SAFETY DATA SHEET

according to Workplace Safety and Health Regulations Singapore

Galva Spray

Section 1. Identification
Product identifier : Galva Spray
Product code : 110050

Relevant identified uses of the substance or mixture and uses advised against
Aerosol product

Supplier's details : WEICON GmbH & Co. KG

Königsberger Str. 255
48157 Münster
Germany
Phone: +49 251 93220
Fax: +49(0)251 / 9322 - 244
Internet: www.weicon.de
e-mail address of person : [email protected]
responsible for this SDS
Emergency telephone : EMERGENCY CONTACT – UK, UAE, South Africa (24h): Tel: ++44 1865 407333
number (English)
TRANSPORT EMERGENCY CONTACT - UK, UAE, South Africa (24h): Tel: ++44
1865 407333 (English)

Section 2. Hazards identification

Classification of the : AEROSOLS - Category 1
substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
AQUATIC HAZARD (LONG-TERM) - Category 1

GHS label elements, including precautionary statements

Hazard pictograms :

Signal word : Danger

Hazard statements : H222, H229 - Extremely flammable aerosol. Pressurized container: may burst if
heated.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
H373 - May cause damage to organs through prolonged or repeated exposure.
(central nervous system (CNS))
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention : P280 - Wear eye or face protection.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P211 - Do not spray on an open flame or other ignition source.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P260 - Do not breathe dust or mist.
P264 - Wash thoroughly after handling.
P251 - Do not pierce or burn, even after use.

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Section 2. Hazards identification

Response : P391 - Collect spillage.
P314 - Get medical advice or attention if you feel unwell.
P304 + P312 - IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice or attention.
Storage : P405 - Store locked up.
P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
Disposal : P501 - Dispose of waste according to applicable legislation.

Other hazards which do not : None known.

result in classification

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

acetone ≥10 - ≤25 67-64-1

ethyl acetate ≥10 - ≤25 141-78-6

Solvent naphtha (petroleum), light arom. ≤10 64742-95-6

xylene isomers mixture <10 1330-20-7

zinc dust <2.5 7440-66-6

Naphtha (petroleum), hydrodesulfurized heavy ≤3 64742-82-1

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Chemical formula : Not applicable.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention. If necessary, call a poison center or physician.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention following
exposure or if feeling unwell. Wash clothing before reuse. Clean shoes thoroughly
before reuse.

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Section 4. First aid measures

Ingestion : Wash out mouth with water. Remove dentures if any. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention. If necessary, call a poison center or physician. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : No known significant effects or critical hazards.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

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Section 5. Fire-fighting measures

Specific hazards arising : Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion. Gas may accumulate in low or confined areas
or travel a considerable distance to a source of ignition and flash back, causing fire
or explosion. Bursting aerosol containers may be propelled from a fire at high speed.
This material is very toxic to aquatic life with long lasting effects. Fire water
contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the
rapid escape of the pressurized contents and propellant. If a large number of
containers are ruptured, treat as a bulk material spillage according to the
instructions in the clean-up section. Do not touch or walk through spilled material.
Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid
breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C.
Do not pierce or burn, even after use. Do not breathe vapor or mist. Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid release to
the environment. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Store and use away from heat, sparks, open flame
or any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Empty containers
retain product residue and can be hazardous.
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Section 7. Handling and storage

Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry,
including any cool and well-ventilated area, away from incompatible materials (see Section 10)
incompatibilities and food and drink. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
acetone Workplace Safety and Health Act
(Singapore, 2/2006).
PEL (long term): 750 ppm 8 hours.
PEL (long term): 1780 mg/m³ 8 hours.
PEL (short term): 2380 mg/m³ 15 minutes.
PEL (short term): 1000 ppm 15 minutes.

ethyl acetate Workplace Safety and Health Act

(Singapore, 2/2006).
PEL (long term): 400 ppm 8 hours.
PEL (long term): 1440 mg/m³ 8 hours.

xylene isomers mixture Workplace Safety and Health Act

(Singapore, 2/2006). [Xylene]
PEL (long term): 100 ppm 8 hours.
PEL (long term): 434 mg/m³ 8 hours.
PEL (short term): 651 mg/m³ 15 minutes.
PEL (short term): 150 ppm 15 minutes.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection

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Section 8. Exposure controls/personal protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. Recommended : 1 - 4 hours
(breakthrough time): nitrile rubber 4 - 8 hours (breakthrough time): Viton®/butyl
rubber
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Recommended : organic vapor (Type AX) and particulate filter

Section 9. Physical and chemical properties

Appearance
Physical state : Aerosol.
Color : Silver.
Odor : Solvent. Sweetish.
Odor threshold : Not available.
pH : No results available.
Melting point/freezing point : Not available.
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: Not applicable.
Evaporation rate : Not available.
Flammability : Flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge and heat.
Lower and upper explosion : Not available.
limit/flammability limit
Vapor pressure :
Vapor Pressure at 20˚C Vapor pressure at 50˚C
Ingredient name mm Hg kPa Method mm Hg kPa Method
propane 6300.51 840

butane 1602.88 213.7

acetone 180.01 24

ethyl acetate 81.59 10.9

xylene isomers mixture 6.7 0.89

Hydrocarbons, C10-C13, n- 0.37503 0.05

alkanes, isoalkanes, cyclics, < 2%
aromatics

Relative vapor density : Not available.

