Surface Post-Treatments For Metal Additive Manufacturing: Progress, Challenges, and Opportunities
Surface Post-Treatments For Metal Additive Manufacturing: Progress, Challenges, and Opportunities
Additive Manufacturing
Volume 37, January 2021, 101619
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Abstract
Metal additive manufacturing is a rapidly expanding area owing to its capacity to
fabricate parts of intricate geometries with customized features for a wide range of
applications. However, these parts generally exhibit inadequate and poor surface quality
in the as-built configuration. The surface imperfections and defects ranging from
staircase effect due to the layer by layer nature of the deposition techniques, partially
fused feedstock material, balling effects, spatters, or inadequate fusion lead to a notably
irregular surface morphology. This high surface roughness can significantly deteriorate
the performance of the additive manufactured parts imposing a substantial limit on their
prospective applications; for instance, fatigue performance, wear and scratch resistance,
dimensional accuracy, and aesthetical aspects can be highly affected by these surface
defects. A great effort has been lately dedicated to developing post-treatments for
improving the surface quality of additively manufactured metallic parts. In this paper,
various treatments applied to as-built samples fabricated using different additive
manufacturing technologies are introduced and discussed. The advances in this area are
highlighted, and the results obtained from different categories of post-treatments are
compared and reviewed. Challenges and opportunities to gain more control on the
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Abbreviations
AcAl, Acid-Alkali; AM, Additive Manufacturing; CP, Cavitation Peening; DED, Direct
Energy Deposition; ECP, Electro-Chemical Polishing; EPD, Electrophoretic Deposition; HT,
Heat Treatment; HIP, Hot Isostatic Pressing; HCAF, Hydrodynamic Cavitation Abrasive
Finishing; LPBF, Laser Powder Bed Fusion; LSP, Laser Shock Peening; MIG, Metal Inert
Gas; MAO, Microarc Oxidation; PEO, Plasma Electrolytic Oxidation; PBF, Powder Bed
Fusion; SB, Sand Blasting; SEM, Scanning Electron Microscopy; SP, Shot Peening; SBF,
Simulated Body Fluid; TF, Tumble Finishing; UCAF, Ultrasonic Cavitation Abrasive
Finishing; UC, Ultrasonic Consolidation; UNSM, Ultrasonic Nano-crystal Surface
Modification; WAAM, Wire and Arc Additive Manufacturing
Keywords
Metal additive manufacturing; 3D printing; Post-treatment; Surface roughness; Surface
morphology
1. Introduction
During the last decades, multiple approaches have been developed and presented for
additive manufacturing (AM) of metallic materials. The American Society for Testing and
Materials (ASTM International) has classified these technologies based on the state of
fusion, material feedstock and distribution, source of fusion and process category.
According to the ASTM classification, direct energy deposition (DED) and powder bed
fusion (PBF) are the two major AM technologies for metals. In addition to these main
categories, a few alternative methods such as sheet lamination and binder jetting, are
also recognized by ASTM for metal AM [1], [2], [3]. More recently, few other methods
have been suggested by researchers as alternative technologies with higher production
rates for metallic materials such as friction stir welding also known as friction stir
additive manufacturing [4], [5], cold spraying [6], [7], [8], [9], direct metal writing [10]
and diode-based processes [11]. These methods are still being evaluated regarding their
potential to be recognized in the AM classification by ASTM.
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The common theme among all the mentioned AM technologies is that, oftentimes, in
comparison with conventional manufacturing methods, the surfaces of the fabricated
metallic parts show insufficient morphological quality represented by highly irregular
and randomly positioned features. These irregularities are mostly created owing to the
layer-by-layer nature of the fabrication process and the complex physical phenomena
occurring during the deposition and fusion of the material [12]. Several independent
factors associated with the feedstock characteristics, design of the part and fabrication
process parameters as shown in Fig. 1 can contribute to the scale and extent of these
irregularities.
Fig. 1. Major parameters affecting the surface roughness of as-built metallic AM parts.
Major sources of this uncontrolled surface roughness include the stair-case effect due to
layer by layer deposition, agglomerates of partially fused feedstock (typical for PBF
technologies), spatters, splashing particles due to evaporation and balling effects, as well
as movement and instability of the melt pool due to wetting [13], [14], [15], [16]. For
example good wetting behavior of specific materials like Zn, make it even more
challenging to control the surface quality of their PBF products, as the excellent
wettability facilitates uncontrolled horizontal movement of the melt pool on its
boundaries [17], [18]. Part geometry, the surface orientation with respect to the build-up
direction as well as design of support structure, can highly affect the quality of the
surface. For example, studies have shown that in geometries with inclined features,
down-skin surfaces exhibit higher surface roughness compared to the up-skin ones [19];
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the surface roughness also varies with the change in the inclination angle [20]. The
removal of the supporting structure, the extension of which is directly defined by the
part geometry, can also affect surface quality [21]. As well as their role in restricting
dimensional accuracy, these features on the surface of as-built AM materials can act as
potential stress concentration sites leading to early crack initiation. The process
parameters including size and morphology of feedstock and deposition parameters also
play a key role in defining the surface roughness of AM materials [22], [23], [24], [25]. In
the case of parts fabricated by DED processes, visible weld beads resulting in surface
waviness of several millimeters characterize the surfaces. This is due to large melt pools,
which are difficult to manipulate and control, caused by large spot size of the arc or
plasma beams [26], [27].
