Amt 1 Soln.

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DIVISION: JEE (MAIN+ADVANCED)

COURSE COURSE
CLASS XII VIJETA JP
NAME CODE
01JAZP,01IP 01JP,03JP,
PHASE TOTAL BATCH
01JP,03JP, 20 JP03PAH1,05JP,
CODE(S) PAGES CODE(S)
JP03PAH1,05JP, 01JAZP,01IP

JEE (MAIN+ADVANCED) 2024

TEST TEST CODE &


TEST TYPE
PATTERN SEQUENCE

JEE MAJOR TEST
AMT 01
(ADVANCED) (MT) 

01st December 2023 | Friday

Paper-1 : 3 Hrs | 9:30 AM to 12:30 PM


Paper-2 : 3 Hrs | 2:30 PM to 5:30 PM

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ANSWER KEY (AK)
PAPER-1
Q.No. 1 2 3 4 5 6 7 8 9 10

Ans. AB BCD ACD B A D D 1839 0003 0197


PART-I : MATHEMATICS
Q.No. 11 12 13 14 15 16 17
Ans. 0008 0030 0002 D A C C
Q.No. 18 19 20 21 22 23 24 25 26 27
Ans. ABD AD ABCD AD A D C 0006 0004 0008
PART-II : PHYSICS
Q.No. 28 29 30 31 32 33 34
Ans. 0008 0004 0005 B A C D
Q.No. 35 36 37 38 39 40 41 42 43 44
Ans. ABC ABD ABC B B A C 0000 0003 0500
PART-III : CHEMISTRY
Q.No. 45 46 47 48 49 50 51
Ans. 0007 0006 0015 B A A B
PAPER-2
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans. C C A B AD ACD AC 0001 0008 0002
PART-I : MATHEMATICS
Q.No. 11 12 13 14 15 16 17
Ans. 0027 0005 0011 49.00 18.00 01.00 08.00
Q.No. 18 19 20 21 22 23 24 25 26 27
Ans. D B A C ABD ABCD ACD 0024 0015 0003
PART-II : PHYSICS
Q.No. 28 29 30 31 32 33 34
Ans. 0005 0002 0009 01.46 00.86 03.00 12.00
Q.No. 35 36 37 38 39 40 41 42 43 44
Ans. C C A B AB ACD ACD 0002 0006 0008
PART-III : CHEMISTRY
Q.No. 45 46 47 48 49 50 51
Ans. 0003 0010 0041 01.00 05.00 02.00 10.00

STUDENT'S SPACE

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TEXT SOLUTIONS (TS)
PAPER-1 Case-l; If a1 =1 
1

1

1

5
a2 a3 a 4 6
PART-I: MATHEMATICS 18
If a2 = a3 = a4 a  3.5
5
1. Let ekuk P(ABC) = P(ACB) = a
 Possibilities for a2 = 2, 3
P(BCA) = P(BAC) = b
P (CAB) = P(CBA) = c
P(AB) = P(ABC) + P(ACB) + P(CAB)
2
= 2a + c =
3 a2 = 2 a2 = 3
P(BC) = P(ABC) + P(BCA) + P(BAC)
1
= a + 2b = 1 1 1 1 1 1
2    
P(AC) = P(ABC) + P(ACB) + P(BAC) a3 a 4 3 a3 a 4 2
2 3a 3
= 2a + b = a4 = not possible
3 a3  3
5 1 1 a3 = 4 , a4 = 12
Solving gy djus ij a  ,b ,c
18 9 9 a1 = 1, a2 = 2, a3 = 4, a4 = 12
5 2 a4 – a2 = 10
P( A )  2a  P(B)  2b  1 1 1 4
9 9 Case-II: a1 =2    
13 a 2 a3 a 4 3
P(CB)  a  c  c 
18 9
5 If a2 = a3 = a4  
P(AB  AC)  P(ABC)  P(ACB)  2a  4
9 Not Possible
2 2 4
P(AB) .P( AC)  . 
3 3 9 1 
 P( AB  AC )  P(AB ) .P(AC ) 4. We note that a0 = = cos . If an-1 =
2 3
hence they are dependent. vr% os ijra=k gSA

cosn,0 < n–1< , then
2
x
2. f(x) = , x  1
x 1 1  a n 1 1  cos n 1    
an    cos2  n 1   cos n 1 
f2(x) = f f x  
x 2 2  2   2 
2x  1   
So, 0n =  n 1  . Since 0= , it follows
f3 (x) = f f2 x  
x
 2  3
3x  1

…………………….. that n =
x 3  2n
fn(x) =
nx  1   
1  cos 
f1(–2). f2(–2)….. fn(–2) =
lim 4n 1  an   lim  3  2n  
  2   2   2   2  n  n  1
   ......  
  2  1   4  1   6  1    2n  1  4n
2n x2
=
1.3.5..... 2n  1 2
lim 18  4 
n

Ans. (A) n 1 18


4n
1 1 1 1 11
3.     x2
a1 a 2 a3 a 4 6 (since 1 – cosx ~ ,x  0 )
2
24
If a1 = a2 = a3 = a4  a1 =  2.2
11 5. Let common difference = d
 Possibilities for a1 = 1, 2 a4 = a1 + 3d  30
If d = 1 a1  27
 number of possible arithmetic
progression a1, a2, aз, a4 is 27
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d = 2 a1  24  number of possible 40150 = 1+50 x 400+
arithmetic progression a1, a2, aз, a4 is 24 50  49  50 
50
 50  50
 4002  
 400n  196020001  400n 
d = 3 a1  21  number of possible 2 n 3  n  n 3 
n

arithmetic progression a1, a2, aз, a4 is 21]  50 



 400n is divisible by
50
Note that
……………………………………………. n3 
n
…………………………………………….
1000000. It follows that 40150 ends in
20001.
d = 9 a1  3  number of possible
arithmetic progression a1, a2, aз, a4 is 3 9999


 No of ways = 3 + 6 +9 +…….27 1
10. Let S 
= 3 (1+2+3+….+ 9) n2 n
= 3.
9.10
 135  2 n 1 – n   2

1

2
2 n 1 n n n  n –1

6. We verify by induction that f(x + k) =



= 2 n – n –1 
 2 <   
9999
1 1
f(x), k  0. Indeed, for k = 0 this is 2 10000 –  2 9999 – 1
2k n2 n
obvious. If the result is true for k, then 9999 1 
f(x + k + 1) = f x  k   k1 f x  .
1 1   
  197
 n2 n 
2 2
n 1 1 Alternate method
f x dx    f x  k dx 
n
Hence, an   0
k 0
0 Compare the sum with the integral of
1
x
n 1 n 1

