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Cartridges - Centerfire

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0% found this document useful (0 votes)
29 views10 pages

Cartridges - Centerfire

Uploaded by

thriftersnh01
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 10

SAFETY DATA

SHEET
Page 1 of 4

Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, Japanese Standard JIS Z 7250:2000, and EU REACH Regulations

1. PRODUCT AND COMPANY IDENTIFICATION


Product Name: CARTRIDGES – CENTERFIRE
CAS Number: Mixture – Metal Alloy
Synonyms: Centerfire Rifle Brands: Super-X, Super-X Subsonic, Supreme, Varminator, Defender, Match, USA Brand,
Metric Calibers, Ranger, Power Max Bonded, Varmint X, XP3, AccuBond CT, Ballistic Silvertip, Safari, Win
3 Gun, Deer Season XP, Deer Season XP Copper Impact, Extreme Point, Extreme Point Copper Impact,
Expedition Big Game, Expedition Big Game Long Range, Hog Special, Super Suppressed, E-Tip Lead-
Free, PowerCore, SRTA (Short Range Training Ammunition), Super Clean ZFMJ, Varmint X Lead Free,
Razorback, Razorback XT, Razor Boar XT, Ballistic Silvertip Lead Free, Safari, Nosler Solid, Deer Season
XP Copper Impact, USA Dove & Clay, USA Game & Target, USA READY, WWII Victory Series, Service
Grade, Ranger ONE.

Centerfire Pistol/Revolver Calibers: 5.7x28mm, 25 Automatic (6.35mm), 30 Carbine, 30 Luger (7.65mm), 32


Smith & Wesson, 32 Smith & Wesson Long, 32 Short Colt, 32 Automatic, 357 Magnum, 38 Special, 38
Special +P, 38 Special +P+, 38 Smith & Wesson, 38 Super Automatic +P, 7.62x25 Tokarev, 9mm, 9mm
Luger, 9mm Luger +P, 9mm NATO, 9mm +P+, 9mm Makarov, 9x18mm, 9x21mm, 9x23 Winchester, 357
Magnum, 357 Sig, 40 Smith & Wesson, 10mm Automatic, 41 Remington Magnum, 44-40 Winchester, 44
Remington Magnum, 44 Smith & Wesson Special, 45 Glock, Automatic Pistol (G.A.P.), 45 Automatic, 45
Colt, 45 Winchester Magnum, 454 Casull, 460 Smith & Wesson Magnum, 500 Smith & Wesson Magnum.

Centerfire Rifle Bullet Names: Power-Point, Power Point Plus, Power-Point Subsonic, Silvertip, Ballistic
Silvertip, AccuBond CT, AccuBond LR, Pointed Soft Point, Full Metal Jacket, Positive Expanding Point,
Match BTHP, PDX1, Partition, Partition Gold, Fail Safe, Power Max Bonded, Hollow Point Boattail, Boattail
Hollow Point, Polymer Tip, Protected Hollow Point, Split Core Hollow Point, XP3, Bonded Solid Base, Open
Tip, Extreme Point, Bonded, M1, M2.