Fig. 2, exhibits few representative examples of the highly irregular surface morphologies
obtained via different AM technologies highlighting the effect of the process parameters
on the extent and distribution of the irregular surface features [15], [28], [29].
(e) powder diameter of 45–100 µm and layer thickness of 50 µm and (f) powder diameter
of 25–45 µm and layer thickness of 70 µm adopted from [29]. Surface morphology of
ER5356 Al alloy samples fabricated by a direct energy deposition (DED) technology using
different laser powers of (g) 0 W, (h) 200 W and (i) 400 W adopted form [15].
These observations confirm the critical role of surface post-treatments on AM materials
for obtaining a controlled, regular and repeatable surface morphology [30], [31]. Since
most types of mechanical failures are very sensitive to the surface properties, it is
expected that the performance and functionality of as-built AM materials can be highly
improved by modulating the surface topographical features [32], [33], [34]. Therefore,
adapting surface post-processing technologies has become a growing area of interest as
an effective tool for improving the functionality and service lifetime of AM materials [35]
, [36]. To this aim, a variety of surface post-treatments have been developed and tailored
to improve the surface quality and enhance the performance of AM metallic materials.
Some of these treatments remove a thin surface layer of material to achieve the desirable
surface roughness, whereas others induce specific surface patterns producing a more
homogeneous and regular surface morphology.
Despite the advancements in AM technology and post-processing field, the surface state
remains a critical point in the AM technological cycle and there are still multiple
challenges to be addressed in this area, including optimizing process parameters, as well
as efficiency and side effects of the applied post-processing treatments. Other significant
issues to be tackled are related to the scalability and practicality of the suggested post-
treatments. The present paper reviews the developed surface post-treatments aimed at
improving the surface quality of metallic structures fabricated using different AM
technologies. Current technologies are critically discussed, and future developments and
opportunities are highlighted.
2. Surface post-treatments
A wide variety of surface post-treatments have been applied to AM metallic parts in
attempt to overcome the issues related to the poor surface quality of as-built material.
Herein, these treatments are classified as described in Fig. 3, mainly based on the
intrinsic characteristics of the applied technology and the final effects of the treatment
on the surface of AM part; the major groups are those based on “material removal”, “no
material removal”, “coating” and the combination of different treatments considered as
“hybrid treatments”. Each of the mentioned surface post-treatments is explained and
discussed in detail in the following sections.
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2.1.1.1. Machining
There are few other mechanical material removal techniques that can be categorized as
machining, that have been occasionally employed to improve the surface quality of AM
metallic parts. These include grinding [41], [42], [43], and milling [41], [44], [45].
Fig. 4 depicts the effects of some of the above-mentioned techniques in reducing the
surface roughness of different AM metallic materials.
Fig. 4. Surface topography of PBF Ti–6Al–4V (a) before grinding with Ra = 4.13 µm; after
grinding using different grinders including (b) 40 µm Nickel bonded-grinder leading to Ra
= 130.8 nm, (c) 9 µm Nickel bonded-grinder with Ra = 65.6 nm and (d) 3 µm Resin
bonded-grinder with Ra = 8.6 nm adopted from [42]. SEM surface micrographs of (e) as-
built with Ra of 17.9 µm and (f) milled laser beam melting LPBF Ti–6Al–4V plates with Ra
= 0.3 µm adopted from [45].
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2.1.1.2. Polishing
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Fig. 5. SEM and confocal microscopy images of PBF pure Cu samples (a, b) as-built with Ra
≈ 40 µm and (c, d) after magnetically driven abrasive polishing with Ra ≈ 4 µm adopted
from [47]. Effects of HCAF on surface roughness reduction of LPBF Al alloy AlSi10Mg: (b)
as-built and (c) after HCAF adopted from [48]. The influence of UCAF on surface
morphology of LPBF Inconel 625: (d) as-built and (e) after HCAF adopted from [49].
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Fig. 6. SEM micrographs illustrating the surface morphology of LPBF Ti–6Al–4V ELI
samples: (a) as-built, (b) after tribo-finishing adopted from [51].
Fig. 7. Surface morphology of LPBF fabricated Ti–6Al–4V: (a) as-built and (b) after
femtosecond laser micro-machining adopted from [53].
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techniques are displayed in Fig. 8. These chemical treatments are generally very similar
all based on submerging the AM part in temperature-regulated baths of chemical
solutions with slight differences in the duration or the temperature of operation that
directly affect the depth of material removal. The parameters in chemical brightening, for
example, are set to obtain a mirror-like finish and induce shininess on the metallic
surface. Chemical brightening was found to be more effective in roughness reduction
compared to chemical machining, as is shown in Fig. 8c. Jung et al. [62] studied the
effects of electrochemical polishing (ECP) at different times and voltages on the
roughness reduction of PBF pure Ti samples. As depicted in Fig. 8h–m, ECP was effective
in reducing surface roughness especially at the highest considered time and voltage (600
s and 30 V respectively).