 2  f x dx  f x dx 2
1 1 1 1 9999 9999
1 1 dx
 
n 9999

k 0
k 0 0
k 0
k
n2 n n2
n1 x
dx  
1
x

 2 9999  2  2.100  2  198
 f x dx 2  2 f x dx,
1 1 1
lim an =
n 0 k 
0 9999
1 9999 n 1 1 dx
 
k 0 10000

n2 n n2
n x
dx  
1
x
1 2n r 1 2n 1
2n
 2n
1     2 10000  2 2  200  2 2  197
7.  r   
2n
r
2n


1 n r 1 n n r 1 r
lim
r 1  r 1 r
 lim r 1 r 1 r  lim n Hence, the integer part of the sum is 197.
n  n n  2n(n  1) n  1
4 r 2(1  )
r 1 n
2 2 11. 2a + 2b – 2c = 144 = 24. 32
1 3 1

 xdx  x
dx 2. 2
2 .2.2 2
8
 2a–4 + 2b–4 –2c – 4 = 32
 0 0
 3  c = 4 2a –4 + 2b–4 = 10  2a–5 + 2b–5 = 5
2 2 3 a– 5 = 2 b–5=0
a = 7, b=5
8. let f(1) is taken after leaving x1 numbers a+b–c = 12 – 4 = 8
from left
f(2) is taken after leaving 19 + x2 12. Let t1 letters between z and y, t2 letters
numbers from f(1) between y and x & t3 letters after x
f(3) is taken after leaving 19 + x3 numbers t1 t2 t3
from f(2) z y x
…………………………………………………
………… t1 < t2
after f(10) x11 numbers are left t1 + t2 + t3 = 23
x+ 9× 19 + x2 + x3 + …….. + x11 = 2000 t2 = t1 + x + 1
– 10 t1 + x + t3 = 22 t1, x, t3  0
x+ x2 + x3 + …….. + x11 = 1819 , xi 0 x+ t3 = 22–2t1, 0 t1 11
Required number of ways = 1829C10 Required number of ways
11

9. By the binomial formula,   23  2t .23!


t1 0
1
50
 50 
40150  400  1
50
   n 400
n 0
n
= (23)!.(12×23–2.
11
(1+11))
3
Consider first three terms separately. = (23)! (12)2 = 6 (24)!

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d  dy  x
13. x  = log x OA : y = ;k, x – 2y = 0 …(i)
dx  dx  2
OB : y = 3x ;k, 3x – y = 0 …(ii)
dy (i) ij (2, 1) rFkk (ii) ij (1, 3) gSA
x = xlog x – x + c  (1)(–1) = 0 – 1 + c
dx fcUnq (a, a2) dks.k AOB ds vUnj fLFkr gS ;fn
c=0 (2, 1) rFkk (a, a2) js[kk (ii) ds ,d gh vkSj fLFkr gS
dy
x = xlog x – x  dy = (log x – 1) dx rFkk (1, 3) vkSj (a, a2), (i) ds leku vksj fLFkr gS
dx
;fn 6 – 1 rFkk 3a – a2 leku fpUg ds gS rc
 y = x logx – x – x + c1  c1 = 3
1 – 6, a – 2a2 ds leku fpUg gSA
so blfy, p = 2
 3a – a2 > 0 vkSj a – 2a2 < 0
 a2 < 3a vkSj a < 2a2
14.  a < 3 vkSj 1 < 2a [a > 0 pwfd x > 0]
A 1
(P) vFkkZr~ ;fn <a<3
2
y =0
x-2  1 25 3
(2,1) =  and 2µ = 3 µ =
O (a,a2 ) 25 2 2 2
(1,3)
3x- 75
y=0  µ = = 18.75
4
B
(Q)
Given lines are A(0, 0)

x
OA : y = or, x – 2y = 0
2
x + 2y – 5 = 0
…(i)
OB : y = 3x or, 3x – y = 0 3x – y – 10 = 0
…(ii)
We take a point (2, 1) on (i) and (1, 3) on
(ii).
(a, a2) lies inside the angle AOB if (2, 1) B (x, y)
C
and (a, a2) lie on same side of (ii) and (1, 3)
Point C will be image of A in 3x – y – 10 = 0
and (a, a2) lie on same side of (i) i.e. if 6 – 1
and 3a – a2 have the same sign. and 1 – 6 fcUnq C, A dk js[kk 3x – y – 10 = 0 esa izfrfcEc
and a – 2a2 have the same sign. gksxkA
 3a – a2 > 0 and a – 2a2 < 0 x0 y0   10 
  2 
 a2 < 3a and a < 2a2 3 1  10 
 a < 3 and 1 < 2a [a > 0 as x > 0]  C  6,2
1 Image of A in x + 2y – 5 = 0 lie on BC
i.e. if <a<3
2 x + 2y – 5 = 0 esa A izfrfCkEc] BC ij fLFkr
 1 25 3
gksxkA
=  and 2µ = 3 µ = x0 y0  5
25 2 2 2   2  
75 3 1  5 
 µ = = 18.75  x, y  2,4
4
gy-
A 6 3
 mBC  
y =0 4 2
x-2
3
O
(2,1)
(a,a2 )   1 .5
(1,3) 2
3x-
y=0
B
nh xbZ js[kk,¡

