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Paper / Subject Code: 50722 / Industrial & Engineering Chemistry I

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1T00533 - S.E.(Chemical Engineering)(SEM-III)(Choice Base Credit Grading System ) (R- 19) (C

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Scheme) / 50722 - Industrial & Engineering Chemistry I

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QP CODE: 10024724 DATE : 26/05/2023

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Time: 3 Hours Marks: 80

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N.B.: 1. Questions no. 1 is compulsory.

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2. Attempt any three questions from remaining five questions

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3. Figures to the right indicates full marks.

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Q1. Attempt any four questions of the following: 20

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a. Explain the moving boundary method for determination of transport number.

1
00
8

F7
AB

D2
3
What is CFSE? Calculate CFSE FOR d4 and d6 in octahedral complexes.

1
D3
b. F

2
B

A1
3

82

CB

51
8C

74
00
2

24
c. Explain briefly the principles of solvent extraction.
B

F0

D2
3
1
74

1F
3
E
CA

B2
0B
d. Differentiate between Transition and Intermediate.

4D
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51
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2A
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C
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AB

E2
e. Discuss the synthesis of Methyl orange with reaction

23
2A

B1
74

1D
D
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CB
8C
F

f. Related with chirality explain the following terms with examples-

1D

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2

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1

B
A

1
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3
3F

2E
CA
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2

(i) Plane of symmetry (ii) Centre of symmetry

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1

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2
1

E
A
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1C

0B
7

4D
2

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C
F

Q.2. a) What is EAN? Calculate EAN of [Ni(CO)4]. [05]

D
B2
0B

A1

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AB

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51

2E
C

F7
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4D
D2

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3

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1

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08
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b) Write short notes on- Separation of Lanthanides. [05]

4D

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3F
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5
1C

7
30
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D2

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3

8C
F

2
2
B
4D

B
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51

c). Discuss the synthesis of Alizarin with reaction. [05]

2A

4
0

CA
C

F7
0
F0

E2

23
23
1
3

1D
B
4D

A1

48
23

AB
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CB
00
8

d) What is the principle of conductometric titration? Explain weak acid- strong base
35

7
AB

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E2

8C
B1

1F
D3

1D
B2

titration, with help of graphical representation. [05]

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D2
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1F
3
F

E
A

2
0B
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51
8C
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2A

Q.3. a) Explain in detail, what is the effect of temperature on conductance. [05]

8

C
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AB

E2

23
2A

B1
74

1D
4D
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CB
C
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1D

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b) Write a note on optical isomerism of Lactic acid. [05]

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8

E2
A

B1
4

D3
F
CA

B2
7
2

23

2
1F
1D

00

c) Explain the geometrical isomerism in co-ordination compounds with respect to

8

1C
48

E2
2A

D3
F
A
35

0B
F7

82
C

co-ordination no 6. [05]
D

2
B2

24
A1

30
B

F0
1

2E
A
5
1C

F7

4D
D2

23
3

8C

d) Discuss inductive effect and hyperconjugation with suitable example to explain the
08
B2
0B

A1

AB

E2
51

3F
C

F7
2

82
23

stability of carbocation. [05]

8C
B1

B2
1

F0
B

74
00

CA
5
C

23

Q.4. a) Explain preparation,properties, and bonding involved in Fe (Co)5 [05]

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B1

F
D3

A1

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AB
CB

51
00
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F7

b) Describe following terms.

2
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1
D3
2E

1D
B

A1
B

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35
C

(i)Specific Conductance. (ii) Equivalent Conductance. (iii) Molar conductance [05]

2

D2
1

1F
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2
0B

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2A
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1C

c) Discuss R &and S system of Nomenclature. [05]

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3
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2E

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35
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d) Give mechanism and applications of Pinacol-Pinacolone rearrangement. [05]

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1
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2

08

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24724 Page 1 of 2
A1

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1D2A1F748CAB23F082E24D300B1CB235
8C
1F
 D2 CA 0B
2E 1D
A1
F7 B23 241C 2A
F D3 B2 1F
D2 08 48 00 35 74
CA 2E B1 1D 8C
A1
F7 B 2 2 4 C 2 A AB
3F D3 B2 1F
48 08 00 35 74 23
CA 2E B1 1 D 8C F0
82
1F B2 24 C B 2A A B2 E2
74 3F D3 23 1F 4D
8C 08 00 51 74 3 F0
2 B 8 30

