RPT 1 M Sol.
RPT 1 M Sol.
RPT 1 M Sol.
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SOL01JPRPT1041223-C1-1
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Academic Session: 2023-24
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SOL01JPRPT1041223-C1-2
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Academic Session: 2023-24
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SOL01JPRPT1041223-C1-3
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Academic Session: 2023-24
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SOL01JPRPT1041223-C1-4
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ANSWER KEY (AK)
PAPER
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans. 2 4 3 1 3 4 2 4 2 3
PART-A: Q.No. 11 12 13 14 15 16 17 18 19 20
PHYSICS Ans. 1 1 1 3 2 3 2 1 1 1
Q.No. 21 22 23 24 25 26 27 28 29 30
Ans. 0015 0015 0060 0020 0080 0003 0050 0200 0015 0003
Q.No. 31 32 33 34 35 36 37 38 39 40
Ans. 3 3 2 4 2 1 3 4 3 3
PART-B: Q.No. 41 42 43 44 45 46 47 48 49 50
CHEMISTRY
Ans. 2 1 3 4 1 2 3 2 3 1
Q.No. 51 52 53 54 55 56 57 58 59 60
Ans. 0001 0002 0005 0003 0336 0040 0101 0003 0023 0003
Q.No. 61 62 63 64 65 66 67 68 69 70
Ans. 4 4 3 1 4 2 3 4 1 1
PART-C: Q.No. 71 72 73 74 75 76 77 78 79 80
MATHS Ans. 3 3 2 1 4 4 1 3 3 3
Q.No. 81 82 83 84 85 86 87 88 89 90
Ans. 0000 0032 0002 0011 0006 0008 0025 0004 0006 0054
STUDENT'S SPACE
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SOL01JPRPT1041223-C1-5
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TEXT SOLUTIONS (TS)
/kjkry fojkekoLFkk ij gS rFkk O;fDr dkj ds lkFk
PAPER iwoZ fn'kk esa xfr dj jgk gSA
u2 sin2
6. R=
g
R u2
u 2 sin2
If a v 0 speed will increase.
R g
= 4 cot If velocity V = 0 , t1 < t < t2
7.
H u 2 sin2 V
Hence; acceleration a = =0;
2g t
t1 < t < t2
dx dy Therefore if the velocity is zero for a time
8. 2ct and vkSj 2bt interval, the acceleration is zero at any
dt dt
instant within the time interval.
Speed pky = (2ct)2 (2bt)2
dv
[acc, a = v = u + at ]
9. (2) 16 m dt
Now , v = 0 a = 0 a = – u/t
10. Ground is at rest and person is moving with acceleration may not be zero when vel.
car in east direction. 'V' = 0, 'c' is incorrect.
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SOL01JPRPT1041223-C1-6
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600 km/h
27. 5m/s t t
h1 d/2 10m/s 15m/s
u=20 m/s
d
arg. velocity =
= ut = 60 m. d/ 2
2t
5
24. Assume initial speed is u d
u u = 10t + 15t
then u î ĵ 2
2 2 d = 50t
at 2 sec d
2t =
u u 25
v î g 2 ĵ
2 2 d d
avg velocity =
2 2 d/ 2 d = 1 1
u u d
Given v = 20 = 2g 5 25
10 25
2 2
250 50
u2 u2 40u 40 = =
400 = 400 ; u2 u0; 35 7
2 2 2 2 x 50
=
40 40 7 7
u u 0 u = 0 or u m/s
2 2 x = 50
u2 (sin2 ) 28. V2 – u2 = 2as
Maximum height =
2g 0 – (20)2 = 2 × a× 500
2 400
40 1 – = a a = – 0.4m/s2
1000
2 2 (20)2
= = 20 m (–ve sing tells that direction of acceleration
2g 20 is opposite to direction of velocity)
For train -2
25. V2 – u2 = 2as
v2 – (20)2 = 2 × (–0.4) × 250
v2 = 400 – 200 = 200
v = 200 m/s
x = 200
29.