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(R) h2 = 169 – 25 = 144 3 3 
h =12 coordinates of P be   t 2 , 3t 
2 2 
coordinate of M are (0, 3t)
8 8 3 3
h MP = + t2& MS = 9  9t 2
2 2
2
3 3  9
x 9 + 9t2 =   t 2   (1 + t2)2
5 5 5 2 2  4
5 5 4 = 1 + t2
Length of side = 6
x + r + 8 =12  3
x2 = (5+r)2 – 25 =25 + r2 + 10r – 25 gy- y2 = 6  x  
 2
x = r 2  10r 3 3
fu;rk x  =  x=0
r + r 2  10r = 4 2 2
r2+10r = 16+ r2 – 8r 3 3 2 
P ds funsZ'kkad   t , 3t 
18r = 16 2 2 
16 8 M ds funsZ'kkad (0, 3t)
r= =
18 9 3 3 2
MP = + t vkSj MS = 9  9t 2
2 2
(S) Family of circle S + L = 0 2
o`Ùkksa dk fudk; S + L = 0 3 3  9
9 + 9t2 =   t 2   (1 + t2)2
S1  (x – 3) (x – 6) + (y – 7) (y – 5) +  (2x  2 2  4
4=1+t 2
+ 3y – 27) = 0
x2 + y2 + x(2 – 9) + y (3 – 12) + Hkqtk dh yEckbZ = 6
(53 – 27) = 0
common chord of family of circle and given (R)
circle is S1 – S2 = 0 (S2 given circle)  b2 
  ae,  are the extremities of the latus
fn, x, o`Ùkksa ds fudk; dh mHk;fu"B thok  a
S1 – S2 = 0 (S2 fn;k x;k o`Ùk) rectum having positive ordinates which lies
(–5x – 6y + 56) +  (2x + 3y – 27) = 0 on parabola
which represents family of lines passing  b2 
23   ae,  ukfHkyEc ds fljs gS ftldh
through the point  2,
23   a
 a = 2, b =
 3  3 dksfV;ka] /kukRed gS ijoy; ij fLFkr gSA
 23  x2 = – 2 (y – 2)
fcUnq  2, 3  ls xqtjus okys js[kk fudk; dks
   b2 
a2 e2 = – 2   2  ….. (i)
23  a 
O;Dr djrk gS a = 2, b =
3 b2 = a2 (1 – e2) ……..(ii)
from (i) and (ii)
15. (i) vkSj (ii) ls
(P) Let ekuk y = mx a2 e2 = – 2 (a(1 – e2) – 2)
5y = 2x2–9x + 10 = – 2a + 2ae2 + 4
5mx=2x2–9x +10 a2 e2 = – 2ae2 + 2a – 4 = 0
2x2 – x (9 + 5m) +10 = 0 has roots  and  ae2 (a – 2) + 2 (a – 2) = 0
 2x2 – x (9 + 5m) +10 = 0 ds ewy  vkSj gSA (a – 2) (ae2 + 2) = 0
9  5m a=2
 +  =77
2 (S) Homogenizing chord
9 + 5m = 154
xcos   ysin   p , with hyperbola
5m = 145
M = 29 vfrijoy; dks thok xcos   ysin   p ds
 3 lkFk le?kkr cukus ij
(Q) y2 = 6  x  
 2 x 2 y 2  x cos   y sin  
2
   0
3 3 16 18  p 
Directrix x  =  x=0
2 2 angle is 90°,

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dks.k 90° gSA (x  2 sin x)  x 2  2 sin x  1  sin2 x  x  1 
1

1

 cos2   sin2   0  lim
x 0 x 2  2 sin x  1  sin2 x  x  1
2(x  2 sin x)
16 18 p2  lim
 p =  12
x 0 x  x  2 sin x  sin2 x
2

 2(1  2 cos x) 23


Radius of circle = 12  lim  2
 o`Ùk dh f=kT;k = 12 x 0 2x  1  2 cos x  2 sin x cos x 3
Diameter nwjh = 24
--------------------------------------------------------------
16.
(P) From graph. Two solutions PART-II: PHYSICS
vkjs[k ls nks gy
1/2 hc  dn 
Intensity  
A  dt 
18.

1/4 dh A
O  , since photocurrent in both the
dt hc
5 case is same,
sinn
2  sin  5  355   0 1
So  = same      '  2
(Q) 5   
sin  2 
hc hc
2 KEmax = evst  –  , 5eV  –
(R) range of cos2x – sinx is [–1, 5/4]  
cos2x – sinx dk vkjs[k [–1, 5/4] gSA hc
12eV  –  , solving we will get  = 2
so 3 integers /2
blfy, 3 iw.kkZad eV

19. for   0, xL  0 and xc 


17. for  , xL   and xc 0
1  cos 2x
(P) lim
x 0
2
ex  ex  x b
20. Temperature of Sun’s core is T =
2 sin 2 x m
 lim
x 0
2 Rate of energy radiated by Sun = (4R2)
2 xe x  e x  1 4
4 cos 2 x  b  m 2
 lim   = c
x 0
2
4x 2 e x  2e x  e x
2

 m t
4 1 4 =
  4 net energy obtained from conversion of m ass of Hydrogen in Sun’s core
0  2 1  1 1 total time.
(Q) b
1/ x lw;Z ds xHkZ dk rkieku T =
 (3 / x)  1  m
lim  
x 0  (3 / x)  1  lw;Z }kjk mRlftZr ÅtkZ dh nj = (4R2)
 1  (3 / x)  1  
4
 b  m 2
 exp  lim    1    = c
 x 0 x  (3 / x)  1   
 m t
 2x  gy. Power radiated by sun (lw;Z }kjk mRlftZr
 exp  lim e
2/3
p+q=5
 x  0 x( 3 – x)   b 
4

'kfä) = P = () (4R2)  


 m 
1
(1  x2 )1/ 3 – (1– 2x) 4
(R) im im Intensity falling at earth ( i`Foh ij vkifrr
x 0 x  x2 x 0
 1 1   ()(4R2 )(b / m )4
 4 – 1
rhozrk) =
 2   
4d2
 ....  –  1–    4x 2  .... 
x x 4
 1   
 3  2 2!  4
  1  R2   b 
  = S=  2   
xx 2 2  d   m 
x  2 sin x
(S)  lim
x 0
x  2 sin x  1  sin2 x  x  1
2

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21. the solution i(t) = 29. For equation P0A + kx = Pf A where x =
cost  
V0

 1 
2 2V0  V0
R2   L   = 10 m
 C  A
is actually a steady state solution which is get Pf = 2P0
valid after a long time( t   ), not valid for Pi Vi Pf Vf
=
just after switching on( t  0 ) Ti Tf
P0 V0 ( 2P0 ) (2 V0 )
22. 13.06 eV is gap between n = 1 and n = 5,
T0 = Tf  Tf = 4T0
so the electron will transit from n = 1 to n = 5
nh Note : In this question, heat given to the
Angular momentum of electron L  gas can also be asked, from Ist a law of TD.
2
1 f
(1)h (5)h Q = W gas + U= P0V + kx2 + n RT
Li  ,L  2 2
2 f 2 25
125
  Q = 1.2 × 104 J + To used R =
2 3
L L f – Li 4h / 2 2  6.67  10 –34
()     lehdj.k P0A + kx = Pf A ds fy,] tgk x =
t t 10 –8 3.14  10 –8
2V0  V0
= 10 m
= 4.25 × 10–26 N.m A
izkIr djrs gS] Pf = 2P0
23. 92 U
238