Relative density : Not available.
Solubility(ies) :
Not available.

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Section 9. Physical and chemical properties

Solubility in water : Not available.
Miscible with water : No.
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not applicable.
Decomposition temperature : Not available.
Heat of combustion : 30.61 kJ/g
Viscosity : Not available.
Flow time (ISO 2431) : Not available.
Particle characteristics
Median particle size : Not applicable.
Aerosol product
Type of aerosol : Spray

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.
SADT : Not available.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
acetone LD50 Oral Rat 5800 mg/kg -

ethyl acetate LD50 Oral Rat 5620 mg/kg -

xylene isomers mixture LD50 Oral Mouse 2119 mg/kg -

LD50 Oral Rat 4300 mg/kg -

LD50 Oral Rat 4300 mg/kg -

LDLo Oral Human 50 mg/kg -

LDLo Oral Human 50 mg/kg -

TDLo Dermal Mouse 727.3 uL/kg -

TDLo Dermal Rabbit 4300 mg/kg -

Irritation/Corrosion

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Section 11. Toxicological information

Product/ingredient name Result Species Score Exposure Observation
acetone Eyes - Mild irritant Human - 186300 ppm -
Eyes - Mild irritant Rabbit - 10 uL -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
mg
Eyes - Severe irritant Rabbit - 20 mg -
Skin - Mild irritant Rabbit - 395 mg -
Skin - Mild irritant Rabbit - 24 hours 500 -
mg
xylene isomers mixture Eyes - Mild irritant Rabbit - 87 mg -
Eyes - Severe irritant Rabbit - 24 hours 5 -
mg
Skin - Mild irritant Rat - 8 hours 60 uL -
Skin - Moderate irritant Rabbit - 100 % -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
zinc dust Skin - Mild irritant Human - 72 hours 300 -
ug I
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
acetone Category 3 - Narcotic effects
ethyl acetate Category 3 - Narcotic effects
Solvent naphtha (petroleum), light arom. Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Naphtha (petroleum), hydrodesulfurized heavy Category 3 - Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Naphtha (petroleum), hydrodesulfurized heavy Category 1 - central nervous
system (CNS)
Aspiration hazard
Name Result
Solvent naphtha (petroleum), light arom. ASPIRATION HAZARD - Category 1
Naphtha (petroleum), hydrodesulfurized heavy ASPIRATION HAZARD - Category 1

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.

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Section 11. Toxicological information

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : No known significant effects or critical hazards.
Ingestion : Can cause central nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

General : May cause damage to organs through prolonged or repeated exposure.

Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
acetone 5800 N/A N/A N/A N/A
ethyl acetate 5620 N/A N/A N/A N/A

Acute toxicity estimates

Route ATE value
Not available.

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Section 11. Toxicological information

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
acetone Acute EC50 11493300 µg/l Fresh water Algae - Navicula seminulum 96 hours

Acute EC50 11727900 µg/l Fresh water Algae - Navicula seminulum 96 hours

Acute EC50 7200000 µg/l Fresh water Algae - Selenastrum sp. 96 hours

Acute EC50 20.565 mg/l Marine water Algae - Ulva pertusa 96 hours

Acute LC50 4.42589 ml/L Marine water Crustaceans - Acartia tonsa - 48 hours
Copepodid

Acute LC50 7550000 µg/l Fresh water Crustaceans - Asellus aquaticus 48 hours

Acute LC50 8098000 µg/l Fresh water Crustaceans - Ceriodaphnia 48 hours

dubia - Neonate

Acute LC50 11.26487 ml/L Fresh water Crustaceans - Gammarus pulex 48 hours
- Juvenile (Fledgling, Hatchling,
Weanling)

Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours

Acute LC50 7460000 µg/l Fresh water Daphnia - Daphnia cucullata 48 hours

Acute LC50 7810000 µg/l Fresh water Daphnia - Daphnia cucullata 48 hours

Acute LC50 10000 µg/l Fresh water Daphnia - Daphnia magna 48 hours

Acute LC50 9218000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate

Acute LC50 8800000 µg/l Fresh water Daphnia - Daphnia pulex 48 hours

Acute LC50 8000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours

Acute LC50 7280000 µg/l Fresh water Fish - Pimephales promelas 96 hours

Acute LC50 8120000 µg/l Fresh water Fish - Pimephales promelas 96 hours

Acute LC50 6210000 µg/l Fresh water Fish - Pimephales promelas 96 hours

Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours

Chronic NOEC 0.5 ml/L Marine water Algae - Karenia brevis 96 hours

Chronic NOEC 100 ul/L Marine water Algae - Skeletonema costatum 72 hours

Chronic NOEC 100 ul/L Marine water Algae - Skeletonema costatum 96 hours

Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours

Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days

Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate

Chronic NOEC 5 µg/l Marine water Fish - Gasterosteus aculeatus - 42 days

Larvae

ethyl acetate Acute EC50 2500000 µg/l Fresh water Algae - Selenastrum sp. 96 hours