5m/s
u s in 30
2 2 2 2
u s in 60º
H1 , H2
2g 2g
10m
u2 3u 2
H1 , H1 5m/s
8g 8g
vy
4u2
H1 H2 = 80 m Vy = 2gh 2 10 10 10 2 m/s
8g
26. 750 m v Vx2 Vy2 200 25 = 15 m/s
1000 m 30. | r | = 16 – 8 + 16 – 8 = 16
Vm VMR distance = 16 + 8 + 16 + 8 = 48
Ans. 1/3
Vr --------------------------------------------------------------
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SOL01JPRPT1041223-C1-8
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PART-B: CHEMISTRY 35. PTotal 168 0.68 280 0.32 203.84 torr
PTotal observed 376 mm
31. On addition of non volatile solute, freezing Pobserved PTheoretical , H ve
point decreases.
Entropy of solution is more than entropy of
pure solvent. 107
36. (1)
gy. vok"Ik'khy foys; feykus ij fgekad fcUnq es deh 2
vkrh gSA
37. A – III ; B – I ; C – IV ; D – III
foy;u dh ,UVªkWih 'kq) foyk;d dh rqyuk esa
vf/kd gksrh gSA 38.
Mixture Nature of
32. Mole fraction of solution
740 (1) Benzene + Toluene Ideal
N2 (XN ) 105 solution
2
7.4 107
(2) Acetone + Chloroform Negative
1000 deviation
Since molarity of H2O is
18 (3) Chloroethane + Ideal
n n Boromoethane solution
XN
2 n 55.55 55.55 (4) Ethanol + Acetone Positive
deviation
or, n = 5.55 10–4 mol.
so, Volume at S.T.P. gy.
= 5.55 10–4 22400 = 12.44 ml. feJ.k foy;u dh izÑfr
gy. N2 dh eksy fHkUu (1) csUthu + VkywbZu vkn'kZ foy;u
740 (2) ,slhVksu + DyksjksQkWeZ _.kkRed fopyu
N2 (XN ) 105
2
7.4 10 7 (3) Dyksjks,Fksu + czkseks,Fksu vkn'kZ foy;u
1000 (4) ,FkkukWy + ,slhVksu /kukRed fopyu
pwafd H2O dh eksyjrk
18
n n 39. The total vapor pressure = PH2O Pair
XN
2 n 55.55 55.55 1.2 = PH2O Pair
;k, n = 5.55 10–4 mol. PH2O = mole fraction of H2O × Ptotal
blfy,, S.T.P. ij vk;ru PH2O = 0.02 × 1.2 = 0.024
= 5.55 10–4 22400 = 12.44 ml. PT = PH2O + Pair
33. Given that : Tf = –8ºC so Tf = 8 1.2 = 0.024 + Pair
Pair = 1.176 atm
Tf = i × Kf × m
2 gy. dqy ok"inkc = PH2O Pair
8=1×2×
Wsolvent 1.2 = PH2O Pair
W solvent (as liquid) = 500 g. PH2O = H2O dh eksy fHkUu × Ptotal
so weight of ice separated = 500 gm. PH2O = 0.02 × 1.2 = 0.024
gy. fn;k x;k gS : Tf = –8ºC so Tf = 8
PT = PH2O + Pair
Tf = i × Kf × m
2 1.2 = 0.024 + Pair
8=1×2× Pair = 1.176 atm
Wsolvent
W solvent ¼nzo
ds :Ik esa½ = 500 g. 40. 98% by wt.
blfy, i`Fkd gksus okyh cQZ dk nzO;eku i.e. 98 g H2SO4 present in 100 g of solution
= 500 gm. w(g) 1000
M=
Mw v(ml)
34. (4) Svap of solvent from solution < Svap of gy. 98% Hkkj vuqlkj
pure solvent vFkkZr~ 100 g foy;u esa 98 g H2SO4 mifLFkr gSA
(4) foy;u esa foyk;d dh Sok"i < 'kq) foyk;d w(g) 1000
dh Sok"i M=
Mw v(ml)
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SOL01JPRPT1041223-C1-9
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m 1 18 than that of toluene. As a result the vapour
41. xB = = = will contain a higher percentage of Benzene.