82 Pb206  n1 2  4  n2   1
0
 Pi Vi Pf Vf
238  206 + 4n1 + n2 (0)  n1 = 8 Ti = Tf
92 = 82 + (n1) (2) + (n2) (–1)  n2 = 6 P0 V0 ( 2P0 ) (2 V0 )
T0 = Tf  Tf = 4T0
24. (C) 0 |1 – 2|
uksV : bl iz'u esa xSl dks nh xbZ Å"ek dks Hkh
25. Leq = L1 + L2 – 2 M12 iwN ldrs gSA Å"ek xfr ds izFke fu;e ls
1 2 f
26. 0004 Q = W gas + U= P0V + kx + n RT
2 2
125
27. 0008 Q = 1.2 × 104 J + iz;qDr djus ij R =
28. A and B are short circuited 2
1k 1 2k 2 25
3

2k 1–2 1k

2 1

32V 30.
4
So Reff  k
3
32
1   24mA
4 / 3k
1 R2 2
 
 2 R1 1
To prevent sliding
2
 1   24  16mA  m V2
3 < s mg
1 R
 2   24  8mA
3 V<  sRg
The required current is V < 30 m/s
= I1 – I2
To prevent toppling
= 16 – 8 = 8 mA
 m V2 
 
 R  () < (mg)
 

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gR 5
V< = 5 sec. = 0.2 R  2(500) = 0.2 × 40 (500)= 40 ×
2 2
to prevent sliding as well as toppling 100

V < min of 30 and 5  = 4 kJ
V < 5 m/s
(iii)
P1V1r  P2 V2r
5/3
V
P1 (V)5/3 = P2 =  
8
P2 = (85/3) P1 = 32 P1
U = – 
V
32P  PV
nR(T) P2 V2  P1V1 8
=  = =
r 1 r 1 5
1
3
fQlyu jksdus ds fy,
m V2 3PV 9PV 9 1
< s mg  =  2   3 kJ
R  
2 2 2 3
 
V<  sRg 3

V< 30 m/s (iv)


iyVus ls jksdus ds fy, U = nCV T
 m V2  5
  = nRT
 R  () < (mg) 2
 
gR f 7
V< = 5 sec. CV = R R
2 2 2
fQlyu rFkk iyVus ls jksdus ds fy, 9
Q = n CP T = hRT
V < 3 rFkk 5 dk U;wure 2
V < 5 m/s 7
U = nCV T = nRT
2
31. (B) P → v; Q → i, iii ; R → ii ; S → iv Q 9

U 7
32. (A) (P)  ii, (Q)  i, (R)  iii, (S)  iv 7
U  Q
9

33. (i) W = PV 7


= 9kJ  7kJ
9
= 105 (10–3 – 10–6) J = 100 (10–3 – 106) kJ
–P
= 0.1 kJ  – R
Q = mL  – T
V – Q
10–3 (2250) Ans. (C)
= 2.25 kJ
U = Q =   1  cos 2t 
34. (p) y = sin(1000t)  
= 2.25 – 0.1= 2.15 kJ  2 
~ 2 kJ 1
y = (sin(1000t) + sin(1000t) cos2t)
2
(ii) V  T
1  sin(1000t )  sin(998t ) 
y=  sin(1000t )  
 CV T 2  2 
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So three sounds of angular frequency  = (D) leku le; vUrjky esa lkUnzrk ,d pkSFkkbZ
1000, 998 and 1002 are mixing. Therefore gks tkrh gS vr% 1st dksfVA
beats will be produced
bl izdkj ;gkWa rhu dks.kh; vko`fr  = 1000, 37. P is formed by pinacol-pinacolone
998 rFkk 1002 dh /ofu;kWa fefJr gks jgh gSA rearrangement of vicinal diol Z.
blfy, foLian mRiUu gksxk Br
(q) y = sin(5t) sin3x – cos(5t) cos3x  
Br2
 
KOH
CCl4 DMSO
+ sin(3x) cos5t – cos(3x) sin(5t) Br
y = cos(3x + 5t + ) + sin (3x – 5t) (X) (Y)
These are two waves of same frequency OH
Conc . H2 SO 4
and moving in opposite direction. So   
Pinacol Pinacol one rearrangem ent
standing waves will be formed
OH
;gkWa leku vko`fr dh nks rjaxs foifjr fn'kk esa (Z)
xfreku gSA blizdkj] vizxkeh rjax mRiUu gksxh CHO
(r) y = log (3x – 5t) is in form of x  vt but
the log function is not bounded, when 3x – (P)
5t = 0 then The above product P is formed due to ring
y , so this function cannot represent a contraction during rearrangement.
physical wave. Cyclohexanone is also formed without ring
(r) y = log (3x – 5t), x  vt ds :Ik esa gSA contraction during rearrangement.
ysfdu log Qyu caf/kr ugh gS tc 3x – 5t = 0 gy. P fofluy MkbZvkWy Z ds fiusdkWy&fiusdkWyksu
rc y bl izdkj ;g Qyu ,d HkkSfrd rjax iquZfoU;kl }kjk curk gSA
dks iznf'kZr ugh dj ldrk Br
1 
Br2
 
KOH
CCl4 DMSO
(s) y = is in form of Br
( 3 x – 2t ) 2  5 (X) (Y)
x  vt and this function is bouded (finite) for OH
lkUnz H2SO4
any value of x and t. So it can represent a  
travelling wave (pulse) fiusdkWy fiusdkWyksu iquZfoU;kl
OH
1 (Z)
(s) y = O;taad x  vt ds :Ik esa CHO
( 3 x – 2t ) 2  5
gS rFkk ;g Qyu x rFkk t ds fdlh Hkh eku ds
fy, caf/kr (lhehr) gSA bl izdkj ;g ,d izxkeh (P)
rjax dks iznf'kr dj ldrk gSA mijksDr mRikn P iquZfoU;kl ds nkSjku oy;
ladqpu ds dkj.k curk gSA lkbDyksgsDlsukWu
-------------------------------------------------------------- iquZfoU;kl ds nkSjku oy; ladqpu ds fcuk curk
gSA
PART-III: CHEMISTRY
38. Solution is positively charged.
35. (A) Azurite  2CuCO3.Cu(OH)2 foy;u /kukRed vkos'k gSA
(B) Slag is less dense than molten metal
gy. (A) ,tqjkbV  2CuCO3.Cu(OH)2 39. At low pressure & high temperature z = 1
(B) /kkrqey xfyr /kkrq ls de l?ku gksrk gSA
U;wu nkc rFkk mPp rki ij z =1

Br
36. (A) H = [2(–1263) ] – [(–2238) + (–285)]
= – 3 kJ CH–CH3
(B) C12H22O11 + 12O2 
12 CO2 + 11 H2O
{C6H12O6 + 6O2  6CO2 + 6H2O} × 2 40. X is gS Y is gS Ph–CH–CH3
C12H22O11 + H2O  2C6H12O6 ;
MgBr
H = –3 kJ
(C) Hydrolysis is exothermic T  h  Z is gS Ph–CH–CH3
(C) tyvi?kVu Å"ek{ksih gksrk gS T  h 
CH2–OH
(D) Concentration becomes one-fourth in
equal time interval. Hence, 1st order.

