Class 11th JEE ADVANCED PAPER – 1

Time : 3 Hours Maximum Marks : 180

ANSWER KEY

Solutions with Explanation

PART – 1 : MATHEMATICS

SECTION 1 (Maximum Marks: 24)

• This section contains EIGHT (08) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical
value has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the correct numerical value is entered;
Zero Marks : 0 In all other cases.
Negative Marks : −1 In all other cases.
1. A line with positive rational slope, passes through the point M(6,0) and is at a distance of 5
from N(1,3). The slope of line is in form of x/y, then the value of x will be _______.
2. Line L , perpendicular to the line with equation 𝑦 = 3𝑥 − 5, contains the point (1,4). The 𝑥-
intercept of L , is
3. The orthocenter of the triangle formed by the lines 𝑥 − 7𝑦 + 6 = 0,2𝑥 − 5𝑦 − 6 = 0 and
7𝑥 + 𝑦 − 8 = 0 is (x, y) then the value of y will be
4. Point A(3,4) is reflected about the line x − y = 0. The reflected point is B . Point B translates a
distance equal to OB along the line L , away from origin, upto point C . The line y = x is acute
angle bisector of OA and L. Find the ratio of area of triangle OAB to the area of triangle BNC ,
where N is the mid point of AB .
5. If the point M(h, k) lie on the line 2x + 3y = 5 such that |MA − MB| is maximum where A(2,3)
and B(1,2), then find the value of (3 h + 2k).
𝑥
6. The circumradius of the triangle whose vertices are (1,1), (2, −1) and (3,2) is in the form of √𝑦

then the value of x will be _________.

7. The points (2,1), (5,4) and (1,4) are three of the corners of a parallelogram. The coordinates of
the remaining corner which is opposite to (2,1) is (x, y) then the sum of x + y will be ____.

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 Class 11th JEE ADVANCED PAPER – 1
8. Find the length (BE) of the medians of the triangle whose vertices are (1,2), (0,3) and (−1, −2).

SECTION 2 (Maximum Marks: 24)

• This section contains SIX (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -2 In all other cases.

9. One diagonal of a square is the portion of the line 7x + 5y = 35 intercepted by the axes. Obtain
the extremity of the other diagonal is :
(A) (6,6)
(B) (5,7)
(C) (−1,1)
(D) (7,5)
10. Two sides of a rhombus OABC (lying entirely in first quadrant of fourth) of area 2 square units
x
are y = , y = √3x. Then possible coordinates of B is/are (O being origin)
√3

(A) (1 + √3, 1 + √3)

(B) (−1 − √3, −1 − √3)
(C) (3 + √3, 3 + √3)
(D) (√3 − 1, √3 − 1)

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11. A light ray is incident to a line mirror ' L ' along the line 3x − 4y + 5 = 0 and is reflected along
the line 5x − 12y + 19 = 0. The equation of line 'L' may be:
(A) 7x − 4y + 1 = 0
(B) 7x + 4y − 15 = 0
(C) 4x − 7y + 10 = 0
(D) 4x + 7y − 18 = 0
12. Two equal sides of an isosceles triangle are given by the equations 7x − y + 3 = 0 and x + y −
3 = 0 and its third side passes through the point (1, −10). Determine the equation of the third
side can be:
(A) x + 3y + 29 = 0
(B) x − 3y − 31 = 0
(C) 3x − y = 13
(D) 3x + y + 7 = 0
13. The equation of the straight line passing through (4,3) and making intercepts on the co-
ordinate axes whose sum is −1 is:
x y
(A) 2 − 3 = 1
x y
(B) −2 + 1 = 1
x y
(C) − 3 + 2 = 1
x y
(D) 1 − 2 = 1

14. The lines L1 and L2 denoted by 3x 2 + 10xy + 8y 2 + 14x +22y + 15 = 0 intersect at the point P
and have gradients m1 and m2 respectively. The acute angles between them is θ. Which of the
following relations hold good?
(A) m1 + m2 = 5/4
(B) m1 m2 = 3/8
2
(C) acute angle between L1 and L2 is sin−1 ⁡ 5√5

(D) sum of the abscissa and ordinate of the point P is -1.

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SECTION 3 (Maximum Marks: 12)
• This section contains FOUR (04) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and
(T).
• FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY
ONE of these four options satisfies the condition asked in the Multiple Choice Question.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -1 In all other cases.

