SAGAR PUBLIC SCHOOL

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SPARK BATCH
Integrated Programme

CLASS - IX

CHEMISTRY

ATOMS & MOLECULES

WORKSHEET
Level 2 I Exercise 1 (Fundamental Exploration)
1. What is the difference between permanganate ion and manganate ion? Write two compounds containing
these ions and also write their names. [ K]

2. Natw·ally occurrifig Boron consists of two isotopes whose atmoic masses are l 0.0 l and l l .0 l . The atomic
mass of natural Boron is 10.81. Calculate the percentage of each isotope in natural Boron. [NJ

3. Give the chemical formulae for the formulae for the following compounds and compute the ratio by mass
of the combining elements in each of them. [ C]
(a) Ammonia (b) Carbon monoxide (c) Hydrogen chloride (d) Aluminium fluoride
(e) Magnesium sulphide

4. A sample of ascorbic acid (vitamin C) is synthesized in the laboratory. It contains l .50 g of carbon and 2.00
g of oxygen. Another sample of ascorbic acid isolated from citrus fruits contains 6.35 g of carbon. How
many grams of oxygen does it contain? Which law are you assuming in answering this question? [ C]

5. Write the chemical formulas for the following compounds: [ C]

(a) copper! (I) oxide, (b) potassium peroxide, (c) aluminium hydroxide, (d) zinc nitrate, (e) mercury(I)
bromide, (t) iron (III) carbonate

6. Cinnabar (HgS) is a prominent ore of mercury. How many grams of mercury are present in 225 g of pure
HgS? Molar mass of Hg and Sare 200.6 g mor 1 and 32 g mor 1 respectively. [N]

Questions based on Mole concept

7. How many moles of sodium atoms correspond to 1.56 x 1<>2 1 atoms of sodium? [N]

8. How many moles of Al are in 2.16 mol of Al2O3? [N]

9. Calculate the following quantities: [N]

(a) mass, in grams, ofl.73 mol CaH2 (b) moles of Mg (N03) 2 in 3.25 g of this substance
(c) number of molecules in 0.245 mol CH3OH (d) number of H atoms in 0.585 mol CJ-110
10. Calculate the number of aluminium ions present in 0.051 g of aluminium oxide (Al 2O3).
(Atomic mass: Al= 27 u, 0 = 16u) [N]

11. How many grams of sodium will have the same number of atoms as 6 grams of magnesium? [N]
(Na= 23, Mg= 24).

12. How many gram of Chromium (molar mass Cr= 52 g/mol) are there in 85 g Cr2S 3? [N]

13. Which has more number of atoms : 100 grams of sodium or 100 grams of iron (Given atomic mass of
Na= 23 u and Fe= 56u) [N]

14. How many grams of silver are in 0.263 mol of Ag? [N]
lS. How many atoms are present in 1.00 x 10-9 g oflead? [N]
3
16. (a) What is the mass, in grams of 2.50 x 10- mol of aluminium sulphate? [N]
(b) How many moles of chloride ions are in 0.0750 g of aluminium chloride?
(c) What is the mass, in grams, of7.70 x 1020 molecules of caffeine, C8H 1oN4 0 2?
(d) What istlie molar mass of cholesterol if0.00105 mol weighs 0.406 g?
17. A sample of glucose, CJf12O6, contains 5. 77 x 1020 atoms of carbon. [N]
(a) How many atoms of hydrogen does it contain?
(b) How many molecules of glucose does it contain?
(c) How many moles of glucose does it contain?
(d) What is the mass of this sample in grams?
18. Calculate the volume occupied by 2.8 g of N2 at STP. [N]
19. Calculate the number of molecules present in 16.8 lt of gas 'X' at STP. Also determine its gram molecular
weight if the above sample weights 26.62S grams,
[N]
20. What is the volume occupied by 30. l x I 0 molecules of carbon dioxide gas at STP? Calculate the mass of
23
this
gas. [N]
21. Calcium chloride when dissolved in water dissociates into it ions according to the following equation:
[N]
CaC/i (aq) Ca2 + (aq) + 2c1- (aq)
Calculate the number of ions obtained from CaC/2 when 222 g of its is dissolved in water.