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OH CH4  2O2  CO2  2H2O
W is gS Ph–CH=CH2 U is gS Ph–C–CH3 2CO  O 2  2CO2
5
CH3 CH3 C2H2  O2  2CO2  H2O
2
OH Volume of O2 required = 1.04 m 3
i fdZu vfHkfØ; k O2 dk vko';d vk;ru = 1.04 m3
41.   
Perkin

CHO reaction
1.04  100
Vair   5m3 = 5000 L
20.8
'X'
OH OH O O 45. a, b, c, d, e, g, i
H / 
C 
CH=CH O 

'Y' 'Z' 46. , ,



42. Cu2   CN– [Cu(CN)4 ]3  2

so unpaired electron = 0 , ,
vr% v;qfXer bysDVªkWu =0
 

43. (i) V2O5 is amphoteric and dissolves in very


47. Value of x is 5
strong NaOH and very strong acids forming
x dk eku 5 gSA
VO43– and VO2+ ions respectively.
SH
Cr2O3 is amphoteric and dissolves in acids
and concentrated alkali forming SO3H
CH MgBr
[Cr(H2O)6]3+ and CrO42– ions respectively. H 
3

ZnO is amphoteric and dissolves in NaOH
and acids forming [Zn(OH)4]2– ions and O O Cl
salts respectively. 1eq.
(ii) Mn2O7 is acidic oxide and gives HMnO4 SH
1eq.
when dissolves in water. SO3H
CrO3 is acidic oxide and gives H2CrO4 and
H
H2Cr2O7 when dissolves in water.
(iii) V2O3, CrO, FeO and Cu2O are basic O O Cl
oxides and dissolves in acids forming salts. 1eq.
2eq.
gy. (i) V2O5 mHk;/kehZ gksrk gS rFkk cgqr izcy
NaOH o cgqr izcy vEy esa ?kqydj Øe'k% 48. P Q R S
VO43– rFkk VO2+ vk;u dk fuekZ.k djrs gSaA (B) 2 3 4 1
Cr2O3 mHk;/kehZ gksrk gS rFkk vEy o lkfUnzr
4.1
{kkjh; esa ?kqydj Øe'k% [Cr(H2O)6]3+ rFkk 49. (P) 4.1 gm = mole H2SO3 = 50 m mole
82
CrO42– vk;u dk fuekZ.k djrs gSaA
ZnO mHk;/kehZ gksrk gS tks NaOH o vEyksa esa 2NaOH + H2SO3 
?kqydj Øe'k% [Zn(OH)4]2– rFkk yo.kksa dk Na2 SO3 + 2H2O
m mole of NaOH required
fuekZ.k djrs gSaA = 2  m mole of H2SO3
(ii) Mn2O7 vEyh; vkWDlkbM gS rFkk ty esa
= 100
?kqydj HMnO4 nsrk gSA = m mole of NaOH present
CrO3 vEyh; vkWDlkbM gS rFkk ty esa ?kqydj (200 ml  0.5 N)
H2CrO4 rFkk H2Cr2O7 nsrk gSA Highest O.N. of S = +6
4.9
(iii) V2O3, CrO, FeO rFkk Cu2O {kkjh; (Q) 4.9 gm = mole = 50 m mole of
98
vkWDlkbM gaS tks vEy esa ?kqydj yo.k dk fuekZ.k H3PO4 = 200 m mole 'O' atom
djrs gSA Highest O.N. of P = +5

44. 2H2  O2  2H2

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4.5 O
(R) 4.5 gm = = 50 m mole H2C2O4
90 CH3–CH2–C–O–CH3
(di basic acid)
m mole of NaOH required (R)
= 2  50 = 100
Highest O.N. of C = +4
1
(S) 5.3 gm = mole Na2CO3 It do (S)
20
not react with NaOH and m mole of O atom
1
=  1000  3 = 150
20
4.1
gy. (P) 4.1 gm = eksy H2SO3
82
51. (B) P → 3; Q → 1; R → 4; S → 2
= 50 feyheksy
2NaOH + H2SO3  PAPER-2
Na2 SO3 + 2H2O
NaOH ds vko';d feyheksy
= 2  H2SO3 ds feyheksy
PART-I: MATHEMATICS
= 100
1. We observe that pr is increasing with r, if
= NaOH ds mifLFkr feyheksy
we choose 14 socks, then by the
(200 ml  0.5 N) pigeonhole principle we neccesarily choose
S dh mPpre vkWDlhdj.k voLFkk at least one matching pair. So p14 = 1. We
= +6 compute p13. There are 26C13 choices of a
4.9 bunch of 13 socks. There are no matches if
(Q) 4.9 gm = eksy = H3PO4 ds 50 we choose exactly one sock from each
98
pair, i.e, there are 213 choices when there
feyh eksy = O ijek.kq ds 200 are no matching pairs. Correspondingly, pro
feyheksy
213
P dh mPpre vkWDlhdj.k voLFkk = +5 = p13 = 1 26
C13
4.5
(R) 4.5 gm = = H2 C 2 O 4 2.
90
(f} {kkjdh; vEy) ds 50 feyheksy
NaOH ds vko';d feyheksy
= 2  50 = 100
C dh mPpre vkWDlhdj.k voLFkk = +4
1
(S) 5.3 gm = eksy Na2CO3 , ;g
20
NaOH ds lkFk fØ;k ugha djrk gS rFkk
O ijek.kq ds feyheksy
1
=  1000  3 = 150
20
In  AOC, esa
50. (P) OH OC
tan 30° =
OH h
h
OH OC =
3
OH
O 1  h2  h3
V=  x   xh 
(Q) H–C–O–CH2–CH2–CH3 3 3 9
O O dv  2 dh
CH3  xh
H–C–O–CH CH3–C–O–CH2–CH3 dt 3 dt
CH3 dv h 2
 dh 
   1cm / s 
dt 3  dt 