1000 1000 1018
m 1 csathu ds mPp vkaf'kd ok"i nkc ds dkj.k bldk
MA 18
eksy fHkUu vf/kd gksrk gSA blfy, ok"i esa csathu
PA0 – PA
= xB dh izfr'krrk vf/kd gksxhA
PA0
PA 18 47. Al2(SO4)3 2Al+3 + 3SO4–2 i=5
1– = xB =
PA0 1018 K4[Fe(CN)6] 4K+ + [Fe(CN)6]–4 i = 5
PA 18
1– = in
12.3 1018 48. RLVP =
in N
PA 18 1000
=1– = 2n
12.3 1018 1018 So (vr%) , 0.167 =
180
12.3 1000 12300 2n
PA = = = 12.08 kPa. 18
1018 1018 So (vr%) n=1
42. p = (i1C1 + i2C2 + i3C3) RT
49. (3) Statement (A) and (C) are correct while
= (2 × 0.065 + 3 × 0.02 + 1.2 × 0.05) × 0.08
the statement (B) is incorrect. It's correct
× 300
form is as follows: Total vapour pressure
= (0.13 + 0.06 + 0.06) × 0.08 × 300 = 6 atm.
over the solution varies linearly with the
mole fraction fo component 2.
43. 1 2
gy. (3) dFku (A) rFkk dFku (C) lgh gS tcfd dFku
i 0.004 = 0.01
(B) xyr gSA bldk lgh :i fuEu gSA foy;u dk
0.01
i= = 2.5 i = 1 + (n – 1). dqy ok"i nkc ?kVd 2 ds eksy fHkUu ds lkFk js[kh;
0.004
1.5 :i ls ifjofrZr gksrk gSA
= = 0.75 = 75%
2
50. (1) Two different solutions of sucrose of
same molality prepared in different solvents
44. p = iCRT
will have the same depression in freezing
i is same for all & temp. is same
point.
p conc.
since w/w % is same for all
(1) fofHkUu foyk;dksa esa cus leku eksyyrk
So, conc. is higher for those having lower ds lqØkst ds nks fofHkUu foy;u fgekad esa leku
mol wt. voueu j[ksxsaA
SO, highest osmotic pressure is for 1% NaCl
w/w. 51. (0001)
gy. p = iCRT 52. (0002)
i lHkh ds fy, leku gS rFkk rki leku gS 53. (0005)
p lkUnzrk 54. (0003)
pwafd lHkh ds fy, w/w % leku gS 55. PºA for benzene = 280 mm of Hg
vr% fuEu v.kq Hkkj j[kus okys ds fy, lkUnzrk PºB for octane = 420 mm of Hg
mPp gksrh gSA nA 3
vr% 1% NaCl w/w ds fy, mPpre ijklj.k nkc nB 2
gksrk gSA According to Raoult’s law
P = PAo X A PBo XB
45. Greater tha value of KH for a gas, lesser is
3 2 840 840
its solubility in water. So, order of solubility = 280 × + 420 × =
of gases in water is- 5 5 5
Ar < CO2 < CH4 < HCHO 1680
= = 336 mm Hg
gy. xSl ds fy;s KH dk eku vf/kd gksus ij ty esa 5
bldh foys;rk de gksrh gSA blfy;s ty esa xSlksa gy. csUthu ds fy;s PºA = 280 mm of Hg
dh foys;rk dk Øe fuEu gS% vkWDVsu ds fy;s PºB = 420 mm of Hg
Ar < CO2 < CH4 < HCHO nA 3
nB 2
46. Due to high partial vapour pressure of
Benzene as compare to that of toluene so jkÅUV ds fu;e ds vuqlkj
the mole fraction of Benzene will be higher
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SOL01JPRPT1041223-C1-10
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P = PAo X A PBo XB Pº Ps w M
59.