Centerfire Rifle Calibers: 204 Ruger, 218 Bee, 22 Hornet, 220 Swift, 222 Remington, 22-250
Remington, 5.56mm, 223 Remington, 223 Winchester Super Short Magnum, 225 Winchester, 243
Winchester, 6mm Remington, 243 Winchester Super Short Magnum, 25 Winchester Super Short
Magnum, 25-06 Remington, 250 Savage, 256 Winchester Magnum, 25-20 Winchester, 25-35
Winchester, 257 Roberts +P, 6.5 Creedmoor, 264 Winchester Magnum, 6.5x55mm Swedish, 270
Winchester, 270 Winchester Short Magnum, 280 Remington, 284 Winchester, 7mm-08 Remington, 7mm
Winchester Short Magnum, 7mm Remington Magnum, 7mm Mauser, 7mm Shooting Times Westerner,
7.62x39mm, 30 Carbine, 30-30 Winchester, 30-06 Springfield, 30-40 Krag, 300 Blackout, 300 Holland &
Holland Magnum, 300 Winchester Short Magnum, 300 Winchester Magnum, 300 Savage, 303 British, 307
Winchester, 308 Winchester, 7.62x51mm NATO, 7.62x54R, 9.3x62mm, 8x57mmJRS, 7x64mm,
9.3x74mmR32 Winchester Special, 32-20 Winchester, 32-40 Winchester, 8mm Mauser, 325 Winchester
Short Magnum, 338 Winchester Magnum, 338 Lapua Magnum, 348 Winchester, 35 Remington, 356
Winchester, 357 Magnum, 358 Winchester, 375 Winchester, 375 Holland & Holland Magnum, 38-40
Winchester, 38-55 Winchester, 41 Remington Magnum, 416 Remington Magnum, 416 Rigby, 44
Remington Magnum, 44-40 Winchester, 45-70 Government, 450 Bushmaster, 458 Winchester Magnum,
450 Bushmaster, 350 Legend, 6.5 Creedmoor.

Military Centerfire Rifle/Pistol Bullet Names: XM1152, XM1153, Ball, Full Metal Jacket, Penetrator, Long
Range Sniper, Bonded Solid Base, Open Tip, M193, M855, M855A1, M80, M80A1, M33.

Military Centerfire Rifle Calibers: 5.56mm, 5.56x45mm, 7.62mm NATO, 7.62x51mm, 50 Caliber, Caliber
50.

Centerfire Pistol/Revolver Brands: Super-X, Supreme, Defender, Metric Calibers, Ranger, Subsonic, Dual
Bond, Train & Defend, Platinum Tip, Win 1911, Win 3 Gun, Forged, USA Brand, USA Forged, Service
Grade, Super Suppressed, Hybrid X, WinClean.

Centerfire Pistol/Revolver Bullet Names: Silvertip Hollow Point (STHP), Expanding Point, Full Metal
Jacket, Lead, Lead-Round Nose, Bonded, Bonded Hollow Point, Brass Enclosed Base (BEB), Jacketed
Hollow Point, Jacketed Soft Point, Lead-Wad Cutter, Lead-Semi Wadcutter, Jacketed Flat Point,
Platinum Tip, Dual Bond, Full Metal Jacket Encapsulated, SXT, PDX1, Partition Gold, T-Series, Hybrid X,
M1911.

SDS #00050.0001
Page 2 of 10

Product Use: Centerfire Rifle and Pistol/Revolver Loaded Ammunition


U.N. Number: UN 0012 / UN 0339
U.N. Dangerous Goods Explosive, 1.4S / 1.4C
Class
Manufacturer/Responsible Olin Winchester, LLC
Party:
Manufacturers’ Address: 600 Powder Mill Road, East Alton, IL 62024 www.winchester.com

Emergency Telephone US/Canada: 1-800-424-9300


Number: Outside US/Canada: 703-527-3887

SDS Control Group: 618-258-3507 (Technical Information Only)

Olin SDS No.: 00050.0001 Issue Date: 6/1/15


Revision Date: 03/11/2020

Revision No.: 8

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW : EXPLOSIVE. KEEP AWAY FROM HEAT. DO NOT SUBJECT TO MECHANICAL SHOCK.
PARTICLES FROM FIRING MAY BE HARMFUL IF INHALED. DO NOT TAKE INTERNALLY.

US DOT SYMBOLS CANADA (WHMIS) SYMBOLS GHS HAZARD SYMBOLS

This Product is not subject to WHMIS

Class 6 Explosive

SDS No.: 00050.0001


Page 3 of 10

GHS Classifications: Carcinogenicity Category 1A


Reproductive Toxicity Category 1A
Explosive Division 1.4
STOT RE Category 1
Aquatic Environment, Chronic II

Signal Word: Danger

Hazard Statements : H204: Fire or projection hazard


H350: May cause cancer
H360: May damage fertility or the unborn child
H362: May cause harm to breast-fed children
H372: Causes damage to nervous system, kidney, and hematopoietic system through prolonged
or repeated exposure
H411: Toxic to aquatic life with long lasting effects