15.
Column-I Column-II
(A) For an A.P. 𝑎1 , 𝑎2 , 𝑎3 , … . , 𝑎𝑛 , … a1 = 5 ; a10 = 16. If ∑ni=1 ai = 110 then ' 𝑛 ' (P) 9
2
equals
(B) The interior angles of a convex non-equiangular polygon of 9 sides are in (Q) 10
A.P. The least positive integer that limits the upper value of the common
difference between the measures of the angles in degree is
(C) For an increasing G.P. 𝑎1 , 𝑎2 , 𝑎3 , … . . , 𝑎𝑛 , … . . 𝑎6 = 4𝑎4 ; 𝑎9 − 𝑎7 = 192. (R) 11
If ∑𝑛𝑖=4 𝑎𝑖 = 1016 then 'n' equals
(S) 12
(A) (A)-R ;(B)-Q ;(C)-Q
(B) (A)-R ;(B)-P ;(C)-Q
(C) (A)-P ;(B)-Q ;(C)-P
(D) (A)-P ;(B)-Q ;(C)-R
16.
Column-I Column-II
(A) Number of positive integral ordered pairs of (𝑎, 𝑏) such that 6 , a, b are in (P) 6
harmonical progression, is
(B) If 𝑥, 𝑦 and 𝑧 are positive real numbers and 𝑥 = 12−𝑦𝑧. The maximum value (Q) 7
𝑦+𝑧
of (xyz) equals
(C) If the roots of the equation 3𝑥 3 − 26𝑥 2 + 52𝑥 − 24 = 0 are in G.P. then the (R) 8
largest root, is
(S) 9
(A) (A)-P ;(B)-R ;(C)-P
(B) (A)-Q ;(B)-P ;(C)-P
(C) (A)-R ;(B)-R ;(C)-P
(D) (A)-Q ;(B)-R ;(C)-P
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17.
Column-I Column-II
(A) The harmonic mean of the roots of the equation (5 + √2)𝑥 2 − (4 + √5)𝑥 + (P) 2
8 + 2√5 = 0 is
(B) Let 𝑎1 , 𝑎2 , … . . , 𝑎10 , be in A.P. and ℎ1 , ℎ2 , … … , ℎ10 be in H.P. If 𝑎1 = ℎ1 = (Q) 3
2&a10 = h10 = 3 then a4 h7 is
(C) The number of integer values of m , for which the x coordinate of the point (R) 4
of intersection of the lines 3𝑥 + 4𝑦 = 9 and 𝑦 = 𝑚𝑥 + 1 is also an integer,
is
(D) Between 2 and 5 six geometric means are inserted. If their product can be (S) 6
expressed as (10)n then the value of 𝑛 equals
(A) (A)-Q ;(B)-S ;(C)-P ;(D)-R
(B) (A)-R ;(B)-P ;(C)-S ;(D)-Q
(C) (A)-P ;(B)-S ;(C)-R ;(D)-Q
(D) (A)-R ;(B)-S ;(C)-P ;(D)-Q
18. Let a, b, c, d are positive numbers.
Column-I Column-II
(A) Least value of (𝑎 + 𝑏 + 𝑐) (1 + 1 + 1) is (P) 9
𝑎 𝑏 𝑐
(B) Least value of (𝑎+𝑏)(𝑏+𝑐)(𝑐+𝑎) is (Q) 3
𝑎𝑏𝑐
(C) Least value of (𝑏 + 𝑐 + 𝑑) (𝑎 + 𝑏 + 𝑐 ) is (R)
𝑎 𝑏 𝑐 𝑏 𝑐 𝑑 8
(D) Least value of 𝑏𝑐 + 𝑐𝑎 + 𝑎𝑏 is (S) 7
𝑎2 𝑏2 𝑐2
(T) 6
(A) (A)-P ;(B)-R ;(C)-P ;(D)-Q
(B) (A)-R ;(B)-P ;(C)-P ;(D)-Q
(C) (A)-Q ;(B)-R ;(C)-P ;(D)-P
(D) (A)-P ;(B)-Q ;(C)-P ;(D)-R

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 Class 11th JEE ADVANCED PAPER – 1
PART – 2 : PHYSICS

SECTION 1 (Maximum Marks: 24)

• This section contains EIGHT (08) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical
value has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the correct numerical value is entered;
Zero Marks : 0 In all other cases.
Negative Marks : −1 In all other cases.
19. A particle of mass 4 kg slides with negligible friction on a horizontal table. The spring attached
to the particle has a stiffness of 100 N/m and a free length of 0.5 m. When the particle is at A,
its velocity is 4 m/s directed as shown. The speed of the particle at B where the length of the
spring is 0.8m is √N m/s. Find N.

20. The block A is pulled along the horizontal surface by the constant force F. If the string
connecting the bob B to the block maintains the constant angle θ = 45° to the vertical,
determine the magnitude of F (in Newtons).

