Neet and Jee

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CHEMISTRY WORKSHEET(NEET & JEE)

1.The relative lowering of vapour pressure produced by dissolving 71.5 g of a substance in 1000
g of water is 0.00713. The molecular weight of the substance will be
(a) 18.0 (b) 342 (c) 60 (d) 180
2.If two substances A and B have PA0 : PB0  1: 2 and have mole fraction in solution 1 : 2 then
mole fraction of A in vapours
(a) 0.33 (b) 0.25 (c) 0.52 (d) 0.2
3.Assertion : Azeotropic mixtures are formed only by non-ideal solutions and they may
have boiling points either greater than both the components or less than both the
components.
Reason : The composition of the vapour phase is same as that of the liquid phase of an
azeotropic mixutre.
(a) If both assertion and reason are true and the reason is the correct explanation of the
assertion.

(b) If both assertion and reason are true but reason is not the correct explanation of the
assertion.

(c) If assertion is true but reason is false.

(d) If the assertion and reason both are false.

4.The unit of molality is


(a) Mole per litre (b) Mole per kilogram (c)Per mole per litre (d) Mole litre

5.H2 S, a toxic gas with rotten egg like smell, is used for the qualitative analysis. If the solubility
of H2S in water at STP is 0.195 molal, calculate Henry’s law constant.
a) 2oo atm b) 280 atm c) 285.7atm c) 260 atm

6.The weight of H2C2O4 . 2H2O required to prepare 500 ml of 0.2 N solution is


(a) 126 g (b) 12 . 6 g (c) 63 g (d) 6 .3 g

7.For a solution of volatile liquids the partial vapour pressure of each component in solution is
directly proportional to
(a) Molarity (b) Mole fraction (c)Molality (d)Normality
8.The molarity of pure water is
(a) 55.6 (b) 5.56 (c) 100 (d) 18
9.Increasing the temperature of an aqueous solution will cause
(a) Decrease in molality (b)Decrease in molarity
(c)Decrease in mole fraction (d)Decreasein%w/w
10.The normality of 0.3 M phosphorus acid H3PO4 is
CHEMISTRY WORKSHEET(NEET & JEE)

(a) 0.1 (b) 0.9 (c)0.3 (d) 0.6


11.The sum of the mole fraction of the components of a solution is
(a) 0 (b) 1 (c) 2 (d) 4
12.The vapour pressure of pure benzene at a certain temperature is 0.850 bar. A non-volatile,
non-electrolyte solid weighing 0.5 g when added to 39.0 g of benzene (molar mass 78 g mol-1).
Vapour pressure of the solution, then, is 0.845 bar. What is the molar mass of the solid
substance?

a) 160 b) 170 c) 180 d) 130

13.Calculate the molarity of a solution containing 5 g of NaOH in 500 mL solution

a) O.35 b) 0.25 c) 0.025 d) 0.0025

14.If P o and P are the vapour pressure of a solvent and its solution respectively and N1 and
N 2 are the mole fractions of the solvent and solute respectively, then correct relation is

(a) P  P N 1 (b) P  P N 2 (c) P  P N 2 (d) P  P (N1 / N 2 )


o o o o

15.The solubility of a gas in water depends on


(a) Nature of the gas (b) Temperature (c)Pressure of the gas (d)All of the above
16.When the concentration is expressed as the number of moles of a solute per litre of solution it
known as
(a) Normality (b) Molarity (c)Mole fraction (d) Molality
17.When WB gm solute (molecular mass M B ) dissolves in WA gm solvent. The molality M of the
solution is
WB MB WB 1000 W A 1000 WA  M B
(a)  (b)  (c)  (d)
W A 1000 MB WA WB MB WB  1000

18.A molal solution is one that contains one mole of a solute in


(a 1000 gm of the solvent (b)One litre of the solvent
(c) One litre of the solution (d)22.4 litres of the solution
19.Which of the following is a colligative property
(a) Osmotic pressure (b) Boiling point (c)Vapour pressure (d Freezing point
20.The colligative properties of a solution depend on

(a) Nature of solute particles present in it (b) Nature of solvent used


(c) Number of solute particles present in it (d)Number of moles of solvent only
21.“The relative lowering of the vapour pressure is equal to the mole fraction of the solute.”
This law is called
(a) Henry's law (b) Raoult's law (c)Ostwald's law (d) Arrhenius's law
CHEMISTRY WORKSHEET(NEET & JEE)

22.When a substance is dissolved in a solvent the vapour pressure of the solvent is decreased.
This results in
(a) An increase in the b.p. of the solution (b)A decrease in the b.p. of the solvent
(c) The solution having a higher freezing point than the solvent
(d) The solution having a lower osmotic pressure than the solvent
23.Which one of the following is the expression of Raoult's law
p  ps n ps  p N p  ps N ps  p N  n
(a)  (b)  (c)  (d) 
p nN p N n ps N n ps N

p  vapour pressure of pure solvent


p s  vapour pressure of the solution
n  numberof moles of the solute
N  number of moles of the solvent
24.Which pair from the following will not form an ideal solution
(a) CCl 4  SiCl 4 (b) H 2 O  C4 H 9 OH (c) C2 H 5 Br  C2 H 5 I (d) C6 H14  C7 H16
25.Which property is shown by an ideal solution

(a) It follows Raoult's law (b) H mix 0 (c) Vmix 0 (d) All of these
26.In mixture A and B components show –ve deviation as

(a) Vmix  0 (b) H mix  0


(c) A-B interaction is weaker than A-A and B-B interaction
(d) A-B interaction is strong than A-A and B-B interaction
27.Azeotropic mixture are
(a) Constant temperature boiling mixtures (b)Those which boils at different temperatures
(c) Mixture of two solids (d)None of the above
28.When 6 gm urea dissolve in 180 gm H 2 O . The mole fraction of urea is
10 10 . 1
(a) (b)
10 . 1 10
10 . 1 0 .1
(c) (d)
0 .1 10 . 1
29.The molarity of a 0.2 N Na 2 CO 3solution will be
(a) 0.05 M (b) 0.2 M
(c) 0.1 M (d) 0.4 M
30.Which of the following is not a colligative property
(a) Osmotic pressure
(b) Elevation in B.P.
(c) Vapour pressure
(d) Depression in freezing point
CHEMISTRY WORKSHEET(NEET & JEE)

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