22. The difference in the mass of 100 moles each of sodium atoms and sodium ions is 0.0548002 g. Compute
the mass of an electron.
[N]
23. The mass of one steel screw is 4.11 g. Find the mass of one mole of these steel screws. Compare this
value
with the mass of the Earth (5.98 x 1024 kg). Which one of the two is heavier and by how many times?
[N]
24. The visible universe is estimated to contain 1022 stars. How many moles of stars are present in the
visible
universe?
[N]
25. Compute the difference in masses of 103 moles each of magnesiu m atoms and magnesiu m ions. (Mass
of
an electron= 9.1 x 10-31 kg)
[N]
26. Which has more number of atoms?
[N]
100 g of N2 or 100 g of NH3

27. Compute the number of ions present in 5.85 g of sodium chloride.

[N]
28. A sample of ethane (C2H6) gas has the same mass as 1.5 x 1020 molecules of methane (CH ). How many
4
C2H6 molecules does the sample of gas contain?
(N]
29. A person spends ten thousand rupees per second. How many years will it take approxim ately to spend one
mole of rupees?
(N]
30. In photosynt hesis, 6 molecules of carbon dioxide combine with an equal number of water molecules
through a complex series of reactions to give a molecule of glucose having a molecular formula C<,11
0 • 12 6
How many grams of water would be required to produce 18 g of glucose? Compute the volume of
water so
consumed assuming the density of water to be 1 g cm-3 •
[N]
Level 2 I Exercise 2
1. The atomicities of ozone, sulphur, phosphorus and argon are respectively: [K]
(A) 8, 3. 4 and 1 (B) 1, 3, 4 and 8 (C) 4, I, 8 and 3 (D) 3, 8, 4 and 1

2. If 1·4 g of calcium oxide is formed by the complete decomposition of calcium carbonate, then the
amount of calcium carbonate taken and the amount of carbon dioxide formed will be respectively: [N]
(A) 2.2 g and 1.1 g (B) I. I g and 2.5 g (C) 2.5 g and I. I g (D) 5.0 g and I. I g

3. Which of the following elements has the same molecular mass as its atomic mass? [A]
(A) nitrogen (B) neon (C) oxygen (D) chlorine

4. In hydrogen peroxide (H2O2), the proportion of hydrogen and oxygen by mass is: [C]
(A) 1: 8 (B) I: 16 (C) 8: 1 (D) 16: 1

5. Which of the following represents a correct chemical formula? (C]

(A) CaC/ (B) Na~ (C) NaSO4 (D)NaS

6. A particle X has 17 protons, 18 neutrons and 18 electrons. This particle is most likely to be: [L]
(A) a cation (B) an anion (C) a molecule (D) a compound

7. A particle P has 18 electrons, 20 neutrons and 19 protons. This particle must be: (L]
(A) a molecule (B) a binary compound (C) an anion (D) a cation

8. An ionic compound will be formed by the combination of one of the following pairs of elements. This
pair of elements is: [K]
(A) chlorine and calcium (B) calcium and sodium (C) sulphur and carbon (D) chlorine and chlorine

9. The percentage of hydrogen in H 20 is - [N]

(A) 8.88 (B) 11.12 (C) 20.60 (D) 80.0

10. Find the mass of oxygen contained in 1 kg of potassium nitrate (KNO3) [N]
(A) 475.5 g (B) 485.5 g (C) 475.2 g (D) 485.2g

10 11
11. Boron has two stable isotopes, B (19%) and B (81 %). The atomic mass that should appear for
boron in the periodic table is [N]
(A) 10.8 (B) 10.2 (C) 11.2 (D) 10.0

12. The value of amu is: [K]

27
(A) 1.57 X 10-24 kg '(B) 1.66 X 10- 24 kg (C) 1.99 X 10- 23 kg (D) 1.66 X 10- kg

Questions based on Mole concept

13. Which of the following pair of elements represents a mole ratio of 1: 1? [A]
(A) IO g of calcium and 12 g of magnesium (B) 12 g of magnesium and 6 g of carbon
(C) 12 g of carbon and 20 g of calcium (D) 20 g of sodium and 20 g of calcium

14. Which of the following correctly represents 360 g of water? [C]

(i) 2 moles of H 20 (ii) 20 moles of water
25
(iii) 6.022 x 1023 molecules of water (iv) 1.2044 x 10 molecules of water
(A) (i) (B) (i) and(iv) (C) (ii) and(iii) (D) (ii) and(iv)
 [L]
15. If 32 g of sulphur has x atoms, then the number of atoms in 32 g of oxygen will be:

X (C) x (D ) 4x
(A) - (B) 2.x
2
th
16. A student wants to have 3.011 x 1023 atoms each of magnesium and carbon elements. For is
purpose, be will have to weigh: [A]
(A) 24 g of magnesium and 6 g of carbon (B) 12 g of carbon and 24 g of magnesium
(C) 20 g of magnesium and l Og of carbon (D) 12 g of magnesium and 6 g of carbon
[C]
17. Which of the following has smallest mass -
(A) 4g of He (B) 6.022 x 1023 atoms of He
(C) l atom of He (D) lmole atoms of He

Which of the following has largest number of particles -

[C]
18.
(A) 8 g of CH4 (B) 4.4 g of CO2 (C) 34.2 g of C1 2H 22 0 11 (D) 2 g of H 2

19. How many moles of electron weight one kilogram - [N]

1 6 023 54 (D) l X 10
8
(A) 6.023 x 1023 (B) - -x 1031 (C) · x 10
9.108 9.108 9.108 x 6.023

20. 25.4 g of iodine and 14.2 g of chlorine are made to react completely to yield a mixture of ICI and IC/3.
Calculate the ratio of moles of ICI and IC/3 [N]
(A) l : 1 (B) 2 : 1 (C) 3 : 1 (D) 1 : 2

21. 0.001 g of C is required to write a letter with a graphite pencil. The total number of C atoms used in
writing the letter is - [A]
12 19 24 23
(A) 5.oo x 10 (B) 5 x 10 (C) 5.o x 10 (D) 6.023 x 10

22. 1 mol of CH4 contains [L]

(A) 6.02 x 1023 atoms of H (B) 4 g atom of Hydrogen

23
(C) l.8lxl0 molecules of CH4 (D) 3.0 g of carbon

23. The mass of a molecule of water is: [A]

26
(A) 3 X 10- kg 26
(B) 3 X 10- kg
25
(C) 1.5 X 10- kg
26
(D) 2.5 X 10- kg
24. How many mole of Helium gas occupy 22.4 L at 0°C at 1 atm. pressure. [C]
(A) 0.11 (B) 0.90 (C) 1.0 (D) l. 11

7
25. Volume of a gas at STP is 1.12 x 10- cc. Calculate the number of molecules in it [N]
(A) 3.01 X 1020 (B) 3.01 X 1012 (C) 3.01 X ID2 3
(D) 3.01 X 1024

26. Which one of the following pairs of gases contains the same number of molecules [A]
(A) 16gof 0 2 and 14gof N2 (B) 8gof 0 2 and22gof CO2
(C) 28 g of N2 and 22 g of CO2 (D) 32 g of 0 2 and 32 g of N2

27. Number of gm of oxygen in 32.2 g Na2 S04 .1 0H2O is [N]

(A) 20.8 (B) 22.4 (C) 2.24 (D) 2.08

28. The volume occupied by 4.4 g of CO2 at STP is [N]

(A) 22.4 L (B) 2.24 L (C) 0.224 L (D) 0.1 L
 HINTS AND SOLUTION Level 2 EXERCISE 1
Sol.l: Permanganate ion is Mno; and Manganate ion is Mno;-
Thus, both have same formula but different valencies.
Example of compound containing. permanganate ion = KMn0
4.
Name = Potassium permanganate
Example of compound containing manganate ion = K Mn0
2 4
Name = Potassium manganate

Sol.2: Suppose percentage of isotope with atomic mass l 0.0 I = x

Then percentage of isotope with atomic mass I 1.01 = 100-x
. xx 10.01+(1 00-x)x11 .01
:. average atomic mass = ------- '---.;._ ___
100
10.0lx+ 1101-1 l.0lx 1101-x
=
100 100
1101-x .
:. - - = l0.8l(g1v en)
100
or 110 I - x = 1081 or x = 1101 - 1081 = 20
:. % of isotope with atomic mass 10.01 = 20%
% of isotope with atomic mass 11.01 = 80%

Sol.3: Chemical formula Ratio by mass

(a)NH3 N : H = 14 : 3
(b) CO C: 0 = 12: 16 = 3 : 4
(c) HCl H: Cl = l : 35.5
(d) AlF3 Al: F = 27: 57 (At mass of Al= 27, At mass of F= 19)
(e) MgS Mg : S = 24 : 32 = 3 : 4

Sol.4: 8.47 g 0, the law of constant composition

Sol.5: (a) Cu20 (b) K202 (c)Al(O H)J (d) Zn (N03)z

(e)HgBr (f) Fe2 (C03)3

Sol.6: Molar mass of HgS = (200.6 + 32) g mor1 = 232.6 g mor 1

Thus, 232.6 g of HgS contain Hg= 200.6 g
200.6
:. 225 g of HgS will contain Hg= _ x 225 g = 194.045 g.
232 6
 Questions based on Mole concept
Sol.7: 2.59 x 10-' mole No