Target organs: Nervous, renal and hematopoietic systems

Precautionary Statements: P102: Keep out of reach of children


P210: Keep away from heat/sparks/open flame/hot surfaces
P250: Do not subject to shock/friction
P260: Do not breathe fumes
P264: Wash hands thoroughly after handling
P270: Do not eat, drink or smoke when using this product
P271: Use only outdoors or in a well-ventilated area
P273: Avoid release to the environment
P280: Wear /protective clothing/eye protection/hearing protection
P370+P380: In case of fire: Evacuate area
P374: Fight fire with normal precautions from a reasonable distance
P410: Store in accordance with local regulations
P501: Dispose of contents in accordance with local regulations

GHS Pictograms: Explosive; Pictogram: exploding bomb


Specific Target Organ Toxicity; Pictogram Code: GHS08
Environment; Pictogram Code: GHS09

EU Classifications:
Hazard Symbols E, T, N
Risk Phrases R2: Risk of explosion by shock, friction, fire or other sources of ignition
R45 (Category 1): May cause cancer
R48: Danger of serious damage to health by prolonged exposure
R60/61 (Category 1): May impair fertility or cause harm to the unborn child
R63: Possible risk of harm to the unborn child
R64: May cause harm to breast-fed children
R51/53: Toxic to aquatic organisms and many cause long-term adverse effects in the aquatic
environment
Safety Phrases S2: Keep out of reach of children
S15: Keep away from heat
S20/21: When using do not eat, drink or smoke
S23: Do not breathe fumes
S39: Wear eye/face protection
S43: In case of fire, use Class A equipment
S51: Use only in well-ventilated areas
S61: Avoid release to the environment

SDS No.: 00050.0001


Page 4 of 10

Health Hazards or Risks From Exposure

This product is composed of a finished metal alloy cartridge which contains the various components completely sealed within.
Therefore, under normal handling of this product, no exposure to any harmful materials will occur. When the ammunition is fired, a
small amount of particles may be generated which may be slightly irritating to the eyes and the respiratory tract. The particles may
contain trace amounts of these harmful substances:

Lead: Ingestion of large amounts of lead can cause abdominal pain, constipation, cramps, nausea and/or vomiting. Chronic
exposure to lead can cause kidney damage, anemia, reproductive effects, developmental effects and permanent nervous system
damage in humans including changes in cognitive function. Occupational exposure to lead is associated with lung and stomach
cancer. Lead is classified as a probable human carcinogen.
Nitroglycerin: Will produce dilation of blood vessels and drop in blood pressure which may affect the heart. It has also been shown to
cause methemoglobinemia (cyanosis).
Copper: Inhalation of high concentrations of metallic copper dusts or fumes may cause nasal irritation and/or nausea, vomiting and
stomach pain.

It is unlikely that the amount of particles that someone would be exposed to from firing a loaded round would be sufficient to cause
any of these effects.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Components % By Weight CAS Number EINECS/ ELINCS #

Lead 0.5 - 70 7439-92-1 231-100-4


Copper 0.5 - 60 7440-50-8
231-159-6
Iron 0 – 60 7439-89-6 231-096-4
Zinc 0.1- 20 7440-66-6 231-175-3
Nitrocellulose 1 - 20 9004-70-0
Not listed
Nitroglycerin 0.2 - 2 55-63-0
200-240-8
Lead Styphnate 0 -1 15245-44-0
239-290-0
Antimony 0 – 1.5 744036-0
231-146-5
Tin 0 – 30 7440-31-5
231-141-8
Polyethylene 0–3 9002-88-4
Not listed

4. FIRST AID MEASURES

Eye Contact: Immediately flush out fume or particles with large amounts of water for at least 15 minutes, occasionally lifting
the upper and lower eyelids. If eye irritation develops, call a physician at once.
Skin Contact: Wash skin with plenty of soap and water.
Inhalation: If symptoms of lung irritation occur (coughing, wheezing or breathing difficulty), remove from exposure area to
fresh air immediately. If breathing has stopped, perform artificial respiration. Keep affected person warm and at
rest. Get medical attention.
Ingestion: If ingested, immediately call a physician.