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21. The chain of linear mass density 3 kg/m is raised at the constant speed of 1.5 m/s. Determine
the tension (in N) in the chain at A. (g = 10m/s2 )

22. The displacement of a body of mass 2 kg varies with time 𝑡 as 𝑥 = 𝑡 2 + 2𝑡, where 𝑥 is in meter
and 𝑡 is in second. The work (in J) done by all the forces acting on the body during the time
interval t = 2 s to t = 4 s is
23. Velocity-time graph of a particle of mass 2 kg , moving in a straight line is as shown in figure.
Work (in J) done by all the forces acting on the particle from 𝑡 = 0 to 𝑡 = 10 s is

24. Two sphere 1kg and 2kg are connected by a spring of unstretched length 0.3m with a modulus
of 800 N/m along a smooth plane at the instant shown force F = 20N acts on m2 . The
acceleration of mass m1 is a1 and that of mass m2 is a2 . Find |a1 | + |a2 | (in m/s 2 ).

25. In an elastic head-on collision of bodies of mass m and (x 2 − 9x + 21)m, the second body is at
rest and the maximum transfer of momentum takes place. The values of x be x1 and x2 . Find
x1 + x2 .

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26. It is observed that when the 2kg smooth collar is slided back to point B and released from rest,
the collar attains a speed of 3ms −1 when it arrives at point A as shown in figure.

Calculate the necessary unstretched length (in m) of the spring, in metre, if it has a stiffness k =
2Nm−1.

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SECTION 2 (Maximum Marks: 24)
• This section contains SIX (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -2 In all other cases.

27. A particle of mass 5kg moving in the x-y plane has its potential energy given by U =
(−7x + 24y)J,where x and y are in metre. The particle is initially at origin and has a velocity
⃗ = (2.4î + 11.2ĵ)ms −1.
u
(A) The particle has a speed of 10ms−1 at t = 4s
(B) The particle has an acceleration of 5ms−2
(C) The acceleration of the particle is perpendicular to its initial velocity
(D) None of the above is correct
28. A pendulum of length l is suspended on a flat car that is moving with a velocity v on the
horizontal road. If the car is suddenly stopped, then, (assume bob of pendulum does not collide
anywhere)

(A) the maximum angle θ with the initial vertical line through which the pendulum swing is
v
sin−1 [ ]
2√gℓ
(B) the maximum angle θ with the initial vertical line through which the pendulum swing is
v
2 sin−1 [ ]
2√gℓ
(C) if maximum angle θ is 30o , ℓ = 5m and g = 9.8ms−2 , then the initial speed of car v is 6ms −1
(D) if maximum angle is 60o , ℓ = 10m and g = 10ms−2 then the initial speed of car v is 10ms −1
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29. A particle moving along x-axis has its velocity (v) varying with x co-ordinate (x) as v = 2√x.
Then
(A) initial velocity of particle is zero
(B) motion is uniformly accelerated
(C) acceleration of particle at x = 4m is 1ms −2
(D) acceleration of particle at x = 2m is 2ms −2
30. A particle P lying on smooth horizontal x-y plane starts from (8î + 8ĵ)m with velocity (4î)ms −1.
Another particle Q is projected (horizontally from origin with velocity (aî + bĵ) so that is
strikes P after 4s. Then
(A) a = 6 (B) a = 5 (C) b = 2 (D) b = 8
31. A ball A collides elastically with another identical ball B with a velocity of 20ms −1 making an
angle of 60o with the line joining their centres C1 and C2 . Select the correct statement(s)

(A) Velocity of ball A after collision is 10√3ms−1

(B) Velocity of ball B after collision is 10ms−1
(C) Both the balls move at right angles after collision
(D) Kinetic energy will not be conserved here, because collision is not head on
32. The maximum value of the force F such that the block shown in the arrangement, does not
move is

(A) 20 N (B) 10N (C) 12N (D) 15N

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 Class 11th JEE ADVANCED PAPER – 1
SECTION 3 (Maximum Marks: 12)
• This section contains FOUR (04) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and
(T).
• FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY
ONE of these four options satisfies the condition asked in the Multiple Choice Question.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -1 In all other cases.

33. In the figure shown, upper block is given a velocity 6m/s and very long plank, velocity 3m/s.
The following quantities are to be matched when both attain same velocity.

Column – I Column – II
(A) Work done by friction on 1 kg block in Joule (P) Positive
(B) Work done by friction on 2 kg plank in Joule (Q) Negative
(C) Magnitude of change in momentum in N-s of 2 kg plank (R) 3
Change in K.E. of system consisting of block and plank
(D) (S) 7
in joule
(T) 2
(A) (A − P, S); (B − Q); (C − P, T); (D − Q, R)
(B) (A − Q); (B − P, S); (C − P, T); (D − Q, R)
(C) (A − Q, R); (B − P, S); (C − P, T); (D − Q)
(D) (A − Q); (B − P, T); (C − P, S); (D − Q)

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34. Assume that in space potential energy U-depends on x-coordinate only by :
U = (x − 3)2 (2 − x)
A mass m can be kept on x-axis. In each position indicated in column-I, comment on the
situation from column-II.
Column – I Column – II
7
(A) x= (P) Stable equilibrium
3
(B) x=2 (Q) Unstable equilibrium
(C) x=3 (R) Neutral equilibrium
(S) Not in equilibrium
(A) (A − Q); (B − S); (C − P)
(B) (A − Q); (B − P); (C − S)
(C) (A − P); (B − Q); (C − S)
(D) (A − P); (B − S); (C − Q)
35. The bob of a simple pendulum is given a velocity 10 m/s at its lowest point. Mass of the bob is
1 kg and string length is 1 m.

