reaction is b) 0.225 kJ, the reaction is

not spontaneous spontaneous
c) 0.164 kJ, the reaction is d) 0.225 kJ, the reaction is

spontaneous not spontaneous
16. Thermodynamics is applicable to: [1]
a) homogeneous system b) microscopic system only

only
c) macroscopic system only. d) heterogeneous system

only
17. Consider the reactions given below. On the basis of these reactions [1]
find out which of the algebraic relations given in options (i) to (iv) is
correct?
A. C (g) + 4 H (g) → CH4 (g) ; Δ
r
H
= x kJ mol−1
B. C (graphite,s) + 2H2 (g) → CH4 (g) ; Δ

r
H
= y kJ mol−1
a) x = y b) x = 2y
c) x < y d) x > y
18. Assertion (A): Molecular mass of methane is 16.034u. [1]

Reason (R): Molecular mass of methane, which contains one carbon
atom and four hydrogen atoms.
a) Both A and R are true and b) Both A and R are true but
R is the correct R is not the correct
explanation of A. explanation of A.
c) A is true but R is false. d) A is false but R is true.
19. Assertion (A): A certain element X, forms three binary compounds [1]
with chlorine-containing 59.68%, 68.95% and 74.75% chlorine
respectively. These data illustrate the law of multiple proportions.
Reason (R): According to law of multiple proportions, the relative
amounts of an element combining with some fixed amount of a
second element in a series of compounds are the ratios of small
whole numbers.
20. Assertion (A): Equivalent weight of Cu in CuO is 63.6 and in Cu2O is [1]
31.8.
Atomic weight of the element
Reason (R): Equivalent weight of an element =
Valency of the element
21. Assertion (A): Isomorphous substances form crystals of the same [1]
shape and can grow in a saturated solution of each other.
Reason (R): They have a similar constitution and chemical formulae.
22. Assertion (A): Spin quantum number can have the value ±1
2
or −1
2
. [1]
Reason (R): (+) sign here signifies the wave function.
23. Assertion (A): VIBGYOR signifies the seven colour of visible light. [1]
Reason (R): Red colour corresponds to higher frequency and blue
colour to lower frequency region.
24. Assertion (A): Transition elements exhibit variable valency. [1]

Reason (R): Transition elements possess unpaired electrons.
25. Assertion (A): Among the Mg, Mg2+, Al, Al3+ the smallest radius is of [1]
Al3+.
Reason (R): Cations are larger than their parent atoms.
26. Assertion (A): Ionic compounds conduct electricity in solution as well [1]
as in molten form.
Reason (R): Ionic compounds are formed by sharing of electrons.
27. Assertion (A): The bond enthalpy in H—O—H is not the same for both [1]
the O−H bonds.
Reason (R): This is because the electronic environment around
oxygen is the same even after the breakage of one O-H bond.
28. Assertion (A): PCl5 molecule has trigonal bipyramidal structure. [1]
Reason (R): The hybridisation of PCl5 is sp3d.

29. Assertion (A): Octet theory cannot account for the shape of the [1]
molecule.
Reason (R): Octet theory can predict the relative stability and energy
of a molecule.
30. Assertion (A): Heat energy is completely transformed into work [1]
during the isothermal expansion of a gas.
Reason (R): During an isothermal process, the changes in the internal
energy of gas due to the decrease in pressure are nullified by the
changes due to the increase in volume.
31. Assertion (A): The dissolution of gases in water is always an [1]

endothermic process.
Reason (R): The dissolution of gases in water proceed with negative
value of ΔS .
32. Assertion (A): Enthalpy change for a reaction is same whether it [1]
occurs in one step or in a series of steps.
Reason (R): Enthalpy is state function as the change in enthalpy is
independent of the path between initial state and final state.
33. How do metals react in a group? [1]
34. Among alkali metals which element do you expect to be least [1]
electronegative and why?
35. What is the valency of noble gases? [1]
36. How many σ - and π - bonds are there in CH2 = CH-CH = CH2 ? [1]
37. HCl is a covalent compound but it ionises in solution. Explain. [1]
38. Define an ionic bonding. [1]
39. Two liters of an ideal gas at a pressure of 10 atm expands [1]