Medical Conditions Aggravated By Exposure:


There are no medical conditions known to be aggravated by exposure to this product in its solid form. Exposure to lead can
aggravate anemia, cardiovascular and respiratory disease.

Recommendations To Physcians:
Remove from exposure, if possible, and treat symptoms

SDS No.: 00050.0001


Page 5 of 10

5. FIRE FIGHTING MEASURES

PROPERTY VALUE PROPERTY VALUE


Explosive Yes Flammable Not applicable
Combustible Not applicable Pyrophoric No
Flash Point (C): Not applicable Burning Rate of Material: Not applicable
Lower Explosive Limit: Not applicable Autoignition Temp.: No data
Upper Explosive Limit: Not applicable Flammability Classification: (defined by 29 CFR 1910.1200) Explosive

Unusal Fire and Explosion Hazards: Possible projection hazard.

Special Firefighting Procedures: Do not fight fire when fire reaches cargo. Cargo may explode.

Firefighters must wear self-contained breathing apparatus (SCBA) and full


protective equipment. Structural firefighters’ protective clothing will only provide
limited protection.

Isolate materials not yet involved in the fire. Move containers from fire area if
possible; otherwise, cool with carefully applied water spray.

Prevent runoff water from entering storm drains, bodies of water, or other
environmentally sensitive areas, if practical.

NFPA RATING SYSTEM HMIS RATING SYSTEM

Flammability
HEALTH HAZARD (BLUE) 0*

FLAMMABILITY HAZARD (RED) 1


1
PHYSICAL HAZARD (YELLOW) 2
Health 0 2 Reactivity
PROTECTIVE EQUIPMENT
EYES PPE RESPIRATORY HEARING
- CODE

See Sect 8 See


A
Sect 8
Other

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard

6. ACCIDENTAL RELEASE MEASURES

FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC AT 800-424-9300.

Spill Response: A spill of this material will normally not require emergency response team capabilities. If,
however, a large spill occurs, call 1-888-289-1911 for technical assistance.
Accidental Release Procedures: Spills of this material should be handled carefully. Do not subject materials to mechanical
shock. Collect material and place in a designated, labeled waste container. See Section 13 for
waste disposal.

SDS No.: 00050.0001


Page 6 of 10
7. HANDLING AND STORAGE

Precautions for Safe Handling: Use appropriate personal protective equipment (see Section 8). Workers should
wash thoroughly after handling. Eating, drinking and smoking should be
prohibited in areas where this material is handled and stored.
Conditions for Safe Storage: Store in accordance with local regulations. Store in original containers in a cool,
dry location away from Acids, Class A & B explosives, strong oxidizers, and
caustics. Avoid mechanical impact or shock and electrical discharge.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters:

CAS # CHEMICAL ACGIH TLV OSHA PEL INTERNATIONAL OELS


NAME
7439-92-1 Lead 0.05 mg/m3 0.05 mg/m3 EU: 0.15 mg/m3 (inhalable aerosol)
(total dust) Finland, Japan, Sweden, Switzerland: 0.1 mg/m 3
7440-50-8 Copper 0.2 mg/m3 (fume), 1 0.1 mg/m3 (fume) Austria, Belgium, Canada: 0.2 mg/m3 (fumes), 1
mg/m3 (dusts and 1 mg/m3 (dusts and mg/m3 (dusts)
mists) mists) Denmark: 1.0 mg/m3 (dust and powder)
Germany (MAK): 0.1 mg/m3 (fume), 1 mg/m3 (dusts
and mists)
7439-89-6 Iron None established None established None established
7440-66-6 Zinc None established None established None established
9004-70-0 Nitrocellulose None established None established None established
55-63-0 Nitroglycerin 0.05 ppm (0.46 mg/m3) Ceiling – 0.2 ppm Denmark: 0.02 ppm (0.2 mg/m3)
Skin (2 mg/m3) Norway, Sweden: 0.03 ppm (0.3 mg/m3)
Skin Austria, Belgium, Germany, The Netherlands,
Poland, Switzerland: 0.05 ppm (0.47 mg/m3), skin
Finland, France: 0.1 ppm (0.9 mg/m3), skin
U.K.: 0.2 ppm (2 mg/m3), skin
55-63-0 Lead Styphnate None Established None Established None Established
7440-36-0 Antimony 0.5 mg/m3 0.5 mg/m3 Austria, Belgium,Denmark, France, Finland,
Germany, Hungary, Netherlands, Norway, Poland,
Sweden, UK: 0.5 mg/m3
7440-31-5 Tin 2 mg/m3 2 mg/m3 U.K. (LTEL): 5 mg/m3
Austria & Germany (MAK), Belgium, Finland,
Denmark, The Netherlands, Poland, Switzerland: 2
mg/m3
Hungary, Norway: 1 mg/m3

