Scribd
Upload
15 views5 pages

Q311QQ

Uploaded by

dryasmine4
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
15 views5 pages

Q311QQ

Uploaded by

dryasmine4
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 5

1- The wave function of hydrogen atom is given by:

 ( r , , ) = R(r ) Y( , )
i. Define each of R and Y. What are the quantum numbers for each of them?
ii. What are the relations between these quantum numbers?
iii. Write the Hamiltonian operator for the H-atom.

iv. For n = 2, write all possible wave functions  ( r , , )

2-Consider the following wave function of hydrogen atom:


3/ 2
1 Z 
 2s =   ( 2 −  ) e − / 2 , where  =Zr/a 0
32  a0 
i. What are the values of the quantum numbers n, l, ml.
ii. At what value of r will  be vanished.
iii. Draw the radial probability density of this function.
iv. The geometrical shape of this function is spherical. Explain why?

3- What is the DIFFERENCE between each pair of the following:

• Ψ1s and Ψ2s


• Radial part of wave function and Angular part of wave function
• Orbit and Orbital

4-Give REASON for each of the following: (10 points)


• All s-orbital are spherical in shape
• The atomic spectra of H-atom are not equidistant
• There no common operator for the potential energy of any system
• Schrodinger equation of H-atom can be solved by the separation of
variables method
• The energy of 2s- and 2p-orbital have the same value
• All s-orbital are spherical in shape
• There are NINE solutions in the third level of H-atom
• The WF ψ2pz is localized on the principal axis-z only
• No nodes were found in the WF ψ2pz and The WF ψ1s of H-atom
• The quantum number l and m have a zero value while the quantum
number n not equal zero
• There is no Ψ000 wavefunction in the hydrogen atom
• The energies of 2s and 2p orbitals are the same in hydrogen-like
species, while in many-electron atoms they are not.
• To solve the Schrodinger equation for hydrogen atom it is most
convenient to work in spherical polar coordinates
•

5- The Schrodinger equation and eigen function for H-atom are


given by:

H Ψ = E Ψ and  ( r , , ) = R(r ) Y( , )


-Write the H operator for the H-atom
-Define R(r) and Y (θ, φ)
-what are the quantum numbers for R(r) and Y (θ, φ)
-write the relations between these quantum numbers
-For n=2, write all possible wave functions Ψ(r, θ, φ)
-Calculate the energy of the ground state
6-THE MOST CORRECT ANSWER:

1-Why does the method of separation of variables work better for problems
like the hydrogen atom when done in spherical coordinates (r,θ,φ) than it
does when you work in Cartesian coordinate (x,y,z)?
A) Because Schrodinger’s equation treats the three directions (x,y,z) completely
differently, while it treats (r,θ,φ) all the same
B) Because the derivative terms in spherical coordinates are independent on each other
C) Because the energy term only gets simpler in spherical, not Cartesian coordinates
D) Because Schrodinger’s equation is naturally written in spherical coordinates
2-In class we divided up the hydrogen atom into a radial function R (r) and an
angular function Y (θ, φ). Under what circumstances can we reuse these
functions Y (θ, φ) on another problem?
A) They can be used on any problem in 3D, and they are always exactly the same
B) They can be used on any problem in 3D, though their functional form will change
C) They can be used on any spherically symmetric problem, and they are always
exactly the same
D) They are worked out and can only be used for hydrogen-like atoms
3- Which of the following statements about the hydrogen atom ground state is
INCORRECT?
A) It is described by the quantum numbers n = 1, 𝓵 = 0, m = 0.
B) The electron’s angular momentum equals h/2π.
C) The wave function is spherically symmetrical.
D) The radial distribution function has its maximum at the Bohr radius a0.

4- Which one of the following sets of quantum numbers is valid?


n 𝓵 𝒎𝓵 ms
A) 2 3 –3 +½
B) 4 3 4 –½
C) 3 1 0 +½
D) 1 –1 1 +½
5-In the second level of H-atom, there are FOUR solutions of Schrodinger equation
designated
as:

A) Radial solutions B) Angular solutions


C) Radial and Angular solutions D) None of the above

6- Which of the following is a wave function, (r,,), for an s electron?


A) 𝑨(𝟐 − 𝒓)𝒆−𝒓/𝟐
B) 𝑨𝒓𝒆−𝒓/𝟐 𝒔𝒊𝒏𝜽𝒄𝒐𝒔
C) 𝑨𝒓𝒆−𝒓/𝟐 𝒄𝒐𝒔𝜽
D) 𝑨𝒓𝒆−𝒁/𝟐 𝒔𝒊𝒏𝜽𝒔𝒊𝒏

7-State whether each of the following statements is TRUE or FALSE


1- The probability of finding an electron in the 1s-orbital increases, as the distance from

the nucleus increases.

2 - In the first level of H-atom, there is only one radial-angular solution.


3-The size of the 1s-orbital and 2s-orbital are equal.

4- In the 3rd level of H-atom, there are 6-solutions of Schrödinger equation.

5- The wave function for 2pz-orbital is ψ211.

6- There are two nodes in the ψ2s wave function.

7- The energy of the 2s-orbital and 2p-orbital are equal.

8- No nodes were found in the first level ψ1s of H-atom.

You might also like