JEE Main Question Paper (29-09)

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JEE MAIN PAPER

CLASS 12th IIT SCHOOL VIJETA BATCH

Time : 3 Hours Maximum Marks : 180


PART – 1 : MATHEMATICS
• This question paper contains two sections, section A & B.
• Section A contains 20 multiple choice questions (SCQs) with four options (A),(B),(C),(D) out
of which only one option is correct.
• Section B contains 10 Integer Type questions, out of which candidate have to attempt only 5
questions.

Section-I
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

x2 dx B
1. ∫ = A(a + bx) − a+bx + Cln⁡ |a + bx| + D, then A + B + C =
(a+bx)2

1+2a−a2
(A) b3

(1−a)2
(B) 3

1−2a+a2
(C) b3

(1+a)2
(D) b3
xx x xx
2. ∫ 22 ⋅ 22 ⋅ 2x dx = A ⋅ 22 + c, where A =
(A) 1
(B) (ln⁡ 2)
(C) (ln⁡ 2)2
(D) (ln⁡ 2)−3
x+sin⁡ x
3. ∫ dx =
1+cos⁡ x
x x
(A) xsin⁡ 2 + c (B) xcos⁡ 2 + c
x x
(C) xtan⁡ + c (D) xcot⁡ + c
2 2

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dx
4. ∫ =
cos3 ⁡ x√2sin⁡ 2x
3
(tan⁡ x)2
(A) √tan⁡ x − +c
3
3
(tan⁡ x)2
(B) √tan⁡ x + +c
3
5
(tan⁡ x)2
(C) √tan⁡ x − +c
5
5
(tan⁡ x)2
(D) √tan⁡ x + +c
5
(x−1)dx
5. ∫ =
(x+1)√x+x2 +x3

1
(A) tan−1 ⁡ √(x + x) + c

1
(B) 2tan−1 ⁡ √(x + x − 1) + c

1
(C) 2tan−1 ⁡ √x + x + 1 + c

1
(D) tan−1 ⁡ √x + x + 1 + c
xcos⁡ x+1
6. ∫⁡√ dx =
2x3 esin⁡ x +x2

(A) ln⁡(2xesin⁡ x + 1) + c
(B) ln⁡(2xesin⁡ x − 1) + c
2xesin⁡ x +1
(C) ln⁡ (2xesin⁡ x −1) + c

√2xesin⁡ x +1−1
(D) ln⁡ ( )+c
√2xesin⁡ x +1+1

7. ∫ tan⁡ xtan⁡ 2xtan⁡ 3xdx =


cos⁡ x√cos⁡ 2x
(A) ln⁡ ( 3 )+c
√cos⁡ 3x
3
√cos⁡ 3x
(B) ln⁡ (cos⁡ x√cos⁡ 2x) + c

sin⁡ x√sin⁡ x2x


(C) ln⁡ ( 3 )+c
√sin⁡ 3x
3
√sin⁡ 3x
(D) ln⁡ (sin⁡ x√sin⁡ x2x) + c
cos⁡ 9x+cos⁡ 6x
8. If ∫ dx = Asin⁡ 4x + Bsin⁡ x + c, then A + B =
2cos⁡ 5x−1
1 3
(A) 2 (B) 4
5 7
(C) 4 (D) 4

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2 a 0
9. Let A = [1 3 1]. If A3 = 4A2 − A − 21I, where I is the identity matrix of order 3 × 3, then
0 5 b
2a + 3b is equal to
(A) −10
(B) −12
(C) −13
(D) −9
10. If A is a square matrix of order 3 such that det⁡(A) = 3 and

det⁡ (adj⁡ (−4adj⁡ (−3adj⁡(3adj⁡((2 A)−1 ))))) = , then m + 2n is equal to :

(A) 2
(B) 4
(C) 3
(D) 6
n2
r 1 +α
2
11. For α, β ∈ R and a natural number n, let Ar = || 2r 2 n − β || . Then 2A10 − A8 is
2
n(3n−1)
3r − 2 3 2

(A) 4α + 2β (B) 0
(C) 2n (D) 2α + 4β

12. If the system of equations


11x + y + λz = −5
2x + 3y + 5z = 3
8x − 19y − 39z = μ
has infinitely many solutions, then λ4 − μ is equal to :
(A) 51