3 2 840 840 Ps m w
= 280 × + 420 × =
5 5 5 Pº 2.8 30 18
……. (1)
1680 2.8 m 90
= = 336 mm Hg
5
Pº 2.9 30 18
……. (2)
56. Relative lowering in vapour pressure 2.9 m 108
P0 – PS nB from equation (1) & (2)
= ¼lehdj.k (1) rFkk (2) ls½
P0 n A nB
M = 23 g/mol
nB = mole of solute
nA = mole of solvent
assuming dilute solution 60. Tƒ = kƒ × m
nA >> nB 5 1000
(Tƒ)A = kƒ × ;
P0 – PS nB MA 95
let P0 = 100
5 1000
P0 nA (Tƒ)B = kƒ ×
Ps = 80 MB 95
100 – 80 8/M ( Tƒ )A M 3
= = B = = 3.
100 114 / 114 ( Tƒ )B MA 1
M = molar mass of solute = 40
gy. ok"inkc esa vkisf{kd voueu --------------------------------------------------------------
0 S
P –P nB
=
P0 n A nB PART-C: MATHEMATICS
nB = foys; ds eksy
61. n(A B C) = n(A) + n(B) + n(C) – n(A
nA = foyk;d ds eky
B) – n(B C) – n(A C) + n(A B C)
ruq foy;u ekU; ij n(A B C) = 10 + 15 + 20 – 5 – 6 –
nA >> nB 10 + 5 = 29
0 S
P –P n n A B C = 21
0
B let P0 = 100
P nA
Ps = 80 62.
100 – 80 8/M
=
100 114 / 114 x 20-x-y
43-x-z
M = foys; dk eksyj nzO;eku = 40 5
z y
–4 3 1
3 10 70. 3 cosx + 5 sinx cos x
2 2
2 3
7
Case – 2 When 0 < x + <1 5 3
= sinx cos x 19, 19,
2 2 2
7 5
x a = – 19 , b = 19
2 2
2
x7 3 71. f(x) 9 sin2 x 16cos2 x 10(3 sinx 4 cos x)
1 and x 7,
2 x 3 2 10(3 sin x 4 cos x ) 100
25sin2 x 60sinx 84
3 x 10x 4 and x 7,
3
2x 3 2 2 (5 sinx 6)2 48
The minimum value of f(x) occurs when sin
10 3
x –x and x 7, x = 1.
3 2 f(x) dk U;wure eku gksxk tc sin x = 1.
x
Therefore, the minimum value of f ( x ) is 7.
So x ,
5 10 3
f (x ) dk U;wure eku 7 gSA
2 3 2
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SOL01JPRPT1041223-C1-12
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32
cosA + cos2A + cos3A = 0 2cos2A cosA 96. sin
72. s in2 5 A 33
= 96 5 =
+ cos2A = 0 2 s inA
1 32 sin
cos2A = 0 or cosA = 33
2
3 5 7 96. sin – 96. sin
A = , , , or =
33
= 33 = 3 Ans.