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Fig. 8. Surface morphology of LPBF lattice Ti–6Al–4V structure for (a) as-built and (b)
chemical-etched sample adopted from [55]. (c) Surface morphologies and SEM
micrographs of the as-built LPBF AlSi10Mg sample before and after chemical machining
and chemical brightening adopted from [58]. Surface texture LPBF Ti (d) before and (e)
after chemical polishing adopted from [60]. Surface morphology of LPBF CoCr stent (f)
before and (g) after ECP adopted from [61]. Influence of ECP on LPBF pure Ti (h) as-built
and electro-polished material at different conditions of time and voltage: (i) 60 s and 10
V, (j) 60 s and 20 V, (k) 60 s and 30 V, (l) 600 s and 20 V and (m) 600 s and 30 V adopted
from [62].
In addition, there are few other chemical treatments applied to AM metallic material not
specifically aimed at reducing the surface roughness but to induce specific surface
features to modulate the surface characteristics based on the final application. A
common example is the acid-alkali (AcAl) treatment widely performed on Ti–6Al–4V
parts for further bio-functionalization [63]. These treatments are used to bio-
functionalize the surface by creating nano-features and modifying the surface chemistry
of the structure.
2.2.1.1. Rolling
Rolling is the process of plastically deforming the top layer by pressing a roller of
different shapes and geometries against the surface of the material. It is conventionally
employed for thickness reduction or controlling the surface level. In the field of metallic
AM, rolling has been mostly used on the DED parts fabricated using wire and arc additive
manufacturing (WAAM) [64], [65], [66], [67], [68], although in some cases it has been
used also on liquid metal deposition produced materials [69]. Rolling has been applied
on both top and side surfaces of AM as-built material, as shown in Fig. 9–h [70]. If proper
parameters are selected, rolling can also generate grain refinement (see Fig. 9i and j) [71]
and induce compressive residual stresses in the treated layer; these features can lead to
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improved mechanical properties (see Fig. 9o and p) [72], as well as reduced surface
roughness. Different strategies have been studied for application of rolling to AM metals
including only one rolling pass on the outer surface/pen-ultimate layer or a rolling pass
applied to every layer during deposition, called as inter-pass rolling (see Fig. 9k–n) [73]
to control the microstructure of the deposits.
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Fig. 9. Wall shape of (a) a control specimen, (b–d) a top-surface inter-pass rolled
specimen and (e–h) a side rolled specimen of DED Al alloy 2319 adopted from [70].
Randomly oriented grains for (i) unrolled and (j) 50 kN rolled DED maraging steel (black
lines indicate grain boundaries) adopted from [71]. Cross-sections near the top of rolled
DED Ti–6Al–4V walls; (k) and (l) just one rolling pass on the penultimate layer using
rolling loads of 50 kN and 75 kN respectively, and (m) and (n) with a rolling pass applied
to each layer, using rolling loads of 50 kN and 75 kN, respectively adopted from [73].
Mechanical properties of the as-built and rolled DED 5087 alloys: (o) microhardness and
(p) tensile strength properties adopted from [72].
Sand/bead blasting (SB) is the operation of propelling abrasive material such as sand or
ceramic beads against the target surface under high pressure. This treatment is
commonly used in multiple industrial sectors to smoothen the surface roughness, shape
form thin structures or remove surface oxides or contaminants. A schematic illustration
of the SB process is presented in Fig. 10a.
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Surface roughness reduction by using SB, especially using ceramic beads, has found its
way also to the biomedical field. SB has been widely applied to as-built cellular
structures designed to replace natural bone defects to improve their surface quality (
Fig. 10d and e) [76], [77].
Shot peening (SP) schematically illustrated in Fig. 11a, is a cold working process in which
the surface of a material is bombarded with a stream of small shots under controlled
intensity and coverage [78], [79], [80], [81], [82], [83]. SP has been applied to the AM
metallic materials as a post-treatment for controlling surface roughness (Fig. 11d–g),
grain refinement of the surface layer (Fig. 11b and c), inducing high compressive residual
stresses, increasing surface hardness and fatigue life improvement [51], [74], [84], [85],
[86], [87], [88], [89], [90], [91], [92], [93]. SP results in more regular surface morphology
compared to the as-built material although the treated surface remains rough. The
choice of parameters in SP process will highly define the final effects of the treatment on
AM parts. For example, using steel and ceramic shots to perform SP on LPBF AlSi10Mg
indicated higher surface microhardness caused by the impact of the steel shots. The
near-surface strain hardening, and compressive residual stresses were reported as the
main cause for rotating fatigue life improvement after SP, especially at high cycle fatigue
regime [87].