(B) 45

(C) 47
(D) 49

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1 2
13. Let A = [ ] and B = I + adj⁡(A) + (adj⁡ A)2 + ⋯ + (adj⁡ A)10 . Then, the sum of all the
0 1
elements of the matrix B is:
(A) −110

(B) 22

(C) −124

(D) −88
14. If the system of equations
x + (√2sin⁡ α)y + (√2cos⁡ α)z = 0
x + (cos⁡ α)y + (sin⁡ α)z = 0
x + (sin⁡ α)y − (cos⁡ α)z = 0
π
has a non-trivial solution, then α ∈ (0, 2 ) is equal to :

(A) 24

11π
(B) 24


(C) 24


(D) 4

1 0 0
15. Let A = [0 α β] and |2 A|3 = 221 where α, β ∈ Z, then a value of α is.
0 β α
(A) 9
(B) 17

(C) 3

(D) 5
1
16. Let A be a square matrix such that AAT = I. Then 2 A[(A + AT )2 + (A − AT )2 ] is equal to

(A) A2 + AT (B) A3 + I

(C) A3 + AT (D) A2 + I

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3 3
1 α+2
2
17. The values of α, for which | 1
1
α + | = 0, lie in the interval
1
3 3
2α + 3 3α + 1 0
(A) (−2,1)

3 3
(B) (− 2 , 2)

(C) (−3,0)

(D) (0,3)
18. The number of symmetric matrices of order 3 , with all the entries from the set
{0,1,2,3,4,5,6,7,8,9} is :
(A) 109

(B) 910

(C) 106

(D) 610
1
1 1 2 −1 −2
19. Let A = [ If B = [
51]. ]A[ ], then the sum of all the elements of the matrix
0 1 −1 −1 1 1

n=1 B is equal to
∑50 n

(A) 50
(B) 75

(C) 100
(D) 125
π cos⁡ θ sin⁡ θ
20. Let θ = 5 and A = [ ]. If B = A + A4 , then det⁡(B) :
−sin⁡ θ cos⁡ θ
(A) is one
(B) lies in (1, 2)
(C) lies in (2,3)
(D) is zero

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Section-II
• This Section contain 10 questions (Q.No. 21 to Q.No. 30) whose answer to be filled as
numerical value (Attempt any five)
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

2x+2 2x+2
21. If ∫ sin−1 ⁡ √4x2 dx = (Ax + B)tan−1 ⁡ ( ) + Cln⁡(4x 2 + 8x + 13) + D, then
+8x+13 3

4(A + B + C) =
−5 −4 −6
22. If ∫ (x + √x 2 + 1) dx = A(x + √x 2 + 1) + B(x + √x 2 + 1) + c then |24(A + B)| =
tan⁡ x−1 tan⁡ x+1+√2tan⁡ x
23. If ∫ √tan⁡ xdx = atan−1 ⁡ ( ) + b⁡ln⁡ (tan⁡ x+1−√2tan⁡ x) + c, then 4√2(a + b) =
√2tan⁡ x
2
(2x−3)3 2x−3 b
24. If ∫ 8 dx = a (4x+5) + c then 66ab =
(4x+5)3

1 1 2
|adjB|
25. If the matrices A = [1 3 4] , B = adj⁡ A and C = 3A, then |C| is equal to:
1 −1 3
x+a x+2 x+1
26. If f(x) = |x + b x + 3 x + 2|, then:
x+c x+4 x+3
a b c
27. Let a, b, c ∈ R be all non-zero and satisfy a3 + b3 + c 3 = 2. If the matrix A = [b c a ] satisfies
c a b
AT A = I, then a value of abc can be :
x − 2 2x − 3 3x − 4
28. If Δ = |2x − 3 3x − 4 4x − 5 | = Ax 3 + Bx 2 + Cx + D, then B + C is equal to:
3x − 5 5x − 8 10x − 17
29. The number of values of α for which the system of equations:
x+y+z= α
αx + 2αy + 3z = −1
x + 3αy + 5z = 4
is inconsistent, is

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30. Let S = {√n: 1 ⩽ n ⩽ 50 and n is odd }


1 0 a
Let a ∈ S and A = [−1 1 0]
−a 0 1
If ∑a∈S det⁡(adj⁡ A) = 100λ, then λ is equal to

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PART – 2 : PHYSICS

• This question paper contains two sections, section A & B.


