Scribd
Upload
31 views2 pages

Solution ws1

Uploaded by

l
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
31 views2 pages

Solution ws1

Uploaded by

l
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
You are on page 1/ 2

CBSE

NAME: GRADE: 12
SUBJECT: Chemistry SEC: J/L/M
TOPIC: Solution

Q1.Henry’s law constant for CO2 dissolving in water is 1.67x 108 pa at 298 K. Calculate quantity of Co2 in
1 Lt soda water when packed under 2.5 atm Co2 pressure at 298 K.
Q2.Heptane and octane form ideal solution. At 373 K, the vapour pressure of the two liquid components
are 105.2 KPa and 46.8 KPa respectively. What will be the vapour pressure of a mixture of 25 gm of
Heptane and 35 gm Octane ?
Q3. A solution containing 30 gm of a non-volatile solute exactly in 90 gm water has a vapour pressure of
2.8 KPa at 298 K. Further 18 gm of water is then added to solution. The new vapour pressure
becomes 2.9 KPa at 298 K. Calculate (a) molecular mass of the solute (b) vapour pressure of the
water at 298 K.
Q4. A solution containing 0.5126 g of naphthalene (MrWt 128) in 50.0 g of CCl4 gives a boiling point
elevation of 0.402ºC while a solution of 0.6216 g of an unkonwn solute in the same weight of the
same solvent gives a boiling point elevation of 0.647ºC. Find the molecular mass of unknown solute.
Q5. An aqueous solution freezes at -0.2ºC ( kf = 1.86ºC/m)
what is i) molality of the solution ii) Elevation in B.P ( kb = 0.152 C/m)
iii) Lowering in Vapour Pressure at 298ºk
Q6. An aqueous solution containing 5% by weight of urea and 10% weight of glucose. What will be its
freezing point (kfH2O = 1.86ºC/m) (iii) A 5% solution (by mass) of cane sugar in water has a freezing
point of 271 K.
Q7. Calculate the freezing point of 5% glucose in water if the freezing point of pure water is 273.15 K.
Q8. Two elements A and B form compounds having molecular formulas AB2 and AB4 when dissolved is
20g of C6H6, 1g of AB2 lowers the freezing points by 2.3 K where as 1 g of AB4 lower it by 1.3K, kb
(C6H6) = 5.1 k/m. Calculate the atomic mases of A and B
Q9. A decimolar solution of potassium ferrocyanide is 50% dissociated at 300K.Calculate osmotic
pressure of solution if R=8.314 JK-1mol-1.
Q10.Determine osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 litres of water
at 250C .
Q11.(i)Calculate the molarity and mole fraction of the solute in aqueous solution containing 3.0g of
urea per 250 ml of water
(ii) Calculate the molarity and molality of a 15% solution (by wieight ) of H2SO4 of density 1.02
g/cm3
(iii) Calculate the number of moles of methanol in 5 litres of its 2 molal solution if the density of the
solution is 0.981 kg/L

Few frequently asked questions in theory:

Q1. Define the terms: mole fraction, Molarity, Molality.


Q2.State the main advantage of molarity over molality as the unit of concentration.
Q3. What is the sum of the mole fractions of all the components in a three component system ?
Q4. What is the effect of temperature on molarity and molality of the solution?
Q6.(i)State Henry’s law and its application.
(ii) State the formula relating pressure of a gas with its mole fraction in a liquid solution in contact
(iii) At the same temperature hydrogen is more soluble than helium in water, then which gas will
have higher KH value and why
Q7. (i) How are vapour pressure and Boiling point related
(ii) Two liquids X and Y boil at 145ºC and 190ºC respectively which of them is more voltile or which
has more vapour pressure at 80ºc
(iii) It takes more time to cook food on hills than in plains why ?
(iv) When NaCl is added to water, s its effect to the vapour pressure
Q8.(i) How is Raoults law a special case of Henrys law; explain
(ii) State Raoults law for solution of non volatile solutes in volatile solvents.
Q9. (i)What are non Ideal solution, what are the conditions to be satisfied by non Ideal solutions, Give
examples.
(ii) Two volatile liqids A and B have pressure as PA and PB repectively and mole fractions as XA and XB
respectively then give the formula for total pressure of the system if they form an ideal solution
Q10. (i)Which type of solutions show negative deviation from Raoults law. (or)Role of molecular
interactions between chloroform & Acetone (or) Why is an increase in temperature observed on
mixing Phenol with Aniline
(ii) Which type of solutions show positive deviation from Raoultslaw (or) Role of molecular
interaction between C2 H5OH & H2O (or) Acetone is added to ethanol (or) CS2 is added to
Acetone explain what temperature change is observed.
11.(i) What is a Azeotrope, define and Give example of high boiling point Azeotropes and low boiling
point Azeotropes and correlate them to deviations from Raoults law.
12. (i).What is a semipermeable membrane and give one example each for a natural and artifical SPM.
(ii) Define osmotic pressure, and give the relation of osmotic pressure with concentration and
temperature.
(iii)Why osmotic pressure is the preferred method for the measurement of the molar
masses of proteins, polymers and macromolecules.
(iv) What is Hemolysis (or) What happens when blood cells are placed in water
(v). What is Plasmolysis. (or) When blood cells are placed in salt solution.
(vi) What is Reverse osmosis, and give its application.
13. Give reasons for the following a) NaCl (or) CaCl2 is used to clear snow from the roads. b) Ethylene
glycol is added to water in a car radiator while driving in hill station.
14. Are equimolar solution of urea and sodium chloride iso osmotic ? justify your answer.
15. The bottle of liquid ammonia is generally cooled before opening the seal why?
16. Define cryoscopic constant and ebulioscopic constant.
17. what is the trend in boiling point and freezing point of equimolar solution of urea, NaCl, K 2SO4 ,
K3[Fe(CN)6]
18. What happens to freezing point of a solution when mercuric iodide is added to an aq solution of KI?
19. Outer hard shell of two eggs are removed by placing them in dilute HCl. If one is kept in
pure water and the other in NaCl solution, what will be the observation?

You might also like