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Fig. 11. (a) Schematic illustration of SP process. Variations of the grains size and
orientations of LPBF 17-4 stainless steel before and after SP (b) SEM micrographs and (c)
crystals orientation map revealing the random distribution of grains orientation after SP
adopted from [86]. Three-dimensional surface texture of LPBF AlSi10Mg samples (d)
before and (e) after SP adopted form [88]. FESEM images of surface morphology and
roughness of a LPBF AlSi10Mg sample (f) before and (g) after SP adopted from [89].
The effects of different surface post-treatments, including TF, ECP, and SP were
investigated in a comparative study performed on the mechanical properties and
biological behavior of LPBF Ti–6Al–4V ELI parts [51]. The highest effect on roughness
reduction was obtained by ECP, followed by SP and TF. Surface roughness of the as-built
material in terms of Ra was decreased from 6.83 µm to 0.54, 3.36 and 4.96 µm after
applying ECP, SP and TF, respectively. The applied SP with Almen intensity of 6.4 A,
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coverage of 200% and impingement angle of 90° was more effective in hardness
improvement in both surface and depth in comparison with TF. As shown in Fig. 12a, SP
had a higher influence in inducing compressive residual stresses compared with the
other two treatments. Fig. 12b depicts the stress amplitude versus the number of cycles
to failure (S–N diagram) for the as-built and treated AM samples. It can be observed that
SP resulted in a notable fatigue strength improvement followed by TF and ECP.
Representative fracture surface of the as-built and treated AM samples after fatigue tests
are shown in Fig. 12c. The fractography analyzes revealed that in the TF and ECP samples,
the fatigue cracks initiated from the surface, similar to the as-built series. However, the
SP samples, despite the midlevel surface roughness between the three treatments,
exhibited the highest fatigue strength, displacing the crack initiation site to subsurface
layers, due to the higher compressive residual stresses. Regarding interaction with cells,
ECP and SP did not show any significant effects on cell growth and metabolic activity
compared to the as-built series.
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Fig. 12. Effects of different surface treatments including TF, ECP, and SP on LPBF Ti–6Al–
4V ELI parts: (a) residual stress profiles, (b) S-N curves of the treated and as-built
samples and (c) fractographic SEM images indicating the fatigue crack initiation sites
adopted from [51].
Cavitation peening (CP) is a shot-less peening technique that employs cavitation impact
instead of solid objects impacting the target. CP reduces the surface roughness and
induces compressive residual stresses in the surface layer, which can improve the fatigue
strength of metallic materials the same way as the SP process. CP is a hydrodynamic
phenomenon, and can be controlled by the flow pattern in the region where the bubbles
collapse [94].
The effects of CP have been surveyed on the fatigue behavior of PBF Ti–6Al–4V parts the
obtained results have been compared with SP treatment [90]. The surface roughness of
the as-built material was decreased in terms of Ra from about 19 µm to 17 and 4.5 µm
respectively, after CP and SP treatments. However, CP was more effective in enhancing
surface hardness. Overall, bending fatigue tests indicated that SP was more effective on
fatigue life improvement compared to CP.
The effects of CP and SP have been compared also in another study considering the two
processes as post-treatments for PBF Ti–6Al–4V samples [91]. The applied CP and SP
treatments had the same intensity based on the measured arc of the Almen strip (about
0.25 mm). As illustrated in Fig. 13a and b, CP minimally reduced the surface roughness of
the as-built sample from about 16.29 µm in terms of Ra to 16.13 µm; while SP decreased
the roughness to about 7.15 µm. The fatigue strength, however, was increased up to about
15% and 12% after CP and SP respectively. The results revealed that CP induced a higher
compressive residual stress (about −180 MPa) in comparison with SP (about −120 MPa).
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Fig. 13. Effect of CP on PBF Ti–6Al–4V: (a) as-built and (b) after CP adopted from [91].
Surface morphology of PBF Ti–6A–l4V treated by abrasive cavitation jet and peening
using different processing times: (c) as-built, (d) 5 s, (e) 10 s, (f) 20 s adopted from [95].
Another very similar process in the same category is an original surface finishing named
as abrasive water cavitation jet and peening process introduced by Soyama and Sanders
[95]. In this process, abrasive cavitation jet and cavitation peening are employed
simultaneously to decrease the surface roughness by abrasion and introducing
compressive residual stresses, respectively. This process was applied to PBF Ti–6Al–4V
samples. As displayed in Fig. 13c–f by using different processing times of 5, 10, and 20 s,
the surface roughness of the as-built material was decreased from 6.9 µm to 3.4, 1.9 and
1 µm, respectively. Furthermore, this post-treatment increased the surface hardness and
induced compressive residual stresses in the top surface layer. The fatigue test results
indicated a 66% plane-bending fatigue strength improvement at the optimum processing
time, which was reported to be 1 min
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been recently applied on AM metallic parts investigating its effect on the surface finish
and wear resistance of LPBF nickel-titanium parts; the obtained results indicated that the
surface roughness of the as-built material in terms of Ra was reduced from 12.1 µm to 9.0
µm after applying UNSM. It was also reported that the corrosion resistance significantly
improved as manifested by a much lower corrosion current [100]. In addition, the effects
of UNSM on surface and mechanical properties of LPBF Ti–6Al–4V were studied [101].