Column – I Column – II
(A) Minimum tension in string (in Newton) (P) 50
Magnitude of acceleration of bob when the string is horizontal
(B) (Q) 60
(inm/s2 )
(C) Minimum magnitude of acceleration of bob (𝑖𝑛𝑚/𝑠 2 ) (R) Zero
(D) Tangential acceleration at the highest point (𝑖𝑛𝑚/𝑠 2 ) (S) 10√65

(A) (A − R); (B − Q); (C − S); (D − P)

(B) (A − S); (B − P); (C − Q); (D − R)
(C) (A − P); (B − R); (C − Q); (D − S)
(D) (A − P); (B − S); (C − Q); (D − R)

36. A man swings a stone tied to a string of length ′ℓ′ in a vertical plane inside a car moving with
acceleration ′a′ as shown. (Take a = √3g). The speed of stone varies from some maximum value
(vmax ) to some minimum value (vmin ) during the motion. We can choose the maximum /
minimum values of the speed during motion by changing initial speed at A. Here all the speeds
are relative to the moving car.

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Column – I Column – II
(A) vmax at which the string always remains tight. (P) √gℓ

(B) vmin at which the string becomes slack. (Q) √3gℓ

vmin at which particle always completes the
(C) (R) √5gℓ
circle
(S) √11gℓ

(A) (A − S); (B − P); (C − P, S)

(B) (A − Q, S); (B − P); (C − Q, R)
(C) (A − P); (B − Q, R); (C − P)
(D) (A − P, Q, S); (B − P); (C − Q, R, S)

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 Class 11th JEE ADVANCED PAPER – 1
PART – 3 : CHEMISTRY

SECTION 1 (Maximum Marks: 24)

• This section contains EIGHT (08) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical
value has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the correct numerical value is entered;
Zero Marks : 0 In all other cases.
Negative Marks : −1 In all other cases.
37. A vessel of volume 3.0 L contains ideal gas at the temperature 0∘ C. After a portion of the gas has
been let out, the pressure in the vessel decreases by 0.8 atm (the temperature remaining
constant). The gas density under the normal condition (0∘ C and 1 atm ) is 1.25 g/L. The mass of
released gas in (g) is _____.

∘ ∘
38. The wavelength of β − line of the Balmer series is 800 A. What is the wavelength (A) of α − line
of the Balmer series of the same atom?

39. An electron is accelerated from rest, by 'V' volts. Uncertainty in position (Δx) is plotted against
minimum uncertainty in de-broglie wavelength (Δλ) as following.

The value of ' V ' is –

40. The number of 90∘ angle in SF6 are :

41. The first, second and third ionisation energies (𝐸1 , 𝐸2 and 𝐸3 ) for an element are 7eV, 12.5 eV
and 42.5 eV respectively. The most stable oxidation state of the element will be:

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42. Sum of number of σ and π bond in (salicyclic Acid)

43. Maximum value of (𝑥 + 𝑦 + 𝑧 + 𝑤), where 𝑥, 𝑦, 𝑧 and 𝑤 represent position according to correct
IUPAC name " 𝑥, 𝑦-diphenyl cyclopentane- 𝑧, 𝑤-dicarboxylic acid".

44. How to many of the following sets are member of same homologous series?
(i) C2H6, C4H10, C6H12 (ii) CH3–COOH, CH3–CH2–COOH, CH3–CH2–COOH
(iii) C3H7Br, C4H9Br, C6H13Br (iv) CH3CHO, CH3CH2CHO, CH3CH2CH3

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 Class 11th JEE ADVANCED PAPER – 1
SECTION 2 (Maximum Marks: 24)
• This section contains SIX (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -2 In all other cases.

