45℃

時間,t/min 滴定量,Vi/ml 濃度Ci, Ai(C∞-Ci) lnAi 1/Ai

0 17.8 0.376648 0.2365688 -1.441516 4.2271
3 18.42 0.3897672 0.2234496 -1.498569 4.475282
7 19.39 0.4102924 0.2029244 -1.594922 4.927944
10 19.95 0.422142 0.1910748 -1.65509 5.233553
15 20.52 0.4342032 0.1790136 -1.720293 5.586168
30 22.34 0.4727144 0.1405024 -1.962531 7.117316
45 23.75 0.50255 0.1106668 -2.201231 9.036134
60 24.9 0.526884 0.0863328 -2.449546 11.58308
∞ 28.98 0.6132168 0

Factor→ 1.058

t-Ci(45)
0.6

0.5 f(x) = 0.00244637017144591 x + 0.389914783856774

R² = 0.972779945695493
0.4

0.3

0.2

0.1

0
0 10 20 30 40 50 60 70

t-Ci(25)
0.7
0.6
f(x) = 0.00152592140798058 x + 0.511915170080413
0.5 R² = 0.599327520354803

0.4
0.3
0.2
0.1
0
0 10 20 30 40 50 60 70
 25℃
時間,t/min 滴定量,Vi/ml 濃度Ci, Ai(C∞-Ci) lnAi 1/Ai
0 22.9 0.484564 0.29624 -1.216585 3.375641
3 22.4 0.473984 0.30682 -1.181494 3.25924
7 25.6 0.541696 0.239108 -1.43084 4.182211
10 26.8 0.567088 0.213716 -1.543107 4.679107
15 26.2 0.554392 0.226412 -1.485399 4.416727
30 26.7 0.564972 0.215832 -1.533255 4.633233
45 27.3 0.577668 0.203136 -1.59388 4.92281
60 27.9 0.590364 0.19044 -1.658418 5.250998
∞ 36.9 0.780804 0

Factor→ 1.058

t-ln[A](45)
0
0 10 20 30 40 50 60 70
-0.5

-1
Axis Title

-1.5
f(x) = − 0.0164742643202094 x − 1.4653842544465
-2 R² = 0.998017610058456

-2.5

-3
Axis Title

t-ln[A](25)
0
0 10 20 30 40 50 60 70
-0.2
-0.4
-0.6
-0.8
-1
-1.2
-1.4 f(x) = − 0.00639855813601241 x − 1.31940290332985
-1.6 R² = 0.649582832015305

-1.8
 25℃改
時間,t/min 滴定量,Vi/ml 濃度Ci, Ai(C∞-Ci) lnAi 1/Ai
0 22.9 0.484564 0.29624 -1.21658534 3.375641 0
0 10
-0.2

7 25.6 0.541696 0.239108 -1.43083995 4.182211 -0.4

-0.6

15 26.2 0.554392 0.226412 -1.48539893 4.416727 -0.8

30 26.7 0.564972 0.215832 -1.53325495 4.633233 -1

45 27.3 0.577668 0.203136 -1.59387957 4.92281 -1.2

60 27.9 0.590364 0.19044 -1.65841809 5.250998 -1.4 f(x) = − 0.00600

R² = 0.81400395
∞ 36.9 0.780804 0 -1.6

-1.8
1.058

t-1/A(45)
6
14
5 f(x) = 0.02613464
12 R² = 0.865022384
10 f(x) = 0.118408489266285 x + 4.00714198849309 4
R² = 0.986810933904392
8 3

6 2
4
1
2
0
0 0 10
0 10 20 30 40 50 60 70

t-1/A(25)
6 0.7
5 f(x) = 0.0272733097842578 x + 3.76043804533697 0.6
R² = 0.700496733887672 f(x) = 0.001399
0.5 R² = 0.7577085
4
0.4
3 0.3
0.2
2
0.1
1 0
0 10
0
0 10 20 30 40 50 60 70
 １次 temp/℃ temp/K
t-ln[A](25) 改 25℃ 298.15
0 45℃ 318.15
0 10 20 30 40 50 60 70
-0.2

-0.4

-0.6 ２次 temp/℃ temp/K

-0.8 25℃ 298.15
-1 45℃ 318.15
-1.2

-1.4 f(x) = − 0.00600556878241437 x − 1.32925042336859

-1.6
R² = 0.814003956315694 1次
0
-1.8 0.0031 0.00315 0.0032 0.00325
-0.5
-1
t-1/[A](25) 改 -1.5
6 -2

5 f(x) = 0.0261346450379516 x + 3.77974682628872 -2.5

R² = 0.865022384056438
4 -3
-3.5 f(x) = − 1849.88226393135 x + 2.6
3 R² = 1
-4
2

1 15375.91

0
0 10 20 30 40 50 60 70
2次
0
0.0031 0.00315 0.0032 0.00325
t-Ci(25) 改 -1
0.7 -2
0.6
f(x) = 0.00139974481263549 x + 0.515649344069372 -3
0.5 R² = 0.757708555788456
0.4 -4
0.3 f(x) = − 4797.84217397795 x + 10.9
-5 R² = 1
0.2
0.1 -6
0
0 10 20 30 40 50 60 70
39888.91
t-Ci(25) 改 Linear (t-Ci(25) 改 )
 1/T k lnk
0.003354 0.02764 -3.58848
0.003143 0.040826 -3.198442

1/T k lnk
0.003354 0.006 -5.115996
0.003143 0.0165 -4.104395

1次
15 0.0032 0.00325 0.0033 0.00335 0.0034

x) = − 1849.88226393135 x + 2.61605514621919
²=1

31195.79

2次
5 0.0032 0.00325 0.0033 0.00335 0.0034

= − 4797.84217397795 x + 10.9760456927713
=1