Engineering Controls: Local exhaust ventilation is recommended if significant dusting occurs or fumes are generated.
Otherwise, use general exhaust ventilation.
Respiratory Protection: Not normally needed. Maintain airborne contaminant concentrations below guidelines listed above.
Use an appropriate approved air-purifying respirator equipped with HEPA cartridges/canisters where
there is the potential for exceeding established occupational exposure limits.
Eye/Face Protection: Use safety glasses.
Hand Protection: Not normally needed
Skin Protection: Not normally needed.
Hearing Protection: Not normally needed. During firing use hearing protection.
General Hygiene: Do not eat, drink, or smoke while using this product. Wash hands thoroughly after use.

SDS No.: 00050.0001


Page 7 of 10
9. PHYSICAL AND CHEMICAL PROPERTIES

PROPERTY VALUE PROPERTY VALUE


Appearance: Cylindrical brass cartridge Physical State: Solid
Odor: None Odor Threshold: None
Boiling Point (F): Not applicable Melting point: Not applicable
Vapor Pressure (mm Hg): Not applicable Freezing point: Not applicable
Vapor Density(air = 1): Not applicable Bulk Density Not applicable
Specific gravity (g/cc): Not applicable Viscosity (cps): Not applicable
pH: Not applicable Decomposition Temperature: Not applicable
Solubility in Water (20 C): Insoluble Evaporation Rate: Not applicable
Volatiles, Percent by volume: Not applicable Octanol/water partition coefficient: Not applicable

10. STABILITY AND REACTIVITY

Stability: Stable under normal temperatures and pressure.


Possibility of Hazardous Reactions: Hazardous polymerization will not occur
Incompatible Materials: Acids, Class A & B explosives, strong oxidizers, and caustics
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, lead oxides, carbon dioxide, lead
dust/fume
Conditions to Avoid: Contact with incompatible materials. Physical damage to containers;
cartridges may detonate if case is punctured.

11. TOXICOLOGICAL INFORMATION

Potential Routes of Entry: Inhalation, Skin, and by Ingestion.

The physical nature of this product makes absorption from any route unlikely. A small amount of inhalable particles may be created
when cartridge is fired.

Effects Of Acute Exposure:


SELECTED COMPONENTS
PRODUCT Lead Antimony Copper Nitroglycerin Nitrocellul Tin Zinc
ose
Inhalation Particles No data No data No data No data No data No data No data
LC50 generated from
firing may be
slightly toxic
Skin Contact Skin absorption No data No data 375 mg/kg, sc > 280 mg/kg No data No data No data
LD50 unlikely (rabbit) (rabbit)
Ingestion Ingestion 763 mg/kg (rat) No data 3.5 mg/kg, ip 105 mg/kg (rat) > 5 g/kg No data No data
LD50 unlikely (mouse) (rat)
Irritation Particles Not irritating No data Respiratory Mild eye and No data Respiratory Eye irritant
generated from irritant skin irritant Irritant
firing may be
slightly irritating
to the eyes
Sensitization Sensitization to No data No data No data No data No data No data No data
this Product has
not been
reported