• Section A contains 20 multiple choice questions (SCQs) with four options (A),(B),(C),(D) out
of which only one option is correct.
• Section B contains 10 Integer Type questions, out of which candidate have to attempt only 5
questions.

Section-I
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

31. A small square loop of wire of side ℓ is placed inside a large square loop of side L(L >> ℓ). If
the loops are coplanar and their centres coincide, the mutual induction of the system is directly
proportional to
L ℓ
(A) ℓ (B) L
L2 ℓ2
(C) (D)
ℓ L

32. A straight conductor of mass m carrying a current i is hinged at one end and placed in a plane
perpendicular to the magnetic field of intensity as shown in the figure. At any moment if the
conductor is let free then the angular acceleration of the conductor will be (neglect gravity)

2Bi
(A) 3m
3Bi
(B) 2m
Bi
(C) 2m
3i
(D) 3mB

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33. A thin flexible wire of length ‘L’ is connected to two adjacent fixed points and carries a current
‘I’ in the clockwise direction as shown. When the system is put in a uniform magnetic field of
strength ‘B’ going into the plane of the paper, the wire takes the shape of a circle. The tension in
the wire, after acquiring the circular shape is

(A) IBL
IBL
(B) π
IBL
(C) 2π
IBL
(D) 4π

34. Let B and  denote induction to magnetic field and energy density at midpoint of a long
solenoid carrying a current i. The graph between  and B will be

(A) (B)

(C) (D)

35. The relation between the charge flow ΔQ through the circuit of resistance r and the change in
the magnetic flux ΔϕB is
ΔϕB
(A) ΔQ = r
ΔQ
(B) ΔϕB = r

(C) ΔϕB = ΔQ
ΔQ
(D) ΔϕB = r2

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36. A and B are two concentric hollow spheres. If A is given a charge Q while B is earthed as shown
in figure.

(A) A and B both will have the same charge densities


(B) the potential inside A and outside B will zero
(C) the electric field between A and B is non zero
(D) the electric field inside A and outside B is non zero.
37. Two positive point charges each of magnitude 10C are fixed at positions A⁡&⁡B at a separation
2d = 6 m. A negatively charged particle of mass m = 90gm⁡& charge of magnitude 10 × 10−6 C
is revolving in a circular path of radius 4 m in the plane perpendicular to the line AB and
bisecting the line AB. Neglect the effect of gravity. If the angular velocity of the particle is ω.
Then the value of ω (in rad/sec) is:

(A) 100 (B) 200 (C) 300 (D) 400


38. The electric potential decreases uniformly from 180 V to 20 V as one moves on the X-axis from
x = −2 cm to x = +2 cm. The electric field at the origin:
(A) must be equal to 40 V/cm.
(B) may be equal to 40 V/cm.
(C) may be less than 30 V/cm.
(D) may be less than 40 V/cm.
39. The magnitude of electric field intensity at point (2,0,0) due to a dipole of dipole moment,
⃗P = î + √3ĵ kept at origin is [ where k = 1/4π ∈0 ] :
√13k
(A) 8

√13k
(B) 4

√7k
(C) 8

√7k
(D) 4

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40. The figure shown represents the electric field between two large metal plates. Which of the
graphs given in figure represents the force on a positive charge as it moves from point P
towards plate B ?

(A) (B)

(C) (D)

41. The capacitors A and B are connected in series with a battery as shown in the figure. When the
switch S is closed and the two capacitors get charged fully, then-

(A) The potential difference across the plates of A is 4V and across the plates of B is 6 V
(B) The potential difference across the plates of A is 6 V and across the plates of B is 4 V
(C) The ratio of electric energies stored in A and B is 2: 3
(D) The ratio of charges on A and B is 3: 2
42. In the circuit shown in fig. C1 = 2C2 . Capacitor C1 is charged to a potential of V. The current in
the circuit just after the switch S is closed is

(A) 0
2V
(B) R

(C) Infinite
V
(D) 2R

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43. Two identical capacitors 1 and 2 connected in series to a battery as shown in fig. Capacitor 2
contains a dielectric slab of dielectric constant k as shown. Q1 , and Q2 are the charges stored in
the capacitors. Now the dielectric slab is removed and the corresponding charges are Q′1 and
Q′2 . Then