2 1
Sol.8: No. of mol of Al =(2.16 mol A/2O3 )( mot / ) =4.32 mot Al
1 molA 20 3

Sol.9: (a) 72.8 g CaH2

(b) 0.0219mol Mg(NO3)i
(c) 1.48 x 1023 CH3OHmolecules
(d) 3.52 x t&4 H atoms
Sol.I 0: The mass of an aluminium ion is the same as that of an aluminium atom. First of all we have to find out the
mass of aluminium atoms in 0.051 g of aluminium oxide (which will give us the mass of aluminium ioos)
1 mole of A/2O3 = Formula mass of A/203 in grams
= 27 X 2 + }6 X 3 = 54 + 48
= 102grams
Now, 1 mole of A/20 3 contains 2 moles of Al.
So, Mass of Al in 1 mole of A/2O3 = Mass of Al x 2
=27 X 2
= 54grams
Now, 102 g alwninium oxide contains = 54 g Al
54
Now, 0.051 g aluminium oxide contains = -x0.051g Al 0.027 g Al
102
The atomic mass of aluminium = 27u.
Now, 27 g of aluminium has ions = 6.022 x 1023
6 022
So, 0.027 g of aluminium has ions = · x 0.027 = 6.022 x 1020 ions
27

Sol.11: Nwnber of moles of magnesium=~ = mol !

24 4

:. Number of moles of sodium should also be !

4

:. mass of i mol Na will be= 23 x i = 5.57 g

Sol.12: Molar mass of Cr2S3 = 52 x 2 + 32 x 3 = 200 g

:. 200 g Cr2S3 contains 2 mol Cr or 2 x 52 = 104 g Cr
104
:. 85 g Cr2S3 contain x 85 = 44.2 g Cr
200 .
 (.) N be f sodium
So.I 13 : 1 um r O atoms of Na = - - - - x/\vogadro number
Molar mass
100
= 23 '<6.022 X 1021 = 2.6 J 8 x 1024

(ii) Number of atoms of Fe

100
= 56 X 6.022 X 1023 = J.075 X 1024

100 g of Na contains more number of atoms than 100 g of Fe.

Sol.14: Mass of Ag = (0.263 mol Ag) ( I o7 .9 g Ag) == 28 .4 A

Imo[ Ag g g

9
Sol.IS: No of atoms of Pb l .OO x I0- gPb 23
· = _ g Pb x6.022xI0 Atoms
207 2
= 2.906x 1012 Atoms

Sol.16: (a) 0.856 g A/2 (S04)3 (b) 1.69 x 10-3 mole er

(c) 0.248 g CsH1oN402 (d) 387 g cholesterol/mol

Sol.17: (a) 1.15 x 1021 H atom

19
(b)9.62 x 10 C£1[12O6 molecules
(c) 1.60 x 10--4 mol C£1[12O6
(d) 0.0287 g C£1/1206

Sol.18: Molecular weight of N 2 = 2 x 14 = 28 g

28 g of N 2 at STP occupies = 22.4 L
2.8 g of N 2 at STP =?
28 gof N 2 = 22.4L, 2.8 gof N2 =?

22.4x 2.8g = _ L
2 24
28g

2.8 g of N2 at STP occupies a volume of 2.24 L.

Sol.19: Volume of the given gas= 16.8 / at STP

Number of moles present in that volume= 16.8 / 22.4 = 0.75 moles
23 23
Number of molecules in 0.75 moles= 0.75 x 6.023 x 10 = 4.52 x 10
Weight of0.75 moles of the gas X = 26.625 grams
Gram molecular weight of'X' =Weight/No. of moles= 26.625/0.75 = 35.5 grams

23
Sol.20: Number of molecules = 30.1 x 10
23
30.1 X 10
Number of moles of gas = 23
= 5 moles
6.023xl0
Volume occupied by 5 moles of gas = 22.4 x S = 112 /
Mass of the given gas = Number of moles x GMW = S x 44 = 220 g
Sol.21: Molar mass of CaC/2 =40 + 2 x 35.5 - 40 71 - 111 g mol 1

i.e., 111 g of CaC/2 = 1 mole of CaC/2

:. 222 g of CaCl2 ,.... 2 moles of CaC/2
= 2 x 6.022 x 1023 formula units of CaCl2
= 12.044 x I023 formula units of CaC/2
But 1 formula unit of CaC/2 contains 1 cd ion and 2 CT1 ions.
:. 12.044 x 1023 formula units of CaC/2 will contain 12.044 x 1023 Ca2 + ions and 2 x 12.044 x io23,
i.e., 24.088 X 1023 er ions.
Total ions present = ( 12.044 + 24.088) x l 023 = 36.132 x l 023 .

