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    Chemistry Assignment

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    pearlsharma0430

    Copyright:

    © All Rights Reserved
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    Chemistry Assignment

    Uploaded by

    pearlsharma0430
    8 views2 pages

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    chemistry assignment

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    8 views2 pages

    Chemistry Assignment

    Uploaded by

    pearlsharma0430

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    1. Why does molality of a solution remain unchanged with temperature while molarity changes?

    (or) Why is it advantageous to use molality over molarity?

    2. Why are aquatic species more comfortable in cold water in comparison to warm water?

    3. Which solution is more concentrated 1 m or 1M. why?

    4. Two liquids boil at 145°C and 190° respectively. Which one has a higher vapour pressure at
    80°C?

    5. If at same temperature, hydrogen is more soluble in water than Helium, which of them will
    have higher KH value?

    6. ) Predict the products of electrolysis in each of the following:


    (i) An aqueous solution of AgNO3 with platinum electrode.

    7.State Kohlrausch’s law of independent migration of ions. Mention one


    application of Kohlrausch’s law

    8A and B on mixing produced a warm solution. What type of deviation is there and why? (or) Why is
    an increase in temperature observed on chloroform and acetone.

    9. When 30 ml of ethyl alcohol and 30 ml of water are mixed, the volume of resulting solution is
    more than 60 ml. Explain

    10. Calculate the time to deposit 1.27 g of copper at cathode when a


    current of 2 A was passed through the solution of CuS04.
    (Molar mass of Cu = 63.5 g mol-1, 1 F = 96500 C mol-1)
    11. The conductivity of 0.20 mol L-1 solution of KC1 is 2.48 X 10-2 S cm-1.
    Calculate its molar conductivity and degree of dissociation (a). Given
    X,°(K+) = 73.5 S cm2 mol-1 and Z°(cr) = 76.5 S cm2 mol-1.
    12. The resistance of 0.01 M NaCl solution at 25 °C is 200 Ω. The cell
    constant of conductivity cell is unity. Calculate the molar conductance.
    13. 1.. The solubility of gases increases with increase of pressure. William
    Henry made a systematic investigation of the solubility of a gas in a liquid.
    According to Henry’s law “the mass of a gas dissolved per unit volume of
    the solvent at constant temperature is directly proportional to the
    pressure of the gas in equilibrium with the solution”. Dalton during the
    same period also concluded independently that the solubility of a gas in a
    liquid solution depends upon the partial pressure of the gas. If we use the
    mole fraction of gas in the solution as a measure of its solubility, then
    Henry’s law can be modified as “the partial pressure of the gas in the
    vapour phase is directly proportional to the mole fraction of the gas in the
    solution”.
    (i) Henry’s law constant for the solubility of methane in benzene at 298
    K is 4.27 × 105 mm Hg. The solubility of methane in benzene at 298 K
    under 760 mm Hg is
    (a) 4.27 × 10–5 (b) 1.78 × 10–3 (c) 4.27 × 10–3 (d) 1.78 × 10–3
    (ii) The partial pressure of ethane over a saturated solution containing
    6.56 × 10–2 g of ethane is 1 bar. If the solution contains 5.00 × 10–2 g of
    ethane then what will be the partial pressure (in bar) of the gas?
    (a) 0.762 (b) 1.312 (c) 3.81 (d) 5.0
    (iii) KH (K bar) values for Ar(g), CO2(g), HCHO(g) and CH4(g) are 40.39,
    1.67, 1.83 × 10–5 and 0.413 respectively. Arrange these gases in the order
    of their increasing solubility
    . (a) HCHO < CH4 < CO2 < Ar (b) HCHO < CO2 < CH4 < Ar (c) Ar < CO2 <
    CH4 < HCHO (d) Ar < CH4 < CO2 < HCHO
    (iv) When a gas is bubbled through water at 298 K, a very dilute
    solution of the gas is obtained. Henry’s law constant for the gas at 298 K
    is 150 K bar. If the gas exerts a partial pressure of 2 bar, the number of
    millimoles of the gas dissolved in 1 L of water is
    (a) 0.55 (b) 0.87 (c) 0.37 (d) 0.66

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