24724
AB E2 1 CB
D2 C AB 8 2 0B
23 4D A1 E2 1C
F0 30 23 F7 23 4D B2
8C 82 0B 5 1 48 F 0 30 35
AB E2 1 D 2 82 0B
23 4D C B
CA
B E2 1
1D
C

(i) N
A1 2A
F0 30 23 F7 23 4D B2
82 0B 51 4 8 F 0 3 0 35 1F
E2 1C D 2 C 8 2 0 B 1 74
23 4 D B A A B E2 1C D 2
8C
F0 2 1 23 4 A AB ii) P
82
30
0B 35
1D
F7
4 F D3 B2
3 1 F 23
1 8C 08 00 51 74 F0
E2 C 2 A 2 B 1 D 8 82
4D A1 B E2 C 2 CA

Friedel-craft reaction.
30
B2
3 F 2 3 4 D B A 1 B E2
iii) K

0B 51 74 F0 3 2 3 F 23 4D
1C D2 8C 8 2
00 5 1 74 F 0 30
B2 A1 AB E2 B1 D2 8C 8 2 0B

d) What are the drawbacks of CFT?.

35 F7 23 4D CB A1 AB E2 1C
1D 48 F0 30 23 F 7 23 4D B2
2A CA 82 0B 51 4 8 F0 3 0 35
E2 1C D2 CA 82 0B 1D
1F B2 4 A 1 B E 2 1 C 2A
74 3F D3 B2
35 F7 2 3 4 D B2
8C 08 00 F 1F
(i) Na[Mn(CO)5] (ii) [Co (NH3)5Cl] Cl2

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AB B1
C C A 2 0 1 D
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23 24 B 2A
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C
8C

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F0 D3 2 F B2 24 B 2A AB
82 00 35
1D 7 4 3F D3 235 1 F 23
8C 08 00 74
b) Discuss the manufacture of ammonium sulphate.

B1 1 F0
E2
4D CB 2 A1 AB 2E2 B 1 D2 8C
23 23 4D CB AB

*************
30 F7 A1
51 4 F 3 2 3 F 23

1D2A1F748CAB23F082E24D300B1CB235
0B 08 5
b) Explain the role of following nutrients in plant growth-

8C 00 1 74 F0
1C D2
A A 2E B 1 D 8 C 82
B2 1F B2 24 CB 2A AB E2
35 7 3 D 23 1F 23
d) Explain oxygen transfer bio molecular reactions containing iron.

F0 30 7
is immiscible with solvent A.[The solute has molecular weight =71] .

1D 48 51 F0
CA 82 0B 48
2A E 1 C
c) Write the IUPAC names of the following co-ordination compounds-

B 2 D2 82
c) Discuss thermodynamically and kinetically controlled reaction wrt

1F 2 4 D CB A AB E2
74 3F 3 23 1F 2 4D
8C 08
2E
00
B1 5 1 74
8C
3F
08 30
2
Paper / Subject Code: 50722 / Industrial & Engineering Chemistry I

AB 2 D2
C A
Q.6. a) What is Nernst distribution law? Explain Continuous extraction in detail.

23 4D B2 A1 B2 E2
F0 30 3 F 3 4D
82 0B 51 74 F 0 30
E2 1 D2 8C 8 2 0B
4D CB A1 AB E2 1
30 23
51 F 7 23 4D
0B 48 F0 30
1C D2 CA 82 0B
Q.5. a) An extraction system has distribution of 10. if 30mg of solute is dissolved in 100 ml of

B2 A1 B E2 1C
[05]

23 4D
[05]

F7
[05]
[05]
[05]
[05]
[05]
solvent find out total amount of solute extracted by two extractions with 50 ml of solvent B which

35 B2
[05]

1D 48
CA
F0
8
30
0B 3
2A 2E 1C
1F B2 24 B2
74 3F D3