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Section 12. Ecological information

Acute LC50 750000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours

Acute LC50 154000 µg/l Fresh water Daphnia - Daphnia cucullata 48 hours

Acute LC50 212500 µg/l Fresh water Fish - Heteropneustes fossilis 96 hours

Chronic NOEC 2400 µg/l Fresh water Daphnia - Daphnia magna 21 days

Chronic NOEC 75.6 mg/l Fresh water Fish - Pimephales promelas - 32 days
Embryo

xylene isomers mixture Acute EC50 90 mg/l Fresh water Crustaceans - Cypris 48 hours
subglobosa

Acute LC50 8.5 ppm Marine water Crustaceans - Palaemonetes 48 hours

pugio - Adult

Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours

pugio

Acute LC50 16940 µg/l Fresh water Fish - Carassius auratus 96 hours

Acute LC50 15700 µg/l Fresh water Fish - Lepomis macrochirus - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)

Acute LC50 20870 µg/l Fresh water Fish - Lepomis macrochirus 96 hours

Acute LC50 19000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours

Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours

zinc dust Acute EC50 10000 µg/l Fresh water Aquatic plants - Lemna minor 4 days

Acute IC50 65 µg/l Marine water Algae - Nitzschia closterium - 4 days

Exponential growth phase

Acute LC50 65 µg/l Fresh water Crustaceans - Ceriodaphnia 48 hours

dubia - Neonate

Acute LC50 68 µg/l Fresh water Daphnia - Daphnia magna 48 hours

Acute LC50 12.21 µg/l Marine water Fish - Periophthalmus waltoni - 96 hours
Adult

Chronic EC10 59.2 µg/l Fresh water Daphnia - Daphnia magna 21 days

Chronic NOEC 0.25 mg/l Marine water Algae - Ulva pertusa 96 hours

Chronic NOEC 9 mg/l Fresh water Aquatic plants - Ceratophyllum 3 days

demersum

Chronic NOEC 178 µg/l Marine water Crustaceans - Palaemon 21 days

elegans

Chronic NOEC 2.6 µg/l Fresh water Fish - Cyprinus carpio 4 weeks

Persistence/degradability
Not available.

Bioaccumulative potential

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Section 12. Ecological information

Product/ingredient name LogPow BCF Potential
acetone -0.23 - low
ethyl acetate 0.68 30 low
Solvent naphtha (petroleum), - 10 to 2500 high
light arom.
xylene isomers mixture 3.12 8.1 to 25.9 low
Naphtha (petroleum), - 10 to 2500 high
hydrodesulfurized heavy

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Empty containers or liners may retain
some product residues. Do not puncture or incinerate container.

Section 14. Transport information

UN IMDG IATA ADR/RID
UN number UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS Aerosols, flammable AEROSOLS

shipping name
Transport hazard 2.1 2.1 2.1 2
class(es)

Packing group - - - -
Environmental Yes. The Yes. Yes. The Yes.
hazards environmentally environmentally
hazardous substance hazardous substance
mark is not required. mark is not required.
Additional information
UN : Special provisions 63, 190, 277, 327, 344, 381
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules F-D, S-U
Special provisions 63, 190, 277, 327, 344, 381, 959
IATA : The environmentally hazardous substance mark may appear if required by other
transportation regulations.
Quantity limitation Passenger and Cargo Aircraft: 75 kg. Packaging instructions:
203. Cargo Aircraft Only: 150 kg. Packaging instructions: 203. Limited Quantities -
Passenger Aircraft: 30 kg. Packaging instructions: Y203.
Special provisions A145, A167, A802

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Section 14. Transport information

ADR/RID : The environmentally hazardous substance mark is not required when transported in
sizes of ≤5 L or ≤5 kg.
Limited quantity 1 L
Special provisions 190, 327, 625, 344
Tunnel code (D)
ADR Classification Code: 5F

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

Section 15. Regulatory information

Singapore - hazardous chemicals under government control
None.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.
Inventory list
Australia : Not determined.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Eurasian Economic Union : Russian Federation inventory: Not determined.
Japan : Japan inventory (CSCL): All components are listed or exempted.
Japan inventory (ISHL): Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Republic of Korea : Not determined.
Taiwan : Not determined.
Thailand : Not determined.
Turkey : Not determined.
United States : All components are active or exempted.
Viet Nam : Not determined.

Date of issue/Date of revision : 10/20/2022 Date of previous issue : 10/19/2022 Version : 3.01 13/14
Galva Spray

Section 16. Other information

History
Date of printing : 5/14/2023
Date of issue/Date of : 10/20/2022
revision
Date of previous issue : 10/19/2022
Version : 3.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Procedure used to derive the classification
Classification Justification
AEROSOLS - Category 1 On basis of test data
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Calculation method
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
AQUATIC HAZARD (LONG-TERM) - Category 1 Calculation method
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

Date of issue/Date of revision : 10/20/2022 Date of previous issue : 10/19/2022 Version : 3.01 14/14