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dv  x(24)2 n! n  1!
 = 192 cm3/s. 6. nC
10.
n+1C
10.= .
dt 3 n  10!10! n  9!10!
2
 n 1 n! 
=  . 
 n  9   n  10!10 
for perfect square
(x0, sin x0) n + 1 = am2 & n – 9 = a2
 a (m– ) (m + ) = 10
3. If a = 1 then not possible
x0 –x0  If a = 2 then m –  = 1, m +  = 5, m = 3,
=2
It a = 5 then not possible
 n = 17
A(Area {ks=kQy) = 2 ( – 2x0)(sin x0)
dA 7. f(1) = 0
= 2[( – 2x0) cos x0 – 2 sin x0] R.H.L. = lim f(1 + h) = lim cos–1
dx 0 h0 h0

dA   2 
=0  sgn  
dx 0   3  3h  1  
 
 x0 + tan x0 = (x0  (0, /2))  2 
2 = lim cos–1  sgn   = 0
h0   2  3h  
4. let ekuk z  cos   i sin  L.H.L. = lim f(1 – h) = lim
h0 h0
| (cos   cos )  i (sin  sin) |    0  
| (cos   cos )  i (sin  sin) | cos–1  sgn    = cos (0)= 2
–1

  3  3h 
 2  2 cos(  )  2  2 cos(  )  f(x) is discontinuous hence non-derivable
at x = 1
 
 2 cos  2 sin  f(1  h)  f(1)
2  2  f(–1+) = lim =0
h0 h
1  | sin x |  | cos x |  2 f(1  h)  f(1)
and f(–1–) = lim =0
h0 h
hence vr% M  2 2 , m = 2 f(–1+) = f(–1–) = 0
f(x) is derivable at x = – 1
5. If I(A) = k, then all other elements of A can gy- f(1) = 0
be arbitrary elements of {1, 2,...,k – 1). It
means that there are 2k-1 subsets of {1, R.H.L. = lim f(1 + h) = lim cos–1
h0 h0
2,...,n) with I(A) = k.
  2 
n
 sgn  
f n   k2
k 1
k 1
  3  3h  1 
  2 
We compute = lim cos–1  sgn   = 0
h0   2  3h  
z n1  z
n


k 1
zk 
z 1
L.H.L. = lim f(1 – h) = lim
h0 h0

n
d n
d z n1
z   0  
 kz k 1  dz  z k 
dz z  1
cos–1  sgn 

  = cos (0)=
 3  3h  
–1
2
k 1 k 1


n  1z n
1

z n1  z
.
  f(x) vlrr~ gS vr% x = 1 ij vodyuh; ugha
z 1 z  12 gSA
At z = 2 we get (n + 1)2n – 1 – 2n+1 +2 = 2n f(1  h)  f(1)
f(–1+) = lim =0
(n –1) +1. h0 h
Answer:(d) f(1  h)  f(1)
rFkk f(–1–) = lim =0
h0 h
f(–1+) = f(–1–) = 0
x = – 1 ij f(x) vodyuh; gSA

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8. Equation 9. Pre multiply by A
x y z A ls xq.kk djus ij
+ + = 1 has three roots a,b, c
t t –1 t 1 A 2  A.adj A  I 2
by solving the equation we get
A2  A .I2  I2
x( t 2 – 1)  y( t 2 t )  z( t 2 – t )
t( t 2 – 1)
=1 A2  1  A  I 2
t3 – t = (x + y + z)t2 + (y – z)t – x | A |2   A - 1
2

a
1
A   A -1  | A |
3 2
t – (x + y + z)t + (–y + z – 1)t + x = 0 b
c 2
abc = – x ........ (1) Determinant (2A – 1) = 8
a+b+c=x+y+z ........ (2) lkjf.kd (2A – 1) = 8
ab + bc + ca = – y + z – 1 ........ (3)
hence 10. D0
x = – abc
y + z = a + b + c + abc a2 – 4(a + 1)  0
y – z = – 1 – ab – bc – ca a 2 – 2 2 , a2 +2 2
2y = a + b + c + abc – 1 – ab – bc – ca    = -a
2y = (a – 1)(b – 1)(c – 1)
  = a + 1
(a – 1)(b – 1)(c – 1)
y=       1  2
2
2z = 1 + a + b + c + ab + bc + ca + abc (  1)(  1)  2
2z = (1 + a)(1 + b)(1 + c) (  1)  2 ,   1  1   1  1 ,   1  2
(1  a)(1  b)(1  c )   1,   0   2 ,   3
z=
2 a = -1 a=5
so (C) is incorrect option
gy- lehdj.k dy xdv
x y z 11. put y = vx j[kus ij  v
+ + = 1 ds rhu ewy a, b, c dx dx
t t –1 t 1 2v dv dx
= Integrating both sides
x( t 2 – 1)  y( t 2 t )  z( t 2 – t ) 1– v2 x
lehdj.k = 1
t( t 2 – 1) 2v dx
lekdyu djus ij 
1 v2  x

dks gy djus ij
t3 – t = (x + y + z)t2 + (y – z)t – x n|v2 –1| + n|x| + nk = 0
a n|(v2 –1)xk| = 0
3 2
t – (x + y + z)t + (–y + z – 1)t + x = 0 b |(v2 – 1)xk| = 1  |y2 – x2| = |x|
c  m = 2, b = 1  m + b = 3
abc = – x ........ (1)
a+b+c=x+y+z ........ (2) 12.   a2  (b  c)2  (a  b  c)(a  b  c)
ab + bc + ca = – y + z – 1 ........ (3)  s(s  a)(s  b)(s  c)  4(s  b)(s  c)
vr%
1 (s  b)(s  c)  A
x = – abc    tan 
y + z = a + b + c + abc 4 s(s  a) 2
y – z = – 1 – ab – bc – ca
2y = a + b + c + abc – 1 – ab – bc – ca 13. n  1 C  nC  nC  n  2C
6 4 5 5
2y = (a – 1)(b – 1)(c – 1)
(a – 1)(b – 1)(c – 1)  n  1C6  n  1C5  n  2C5
y=
2  n  2C6  n  2C5
2z = 1 + a + b + c + ab + bc + ca + abc
2z = (1 + a)(1 + b)(1 + c) 
 n  2 !   n  2 !
(1  a)(1  b)(1  c ) 6! n  4 ! 5! n  3 !
z=
2 n9
blfy, (C) xyr fodYi gSA