Q′ k+1
(A) Q1 =
1 k

Q′ k+1
(B) Q2 =
2 2

Q′ k+1
(C) Q2 =
2 2k

Q′1 k
(D) Q = 2
1

44. A current loop consists of two identical semicircular parts each of radius R, one lying in the x −
y plane and the other in x − z plane. If the current in the loop is i. The resultant magnetic field
due to the two semicircular parts at their common centre is
μ i
(A) 2√2R
0

μ i
(B) 2R
0

μ i
(C) 4R
0

μ0 i
(D)
√2R

45. If the angular momentum of electron is j then its magnetic moment will be –
eJ
(A) m
eJ
(B) 2m

(C) eJ 2m
2m
(D) eJ

46. A particle of charge per unit mass α is released from origin with a velocity v ⃗ = v0 î in a uniform
magnetic field ⃗B = −B0 k̂. If the particle passes through (0, y, 0) then y is equal to
2v0
(A) − B

v0
(B) B0 α
2v0
(C) B

v
(D) − B 0α
0

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47. The spokes of a wheel are made of metal and their lengths are of one metre. On rotating the
wheel about its own axis in a uniform magnetic field of 5 × 10−5 tesla normal to the plane of
the wheel, a potential difference of 3.14mV is generated between the rim and the axis. The
rotational velocity of the wheel is-
(A) 63rev./s (B) 50rev./s (C) 31.4rev./s (D) 20rev./s
48. A conducting rod AB of length l = 1 m is moving at a velocity v = 4 m/s making an angle 30∘
with its length. A uniform magnetic field B = 2T exists in a direction perpendiuclar to the plane
of motion. Then

(A) VA − VB = 8 V (B) VA − VB = 4V (C) VB − VA = 8V (D) VB − VA = 4V


49. The graph between the current and the time for an inductance coil is shown below. Which of
the following graph show the voltage-time variation –

(A) (B)

(C) (D)

50. A bar magnet M is allowed to fall towards a fixed conducting ring C. If g is the acceleration due
to gravity, v is the velocity of the magnet at t = 2s and s is the distance travelled by it in the
same time then

(A) v > 2g (B) v = 2g (C) s > 2g (D) s < 2g

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Section-II
• This Section contain 10 questions (Q.No. 21 to Q.No. 30) whose answer to be filled as
numerical value (Attempt any five)
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

51. A circular coil of radius 10 cm and 50 turns is rotated about its vertical diameter with an
angular speed of 20 rad/s in a uniform horizontal magnetic field of magnitude 7 × 10−2 T. If the
11
closed loop of resistance of the coil is 20Ω. The maximum value of current in the coil is A.
N

Find N.
52. A rectangular coil of 100 turns and cross-sectional area 5 × 10−3 m2 is placed perpendicular to
a magnetic field of 0.2 T. If the field drops to 0.05 T in 0.5 seconds, the magnitude of emf (in V)
induced in the coil is _______.
53. The magnetic flux linked with a loop is ϕ = 6t 2 + 7t + 1 where ϕ is in milli weber and t is in
second. The e.m.f induced at t = 2sec is – (n + 11) mV. Find n
π
54. A magnetic field of 1 T applied at an angle to the vertical direction is decreased to zero at a
3

steady rate in one second. The magnitude of induced emf in a horizontally placed circular loop
of radius 5 cm is given by 0.25Nπ⁡⁡mV. Find N.
55. A circular coil of area 0.01m2 and 40 turns is rotated about its vertical diameter with an
angular speed of 50rads −1 in a uniform horizontal magnetic field 0.05 T. If the average power
loss due to joule heating is 25 mW. Then, the closed loop resistance (in ohms) of the coil is ___
56. The magnetic field due to current carrying circular loop of radius 6 cm at a point on the axis at
a distance of 8 cm from centre is 27μT. The magnetic field (in μT) at the centre of the current
carrying loop is.
57. If the switches S1 , S2 and S3 in the figure are arranged such that current through the battery is
minimum, the voltage across points A and B is (in V)
58. The resistance of an ammeter is 13Ω and its scale is graduated for a current upto 100 A. After
an additional shunt has been connected to this ammeter it becomes possible to measure
currents upto 750 A by this meter. The value of shunt resistance is in ohm

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59. For what value of unknown resistance X, the potential difference between B and D will be zero
in the arrangement of figure shown.