45. A 1 litre vessel contains 2 moles of a van der waal's gas.

Given data: a = 2.5 atm − L2 mole−2 T = 240 K
b = 0.4 L − mole−1 RT = 20 L − atm mole−1
Identify the correct options about the gas sample:
(A) Pressure of gas = 190 atm
(B) Compressibility factor = 4.75
(C) Attraction forces are dominant in the gaseous sample
(D) TB (Boyle temperature) = 75 K
46. Which of the following statement(s) is/are correct?
(A) The ratio of the radii of the first three Bohr orbits of hydrogen atom is 1: 8: 27.
(B) The ratio of magnitude of total energy: kinetic energy: potential energy for electron in any
orbit of hydrogen atom is 1: 1: 2.
(C) The frequency of a green light is 6 × 1014 Hz, then its wavelength is 500 nm.
(D) The ratio of de-Broglie wavelength of a H-atom, He-atom and CH4 -molecule moving with
equal kinetic energy is 4: 2: 1.
47. Which of the following statement(s) regarding periodic properties is/ are incorrect?
(A) Alkali metals have highest I.E. in respective period
(B) Noble gas have highest I.E. in respective period
(C) First electron affinity of nitrogen is less than oxygen
(D) F atom has smallest radius in periodic table
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48. Select the correct statement(s):
(A) The overlap become better when the overlapping orbitals have comparable energy
(B) The order of increasing tendency of polymerizations SiO4− 3− 2− −
4 > PO4 > SO4 > ClO4

(C) With the increase in positive oxidation state the energy of the 3d-orbitals gradually
decreases and it favours the π-bonding interaction
(D) The system where the π bonding is not effective, the stabilization is attained through the
single bonded structure, i.e., through the polymerization
49. Compound with only 1o Hydrogen atom is/are :

(A) (B)

(C) (CH3 )2 C = C(CH3 )2 (D)

50. In the given general formula Cn H2n−4 O4 which of the following statements are correct
(A) Compound may have two carboxylic acids
(B) Compound may have two alcohol and one ether
(C) Compound may have two aldehyde and one ketone
(D) Compound may have one acid anhydride

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SECTION 3 (Maximum Marks: 12)
• This section contains FOUR (04) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and
(T).
• FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY
ONE of these four options satisfies the condition asked in the Multiple Choice Question.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -1 In all other cases.

51. Match the column:

Column I Column II
(For an ideal gas at constant pressure) (Correct graph)

1
(a) (log⁡ V) vs log⁡ ( T) (p)

1
(b) (TV) vs ( T2 ) (q)

V
(c) (T) vs V (r)

(d) (TV) vs T (s)

Options:
(A) (a)- s, (b)- r, (c)- p, (d)- q
(B) (a)- s, (b)- r, (c)- q, (d)- p
(C) (a)- r, (b)- s, (c)- p, (d)- q
(D) (a)- r, (b)- p, (c)- s, (d)- q

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52. Column-I Column-II
(I) F > Cl > Br > I (P) Ionisation energy

(II) Fe3+ > Fe2+ > Fe (Q) Size

(III) I− > I > I + (R) Magnitude of Δ𝐻eg

(IV) O > C > B > N (S) Effective nuclear charge

(A) I → R, S; II → P, R, S; III → P; IV → R
(B) I → P, S; II → R, S; III → Q; IV → S
(C) I → R, S; II → P, R, S; III → S; IV → R
(D) I → P, S; II → P, R, S; III → Q; IV → R
53. Column-I Column-II
(I) AsO3−
4 (P) All three p-orbitals used in hybridization

(II) ICl2+ (Q) Tetrahedral shape

(III) SOF4 (R) Axial 𝑑-orbital with two nodal cones used in hybridization

(IV) XeOF4 (S) All bond lengths are identical

(T) 𝑝𝜋 − 𝑑𝜋 bond(s) present

(A) I → P, Q, T; II → P, R; III → P, S, T; IV → P, T

(B) I → P, Q, S, T; II → P, S; III → P, R, T; IV → P, R, T

(C) I → P, Q, T; II → P, S; III → P, R; IV → R, T

(D) I → P, Q, S, T; II → R, S; III → R, T; IV → P, R, T

54.
Column I Column II
(General formula) (Compound may have)
(I) Cn H2n−4 O4 (P) Two carboxylic acid
(II) Cn H2n O3 (Q) Two alcohol and one ether
(III) Cn H2n−2 O4 (R) One acid anhydride
(IV) Cn H2n−6 O3 (S) Two aldehyde and one ketone
(T) One ester, one ketone and one aldehyde

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Options:
(A) (I → Q), (II → P, Q, R, S, T), (III → P, Q, R), (IV → Q, R, S)
(B) (I → P, Q, R, S, T), (II → Q), (III → P, Q, R), (IV → Q, R, S)
(C) (I → P, Q, R, S, T), (II → P, Q, R), (III → Q), (IV → Q, R, S)
(D) (I → P, Q, R, S, T), (II → Q), (III → Q, R, S), (IV → P, Q, R)

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ANSWER KEY

SECTION – 1
Q. 1 2 3 4 5 6 7 8
A. 8 13 1 2 4 5 11 3
SECTION – 2
Q. 9 10 11 12 13 14
MATHS
A. AC AB BC BD AB BCD
SECTION – 3
Q. 15 16 17 18
A. A D A D

SECTION – 1
Q. 19 20 21 22 23 24 25 26
A. 20 6 126.75 64 300 590 9 1.75
SECTION – 2
Q. 27 28 29 30 31 32
PHYSICS
A. AB BD ABD AC ABC A
SECTION – 3
Q. 33 34 35 36
A. B D D D