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Sol. (14 to 15) Lets find electric field at radial distance (r)
 using gauss’s theorem
Let ekuk r = x î + y ĵ
ekuk f=kT; nwjh (r) oS|qr {ks=k xkml izes; ds
 
 r .(10 ĵ – 8 î – r ) = 40 mi;ksx ls Kkr djrs gSA
 (x î + y ĵ ).((10 –y) ĵ – (8 + x ) î ) = 40 qin
 E.ds = 0
– x(8 + x) + y(10 – y) = 40
 x2 + y2 + 8x – 10y + 40 = 0 r r

 ( r) 4r
2
 (x + y)2 + (y – 5)2 = 1 E (4r2 ) = 0 dr
r 0

 r lies on circle o`Ùk ij fLFkr gSA  0r 2
  E=
 | r + 2 î – 3 ĵ | = | r – (–2 î + 3 ĵ )| 40
 For equilibrium of the electrons
= distance of r from (–2, 3) bySDVªkWuksa dh lkE;koLFkk ds fy,

= (–2, 3) ls r dh nqjh   r2  1 e2  e 
1/ 4

(e)  0  = ,r=  
 M = (Radius + Distance between centre
 40   40 
2
4 (2r)
and (–2, 3))2
 M = (f=kT;k + dsUnz vkSj (–2, 3) ds e/; nwjh)2 distance between the electrons bySDVªkWuksa dh
1/ 4
= (1 + 4  4 )2 = (1 + 2 2 )2 = 9 + 4 2  e 
e/; nwjh = 2r = 2  
 m = (2 2 –1)2 = 8 + 1 – 4 2 = 9 – 4 2  40 

Sol. (16 to 17) 20. Using moment of conservation


/2
laosx laj{k.k ds mi;ksx ls
f(x) – sinx
 cos t f(t) dt = sinx
0
mv + 2m(0) = mv1 + 2mv2
v1 + 2v2 = v ...(i)
f(x) – Asinx = sinx
/2
v 2  v1
and rFkk e = 1 =
(where A = 
 cos t f(t) dt
0
v2 – v1 = v
v 0
...(ii)
 f(x) = (A + 1) sinx from eq. (i) and (ii) lehdj.k (i) rFkk (ii) ls
/2 1
mv 2
so A = 
 cos t(A  1)sint dt v1 =
v K ini
3 K final
= 2
2

9
1
0 1 v
/2 m 
(A  1) 2 3
 A=
2  sin2t dt
0
 
A = (A + 1)  A = 21.
2 2–
 2  T1 T2 T3
f(x) =   sinx
2–
-------------------------------------------------------------- 1 2

T2 T
PART-II: PHYSICS 1  1 , 2  1 3
T1 T2

18. Option with highest quality factor sould be   1


T3
1  1 (1  2 )  T3
chosen as most appropriate answer. T1 T1
1 L  = 1 – (1 – 1)(1 – 2) = 1 + 1 – 12
Q=
R C
19.
22. Process in which resultant nuclei with
greater BEPN will release energy. so.
R  2s will consume energy
P Q + S will consume energy
 P  2R will release energy
 QR+S will consume energy

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P P 1.5  T1
X36 4 Circuit L–C1 is on for = sec.
23. Y36 100 4
Mass number for y is 8 times that of - the charge on capacitor C1 will be zero, so
particle so the nuclear radius is (8)1/3 = 2 1 2 
times that of -particle. the entire energy  2 C1V1  will go in
 
24. Conservation of energy between x = – a inductor.
and x = +a. 0.5  T
Now after sec. = 2 sec., 'i' in the
– PEi + KEi = PEf + KEf 100 4
K 1 k inductor will be zero, so now all the energy
–  mu2 =
2a 2 2a 1 2 
 2 C1V1  will go in the capacitor C2.
2k  
u=
ma 1 1
 CV2= CV2
2k 2 1 1 2 2 2
For any value greater then object 1 1
ma (900 ) (1)2 = (100 ) v22
reaches x  + 2 2
 v2 = 3 volt.
2k
For any value less then object goes 1 100
ma gy. L–C1 fudk; ds fy,, 1 = 
LC1 3
to x  – 
Total energy at x = +a = KE + PE 6
rFkk T1 = 2 LC1 = sec.
k k 100
=0+ =
2a 2a 1
L–C2 fudk; ds fy, 2 = = 100
x = – a rFkk x = +a e/; ÅtkZ lja{k.k yxkus ij LC2
– PEi + KEi = PEf + KEf
2
K 1 k rFkk T2 = 2 LC2 = sec
–  mu2 = 100
2a 2 2a
1.5  T1
2k ifjiFk L–C1 lEifdZr gS = sec.
u= 100 4
ma
la/kkfj=k C1 ij vkos'k 'kwU; gksxk] vr% lEiw.kZ
2k
ls vf/kd eku ds fy, oLrq x  + ij  1 
ma ÅtkZ  C1V12  çsj.k dq.Myh esa pyh tk,xhA
 2 
igqapsxhA
0.5  T2
2k = sec, i'pkr~ çsj.k dq.Myh esa /kkjk
ls de eku ds fy, oLrq x  – ij 100 4
ma 1 
igqapsxhA 'i''kwU; gksxh] vr% vc lEiw.kZ ÅtkZ  C1V12 
2 
la/kkfj=k C2 esa pyh tk,xhA
x = +a = KE + PE ij dqy ÅtkZ
1 1
k k  CV2= CV2
=0+ = 2 1 1 2 2 2
2a 2a
1 1
(900 ) (1)2 = (100 ) v22
25. 0024
2 2
 v2 = 3 volt.

26. 0015 28. When the sphere leaves the surface, its
speed will be
1 100 2  10  7
27. For L–C1 system 1 =  2gh

LC1 3  2  v = 10 m/s
v = 1 1
6 mR 2
5
and T1 = 2 LC1 = sec.
100 Then the ball will perform a projectile
1 motion.
For L–C2 system 2 = = 100 2h 2  1.25
LC2 Range = u  10  5m
g 10
2
and T2 = 2 LC2 = sec.
100
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tc xksyk lrg dks NksM+rk gS] rc bldh pky v (aA)net = g2  (3g)2 = 10 g, At point B
2gh 2  10  7
 VB2 gR
=  2  v = 10 m/s fcanq ij, at = 0 and rFkk ac = = =g
1 1 R R
mR2 5 2 2
rc xsan iz{ksI; xfr djsxhA a1 – a 2
So aB =g  = +9
net
g2
ijkl = u 2h  10 2  1.25  5 m
g 10
29. 31. Total energy released from Au198 Hg198
Ts Tc
in ground state
= (mloss) c2
= (197.9682 – 197.9662) (930)
60º 30º = 1.86 MeV
Energy released from 198Hg in first excited
state  Hg in ground state
100 N = (–1.6) – (–2) MeV
= 0.4 MeV
Ts  Energy released from Ag198 Hg198
3
 Tc second excited state
2 2
= 1.86 – 0.4 = 1.46 MeV = max. K.E. of 2
particle
Ts = 3 Tc
gy. Au198 ls mRlftZr dqy ÅtkZ  Hg198 ewy