isothermally at 25 °C into a vacuum until its total volume is 10 liters.
How much heat is absorbed and how much work is done in the
expansion?
40. Consider the same expansion, to a final volume of 10 L conducted [1]

reversibly. In such condition how much heat is absorbed?
41. Define reaction enthalpy. [1]
42. Define enthalpy. [1]
Section B
43. Calculate molecular mass of – C2H6, C12H22O11, H2SO4, H3PO4 [2]
44. Calculate the number of carbon and oxygen atoms present in 11.2 [2]
litres of CO2 at N.T.P.
45. How many moles of CO2 will be obtained when 0.274 mole of [2]
C2H5OH is burnt?
46. Calculate the wavelength of the radiation which would cause [2]
photochemical dissociation of a chlorine molecule. The bond
dissociation energy Cl - Cl of bond is 245 kJ mol-1.
47. Calculate the uncertainty in the momentum of an electron, If it is [2]

confined to a linear region of length 1×10-10 m.
48. Would you expect the first ionization enthalpies of two isotopes of [2]
the same element to be the same or different?
49. What are inner transition metals? Why are they called rare earth [2]
metals?
50. Write the favorable factors for the formation of the ionic bond. [2]
51. Out of H and H2, the latter has higher first ionisation energy while out [2]
O and O2, the former has higher first ionisation energy. Explain why?
52. Why N2 is more stable than O 2 ? Explain on the basis of molecular [2]
orbital theory.
o [2]
53. i. 5.2 mol of ideal gas at 3 atm and 25 C expands isothermally to 3
times of its original volume against the external pressure of 1 atm.
Calculate work done.
ii. If the same gas expands isothermally in a reversible manner, then
what will be the value of work done?
-1
54. The reaction C (graphite) + O2 (g) →CO2(g) + 393.5 kJ mol [2]
represents the formation of CO2 and also combustion of carbon.
Write the ΔH values of the two processes.
o
55. What is the relation between the enthalpy of reaction and bond [2]
enthalpy?
Section C
56. A flask P contains 0.5 mole of oxygen gas. Another flask Q contains [3]
0.4 mole of ozone gas. Which of the two flasks contains greater
number of oxygen atoms?
57. Balance the following skeleton equation by the method of partial [3]
equations
KMnO4 + H2 SO4
+ (COOH)2 ⟶ K2 SO4
+ MnSO4 + CO2 + H2 O
58. Calculate the molecular mass of the following. [3]

i. H2O
ii. CO2
iii. CH4
o [3]
59. For H-atom the Bohr radius for the first orbit is 0.529 A and the radius
of maximum probability for H-atom according to wave mechanical
o
model is also 0.529 A. How do the two approaches differ?
60. Which of the following representation of electronic configuration is [3]

excluded by the Aufbau principle? Which by the Pauli exclusion
principle? Which by Hund's rule? Which is correct? Explain how a
principle or rule is violated in the others.
61. Consider the following species: [3]

N3-, O2-, F-, Na+, Mg2+ and Al3+
i. What is common in them?
ii. Arrange them in order of increasing radii.
62. Arrange the following as stated. [3]

i. Increasing order of bond dissociation energy of N2, O2, F2, Cl2.
ii. Decreasing order of electropositive character of Cu, Fe, Mg.
iii. Increasing order of valency of nitrogen in HNO3, HNO2, NO2.
63. Which out of NH3 and NF3 has a higher dipole moment and why? [3]
64. Explain the important aspect of resonance with reference to the [3]
CO
2−
3
ion.
65. 10 g of argon is compressed isothermally and reversibly at a [3]