The results revealed decreased surface roughness of the as-built material from 10.4 µm to
6.8 µm in terms of Ra after UNSM (Fig. 14b and c). UNSM increased the hardness of the
as-built material from 372 Hv to 422 Hv showing also high compressive residual stresses
of about 1050 MPa in the surface of the treated material. Amanov [102] investigated
effect of UNSM on microstructure, roughness, hardness, tensile behavior and wear
resistance of LPBF 316 L parts. The results indicated that the surface roughness was
reduced from 1.6 µm to 0.3 µm in terms of Ra after UNSM; the UNSM treatment resulted
in notable surface hardness, tensile strength and dry sliding wear resistance
improvement, although the elongation was reduced from 40% to 24% after UNSM. In
addition, microstructural observations revealed that nanostructured grains were
generated on the top surface of the UNSM treated samples (Fig. 14d–g). Studying the
effect of different UNSM treatments on roughness and hardness of the DED AISI M4
revealed the importance of optimizing the process parameters particularly scanning
speed and static load on surface roughness reduction and hardness improvement (Fig. 14
h and i) [103].
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Fig. 14. (a) Schematic illustration of UNSM process. Surface scans of (b) as-built and (c)
UNSM-treated of LPBF Ti–6Al–4V adopted from [101]; cross-sectional images and IPF
EBSD maps of (d, e, g) as-built and (f, g) UNSM treated LPBF 316 L parts showing the
extent of surface plastic deformation adopted from [102]. Comparison of the micro-
hardness variation in depth for as-built and UNSM treated DED AISI M4 as a function of
UNSM process parameters (h) static load of 30 N and (i) scanning speed of 2500 mm/min
adopted from [103].
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covers the laser-based treatments that have been solely used to reduce the surface
roughness of as-built AM materials.
In laser shock peening (LSP), a laser beam is pulsed on the surface of a metallic target
material generating shock waves induced by laser ablation of a sacrificial layer (or water)
on the sample's surface; these shock waves travel throughout the surface layer of the
material causing plastic deformation and inducing compressive residual stresses [104].
The schematic illustration of LSP process is shown in Fig. 15a. The compressive residual
stresses induced by LSP are generally higher than those generated by SP, not only on the
surface but also in-depth (see Fig. 15b). 3D LSP, which is a novel approach that introduces
a repetitive LSP treatment in different directions, has been reported to have the highest
capacity between conventional LSP and SP treatments.
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Fig. 15. (a) Schematic illustration of LSP treatment. (b) Typical distribution of residual
stresses in LPBF parts, showing the influence of SP, LSP, and 3D LSP adopted from [105].
Effects of different post-treatments including SP, CP, and LSP on the surface morphology,
mechanical properties and fatigue behavior of PBF Ti–6Al–4V; surface morphology of the
(c) as-built and (d) LSP material, (e) arithmetical mean roughness Ra, (f) maximum
height of the roughness profile Rz (g) surface hardness and (h) fatigue behavior adopted
from [90].
LSP has been used in different studied as a post-treatment to improve the surface
properties of the AM metallic materials [105], [106], [107], [108], [109], [110]. The effects
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of SP, CP, and LSP have been examined and compared on mechanical properties and
fatigue behavior of PBF Ti–6Al–4V samples [90]. An injection pressure of 12 MPa and shot
diameter of 3.2 mm was used for SP; an injection pressure of 30 MPa and processing time
per unit of 10 s/mm for CP; for LSP a maximum energy of 0.35 J, a laser beam diameter of
6 mm, pulse width of 6 ns and repetition frequency of 10 Hz were considered. The
surface morphology of the as-built and LSP treated samples are shown in Fig. 15c and d.
Fig. 15e–g represent the effects of SP, CSP, and LSP on the surface roughness and surface
hardness. The results indicated that SP was the most efficient in reducing surface
roughness and increasing surface hardness. CP, LSP, and SP induced surface residual
stresses of −648 MPa, −450 MPa and −348 MPa, respectively compared to the as-built
material with on-surface residual stresses of −220 MPa [111]. All the applied post-
treatments resulted in considerable fatigue strength improvement compared to the as-
built material as shown in Fig. 15h. SP had the highest capability to improve fatigue life
followed by LSP and then CP treated series. This could be attributed to the counteracting
effect of surface roughness and compressive residual stresses.
Laser re-melting is the process of a second passage of laser source on the deposited layer
in order to melt the residual partially attached powders before the deposition of a new
layer. Different strategies have been implemented in this case: either applying the re-
melting on every single layer during production, which can considerably increase the
production time or applying it only after fabrication of the last outer layer of the
geometry. This technique has been performed with the aim of reducing roughness and
porosity [112], [113], [114], [115]. Increased current, reduced scanning speed, and higher
overlaps have been reported to result in improved performance of the laser re-melting
process [113], [116].
