Cl
F 10; SO24 100; NO3 50
NO3 SO24 NO3
SO24
h uv
O H(g) Cl(g) Cl(g) CF2 Cl(g)
ClO(g) O(g) Cl(g) O2 (g)
H 3C–C–OONO2
O
(4) in the stratophere, CFCs release chlorine free radicals (Cl)
(Cl)
UV
Cl (g) CF
Cl(g)
2
(ClO) )
(ClO 2
O (g) ClO(g)
Cl(g) O2 (g)
3
740 ºC
10H2 O
Hydrolysis
Excess NH
3
low temperature
hydrolysis
,
H2O
condensati on
Me Me Me Me Me
| | | | |
Cl — Si — Cl OH — Si — O H OH — Si — OH OH — Si — O — Si — OH .
H2O
| | | | |
Me Me Me Me Me
| | |
CH – OH CH – O O – CH
| | B |
CH – OH CH – O O – CH
| | |
2
2–
Sr C2
Na
heated
ti tan ium metal filament
10H2O
OH
H
Column-I Column-I
(A) Silica gel (i) Transistor
(B) Silicon (ii) Ion-exchanger
(C) Silicone (iii) Drying agent
(D) Silicate (iv) Sealant
B2 H6 O2
B2 O3 H2O
B2 H6 H2 O
H3 BO3 H2
673K
Catalyst
1270 K
Ni
1270K
1273K
CO(g) H 2 O(g)
673K
catalyst
CO 2( g) H 2(g)
CH 4(g) H 2 O (g)
1270K
Ni
CO(g) 3H 2(g)
C (s) H 2 O ( g) CO ( g ) H 2( g)
1270 K
2C(s) O2(g) 4N2(g)
1270K
2CO(g) 4N 2(g)
CH 4 H 2 O CO 3H 2 both reactions are carried out at
C3H 8 H 2 O 3CO H 2 1270K temp. with Ni catalyst
CaO, BaO = Basic Nature
B2O 3, SiO2 = Acidic Nature
N2O = Neutral oxide
(3) SiO
Me Me
| |
— O — Si — O — Si — O —
| |
O O
| |
— O — Si — O — Si — O —
| |
Me Me
R
–(Si–O)–n (R=Me)
R
H 3 N3 B3 Cl3 3LiBH 4
In tetrahydrofurane
(T.H.F.)
H3 N3 B3 H3 3LiCl
(B)
Inorganic Benzene 3BH 3 .THF
(A)
(Borazene)
H 3 N 3 B3 Cl3 3CH 3 MgBr H 3 N 3 B3 (CH 3)3 3MgBrCl
(A) ( C)
H
H 90 H
2 B 1 B
H H
H
2 > 1
20 12
I I I I I I I I
Ans. (C)
Sol.
1
2
(liquid)
[ C C ]2
Column I Column II
(i) Na2CO3·10 H2O (P) Portland cement
ingredient
(ii) Mg(HCO3)2 (Q) Castner-Keller
process
(iii) NaOH (R) Solvay process
(iv) Ca3 Al2 O6 (S) Temporary
hardness
2Mg O2
2MgO
3Mg N 2
Mg 3N 2
393K 1 3
CaSO 4 .2H 2 O CaSO 4 . H2O H 2 O
Gypsum 2 2
Plaster of paris
All alkali metal hydrogen carbonate exist in solid state except LiHCO
[M(NH3 )x ] [e (NH3 )y ]
M(g ) (x y)NH3
~ 30 times
3Mg + N2 Mg3N2
(
(A) (B)
6H2O
3Mg(OH)2 + 2NH3
colourless gas
CuSO4 + 4NH3 [Cu(NH3)4]SO4
deep blue solution
3NaH 2 PO 2
(X)
H3 PO2
( Y)
O
P (mono basic acid)
HO H
H
S.No. Column I S.No. Column II
(I) Ca(OH)2 (A) casts of statues
(II) NaCl (B) white wash
1
(III) CaSO 4 . H 2O (C) antacid
2
washing soda
(IV) CaCO3 (D)
preparation
1
2
List-I List-II
(Salt) (Flame colour
wavelength)
(a) LiCl (i) 455.5 nm
(b) NaCl (ii) 670.8 nm
(c) RbCl (iii) 780.0 nm
(d) CsCl (iv) 589.2 nm
Colour /nm
Li Crimson red 670.8
Na Yellow 589.2
Rb Red violet 780.0
Cs Blue 455.5
CaCl 2 .6H 2O CaCl 2 6H 2 O
(Anhydrous)
MgCl2 .8H2 O MgO 2HCl 6H 2O
MgO
CaO
All are basic oxide
SrO
BaO
573K
O O 2
+ +
K Mn 2K Mn
O O O O
O O
Tetrahedral Tetrahedral
unit unit
diamagnetic paramagnetic
1
H2O
2
1
H2O
2
(B) 2KO
Not To Be Discussed in Class
Not To Be Discussed in Class
H4
(A) Al(OH)Cl
Hydrolysis
Excess NH
3
low temperature
Hydrolysis
Hydrolysis
2B 3O 2
B2 O3 (white powder)
2B N 2
2BN (white powder)
'A' 'B'
2H3BO3 heat
strongly
B2O3 3H 2O
'C' 'E '
on
s tan ding
3HCl
Si2O76
CH3
Cu powder |
2 H2 O
HO – Si – OH
570 ºC – 2HCl
|
CH3
CH3 CH3 CH3
|
nHO – Si – OH HO Si O Si O
– n H2 O
|
CH3 CH3 n
CH3
linear silicone
(thermoplastic polymer)
1400 º C
Na 2B 4 O 7 .10H2 O Na 2B 4 O 7 Na 2B 4 O 7 2HCl 2NaCl H2B 4 O 7
red hot
H2B 4 O 7 5H2O 4H3BO 3 2H3BO3 B 2O 3 3H2O
Boric acid Boric anhydride
Fusion
B 2O 3 3Mg 2B 3MgO
10H2O
10H2O
ether
3NaBH 4 4BF3 3NaBF4 2B 2H6
100
B 2H6 2NH3 B 2H6 .2NH3
tempt .
o
200 C
B 2H6 .2NH3
B 3N3H6 H2
2B 6HNO3 (or H2 SO 4 ) 2H3BO 3 6NO 2
4H3BO 3 Na 2CO 3 Na 2B 4 O 7 6H2 O CO 2
p p
COOH
P4 O10
CH2
C3O2 (Carbon suboxide) + 2H2O
COOH
10 H2O
BF
Statement
Not To Be Discussed in Class
1
2
1
2
) )
1 1
2 2
1
2
(C)
Al (SO )
2 43
aq.
CaCO3
NH3 + H2O
H2O CaO + CO2
B
A NaHCO3 + D NaCl
C + H2O
NH3+ H2O + E
SO 2 Na CO elemental S 2
2
3
H2 O
I I
Statement-II