temperature of 27 ∘
C form 10 L to 5 L. Calculate q, W, ΔU and ΔH for
this process R = 2.0 cal K −1
mol
−1
, log 2 . Atomic weight of Ar = 40.
= 0.30
66. i. What is a spontaneous process? Mention the conditions for a [3]
reaction to be spontaneous at constant temperature and pressure.
ii. Discuss the effect of temperature on the spontaneity of
anexothermic reaction.
Section D
67. Read the following text carefully and answer the questions that [4]
follow:
The amount of substance present in volume can be expressed by
Mass or weight per cent (w/w %), Mole fraction, Molarity, Molality. It is
the ratio of a number of moles of a particular component to the total
number of moles of the solution. Molality It is defined as the number
of moles of solute present in 1 kg of solvent. M NaOH means 1 mol of
NaOH present in 1 litre of the solution. For 0.2 M solution, we require
0.2 moles of NaOH dissolved in 1 litre solution. Hence, for making
0.2M solution from 1M solution, we have to take that volume of 1M
NaOH solution, which contains 0.2 mol of NaOH and dilute the
solution with water to 1 litre. one reactant is in more amount than the
amount required by a balanced chemical reaction. The reactant
which is present in the least amount gets consumed after some time
and after that further reaction does not take place whatever be the
amount of the other reactant. Hence, the reactant, which gets
consumed first, limits the amount of product formed and is,
therefore, called the limiting reagent.
i. What is the concentration of nitrate ions if equal volumes of 0.1M
AgNO3 and 0.1M NaCl are mixed together?
ii. What is the normality of a 1M solution of H3PO4?
iii. Does 20 g NaOH in 200 mL of solution and 0.5 mol of KCl in 200
mL have the same concentration?
OR
Write is the difference between molality and molarity.
follow:
The molecular orbital theory is based on the principle of a linear
combination of atomic orbitals. According to this approach when
atomic orbitals of the atoms come closer, they undergo constructive
interference as well as destructive interference giving molecular
orbitals, i.e., two atomic orbitals overlap to form two molecular
orbitals, one of which lies at a lower energy level (bonding molecular
orbital). Each molecular orbital can hold one or two electrons in
accordance with Pauli's exclusion principle and Hund's rule of
maximum multiplicity. For molecules up to N2, the order of filling of
orbitals is:
∗ ∗
∗ ∗ ∗
σ(1s)σ (1s), σ(2s)σ (2s), = π (2py ) , σ (2pz ) ,π (2px )=π (2py ) , σ (2pz )
π (2px )
and for molecules after N2, the order of filling is:

∗ ∗
∗ ∗ ∗
σ(1s)σ (1s), σ(2s)σ (2s), = π (2py ) ,π (2px ) =π (2py ) , σ (2pz )
σ (2pz ) , π (2px )
Bond order = [bonding electrons - antibonding electrons]

1
Bond order gives the following information:

I. If bond order is greater than zero, the molecule/ion exists
otherwise not.
II. Higher the bond order, higher is the bond dissociation energy.
III. Higher the bond order, greater is the bond stability.
IV. Higher the bond order, shorter is the bond length.
i. Arrange the following negative stabilities of CN, CN+ and CN- in
increasing order of bond. (1)
ii. The molecular orbital theory is preferred over valence bond theory.
Why? (1)
iii. Ethyne is acidic in nature in comparison to ethene and ethane.
Why is it so? (2)
OR
Bonding molecular orbital is lowered by a greater amount of
energy than the amount by which antibonding molecular orbital is
raised. Is this statement correct? (2)
follow:
The enthalpy change occurring during a reaction when all the
involved substances are in their standard states, is called the
standard enthalpy of the reaction.
The purest and most stable form of a substance at 1 bar and at a
specified temperature is called its standard state. e.g. The standard
state of solid iron at 500 K is pure iron at 1 bar. The standard
enthalpy change is represented by writing the superscript ⊖ to the
symbol ΔH , i.e. by ΔH .⊖
i. If total enthalpy of reactants and products is HR and HP

respectively, then what is the relation between HR and HP for
exothermic reaction? (1)
ii. Why is the standard enthalpy of formation of diamond not zero
although it is an element? (1)
iii. The standard heat of formation at 298 K for CCl4(g), H2O(g),
CO2(g) and HCl (g) are -25.5, -57.8, -94.1 and -22.1 kcal mol-1
respectively. Calculate ∆rHΘfor the reaction. (2)
CCl4(g) + 2H2O(g) ⟶ CO2(g) + 4HCl(g)
OR
Calculate the enthalpy change for the following reaction. (2)
CH4(g) + 2O2(g) ⟶ CO2(g) + 2H2O(l)
given enthalpies of formation of CH4, CO2 and H2O are -74.8 kJ
mol-1, -393.5 kJ mol-1 and -286.2 kJ mol-1 respectively.
Section E
70. 50.0 kg of N2 (g) and 10.0 kg of H2 (g) are mixed to produce NH3 [5]
(g). Calculate the amount of NH3 (g) formed. Identify the limiting
reagent in the production of NH3 in this situation.
71. In a reaction [5]