  = TL/AY
voLFkk esa
= (mloss) c2
 c  Tc  c   Ys  = (197.9682 – 197.9662) (930)
   
 s  Ts  
 s
Y
 c


= 1.86 MeV
198
Hg }kjk izFke mÙksftr voLFkk ls mRlftZr
dqy ÅtkZ  ewy voLFkk esa Hg
 1   3   2  1011 
=     2 = (–1.6) – (–2) MeV
  11 
 3   1   1 10  = 0.4 MeV
 Ag198 ls mRlftZr ÅtkZ Hg198 f}rh;
30.
mÙksftr voLFkk
VB  gR B
m = 1.86 – 0.4 = 1.46 MeV = 2 d.kksa dh
VA  3gR vf/kdre xfrt ÅtkZ
VA2
aC 
R
mA 32. Similarly maximum kinetic energy of 1
particle = 1.86 – 1
at=g blh izdkj 1 d.k dh vf/kdre xfrt ÅtkZ =
m 1.86 – 1 = 0.86 MeV
u  5gR
To just complete the vertical circle, the
speed given to block at lowest position is 33. 03.00
Å/okZ/kj o`rh; xfr dks dsoy iw.kZ djus ds fy,]
fuEure fcanq ij CykWd dks nh xbZ pky n = 34. At O,path difference(iFkkUrj)
5gR  g   1.5 
so from energy conservation blizdkj ÅtkZ x =   1 t=   1 10.4m=1.3 m
 m  4/3 
laj{k.k ls VA = 3gR , VB = gR At point A Corresponding phase difference(blds laxr
fcanq ij
2 2  1.5 
F mg V2 dykUrj),  = . x = 7  4 / 3
 1
at = t = = g, and rFkk ac = A =  6  10  
m m R
3gR  13 
= 3g ( 10.4 × 10-6 ) =  
R  3 

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eq  1  2  2 1 2 cos   41. It is based on definition.
;g ifjHkk"kk ij vk/kkfjr gSA
 eq  0  0  2 0 0 cos4   / 3 
42. MX3 M3+ + 3X–
 eq  3 0
1–  3
-------------------------------------------------------------- i = 1 + 3
 =2
PART-III: CHEMISTRY 1
43. Number of A atoms = 8 × 1
8
35. (B) Na2S  Na2 [Fe(CN)5 (NO)]  1 1
Number of B atoms = 2   4   2
Na4 [Fe(CN)5 (NOS)] 2 4
1
(C) Complex(A) [Ni(en)3]2+ Number of C atoms = 1  4   3
 3 chelate ring 2
 AB2C3
gy. (B) Na2S  Na2 [Fe(CN)5 (NO)] 
1
Na4 [Fe(CN)5 (NOS)] gy. A ijek.kqvksa dh la[;k = 8 × 1
8
(C) ladqy (A) [Ni(en)3]2+  3 dhysV oy; 1 1
B ijek.kqvksa dh la[;k = 2   4   2
2 4
36. HCl  O3  H2O  Cl2  O2 1
C ijek.kqvksa dh la[;k = 1  4   3
2
37. Gabriel phthalimide synthesis is used for  AB2C3
the preperation of primary amine
xsfczy FksfyekbM la'ys"k.k izkFkfed ,ehu ds 44. sp3
fojpu ds fy, iz;qDr gksrk gSA PCl3, [Ni(CO)4], SO24 , SnCl4, ClO4 ,
CH3 , NH4 , ClO3
38. Guanine is not a pyrimidine base.
Xokuhu fifjfeMhu {kkj (pyrimidine) ugh gSA
45. A(g) B(g)  C(g)
39. M HCl  NaC  NaCl at t = 0 a 0 0
at t = t (a – x) x x
= 426 + 83 – 126
= 383 –1 cm2 mol–1 2.303  a 
K log  
K t ax
M (HC)   1000
C  K 
log(a – x) =    t  loga
5
3.83  10  2.303 
  1000
0.001 K 2
slope =  
= 38.3 2.303 10
38.3 2 2.303
  0. 1 K=  sec 1
383 10 60
C 2 = 7.7 × 10–3 sec–1
Ka   1.11 10 5
1  gy. A(g) B(g)  C(g)
t = 0 ij a 0 0
40.  On temp, reaction moves in t = t ij (a – x) x x
backward direction, [A(g)] will increase.
 2.303  a 
On decreasing volume, K log  
concentration of all species will increase. t ax
 On adding B(g), reaction will move  K 
in backward direction, [A(g)] will increase. log(a – x) =    t  loga
 2.303 
gy.  rki ij] vfHkfØ;k i'p fn'kk esa tkrh
K 2
gS [A(g)] c<+sxhA <+ky =  
2.303 10
 vk;ru ?kVkus ij] lHkh Lih'kht dh
2 2.303
lkUnzrk c<+sxhA K=  sec 1
10 60
 B(g) feykus ij, vfHkfØ;k i'p fn'kk = 7.7 × 10–3 sec–1
tk;sxh] [A(g)] c<+sxhA
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46. C4H9N has following cyclic isomers
Four primary amine, seven 2º and three 3º
amines.
C4H9N fuEu pØh; leko;oh j[krk gSA
pkj izkFkfed ,ehu] lkr 2º rFkk rhu 3º ,ehu
gSA

Total four primary amines. (dqy pkj


izkFkfed ,ehu)

Total seven secondary amines.


(dqy lkr f}rh;d ,ehu)


Total three tertiary amines. (dqy
rhu r`rh;d ,ehu)

47. (0041)

48. (a) only

49. 4A(g) B(g) + 2C(g)


t=0 800 – –
t = 10
minutes,800 – 4p p 2p
800 – p = 650
 p = 150
Pressure of A (A dk nkc)
= 200, so (blfy;s)
 2 x t1/2 = 10 minutes
t1/2 = 5 minutes

50. (50 to 51)

---- TEXT SOLUTIONS (TS) END ----

Corp. Reg. & Corp. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
SOL01JPAMT1011223C1-19
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
Corp. Reg. & Corp. Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
SOL01JPAMT1011223C1-20
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029

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