Laser polishing, very similar in concept to laser re-melting, provides the possibility of
reducing the surface roughness of AM parts while avoiding ablation phenomena. In this
process, the laser irradiates the material top surface with low laser pulses with a power
density able to cause local surface melting of the order of few nanometers up to
micrometers [117]. The effect of laser polishing on AM CoCr components has been
investigated in terms of surface state [118], mechanical properties [119], wettability [120]
, and corrosion behavior [121]. The efficiency of laser polishing in surface roughness
reduction has also been confirmed in another study on 18 Ni (300 grade) maraging steel
[122]. Fig. 16a and b illustrate the difference between the surface roughness of PBF Ti–
6Al–4V parts in as-built configuration and after laser polishing [123] and Fig. 16c and d
reveal the effects of laser polishing on LPBF CoCr parts [118]. In addition effects of laser
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polishing on surface roughness reduction and fatigue behavior improvement of LPBF Ti–
6Al–4V parts were investigated [124]. The results indicated remarkable surface
roughness decreasing from 14.21 µm in terms of Sa (as-built) to about 1.77 µm after laser
polishing. Comparison of the surface morphology of the treated material with different
treatments of laser plashing, grinding, SP and LSP is illustrated in Fig. 16e–i.
Fig. 16. Laser polishing effects on the surface of PBF Ti–6Al–4V samples (a) SEM
observation, (b) the 3D micrograph obtained by laser profilometer adopted form [123].
Effects of laser polishing on roughness reduction of a LPBF CoCr part: (c) as-built with Ra
of 7.8 µm and (d) laser polished material with Ra of 1.5 µm adopted from [118].
Comparing the surface morphology of the LPBF Ti–6Al–4V samples (e) as-built, and after
different treatments of (f) laser plashing, (g) grinding, (h) SP and (i) LSP adopted from
[124].
2.3. Coating
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Electro spark deposition was used to coat the surface of Inconel 625 samples fabricated
via binder jetting for roughness reduction and improving resistance to high temperature
oxidation [127]. Three different low, medium, and high energy parameters were used to
deposit AA4043 Al alloy on Inconel samples. As shown in Fig. 17a–d, the coatings
reduced the surface roughness of as-built material from 25.9 µm (in terms of Ra
parameter) to 7.8 µm, 10.9 µm, and 15.6 µm for the low, medium and high energy
processes, respectively. The high energy coating also increased the surface
microhardness. Likewise, other coating materials and methods were used on the AM
metallic materials for the improvement of mechanical properties such as hardness [128],
tensile strength [129], wear [130] and corrosion [131].
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A vast number of studies in this area have been targeted to tailor the interaction of AM
metallic implants with the biological environment regarding hydrophilicity,
biocompatibility, and osseointegration [132], [133]. Yan et al. [134] investigated the
effects of hydroxyapatite coating on lattice structures of LPBF Ti–6Al–4V to reduce
surface roughness and improve the bioactivity at the same time. Hydroxyapatite coatings
were formed by soaking the Ti–6Al–4V structures in simulated body fluid (SBF) up to 3
weeks. As can be observed in Fig. 17e–g, the surface roughness of the as-built lattice
structure was remarkably decreased and their bioactivity improved, confirmed by bone-
like apatite formation in SBF [135].
Anodizing has also been widely used to generate surface nano-features on especially on
AM Ti-based materials. Anodizing increases the thickness of the natural oxide layer on
the surface of the Ti part, generating an organized array of Titania nanotubes; it can
convert the surface into a durable, corrosion-resistant surface with improved bioactivity
and biocompatibility [137]. The bioactivity of PBF Ti–6Al–4V mesh structures was
assessed via immersion in SBF, after anodization. The nucleation and growth of fine
globular nanoscale apatite confirmed the favorable effect of anodization in improving the
biological response of the structures compared to the as-built material [138]. Fig. 17h–o
represents the efficacy of surface anodization in promoting cell attachment and
improving cell seeding efficiency [139]. Studies on the effects of anodizing on mechanical
properties showed improvement in corrosion resistance and increasing of voltage-time
response as electrical functionalities [140], [141].
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Plasma electrolytic oxidation (PEO) also known as microarc oxidation (MAO) is another
electrochemical surface coating derived from anodization technique to generate oxide
layers on the surface of metal substrates. PEO has been mostly employed to produce
thick, crystalline, oxide coatings mainly on as Ti, Al, and Mg alloys to improve hardness
and induce protection against wear, corrosion or heat, create electrical insulation, or
improve osseointegration and biocompatibility [142], [143]. The PEO process has been
used on porous LPBF Ti–6Al–4V structures to address the problem of implant-associated
infection (IAI) [144]. PEO induced a micro/nano-porous structure of Ti oxide (Fig. 17p) on
the surface of the implants. In vitro and ex vivo antimicrobial tests and cytotoxicity assays
were used to evaluate the performance of the developed implants in the biological
environment evidencing a strong bactericidal activity of the treated AM material.