SECTION – 1
Q. 37 38 39 40 41 42 43 44
∘
A. 3 1080𝐀 75 12 2 20 14 4
SECTION – 2
CHEMISTRY Q. 45 46 47 48 49 50
A. A,B,D B,C,D A,D A,B,C,D A,B,D A,B,C,D
SECTION – 3
Q. 51 52 53 54
A. B D B B

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Solutions

PART – 1 : MATHEMATICS
1. Let required line be, (𝑦 − 0) = 𝑚(𝑥 − 6), 𝑚 > 0
⇒ 𝑚𝑥 − 𝑦 − 6𝑚 = 0
As distance of above line from 𝑁(1,3) is 5 , so
m−3−6 m
| √1+m2
| = 5⁡ ⇒ ⁡(3 + 5 m)2 = 25(1 + m2 )
16 8
⇒ 9 + 30 m = 25⁡ ⇒ m = 30 = 15
−1
2. 𝐿: (𝑦 − 4) = (𝑥 − 1) put 𝑦 = 0, 𝑥 = 13
3
3. As 𝑥 − 7𝑦 + 6 = 0 and 7𝑥 + 𝑦 − 8 = 0 are perpendicular.
∴ The triangle is right angled, and hence, the orthocentre is the point of intersection of
𝑥 − 7𝑦 + 6 = 0 and 7𝑥 + 𝑦 − 8 = 0 is 𝐻(1,1).
xC −4 yC −3
4. B(4,3); = =5
4/5 3/5

xC = 8, yC = 6⁡ ∴ ⁡C(8,6)
3 4 1
1 7
∴ Area of △ OAB = 2 |0 0 1| = 2
4 3 1

7 7
1
1 2 2
Area of △ BNC = 2 |4 3 1|
8 6 1

1 7 7 1 −21 28
= 2 [2 (−3) − 2 (−4) + 24 − 24] = 2 ( + )=
2 2
Area of △OAB 7/2
∴⁡ = 7/4 = 2.
Area of △BNC

5. As, |MA − MB| ≤ AB

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∴ |MA − MB|maximum = AB, which is possible when
M is the point of intersection of line joining A(1,2), B(2,3) are 2x + 3y = 5.
2 7
So, M (x = 5 , y = 5)

6. AC = √5; ⁡BC = √10; ⁡AB = √5 Δ is triangle angled at A.

5
R = DC = BD = AD = √2.

7. Diagonals of parallelogram bisect each other.

a+2 b+1
∴ = 3 and =4
2 2

a = 4 and b = 7: (4, 7)
8. Method-1:

1 1 3√2
ℓA = √2b 2 + 2c 2 − a2 = √40 + 4 − 26 =
2 2 2
1 1
ℓB = √2a2 + 2c 2 − b 2 = √52 + 4 − 20 = 3
2 2
1 1 3√10
ℓC = √2b 2 + 2a2 − c 2 = √40 + 52 − 2 =
2 2 2

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Method-1:

9 9 3 3√2
Using Distance formula, AD = √4 + 4 = =
√2 2

9 81 √90 3√10
BE = 3; ⁡CF = √ + = =
4 4 2 2

14. f(x, y) = (x + 2y + 3)(3x + 4y + 5)

2h 10 −5
m1 + m2 = − =− =
b 8 4
a 3
m1 m2 = b = 8

Also L1 and L2 intersect at (1, −2)

∴ Sum of abscissa and ordinate = −1
2√h2 − ab 2√25 − 24 2
tan⁡ θ = = =
a+b 11 11
2 2
sin⁡ θ = ⇒ θ = sin−1 ⁡ ( )
5√5 5√5

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PART – 2 : PHYSICS
19. Energy is conserved:
K A + UA = K B + UB
1 1 1 1
mvA2 + xA2 = mvB2 + xB2
2 2 2 2
Solving the above equation for vB , we get N = 20
20. As θ = 45°, horizontal acceleration has to be equal to g.
F = (mA + mB )g = 6N
21. Let ρ be the mass of the chain per unit length.

Consider the potion AB, the thrust force on it is given by

.
∑F = m(vout − vin )
Where
vin = 0 (bottom link has no velocity) vout = 1.5m/s
.
m = ρvout = 3(1.5) = 4.5kg/s
∴ ∑F = 4.5(1.5 − 0) = 6.75N
From FBD:
∑F = T − ρgL
∴ T = ∑F + ρgL = 6.75 + 3(10)(4) = 126.75N
dx
22. v= = 2t + 2
dt

From Work Energy Theorem

1
Wnet = ΔKE ⇒ Wnet = K t − K i = 2 m(v12 − v12 )
1
Wnet = × 2[((2 × 4) + 2)2 − ((2 × 2) + 2)2 ] = 64 J
2
23. From Work Energy Theorem 𝑊 = ΔKE

1 1
⇒ W = Kt − Ki = m(v12 − v12 ) ⇒ W = (2)(400 − 100) = 300 J
2 2

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24.

