Class -12th Maths Batch-2: Day -8 (Test Paper)

Data required : log 2 = 0.3010, Antilog 0.0573 = 1.141, log 33.05 = 1.5191, log 26.80 = 1.4281,
log 45 = 1.6532, log 22.5 = 1.3522 , log 233.8 = 2.3689, log 46.5 = 1.6665,
log 39.6 = 1.6010, log 36.5 = 1.5622 , log 22.79 = 1.3577, log 15.43 = 1.1883,
log 17.83 = 1.2511, log 42.9 = 1.6325, log 1.79 = 0.253, log 31.25 = 1.495,
Antilog 1.2993 = 19.9., log (2.77) = 0.443, Antilog (1.232) = 17.06, Antilog (0.1563) = 1.433

11. For a reaction,

4 KClO3  3 KClO4 + KCl
d
If  [KClO 3 ]  k 1 [KClO 3 ]4
dt
d
[KClO 4 ]  k 2 [KClO 3 ]4
dt
d
[KCl]  k 3 [KClO 3 ]4
dt
The correct relation between k1, k2 and k3 is
(a) k 1  k 2  k 3 (b) 4k 1  3k 2  2k 3 (c) 3k 1  4k 2  12k 3 (d) k 1  4k 2  3k 3
12. Reaction A 2  B 2  2AB is completed according to the following mechanism.


Kf
A 2  
 2A (Fast and reversible)
K b

A + B2  AB + B (slow step)
A + B  AB
The overall order of reaction is
(a) 1 (b) 3/2 (c) 1/2 (d) 2
13. The following data pertains to the reaction between A and B :
S. No. [A]/mol L–1 [B]/mol L–1 Rate/mol L–1 t–1
I 1  10–2 2  10–2 2  10–4
II 2  10–2 2  10–2 4  10–4
III 2  10–2 4  10–2 8  10–4
Which of the following inferences are drawn from the above data?
1. Rate law of the reaction is k [A] [B]
2. Rate constant of the reaction is 10–4.
3. Rate of reaction increases four times by doubling the concentration of each reactant.
Select the correct answer from the codes given below :
(a) 1 and 2 (b) 1 and 3 (c) 1, 2 and 3 (d) 3 alone
Space for rough
14. 
k1
Consider the elementary reaction H2 + I2  
 2HI , the net rate of formation of HI is
k2

(a) 2 (k1[H2] [I2] – k2[HI]2) (b) 2 (k1[H2] [I2])

2
(c) 2 k2 [HI] (d) k1[H2] [I2] – k2[HI]2
15. 
k1
In elementary reversible reaction: 2NO2  
 N2O4 the rate of disappearance of NO2 is equal to
k2

2k 1
(a) [ NO 2 ] 2 (b) 2k1[NO2]2 – 2k2[N2O4]
k2
(c) 2k1[NO2]2 – k2[N2O4] (d) (2k1 – k2 [NO2]
16. 3A  2B. Point ‘x’ in the given figure represents

B
Conc.

A
x time
(a) half life time. (b) average life time.
(c) time when 60% of A is reacted. (d) time when 40% of A is reacted
17. A and B are two reactants which have same initial concentration undergoing different reactions of order one,
A KA
D and B  KB
E . Where KB = 2KA. After ‘n’ half lives of A, the rate of reaction of A and B are
equal. The value of ‘n’ is
(a) 1 (b) 2 (c) 3 (d) 4
18. For a zero order reaction, the concentration of reactant after 10s is 0.2 mol/l. If k 0 is 2  10 2 mol l–1 s–1, the
initial concentration of reactant is
(a) 0.6 mol/l (b) 0.4 mol/l (c) 0.8 mol/l (d) 1 mol/l
19. A zero order reaction is completed in 2 min. After how many second 60% reaction will be completed?
(a) 60 sec. (b) 65 sec. (c) 72 sec. (d) 80 sec.
20. A  P + Q is a first order reaction. The degree of dissociation is
(a) e  kt (b) 1  e  kt (c) 1  e kt (d) 1  e  kt
 Hints and Solution
1 d 1 d d
11.[c]  [ KClO 3 ]  [ KClO 4 ]  [ KCl ]
4 dt 3 dt dt
k1 k
 [KClO 3 ]4  2 [KClO 3 ] 4  k 3 [KClO 3 ] 4
4 3
k1 k 2
   k 3  3k 1  4k 2  12k 3
4 3
12.[b] rate = k [A] [B2]
[A]2
K  [A] = K [ A 2 ]1 / 2
[A 2 ]
rate = k K [ A 2 ]1 / 2 [ B 2 ]
3
Overall order 
2
13.[b] Comparison of data at S. No. I and II shows that when [A] is doubled, the rate is doubled, hence order
of reaction with respect to A is first and comparison of data S.No. II and III show that when [B] is
doubled, the rate is also doubled hence first order with respect to B. Therefore inferences 1 and 3 are
correct.
d[HI]
14.[a] Net rate of formation of HI   2 k 1 [H 2 ][I 2 ]  2 k 2 [ HI] 2
dt
15.[b] 
k1
2NO 2  
 N 2O4
k 2

1 d[ NO 2 ] d[ NO 2 ]
  k 1 [ NO 2 ] 2  k 2 [ N 2 O 4 ]    2k 1 [ NO 2 ]2  2k 2 [ N 2 O 4 ]
2 dt dt
16.[c] 3A  2B
Initially no. of moles, a 0
At x, (a – 3y) 2y
a – 3y = 2y
a
y
5
3y 3a
% of A reacted =  100   100  60%
a 5a
0.693 0.693 t   
17.[a]  2   1   2 t 1 
t1  t1     2
     2 A  B
 2  2
 B  A
Hence, n half lives of A = 2n half lives of B.
n
1
C A  C0  
2
n
1
 rate of reaction of A = k A C A    k A C 0
2
2n
1
and rate of reaction of B = k B C B    k B C 0
2
n 2n 2n
1 1 1
  k A C o    k B C o    .2 k A C 0
2 2 2
n 2n n
1 1 1 1
      .2     n = 1
2 2 2 2
18.[b] at = a0 – x = a0 – kt
0.2 + (2  10–2  10 ) = 0.4 mol/l = a0
19.[c] at – a0 = – kt
 0 – a0 = – k (2  60)
 a0 a0
k  mol l–1 s–1
t comp 2  60
40 90
a t  a 0  kt  a0  a0   t
100 120
60 t 120  6
 t  = 72s
100 120 10
a a ax x
20.[d] kt  ln   e kt   e  kt   1  e  kt    1  e  kt
ax ax a a