SOLUTION

M M M M

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Q.11 Degree of ionization of a solution depends upon :
(a) Nature of the solvent (b) Nature of the electrolyte
(c) Temperature (d) All of these
Q.12 The molarity of pure water is -
(a) 34.3 (b) 18 (c) 1 (d) 55.5
Q.13 A certain aqueous solution of FeCl3 (formula mass=162) has a density of 1.1 g/mL and
contains 20.0% FeCl3, Molar concentration of this solution is -
(a) 0.028 (b) 0.163 (c) 1.27 (d) 1.47
Q.14 PV=nRT is applicable to -
(a) Isothermal change (b) Adiabatic change
(c) Both (a) and (b) (d) None of these
Q.15 Which of the following are correct -
(a) water-glycerol mixture is called anti freeze mixture
(b) a deliquescent substance absorbs water in more amount than a hygroscopic
substance
(c) an ideal solution obeys Raoult's law
(d) all of these
Q.16 Isotonic solutions of solutes having neither dissociation nor association nature have the
same -
(a) Density (b) Molar cone (c) Viscosity (d) Normality
Q.17 In a 0.2 molal aqueous solution of a weak acid HX the degree of ionization is 0.3 Taking Kf
for water as 1.85, the freezing point of the solution will be nearest to -
0 0 0 0
(a) –0.480 C (b) –0.360 C (c) –0.260 C (d) +0.480 C
Q.18 25ml of a solution of barium hydroxide on titration with a 0.1 molar solution of hydrochloric
acid gave a titre value of 35ml. The molarity of barium hydroxide solution was -
(a) 0.07 (b) 0.14 (c) 0.28 (d) 0.35
Q.20 Formation of a solution from two components can be considered as -
(i) Pure solvent separated solvent, molecules, H1
(ii) Pure solute separated solute, molecules, H2
(iii) Separated solvent and solute molecules solution, H3
Solution so formed will be ideal if :
(a) Hsoln.= H1 + H2 + H3 (b) Hsoln.= H1 + H2 - H3
(c) Hsoln.= H1 - H2 + H3 (d) Hsoln.= H3 - H2 - H1
Q.21 At the freezing point of solution, there occurs equilibrium between -
(a) Solid solvent – liquid solvent (b) Solid solute – solution
(c) Liquid solvent – solute (d) Solid solute – liquid solute
Q.22 The molecular weight of benzoic acid in benzene as determined by depression in freezing
point method corresponds to -
(a) ionization of benzoic acid (b) dimerization of benzoic acid
(c) trimerization of benzoic acid (d) solvation of benzoic acid

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Q.23 Which of the following 0.1 M aqueous solutions will have the lowest freezing point?
(a) Potassium sulphate (b) Sodium chloride
(c) Urea (d) Glucose
Q.24 Equal volumes of 0.1 M AgNO3 and 0.2M NaCl solutions are mixed. The concentration of
NO3– ions in mixture solution will be -
(a) 0.1 M (b) 0.05 M (c) 0.2 M (d) 0.15 M
Q.25 Which of the following salt will have same value of Vant Hoff's factor (i) as that of
K4[Fe(CN)6]
(a) Al2(SO4)3 (b) NaCl (c) Al(NO3)3 (d) Na2SO4
Q.26 Which of the following behaviour is true about ideal binary liquid solution ?
(a) Plot of pTotal vs xA is non-linear (b) Plot of pTotal vs xB is linear
(c) Plot of pTotal vs xB is linear with slope = 0 (d) Plot of pTotal vs xA is linear
with slope = 0
Q.27 Vant Hoff's factor for 0.1M ideal solutions is -
(a) 0.1 (b) 0.01 (c) 1 (d) 2>1
Q.28 Which pair will not form ideal solution ?
(a) C2H5Br, C2H5I (b) C6H5Br, C6H5Cl (c) C6H6, C6H5CH3 (d) C2H5I, C2H5OH
Q.29 The Vant Hoff factor for 0.1 M Ba(NO2)2solution is 2.74. The degree of dissociation is -
(a) 91.3% (b) 87% (c) 100% (d) 74%
Q.30 An aqueous solution of 6.3g oxalic acid dihydrate is made up to 250ml. The volume of
0.1M NaOH required to completely neutralise 10ml of this solution is -
(a) 40 ml (b) 20 ml (c) 10 ml (d) 4 ml
Q.31 0.004 M solution of Na2SO4 is isotonic with 0.01 M solution of glucose at same
temperature. The apparent degree of dissociation of Na2SO4 is -
(a) 50% (b) 25% (c) 75% (d) 85%

Q.32

Q.33

Q.34

Q.35

Q.36

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Q.34 Assertion A - Half-life period is always independent of initial concentration.
Reason R - Half-life period in inversely proportional to rate constant.
(a) (b) (c) (d)
Q.35 Assertion A - G for photochemical spontaneous reaction may or may not be -ve.
Reason R - In photochemical reactions, the activation energy to reactants is provided by
light.
(a) (b) (c) (d)
Q.36 Assertion A - The rate of reaction can also increase with its product if one of the product
act as catalyst.
Reason R - A catalyst lowers with activation energy of reactions.
(a) (b) (c) (d)
Q.37 Assertion A - In zero order reaction, the conc. vs. time graph is a straight time.
Reason R - The rate of change of con. per unit time in zero order reaction remains
constant.
(a) (b) (c) (d)
Q.38 Assertion A - The order of a reaction is always whole number.
Reason R - The molecularity of a reaction is a whole number other than zero, but
generally less than 3.
(a) (b) (c) (d)
Q.39 Assertion A - Order of a reaction cannot be written from the balanced equation.
Reason R - Rate law can provide some clue about the reaction mechanism.
(a) (b) (c) (d)
Q.40 Assertion A - The rate of a reaction changes with the change in time.
Reason R - The concentrations of reactants decrease with the passage of time.
(a) (b) (c) (d)
Q.41 Assertion A - The reaction rate of most of the reactions doubles when temperature is
increased from 298K to 308 K.
Reason R - The activation energy of reaction decreases with increase of temperature.
(a) (b) (c) (d)
Q.42 Assertion A - The order of a reaction is related to molecularity of a reaction.
Reason R - Molecularity of the reaction cannot be fractional.
(a) (b) (c) (d)
Q.43 Assertion A - The slowest step in a reaction is the rate determining step.
Reason R - Order of a reaction is given by the rate law expression.
(a) (b) (c) (d)

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