60. A rectangular coil of length 2 cm and width 1.25 cm with 250 turns carries a current of 55μA
and subjected to a magnetic field of strength 0.64 T. Work done (in μJ) for rotating the coil by
180° against the torque is

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PART – 3 : CHEMISTRY

• This question paper contains two sections, section A & B.


• Section A contains 20 multiple choice questions (SCQs) with four options (A),(B),(C),(D) out
of which only one option is correct.
• Section B contains 10 Integer Type questions, out of which candidate have to attempt only 5
questions.

Section-I
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

61. The standard EMF of a Daniel cell at 298 K is E1. When the concentration of ZnSO4 is 1.0 M and
that of CuSO4 is 0.01 M , the EMF becomes E2 at 298 K . The correct relationship between E1
and E2 is
(A) E1 = E2 (B) E2 = 0
(C) E1 > E2 (D) E1 < E2
62. Which kind of isomerism is exhibited by octahedral Co(NH3 )4 Br2 Cl ?
(A) Geometrical and Ionization
(B) Geometrical and Optical
(C) Optical and Ionization
(D) Geometrical only
63. In which of the following Reactions major product (P) will be 𝟑𝐨 Halide.

(A) only (i) (B) only (i) & (ii)


(C) only (i), (ii) & (iv) (D) only (ii), (iii) & (iv)

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64. What is [Ag + ]in a solution made by dissolving both Ag 2 CrO4 and Ag 2 C2 O4 until saturation is
reached with respect to both salts. K SP (Ag 2 C2 O4 ) = 2 × 10−11 , K SP (Ag 2 CrO4 ) = 2 × 10−12
(A) 2.80 × 10−4
(B) 7.6 × 10−5
(C) 6.63 × 10−6
(D) 3.52 × 10−4
65. Soda extract is prepared by:
(A) Fusing soda and mixture and then extracting with water
(B) Dissolving NaHCO3 and mixture in dil. HCl
(C) Boiling Na2 CO3 and mixture, in dil. HCl
(D) Boiling Na2 CO3 and mixture, in distilled water
66. The major product of the following reaction is :

Major Product

(A) (B) (C) (D)

67. The standard reduction potential's of half cell OCl− /Cl− , OH − and Cl2 /Cl− are 0.94 volt and +1.36
volt respectively. What is the reduction potential of half cell whose cell reaction is represented
as 2OCl− + 2H2 O + 2e ⟶ Cl2 ( g) + 4OH −
(A) 0.21 V
(B) 0.52 V
(C) 1.04 V
(D) 2.1 V
𝐂𝐨𝐥𝐝 Filtered
68. A → White ppt. →
Mixture 𝐄𝐱𝐜𝐞𝐬𝐬⁡𝐨𝐟⁡𝐁𝐚𝐂𝐥𝟐
of two anions
Boil
filtrate → White ppt.
Find out (A).
(A) SO2− −
3 , HSO3

(B) CO2− 2−
3 , SO3

(C) SO2− −
3 , HCO3

(D) None of these


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69. Which of the following is not the product of acidic dehydration of

(A) (B) (C) (D)


70. An ideal diatomic gas undergoing the following process as shown:

The value of q for the process is :


(A) 37⁡P1 V1
(B) 43⁡P1 V1
(C) 96⁡P1 V1
(D) 90⁡P1 V1
71. Which of the following statement is not correct?
(A) La(OH)3 is less basic than Lu(OH)3
(B) In Lanthanide series, ionic radius of Ln3+ ions decreases
(C) La metal is actually an element of transition series rather than lanthanide series
(D) Atomic radii of Zr and Hf are almost same because of lanthanide contraction

72.
In the given Reaction choose the Incorrect statement:-
(A) 1,2 product will be K. C. P & T.C.P
(B) 1,4 – Product is T.C.P
(C) (P) will be 1,2 Addition Product.
(D) Intermediate for Product (𝐐) will be less stable.