4 4 4 4
2 4 32 sin 32 sin
A , 33 33
3 3
2x 2x
1 sinx 78. 91 tan 9 tan 10
73. = 2cosx 1+sinx = 2–2sin2x
cos x 9 2
y 10 (where 9 tan x y )
2sin2x + sinx –1 = 0 y
1 1 5 So, 9 + y2 = 10y
sin x = 1, sinx= x = ,
2 2 6 6 y2 –10y + 9 = 0
(y – 1)(y – 9) = 0
74. 16cos A . cos 2A . cos22 A . cos23 A tan 2 x tan 2 x
So, 9 1 & 9 9
2
sin24 tan2x = 0 tan2x = 1
sin2 4 A 15
= 16 4 =
2
2 sinA sin
15
32 x=0 tan x = 1 tanx = –1
sin
=
sin
15 = 1
2
15
x x
4 4
log3 a log3 a
75. log3 a Now =
log3 x log3 x 1
tan
x 0
2
tan2 tan2 tan2
log3 x 1 log3 x
2
3 3 12 12
2
log3 x 3log3 x 1 0
2
= 2 tan
12
The roots of above equation are log3 x1 and
2
log3 x2 = 22 3
nh xbZ lehdj.k ds ewy log3 x1 rFkk log3 x2 gS
log3x1 + log3x2 = 3 x1x2 = 27 =
274 3
= 14 – 8 3
1
76. Let f(x) = cos22x – 2sin4x – 2cos2x ( – 14) 2 32
2 6
1 cos2 2x
= cos22x – 2 – 1 cos 2x
2 79. 26 sin
2
261– sin
2
16 t 64 16
= cos22x – t
where t 26 sin
2
1
1 2 cos 2x cos2 2x – 1 cos 2x t2 – 16t + 64 = 0
2
t = 8 26 sin 23
2
1 3
= cos 2x –
2
1 1
2 2 sin2 = sin =
cos22x [0,1] 2 2
1 1 3 5 7
cos2 2 x 0, , , , as [0,2]
2 2 4 4 4 4
1 3 3
cos2 2x – – ,– 1
2 2 2
77. Let =A
33
96cosAcos2Acos22Acos23Acos24A
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SOL01JPRPT1041223-C1-13
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Number of solutions in [0, ] is 4
2
Now n(S) +
S sin 4
so number of solutions in [–4, 4] = 32
1 1
2 x= or x=
2 4
= 4 2 1
1
1
1
but x should be natural number and greater
cos cos 3 cos 5 cos 7
than equal to 2 so, no value of x can be
=–4 possible
81.
1
1
log3 + log4 = log 27 x 3
2x
1
1
log10 3 2x log10 4 log10 27 31/ x 4
1
1
log10 4. 3 2x log10 27 31/ x
integral value of m for four solns. m = 0
1
1
4. 3 2x 27 31/ x gy- y = |x2 - 6|x| + 5| dk vkjs[k gS
123
1/ 2 x
= 27 + 31/ x
Let 31/ 2x = 2
12t = 27 + t2
t2 – 12t + 27 = 0
t=3 or t=9 4
1/ 2x
3 =3 or 31/ 2x = 9
1
0< n – 5 < 12
12 n 5 0
/4
• /2
•3/4 5 < n < 8.5 1.5 < n < 5
0 5/4
–1/2 • • {6,7,8} n{2, 3, 4}
number of values of n = 6
period of cosis
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SOL01JPRPT1041223-C1-14
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86. (2a)na = (b,c)nb 4 4
tan2 = tan 1 tan 1 tan 2
bn2 = anc 3 3
….. (1)
na(n2 + na) = nb (nb + nc)
Now 1+2 = tan 1 tan 2 = 1 …… (2)
…… (1) 2
n2. nb = nc.na ……..(2) Let tan1 = m1 and tan2 = m2 and 2 is the
1
nb.nb.n2 largest
(na)2 – (nb)2 = – n2na
na 4
So m1 + m2 = , m1 m2 = 1
3
na2 – nb2 1 n2 0 1
na m2 = 3 , m1
3
n2
1 0 1
na Now area of CAB = AB.AB tan30º =
2
a=
1
3 2 3 AB = 3 3
2 Now perimeter of CED = CD + DE + CE
AB + AB tan 60+ AB Sec60º
equation (2) n2 .nb = nc.(–n2)
= AB 1 3 2
nb = –nc
bc = 1
3 3 3 3 = 6
6a + 5bc = 3 + 5 = 8
190
90. n(M) = = 95
5 3 15 3 15 5 2
87. cos cos cos cos 2n
2 2 2 1 2 2 190
n(P) = = 63
2n 3
5 2n n
5 190
n n(C) = = 27
10 2n 5 7
5
P C
p
5
5 p 5 M
=
8 5 1 – 5 1 16
4
5 –1 4
DE BE AC
89. tan=
CD AB
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SOL01JPRPT1041223-C1-15
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SOL01JPRPT1041223-C1-16
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