The effect of the porous oxide surface layer created by PEO was investigated on the
mechanical performance of AM metallic structures [145]. By increasing PEO exposure
time, the oxidation did not have a considerable influence on the static mechanical
properties such as maximum strength, yield stress, and energy absorption, except the
elastic modulus that increased after 2 min oxidation. Comparison of the mechanical and
wear properties of PEO treated Cp-Ti prepared by LPBF showed that higher time and
temperature of PEO process could result in higher surface hardness, which led also to
increased friction and wear resistance [146].
Synergetic effects of SB or SP with HT were studied on LPBF AlSi10Mg samples [74]. The
surface morphologies of the treated materials with HT + SB and HT + SP are depicted in
Fig. 18a–c. Both treatments were very efficient in regulating the surface roughness of as-
built material. It was reported that although both sets of the applied hybrid post-
treatments had positive effects fatigue strength; the improvements were less notable
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compared to the cases where just the surface treatments (SB and SP) were applied to the
as-built material. This observation highlights the importance of calibrating the surface
treatment parameters to the AM metallic material properties after HT.
Fig. 18. Surface morphology of LPBF AlSi10Mg samples in (a) as-built (b) HT + SB and (c)
HT + SP configurations adopted from [74]. Surface morphology of LPBF Ti–6Al–4V lattice
in (d) as-built (e) HT + SB + HCl-etching and (f) HT + SB + HCl-etching + NaOH-etching
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The effects of combined HIP + polishing were also investigated on the fatigue strength of
PBF Ti–6Al–4V samples [155]. The results indicated that the combined effect of heat
treatment with reduced roughness and porosity led to a remarkable improvement in the
fatigue behavior. The influence of combined machining+polishing was investigated on
the fatigue behavior of the LPBF AlSi10Mg samples and the results were compared with
the effect of SB treatment [156]. The obtained data revealed that machining + polishing
(Sa = 0.5 µm) had higher impacts on roughness reduction of the as-built sample (Sa = 15.4
µm) compared to SB (Sa = 8.3 µm) (see Fig. 18n and o). Interestingly in this case, although
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SB induced compressive residual stresses, the fatigue limit was improved more by the
treatments that just reduced the surface roughness; that is, the fatigue limit increased
from 56 MPa (for the as-built sample) up to 194 and 152 MPa after applying machining +
polishing and SB, respectively.
3. Discussion
Surface post-treatments have been recognized to be particularly efficient in addressing
the issues associated with the irregular surface morphology of as-built AM metallic
parts. Applications of these post-treatments have been reported to enhance multiple
properties of the metallic AM parts. Fig. S1 (in the supplementary material) represents
the distribution of the number of studies considered in this review paper in terms of
treatments and its contribution to the target material property.
The choice of the proper surface treatment is mainly dictated by the surface quality,
material properties and part geometry as well as the target function of the AM part. For
instance for cases that will undergo cyclic loading, stricter criteria should be set on the
surface quality and in particular the surface valleys that can act as local notches. In the
absence of a systematic study, which compares different surface treatments against a
unique reference as-built state, we have listed the cases where two or more surface
treatments were compared in Table 1, to provide an overall comparison of the efficiency
of surface post-treatments applied on metallic AM materials.
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Sa = 6.65 µm Sa = 11.19 – –
µm
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peening
Ra = 7.15 µm Ra = 16.13 – –
µm
The order of presented surface post-treatments is based on their capability in reducing surface
roughness.
Ra: Arithmetic mean height of roughness profile, Pa: arithmetic mean height of primary (raw) profile,
Sa: arithmetic mean height of 3D roughness.
The studies highlight the role of shape and geometry of the AM metallic part in the
choice of the applied surface treatment. For instance, chemical surface treatments can
provide the possibility of performing a global surface treatment offering access to
internal surfaces of parts with intricate geometries. Therefore, for complex geometries
such as lattice and mesh structures, chemical treatments are more effective than the
mechanical ones that are highly restricted by the geometry and dimensional aspects of
the part. However, based on the form of the part, the parameters of chemical treatments
should be highly tuned to guarantee a uniform global extent of material removal.
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Moreover, chemical treatments, or in general those that result in material removal, if not
finely controllable, could alter the geometrical aspects of the as-built part. Thus, that is
another factor to include in the selection of the suitable surface treatment based on
dimensional tolerances.
Mechanical and laser-based treatments, both material removal and no material removal
categories, have been reported to be more effective in improving the mechanical
properties of AM metallic materials. Mechanical surface post-treatments that induce
material removal decrease surface roughness, can remove defects and pores within the
top surface layer, although they may induce tensile residual stresses, if not properly
performed; the latter, can have detrimental effect on the mechanical properties of the
AM part; however, the results reported on application of such treatments including
machining, milling, grinding etc., have shown that the roughness reduction has been
typically able to mask the detrimental effect of tensile residual stresses. Considering the
efficiency of these treatments, they have been even sourced for in situ application during
the manufacturing process to tackle the uncertainties associated with the AM process
through improving surface quality and geometrical accuracy [93], [157]. In situ
machining paired with proper monitoring approaches has been suggested for in-process
pore elimination. there are also reports of milling being integrated into the
manufacturing process to improve the geometrical accuracy of the near net shape final
product [158].