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73. The minimum voltage required to electrolyze alumina in the Hall-Heroult process is : (Given,
ΔGf0 (Al2 O3 ) = −1520kJmol−1 ; ΔGf0 (CO2 ) = −394kJmol−1 )
{In Hall-Heroult process, the following reactions occur 3C + 2Al2 O3 → 4Al + 3CO2 }
(A) 1.575 V
(B) 1.60 V
(C) 1.312 V
(D) -2.62 V
74. In the extraction of aluminium by Hall-Heroult process, Purified Al2 O3 is mixed with CaF2 to
(I) Increase the melting point of Al2 O3
(II) Increase the conductivity of molten mixture
(III) reduce Al3+ into Al(s)
(IV) Acts as catalyst
(A) (I), (II) and (III)
(B) (I) and (II)
(C) (III) and (IV)
(D) (II), (III) and (IV)
75. In which of the following reaction major product will not be alkene

(A) → Major product

(B) → Major product

(C) → Major product

(D) → Major product


76. 10 ml of 0.10 M solution of a compound (Na2 CO3 . NaHCO3 ⋅ 2H2 O) is titrated against 0.05 M
HCl. Xml of HCl is used when phenolphthalein is the indicator and Y ml of HCl is used when
methyl orange is the indicator in two separate titration, calculate (Y − X).
(A)30
(B)40
(C)50
(D)60

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CLASS 12th IIT SCHOOL VIJETA BATCH
A Cold Filtered
77. → White ppt. →
(Mixture Excess⁡of⁡BaCl2
of two anions)
Boil
Filtrate ppt. → White ppt.
Find out A :
(A) CO− −
3 , HSO3 (B) CO2− −
3 , HCO3

(C) SO2− −
3 , HSO3 (D) SO2− 2−
3 , CO3

78. The optical purity of an isomer is 40%. It is dextro rotatory. The percentage of 1 isomer is
(A) 40% (B) 60%
(C) 30% (D) 50%
79. A 500 mL sample of a 0.1MCr 3+ is electrolyzed with a current of 96.5 A . If the remaining [Cr 3+ ]
is 0.04 M then the duration of process is
(A) 30 sec.
(B) 90 sec.
(C) 10 sec
(D) None of these
80. Select the correct statement:
(A) Cation and anion are also called acidic or basic radicals, respectively
(B) Classification of anion is systematic as that of cation
(C) All the anions are deducted by soda extract solution without any exception
(D) None of these

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Section-II
• This Section contain 10 questions (Q.No. 21 to Q.No. 30) whose answer to be filled as
numerical value (Attempt any five)
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

81. Find the number of electrons lost by 1/6 molecule of caffeine in the given combustion reaction.
C8 H10 N4 O2 + O2 → CO2 + H2 O + NO2
82. Total number of anions of class A which give colourful gas with conc. acid :
NO− − − − − −2 −2
2 , NO3 , Br , I , F , S2 O3 , C2 O4

83. Consider all possible isomeric ketones including stereoisomers of MW = 100. All these isomers
are independently reacted with CH3 MgBr. The total number of ketones that gives a racemic
product(s) is/are
84. K a for HCN is 5 × 10−10 at 25∘ C. For maintaining at constant pH of 9 , the volume of 5 M KCN
solution required to be added to 10 ml of 2 MHCN solution is
85. Number of moles of SnCl2 required for the reduction of 1 mole of K 2 Cr2 O7 into Cr2 O3 is (in
acidic medium)
86. Among the following free radical bromination reactions, select the total number of reactions in
which 2 halide is the major product.

87. What is ΔS (in cal/K ) for 16⁡gm⁡O2 gas (Assume ideal ; Cv,m = 5/2R ) which is heated and
compressed from 300 K and 1 bar to 600 K and 4 bar ?
[Thermodynamics-E]
Given : R = 2cal/mol. K; ln⁡ 2 = 0.70.

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88. How many maximum number of atoms are present in single plane of Al(CH3 )3 molecule.
89. Consider the following reaction:

Sum of number of halogen atoms present in products 'D' and 'E' is


90. In the given reaction
( i ) K2Cr2O7
( ii ) C6H5MgBr
⎯⎯⎯⎯→
( iii ) H2O 'X'
MajorProduct
( iv ) H+ ,heat
the number of sp2 hybridised carbon (s) in compound ‘X’ is________.

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