Other Adverse Effects:

Target Organ Toxicity: No reported target organ toxicity from this product. Lead has caused nervous
system, kidney and hematopoietic system damage in humans and laboratory
animals.
Reproductive Toxicity: This product is not known or reported to cause reproductive effects. Lead has
been shown to reduce male reproductive function in humans and laboratory
animals.
Teratogenicity (Birth Defects): This product is not known or reported to cause developmental toxicity. Lead has
been shown to affect fetal development including birth defects.
Mutagenicity: This product is not known or reported to be mutagenic. Lead has been shown to be
mutagenic in several in vitro assays.
Carcinogenicity: IARC and US EPA list lead and lead compounds as probable human carcinogens
(Group 2A) based on sufficient evidence from animal studies and limited evidence
from human studies (epidemiology). NTP classifies lead and lead compounds as
reasonably anticipated to be human carcinogens.

SDS No.: 00050.0001


Page 10 of 10

12. ECOLOGICAL INFORMATION

Environmental Effects:

PRODUCT: Product has not been tested for environmental properties. Lead shot has been shown to be toxic to aquatic species.

COMPONENTS:

Copper: Copper concentrations from 0.1 to 1.0 mg/l have been found to be not toxic for
most fish. However, concentrations of 0.015 to 3.0 mg/l have been reported as
toxic, particularly in soft water to many kinds of fish, crustacea, mollusks,
insects, and plankton.
Lead: LC 50 (48 hrs.) to bluegill is reported to be 2-5 mg/l. Lead is toxic to
waterfowl.
Nitrocellulose: LC50 > 1000 mg/l to fish, invertebrates, and algae.
Nitroglycerin: LC50 = 1.228 mg/l to Bluegill, (96 hour, static)
Zinc: The following concentrations of zinc have been reported as lethal to fish: 0.13
mg/l, for 12 – 24 hours to Rainbow trout fingerlings; 1.9 – 3.6 mg/l, 6 hr TLM
(soft water, 30°C) to Bluegill Sunfish; 4 mg/l, 3 days (hard water) to Rainbow
trout; 1 mg/l, 24 hours (soft water) to Sticklebacks.
The presence of copper appears to have a synergistic effect on the toxicity of
zinc towards fish.

Environmental Fate:

MOBILITY: Dissolved lead from degraded bullets may migrate through soil.
PERSISTANCE/DEGRADABILITY: Not biodegradable. Bullets may fragment and decompose in soil leading to accumulation
of lead.
BIOACCUMULATION: No data

13. DISPOSAL CONSIDERATIONS

Care must be taken to prevent environmental contamination from the use of this material. The user of this material has the responsibility
to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations
regarding the treatment, storage and disposal for hazardous and nonhazardous wastes.

14. TRANSPORT INFORMATION


Regulatory Information for US DOT, IATA, IMO, and ADR:
M33 – 50 Cal Ball
Cartridges, small arms (other Cartridges for weapons,inert
Proper Shipping Name:
than blanks) projectile or Cartridges, small arms

Hazard Class Number and Description: Explosive 1.4S Explosives 1.4C

UN Identification Number: UN 0012 UN 0339

Packing Group: PGII PGII

Label Not Required for ground


DOT Label(s) Required: 1.4 C
shipment.

None of the ingredients are classified


by the DOT as a Marine Pollutant (as
Marine Pollutant:
defined by 49 CFR 172.101, Appendix
B)

Additional Information:

SDS No.: 00050.0001


Page 10 of 10

North American Emergency Response Guidebook Number: 114 Most Current Version is 2012

U.S. DEPARTMENT OF TRANSPORTATION SHIPPING REGULATIONS: This product is classified as dangerous goods under 49 CFR
172.101. Note: May be reclassified domestically as an ORM-D or Limited Quantity if packaged in accordance with 49 CFR 173.63.

TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is classified as Dangerous
Goods (If packaged appropriately this product may ship as a Limited Quantity).

INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA): This product is classified as Dangerous Goods.

INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION: This product is classified as Dangerous Goods (If packaged
appropriately this product may ship as a Limited Quantity).

EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR): This
product is classified by the United Nations Economic Commission for Europe to be dangerous goods. (If packaged appropriately this
product may ship as a Limited Quantity).

15. REGULATORY INFORMATION

US FEDERAL

TSCA The components of this product are listed on the Toxic Substance Control Act inventory.
CERCLA: Copper, R.Q.* = 5000 lbs.; Zinc, R.Q. = 1000 lbs.; Lead, R.Q. = 10 lbs.; Nitroglycerin, R.Q. = 10 lbs (No
reporting is required if diameter of the pieces of metal is equal to or exceeds 100 micrometers (0.004
inches).
SARA 313: Copper, Lead and Lead compounds, Nitroglycerin, Zinc (fume or dust)
SARA 311/312: Health: Acute – No Fire: No Reactivity: None Release of Pressure: Yes
Chronic - Yes
SARA 302 EHS List: None of the components of this product are listed.
*RQ = Reportable Quantity

STATE RIGHT-TO-KNOW STATUS

Component California New Jersey Pennsylvania Massachusetts Michigan


Lead X X X X X
Copper Not listed X X X X
Iron Not listed Not listed Not listed Not listed Not listed
Zinc Not listed X Not listed X X
Nitrocellulose Not listed X X X Not listed
Nitroglycerin Not listed X X X Not listed
Lead Styphnate X Not Listed Not Listed X Not Listed
Antimony Not listed X X X X
Tin Not listed Not listed X X Not listed

CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65)

Warning! This product contains det ec t ab l e am o un t s o f a c hem ic a l known to the State of California to cause cancer and/ or
b i r t h def ec t s or other reproductive harm.

GHS CLASSIFICATION
Carcinogenicity Category 1A
Reproductive Toxicity Category 1A
Explosive Division 1.4
STOT RE Category 1
Aquatic Environment, Chronic II

EUROPEAN REGULATIONS

All chemical components listed on EINECS

Lead metal is included on the REACH Candidate List of Substances of Very High Concern for Authorisation (Toxic to
SDS No.: 00050.0001
Page 10 of 10
Reproduction, Category 1A; Article 57c)

Restrictions on use: this substance is subject to REACH restrictions according to:

• Annex XVII, Entry No. 30 (regarding supply to the general public)


• REACH Annex XVII, Entry No. 63.

Hazard Classification
Danger Symbols: E, T
Risk Phrases: R2, R45, R48, R51/53, R60, R61, R63

Safety Phrases: S2, S15, S20/21, S22, S39, S51, S61

German WGK Classification: Not known.

CANADIAN REGULATIONS

DSL/NDSL Inventory: The components of this product are on the DSL

IDL: Lead, Copper

CEPA PRIORITIES LIST: None of the components of this product are on the CEPA First Priorities Substances List.

WHMIS: This product is not subject to WHMIS. It is regulated as a Class 6 Explosive in Canada.

JAPANESE REGULATIONS

Existing National Inventory of Chemical Substances (ENCS): The components of this product are Listed

Japanese MITI Status: Product components are not listed as Class I or II Specified Chemical Substances

OTHER INTERNATIONAL CHEMICAL INVENTORIES

Swiss Giftliste List of Toxic Substances: All Components Listed


Australian Inventory (AICS): All Components Listed
Asia – Pac Inventory: All Components Listed
Korean Existing Chemicals List (ECL): All Components Listed
Philippines Inventory of Chemicals (PICCS): All Components Listed

16. OTHER INFORMATION

REVISIONS: 07
DATE: 02/28/2019
PREPARED BY: Olin Winchester, LLC
OTHER: Additional information available from: www.winchester.com
NOTICE: THE INFORMATION IN THIS SDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT,
OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF
PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS
PRODUCT. OLIN BELIEVES THIS INFORMATION TO BE RELIABLE AND CURRENT AS OF THE DATE OF PUBLICATION, BUT
MAKES NO WARRANTY THAT IT IS.

SDS No.: 00050.0001

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