This Safety Data Sheet (SDS) has been prepared in accordance with the requirements of the OSHA Hazard

Communication
Standard (CFR 29 1910.1200).

SAFETY DATA SHEET United States

Zivion™ M

Section 1. Identification
GHS product identifier : Zivion™ M
Chemical name : Antimycotic preparation. ( aqueous suspensions )
Other means of : Not available.
identification
Product type : Liquid.
Material uses : This product is used as an antimycotic (bio)pesticide formulation
Supplier : DSM Food Specialties B.V.
P.O. Box 1
2600 MA Delft
The Netherlands
Phone: +31 (0) 15 279 4001
Telefax: +31 (0) 15 279 4020
e-mail address of person : [email protected]
responsible for this SDS
Emergency telephone : +31 (0)15 2792380
number

Section 2. Hazards identification

OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe
handling and proper use of the product. This SDS should be retained and available for
employees and other users of this product.
Classification of the : Not classified.
substance or mixture

GHS label elements

Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : Not applicable.
Hazards not otherwise : None known.
classified
Hazardous Material Health 0
Information System (U.S.A.)
Flammability 0
Physical hazards 0
PERSONAL PROTECTION

The PPE (Personal Protection Equipment) designation in the HMIS is provided for use by
employees at supplier sites only. Other users of this product are encouraged to evaluate
the hazards of the product and assign PPE that is applicable to their specific situations.
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200,
the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program.
HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be
purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.

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Safety Data Sheet Zivion™ M

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Chemical name : Antimycotic preparation. ( aqueous suspensions )
Other means of identification : Not available.
No. No. No.
CAS number : Not applicable.

There are no ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Get medical attention if irritation occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur. In case of inhalation of decomposition products in a
fire, symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Get medical attention if symptoms occur.
Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless directed
to do so by medical personnel. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be
delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

See toxicological information (Section 11)

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Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
halogenated compounds
metal oxide/oxides
Nitro dye.

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if there
for fire-fighters is a fire. No action shall be taken involving any personal risk or without suitable training.
Special protective equipment : Fire-fighters should wear appropriate protective equipment and self-contained breathing
for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training. Evacuate
personnel surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not
touch or walk through spilled material. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if
water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water
courses, basements or confined areas. Wash spillages into an effluent treatment plant or
proceed as follows. Contain and collect spillage with non-combustible, absorbent material
e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Note: see Section 1 for emergency contact information and Section 13 for
waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas.

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Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is handled,
occupational hygiene stored and processed. Workers should wash hands and face before eating, drinking and
smoking. Remove contaminated clothing and protective equipment before entering eating
areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, : Store between the following temperatures: 5 to 25°C (41 to 77°F). Store in accordance
including any with local regulations. Store in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10). Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination. Store in original container, protected from direct sunlight.
Keep in a cool place.
Packaging materials
Suitable : Polyethylene. Polypropylene. Stainless steel .

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
None.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure they
controls comply with the requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will be necessary
to reduce emissions to acceptable levels.

Individual protection measures No.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases
or dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: safety glasses with side-shields.
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. 4 - 8 hours (breakthrough time): Rubber ; Replace damaged gloves.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a respiratory
protection program to ensure proper fitting, training, and other important aspects of use.
Remarks : In case of insufficient ventilation, wear suitable respiratory equipment.

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Section 9. Physical and chemical properties

Appearance
Physical state : Liquid. [suspension]
Color : White to off-white. Depending on type.
Odor : Practically odourless
Odor threshold : Not available.
pH : 4 to 5 (Concentration 100%)
Melting point : Not available.
Boiling point : Not available.
Flash point : [Product does not sustain combustion.]
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : Not available.
Density (g/cm³) : Not available.
Bulk density : Not available.
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not applicable.
Decomposition temperature : Not available.
Viscosity : Dynamic (room temperature): 600 to 1300 mPa·s (600 to 1300 cP)
Remarks : More detailed information on the physical and chemical properties can be requested from
the supplier.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Temperatures below : 0 °C

Incompatible materials : No specific data.

Hazardous decomposition : Carbon oxides (CO, CO2)

products

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Zivion™ M LD50 Oral Rat >27300 mg/kg -

Irritation/Corrosion

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Safety Data Sheet Zivion™ M

Not available.

Conclusion/Summary
Skin : Prolonged or repeated skin contact may be irritating.
Eyes : May cause eye irritation.
Sensitization
Not available.

Mutagenicity
Not available.

Carcinogenicity
Not available.

Reproductive toxicity
Not available.

Teratogenicity
Not available.

Specific target organ toxicity (single exposure)

Not available.

Specific target organ toxicity (repeated exposure)

Not available.

Aspiration hazard
Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be
delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : Not available.
Potential delayed effects : Not available.
Long term exposure
Potential immediate effects : Not available.
Potential delayed effects : Not available.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.

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Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Zivion™ M Acute LC50 >100 mg/l Fish 96 hours

Persistence and degradability

Not available.

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Zivion™ M - - Readily

Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Waste should not be disposed of untreated to the
sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste
packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible. This material and its container must be disposed of in a safe way.
Empty containers or liners may retain some product residues. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.
Remarks : Incinerate in a licensed, high-temperature, hazardous-waste incinerator.

Section 14. Transport information

DOT TDG Mexico ADR/RID IMDG IATA
Classification Classification Classification
UN number Not regulated. Not regulated. Not regulated. Not regulated. Not regulated. Not regulated.

UN proper - - - - - -
shipping name

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Transport - - - - - -
hazard class(es)

Packing group - - - - - -
Environmental No. No. No. No. No. No.
hazards
Additional - - - - - -
information

Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright
and secure. Ensure that persons transporting the product know what to do in the event of
an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL and
the IBC Code

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.

Product/ingredient name CAS # %

Clean Air Act Section 112(b) Not listed.
Hazardous Air Pollutants
(HAPs)

Clean Air Act Section 602 : Not listed

Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
No products were found.
SARA 304 RQ : Not applicable.
Form R - Reporting
requirements
Supplier notification
State regulations
Massachusetts : None of the components are listed.
New York : None of the components are listed.
New Jersey : None of the components are listed.
Pennsylvania : None of the components are listed.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Ingredient name List name Status
Not listed.

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Montreal Protocol (Annexes A, B, C, E)

Not listed.
Stockholm Convention on Persistent Organic Pollutants
Ingredient name List name Status
Not listed.

Rotterdam Convention on Prior Inform Consent (PIC)

Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Ingredient name List name Status
Not listed.

International lists
Canada inventory : Not determined.

Section 16. Other information

National Fire Protection Association (U.S.A.)

0 Flammability
Health 0 0 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response
Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete
and official position of the National Fire Protection Association, on the referenced subject which is represented only
by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49
and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.

History No.
Code : WW49483
Date of printing : 5/1/2017
Date of issue/Date of : 5/1/2017
revision
Date of previous issue : 5/22/2015
Version : 2
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Procedure used to derive the classification
Classification Justification
Not classified.
References : Not available.
Indicates information that has changed from previously issued version.

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Notice to reader
The information contained in the Material Safety Data Sheet is based on our data available on the date of publication. The
information is intended to aid the user in controlling the handling risks; it is not to be construed as a warranty or specification of
the product quality. The information may not be or may not altogether be applicable to combinations of the product with other
substances or to particular applications.
The user is responsible for ensuring that appropriate precautions are taken and for satisfying themselves that the data are
suitable and sufficient for the product's intended purpose. In case of any unclarity we advise consulting the supplier or an expert.

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