Sol.22: 100 moles of Na atoms contain Na atoms = 100 x 6.022 x 1023 = 6.022 x 1025
l 00 moles of Na + ions contain Na +ions= 100 x 6.022 x 1023 = 6.022 x l 025
Each Na + ion is formed from Na atom by loss of 1 electron.
Thus, each Na + ioo has 1 electron less than that present in Na atom.
Hence, difference in the number of electrons in l 00 moles of Na atoms and I 00 moles of Na + ions
= 6.022 X 1025 ,
i.e. mass of 6.022 x Io25 electrons= 0.0548002 g
0.0548002
:. mass of I electron = =9.1 x 10-28 g
6.022 X 1025

SoL23: I mole of steel screws= 6.022 x 1023 screws

Mass of I screw= 4.11 g
:. Mass of 1 mole of screws= 4.11 x (6.022 x 1023 ) g
= 24.75 X 1023 g
24.75 xl023 k = 24.75 x 1020 k
1000 g g

= 2.475 X 1021 kg
Mass of earth = 5.98 x 1024 kg
Thus, earth is heavier than 1 mole of the given screws.
Mass of earth 5.98 x1024 = 2xl03 = 2000
Mass of 1 mole of screws 2.475xl0 21

i.e., Mass of earth is 2000 times the mass of 1 mole of the given screws.

Sol.24: I mol of stars= 6.022 x 1023 stars

i.e., 6.022 x 1023 stars = I mole of stars

1
1022 stars = 23 x 1022 moles =0.0166 mole
6.022x10
 3 6
Sol.2S: 10 moles of Mg ::itoms - 10' '< 6.022 x Hi' - 6.022 x 1()7 Ml{ aloms
3 21 1
10 moles of M.,'! ions - 10 x 6.022 x 1026 = 6.022 x 10 Ml( •ions
26

One M..e.2 • inn is funned from Mg atom by loss of 2 electrons

i.e. Difterence in the mass of 1 Mg atom and I Mg2 +ion == Mass of 2 electrons
:. Difference in the mass of 6.022 x 1026 Mg atoms and Mg2 +ions
== Mass of 2 x 6.022 x 1026 electrons
26
== 2 x 6.022 x I 0 x 9.1 x 10-31 kg (Mass of electron == 9. l x I0- kg)
31

5
== 108.516 x 10- kg = 1.08516 x 10-3 kg = 1.08516g.

Sol.26: 1 mole of N2 == 6.022 x 1023 molecules of N 2

= 2 x 6.022 x 1023 atoms of N
== 28g
Thus, 28 g of N 2 has atoms == 2 x 6.022 x 1023
2 X 6.022 X 1023
:. 1OOg of N 2 has atoms = - - - - - x 1 0 0 = 0.430 x l 0
25 = 4.30 x 1024
28
1 mole of NH3 = 6.022 x 1023 molecules of NH3
= 4 x 6.022 x 1023 atoms of N and H (as each molecule of NH3 has 4 atoms)
== 17 g
23
Thus, 17 g of NH3 has atoms == 4 x 6.022 x 10

4x 6.022x 1023
:. 100 g of NH3 has atoms == - - - - - x 100
17
= l.416x 1025 =14.16x 1024
Hence, 100 g of NH3 has more atoms than that present in 100 g of N2•

SoL27: 1 mole of NaCl== 23 + 35.5 g == 58.5 g of NaCl

23
= 6.022 x 10 formula units of NaCl
23
Thus, 58.5 g of NaCl have 6.022 x 10 formula units of NaCl
:. 5.85 g of NaCl will have NaCl formula units

6.022 X 1023 X 5.85 = 6.022 X} 022

58.5
Each formula unit of NaCl contains I Na +ion and I er ion.
22
:. 6.022 x 1022 formula units of NaCl will contain 6.022 x 10 Na +ions and 6.022 x ta22 er ions.
22 22
Total ions= 2 x 6.022 x 10 == 12.044 x 10 .