400 = 1 × a1
a1 = 400m/s 2

F − 400 = m2 a2
20 − 400 = 2 × a2
⇒ a2 = −190m/s 2
25. Maximum transfer of momentum takes place when both the masses are equal i.e.,
x 2 − 9x + 21 = 1
⇒ x 2 − 9x + 20 = 0
⇒ (x − 4)(x − 5) = 0
⇒ x1 = 4 and x2 = 5
26. Let ℓ0 be the unstretched length of the spring, then by Law of Conservation of Energy, we have
(u + K)atA = (u + K)atB
1 1 1 1
k(3 − ℓ0 )2 + mvA2 = k(5 − ℓ0 )2 + mvB2
2 2 2 2
But vB = 0
⇒ (3 − ℓ0 )2 + 9 = (5 − ℓ0 )2
⇒ (9 + ℓ20 − 6ℓ0 ) + 9 = (25 + ℓ20 − 10ℓ0 )
⇒ 16 − 4ℓ0 = 9 ⇒ ℓ0 = 1.75m
27. ⃗ = −∇
F ⃗u⇒F
⃗ = 7î − 24ĵ
⇒ ma⃗ = 7î − 24ĵ-
7 24
⇒ a⃗ = î − ĵ
5 5
⇒ |a⃗| = 5ms−2
Further we have
⃗ =u
v ⃗ + a⃗t
7 24
⃗ = (2.4î + 11.2ĵ) + ( î − ĵ) 4
⇒v
5 5
28 96
⃗ = (2.4î + 11.2ĵ) + ( î −
⇒v ĵ)
5 5
28 96
⃗ = (2.4î + 11.2ĵ) + ( î −
⇒v ĵ)
5 5
⃗ = (2.4î + 11.2ĵ) + (5.6î − 19.2ĵ)
⇒v
⇒v
⃗ = 6î − 8ĵ
⃗ | = √62 + 82 = 10ms −1
⇒ |v

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28. By Law of conservation of Energy, we have
1
mv 2 + 0 = 0 + mgℓ(1 − cos θ)
2
θ
Since 1 − cos θ = 2 sin2 (2)
θ
⇒ v 2 = 2gℓ [2 sin2 ( )]
2
θ v
⇒ = sin−1 ( )
2 2√gℓ
v
⇒ θ = 2 sin−1 ( )
2√gℓ
29. Method – I
Since v = 2√x
⇒ v 2 = 4x
Comparing with
v 2 − 02 = 2ax
We observe that u = 0 and 2a = 4
⇒ u = 0 and a = 2ms −2

30. x0 + ut = vt
⇒ (8î + 8ĵ) + (4t)î = (aî + bĵ)t
At t = 4s, we get
⇒ 24î + 8ĵ = 4aî + 4bĵ
⇒ a = 6 and b = 2
31.

Velocity components in common tangent direction will remain unchanged while velocity
components in common normal direction are interchanged in case of an elastic collision.
Hence, both A and B move at right angles after collision with vA = 10√3ms −1 and vB =
10ms−1 . Kinetic energy is conserved in an elastic collision, whether it is a head on or an oblique
collision.
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32. For no motion Fapplied ≤ f(= μN)

⇒ F cos 6 0o ≤ μ(mg + F sin 6 0o )

F 1 F√3
⇒ ≤ (√3g + )
2 2√3 2
F
⇒2≤g ⇒ Fmax

33.

When relative motion stop, both blocks will move with same velocity v, momentum
conservation gives,
1 × 6 + 2 × 3 = 3v
⇒ v = 4m/s
Work done by friction on block = change in K.E.
1 1
(A) ⇒ Wf1 = 2 × 1 × (4)2 − 2 × 1 × (6)2 = −10J
1 1
(B) ⇒ Wf2 = 2 × 2 × (4)2 − 2 × 2 × (3)2 = 7J
(C) 4 × 2 − 3 × 2 = 2N − s
(D) Now total work done by friction = (−10 + 7) = −3J
 Total change in K.E. = −3J
∂U
34. F= = 2(x − 3)(2 − x) − (x − 3)2
∂x
7
F = −(x − 3)(7 − 3x) is zero at x = 3 and x = 3
∂2 U ∂F
− ∂x = +(1 − 3x) − 3(x − 3) = −6x + 4
∂x2
7 ∂2 U
(A) At x = 3 ∂x2 is +ve, U is minimum.
(B) For x = 2F is not zero.
∂2 U
(C) At x = 3 ∂x2 is −ve , U is maximum.