A + B2 ⟶ AB2
Identify the limiting reagent if any in the, following reaction mixtures:
i. 300 atoms of A + 200 molecules of B
ii. 2 mol of A + 3 mol of B
iii. 100 atoms of A + 100 molecules of B
iv. 5 mol of A + 2.5 mol of B
v. 2.5 mol of A + 5 mol of B
72. A neutral atom of an element has 2K, 8L and 5M electrons. Find out [5]
the following.
i. Atomic number of the element
ii. Total number of s-electrons
iii. Total number of p-electrons
iv. Number of protons in the nucleus
v. Valency of the element
73. What do you understand by isoelectronic species? Name a species [5]

that will be isoelectronic with each of the following atoms or ions.
i. F–
ii. Ar
iii. Mg2+
iv. Rb+
74. The energy of σ 2pz molecular orbital is greater than π 2px and π 2py [5]
molecular orbitals in nitrogen molecule. Write the complete sequence
of energy levels in the increasing order of energy in the molecule.
Compare the relative stability and the magnetic behaviour of the
following species: N2, N , N , N
+
2
−
2
2+
2
75. The figure given below represents pV diagram of different stages of [5]
a thermodynamic process. Calculate the work done in each stage and
also the net work done in the complete cyclic process.

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UDGAM SCIENCE ACADEMY

2. Which of the following quantities have no units? [1]

a) Relative atomic mass b) Weight

c) Molar mass d) Density

4. The molar mass of AgNO3 in g/mol is: [1]

(3+) (2+) + - (2-) (3-)

a) isoelectronic species. b) the same number of

c) the same number of d) the same number of

a) 3.0 × 10-11 m b) 6.0 × 10-11 m

c) 1.2 × 10-11 m d) 5.7 × −11

8. Which of the following groups of elements have highly negative [1]

c) Both Group-16 and 17 d) Group-16

a) pure orbitals b) Atomic orbitals

c) molecular orbitals d) hybrid orbitals

10. VSEPR theory helps in predicting the shape of [1]

a) ionic molecules b) covalent molecules

c) noble gases d) All of these

a) Trigonal bipyramidal b) Octahedral geometry

c) square planar geometry d) Tetrahedral geometry

c) A liquid crystallises into a d) H2(g) → 2H(g)

15. For the reaction 2A(g) + B(g) → 2D(g) ΔU = - 10.5kJ and ΔS = -

reaction may occur spontaneously?

a) 0.165 kJ, the reaction is b) 0.225 kJ, the reaction is

c) 0.164 kJ, the reaction is d) 0.225 kJ, the reaction is

16. Thermodynamics is applicable to: [1]

a) homogeneous system b) microscopic system only

c) macroscopic system only. d) heterogeneous system

B. C (graphite,s) + 2H2 (g) → CH4 (g) ; Δ

18. Assertion (A): Molecular mass of methane is 16.034u. [1]

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

24. Assertion (A): Transition elements exhibit variable valency. [1]

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

31. Assertion (A): The dissolution of gases in water is always an [1]

c) A is true but R is false. d) A is false but R is true.

c) A is true but R is false. d) A is false but R is true.

33. How do metals react in a group? [1]

35. What is the valency of noble gases? [1]

37. HCl is a covalent compound but it ionises in solution. Explain. [1]

38. Define an ionic bonding. [1]

39. Two liters of an ideal gas at a pressure of 10 atm expands [1]

40. Consider the same expansion, to a final volume of 10 L conducted [1]

41. Define reaction enthalpy. [1]

42. Define enthalpy. [1]

47. Calculate the uncertainty in the momentum of an electron, If it is [2]

58. Calculate the molecular mass of the following. [3]

60. Which of the following representation of electronic configuration is [3]

61. Consider the following species: [3]

62. Arrange the following as stated. [3]

65. 10 g of argon is compressed isothermally and reversibly at a [3]