Other mechanical surface treatments that have led to promising results include sand
blasting, shot peening, laser shock peening and rolling; these treatments are able to
induce compressive residual stresses beside reducing surface roughness, and even in
some cases lead to near surface pore closure and surface grain refinement, if optimized
parameters are applied. Thus, they can serve as efficient surface treatments with extra
functionalities. Among these surface treatments, shot peening has been found to be of
particular interest, especially regarding fatigue strength improvement. Shot peening it is
easily scalable, does not considerably alter the dimension and geometry of the part, can
significantly reduce the surface roughness and eliminate the loose and partially attached
powders agglomerated on the surface of the as-built AM parts; moreover, it induces
considerable field of compressive residual stresses besides crack closure in the top
surface layer. The obtained results indicate a competition between the effect of surface
roughness and extension of the induced residual stresses induced by the peening-based
surface treatments. Indeed, there are some contradicting data on the effect of these
treatments that shed light on the prominence of the choice of the treatment parameters.
The comparison between these treatments cannot be straightforward and reliable if the
critical parameters including mainly the Almen intensity and coverage are not
comparable. The data available in the literature highlight the importance of calibrating
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the process parameters to the material and geometrical properties of the part to be
treated.
The application of coatings was mostly considered in the biomedical sector investigating
bio-related properties such as wettability, and the interaction with the cells and bacteria;
there exist also few studies using chemical and mechanical treatments on biocompatible
AM materials. Considering the high sensitivity of the cells and bacteria to the surface
topography at the biological interface, in this regard, the ability of the surface treatments
in generating highly controlled surface morphology is a crucial parameter. For instance,
anodizing and plasma electrolytic oxidation, that can offer precise control over the
dimension and arrangement of the surface features have been widely used for bio-
functionalization of AM materials.
In some cases, to achieve control over multiple target properties, which may not be
modulated using just a single treatment, hybrid treatments have been used. In these
cases, selective combinations of several processes have been considered to fill the gaps
and surpass the limitations of each single treatment. For instance, to considerably
improve the fatigue performance of AM metallic parts, firstly, a peening-based process
can be used for near-surface pore closure, surface layer grain refinement and inducing
compressive residual stresses; then material removal step using mechanical or chemical
treatment can be employed to decrease the surface roughness induced by the previous
peening treatment. Another example more aimed for biomedical application, can be to
apply a mechanical or chemical surface treatment based on slight material removal to
eliminate the random features on the as-built material and provide a smooth base for the
second chemical treatment that will induce surface nano-features with controlled
dimension and arrangement favorable for modulating interaction with the cells and
bacteria.
Fig. 19a shows a rough cost-estimation performed herein considering time and money as
the key factors that determine the cost; time and money were rated into five
comparative levels of very low, low, moderate, high and very high assigning a score from
1 to 5 to each according to the common approach used in cost and risk analysis and
management [159], [160] to construct a semi-quantitative matrix. The symmetric
distribution of cells of each factor’s level in this matrix can be used as a practical tool for
cost and risk ranking and analysis [161]. The final score of each treatment in terms of
cost has been estimated as the product of the time and the money score. Fig. 19b
represents the assigned scores to each of the surface post-treatment categories. The
comparative cost levels correspond to the authors' experience and knowledge. It can be
observed that mechanical and chemical treatments included in the category of material
removal surface post-treatments are ranked first followed by mechanical processes with
no material removal.
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Fig. 19. (a) Rating of the time and cost considering five different levels and the related
scores (b) scores and ranks of the applied surface post-treatments in terms of the cost
analysis.
Coatings have the fourth rank and laser-based processes due to the very high cost come
as the fifth rank. Hybrid treatments, that imply the application of at least two different
procedures through several steps, occupy the last rank in terms of cost analysis.
Based on the reported results in the literature, the application of post-treatments on the
as-built AM metallic materials and structures is essential to achieve favorable surface
properties and the desired bulk performance, regarding the final application of the AM
part. In addition to surface morphology and roughness, multiple mechanical properties
such as wettability, hardness, residual stress, friction, wear, and corrosion resistance,
fatigue behavior, biocompatibility and biological performance of the AM materials can be
tailored using proper surface treatments.
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Specific working conditions such as high temperatures, high dynamic loads in oxidizing
and corrosive environments will require customized surface treatments that in addition
to reducing the surface roughness of the AM metallic materials could ideally contribute
to enhanced performance under in-service conditions.
Another foreseeable area of research in the future that can represent a key to unlock the
full potential of surface post-treatments is focusing on designing hybrid treatments that
can simultaneously exploit combined beneficial effects of individual post-processes.
More systematic studies on hybrid treatments can pave the way for taking full advantage
of individual surface treatments and their synergistic effects to simultaneously improve
surface quality and enhance other mechanical properties of the additive manufacturesd
metallic materials.
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Acknowledgment
The financial support of Peen Service Srl, for funding the Ph.D. Scholarship of EM, is
gratefully appreciated.
Conflict of interest
The authors declare no conflict of interest.
Supplementary material.
Recommended articles
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