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35.

mv2H
(A) Tmin + mg = at highest point
R

v2 2
(B) a = √( R ) + g 2 = √802 + 102 = 10√65

v2H
(C) amin = = 60
R

(D) at = 0 at highest point

36. In car’s frame of reference
mv2min
m(2g) = ℓ

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PART – 3 : CHEMISTRY
37. 𝑃𝑉 = 𝑛𝑅𝑇
𝑅𝑇
⁡𝑃𝑉 = 𝑚 ⋅ ( 𝑀 )
𝑅𝑇0
State1 𝑃1 𝑉 = 𝑚, − (1)
𝑀
𝑅𝑇
State2 𝑃2⁡ V = 𝑚2 ( 𝑀0) − (2)
Δ𝑚 = (𝑚1 − 𝑚2 ) = mass of released gas.
Now
𝑅𝑇0 𝑅𝑇0
𝑃1 𝑉 − 𝑃2 𝑉 = 𝑚1 − 𝑚2
𝑀 𝑀
𝑅𝑇0
⇒ (𝑃1 − 𝑃2 )𝑉 = (𝑚1 − 𝑚2 ) ⋅
𝑀
𝑅𝑇0 Δ𝑃𝑉𝑀
⇒ Δ𝑃 ⋅ 𝑉 = Δ𝑚 ⋅ ⁡ ⇒ Δ𝑚 =
𝑀 𝑅𝑇0

𝑚 𝑚 𝑅𝑇 𝑅𝑇
We also know 𝑃𝑉 = 𝑀 𝑅𝑇 ⇒ 𝑃 = ⋅ (𝑀) ⇒ 𝑃 = 𝑑 ⋅ (𝑀)
𝑉
𝑀 𝑑
⇒⁡ =( )
𝑅𝑇 𝑃
𝑀 𝑑
Now Δ𝑚 = Δ𝑃 ⋅ 𝑉 ⋅ (𝑅𝑇 ) = Δ𝑃 ⋅ 𝑉 ⋅ (𝑝0)
0

0.8 × 3.0 × 1.25

Δ𝑚 = gm = 3⁡gm
1

38. First line is called α-line

Second line is called β-line
1 1 1
= R‾ H Z 2 [ 2 − 2 ]
λ n1 n2
For Balmer series, n1 = 2 and for β line n2 = 4
1 1 1 3
= R‾ H Z 2 [ 2 − 2 ] = R‾ Z 2
λB 2 4 16 H
For α-line n2 = 3 for same series
1 1 1 5
⁡ = R‾ HZ2 [ − ] = R‾ H Z 2
λB ⁡ ′ 22 32 36
′
λB ⁡ 3 36
= ×
λB 16 5
108
λB ⁡′ = 800 × 10−10 × ⁡ = 1080Å
80
λ2 1
39. = 2π
4π

150
λ = √2 = √ V

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42. 16σ + 4π Bond ⇒ 20

an2
45. [P + ] [v − nb] = nRT
v2

v = 12 a = 2.5 T = 240
n=2 b = 0.4 RT = 20
nRT an2
P = v−nb − v2
2×20 2.5×22
= 1−2×0.4 − 12
40 10
= 0.2 − = 200 − 10 = 190⁡atm
1
𝑃𝑉 190×1 190
𝑍 = 𝑛𝑅𝑇 = = = 4.75
2×20 40

(𝑍 > 1, repulsive forces dominant)

𝑎 2.5
𝑇𝑏 = 𝑅𝑏 = 0.082×0.4 ≈ 75 K

46. (a) r1 : r2 : r3 = 12 : 22 : 32 = 1: 4: 9
c 3×108
(c) λ = v = 6×1044 = 5 × 10−7 m = 500 nm
h 1
(d) λ = 2mE ⇒ λα m
1 1 1
∴ λH : λΠc : λcn4 = : : = 4: 2: 1
1 4 16
1
51. (A) V = KT = log⁡ V = log⁡ K + log⁡ T (B) TV = KT 2 = TV × =K
T2
1
log⁡ V = log⁡ K − log⁡ (T)
V nR
(C) (T) = K = (D) V = KT = VT = KT 2
P

54. (I) Cn H2n−4 O4 :- (P) 2 carboxylic acid (-COOH)

(Q) 2 alcohol (-OH) and 1 ether (R – O - R)

(R) 1 acid anhydride

(S) 2 aldehyde (-CHO) and 1 ketone

(T) 1 ester ( R - -OR’ ), 1 ketone ( ) and 1 aldehyde (CHO)

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(II) Cn H2n O3 :- (Q) 2 alcohol (-OH) and 1 ether (R – O - R)

(III) Cn H2n−2 O4 :- (P) 2 carboxylic acid (-COOH)

(Q)2 alcohol (-OH) and 1 ether (R – O - R)

(R) 1 acid anhydride

(IV) Cn H2n−6 O3 :- (P) 2 carboxylic acid (-COOH)
(Q)2 alcohol (-OH) and 1 ether (R – O - R)

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