DPP

For
Solutions
12th JEE
1
The relative lowering of vapour pressure of an
aqueous solution containing a non-volatile solute is
0.0125. The molality of the solution is

A 0.69 m

B 0.50 m

C 0.80 m

D 0.40 m
2 12 g of a non-volatile solute dissolved in 108g of
water produces the relative lowering of vapour
pressure of 0.1. The molecular mass of the solute
(in g mol− 1) is

A 80

B 60

C 20

D 40
3 For a dilute solution containing 2.5 g of non-volatile,
non-electrolyte solute in 100 g of water, the elevation in
boiling point at 1 atm pressure is 2°C. Assuming
concentration of solute is much lower than the
concentration of solvent, the vapour pressure of solution
is (Kb) = − 0.76 K kg mol -1

A 724

B 740

C 736

D 718
4 An aqueous solution freezes at − 0.186° C
(Kf = 1.86 K kg mol-1 ,
Kb = − 0.512 K kg mol-1). What is the elevation in
boiling point?

A 0.186oC

B 0.512oC

C 0.86oC

D 0.0512oC
5
The depression in freezing point of 0.01 M
aqueous solution of urea, sodium chloride and
sodium sulphate is in the ratio of

A 1:1:1

B 1:2:3

C 1:2:4

D 2:2:3
6 When 20 g of naphthoic acid (C11H8O2) is dissolved
in 50 g of benzene (Kf = 1.72K kg mol-1), a freezing
point depression of 2 K is observed. The van't Hoff
factor (i ) is

A 0.5

B 1

C 2

D 3
7

A compound X undergoes tetramerisation in a

given organic solvent. The van't Hoff factor is

A 4.0

B 0.25

C 0.125

D 2.0
8
Which one of the following 0.10 M aqueous
solutions will exhibit the largest freezing point
depression?

A glycine

B KHSO4

C hydrazine

D glucose
9
The degree of dissociation (α) of a weak
electrolyte, AxBy is related to van’t Hoff factor (i by
the expression

D
10 In a 0.2 molal aqueous solution of a weak acid HX,
the degree of ionisation is 0.3. Taking Kf for water
as 1.85 K kg mol−1 , the freezing point of the
solution will be nearest to

A − 0.360° C

B − 0.260° C

C + 0.480° C

D -0.418° C
11
The freezing point (in °C) of a solution containing
0.1 g of K3[Fe(CN)6] (mol. wt. 329 gmol−1) in 100 g
of water (Kf = − 1.86 K kg mol-1) is

A -2.3 x 10-2

B -5.7 x 10-2

C -5.7 x 10-3

D -1.2 x 10-2
12 20% of acetic acid is dissociated when its 5 g is
added to 500 mL of water. The depression in
freezing point of such water is _____ × 10-3o.
Atomic mass of C, H and O are 12, 1 and 16
a.m.u. Respectively.
[Given : Molal depression constant and density of
water are 1.86 K kg mol-1 and 1 g cm-3
respectively.]

JEE Main 2023

13 At 27oC, a solution containing 2.5 g of solute in
250.0 mL of solution exerts an osmotic pressure of
400 Pa. The molar mass of the solution is _____ g
mol-1 . (Given : R = 0.083 L bar K-1 mol-1)

JEE Main 2023

14 Lead storage battery contains 38% by weight
solution of H2SO4. The van’t Hoff factor is 2.67 at
this concentration. The temperature in Kelvin at
which the solution in the battery will freeze is
_____. Given Kf = 1.8 K kg mol-1

JEE Main 2023

15 Sea water contains 29.25% NaCl and 19% MgCl2
by weight of solution. The normal boiling point of
the sea water is ____oC
Assume 100% ionization for both NaCl and MgCl2
Given Kb(H2O) = 0.52 K kg mol-1
Molar mass of NaCl and MgCl2 is 58.5 and 95 g
mol-1 respectively.

JEE Main 2023

16
Which one of the following 0.10 M aqueous
solutions will exhibit the largest freezing point
depression?

JEE Main 2021

A Hydrazine

B Glucose

C Glycine

D KHSO4
17 Boiling point of a 2% aqueous solution of a
non-volatile solute A is equal to the boiling point of
8% aqueous solution of a non-volatile solute B. The
relation between molecular weights of A and B is

JEE Main 2022

A MA = 4MB

B MB = 4MA

C MA = 8MB

D MB = 8MA
18 A solution containing 2 g of a non-volatile solute in
20 g of water boils at 373.52 K. The molecular
mass of the solute is _____ g mol-1.
Given, water boils at 373 K, Kb for water = 0.52 K
kg mol-1.
JEE Main 2023
19 80 mole percent of MgCl2 is dissociated in
aqueous solution. The vapour pressure of 1.0
molal aqueous solution of MgCl2 at 38oC is _____
mm Hg. Given : Vapour pressure of water at 38oC
is 50 mm Hg
JEE Main 2023
20
0.004 M K2SO4 solution is isotonic with 0.01 M
glucose solution, percentage dissociation of K2SO4
is _____ .

JEE Main 2023

Answer Key Ques. No. Answer Ques. No. Answer
1 A 11 A

2 C 12 372

3 A 13 62250

4 D 14 243

5 B 15 116

6 A 16 D

7 B 17 B

8 B 18 100g

9 B 19 48

10 D 20 75
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Solution:
● Concentrations of particles of 0.01 M urea, NaCl
and Na2SO4 are 0.01 M, 0.02 M, 0.03 M
respectively.
● They are in the ratio of 1:2:3.
● Hence, depression in freezing point will be in the
same ratio.
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