Argazol Black G - M

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MATERIAL SAFETY DATA SHEET

(Required under OSHA's Hazard Communication Standard 29 CFR 1910-1200)


According to 93/112 EEC
Argazol Black G
1. Identification of the product and company
Product name Argazol Black G
Manufacture Argus (Shanghai) Textile Chemicals Co. Ltd
No.301 Baoyuan Road 5, Jinbao Industries Park West, Jiading
Emergency Telephone Numbers 0086-21-69136448
2. Composition / Information on ingredients
Composition Mixture of azo reactive dyestuff
Formula C.I. Unknown
Chemical Formula Unknown
CAS Registration Number Unknown
Risk-phrase(s) 42/43

3. Hazard identification section


Cautions May cause sensitization by inhalation and skin contact

Inhalation Dust from the product, if present, may cause respiratory irritation
following an excessive inhalation exposure.
Eye Contact No significant hazards under conditions of normal use.
As with all chemical substance, caution should be taken in handling.
Skin Contact No significant hazards under conditions of normal use.
As with all chemical substance, caution should be taken in handing.
Ingestion No significant hazards under conditions of normal use.
As with all chemical substance, caution should be taken in handling.
Chronic Exposure No significant hazards under conditions of normal use.
As with all chemical substance, caution should be taken in handling.

4. First aid measures


If inhaled Remove to fresh air, If breathing is difficult give oxygen and get
medical attention immediately.(S22)
After Skin Contact Remove affected clothing and wash all exposed area with mild soap
&water. If irritation develops consult physician.(S24)
After Contact with Eyes Flush immediately with water for least 15 minute holding the eyes
apart to irrigate thoroughly and seek medical attention right away.
After Ingestion Dilute with water and induce vomiting. Never give water or induce
vomit if victim is unconscious or convulsing.

5.Fire-fighting measures
Suitable Extinguish Media Water spray, foam, carbon dioxide, dry powder
Unsuitable Extinguish Media Unknown
Special Exposure Hazards High temperature decomposition may liberate H 2O2 and oxides of
carbon, nitrogen and sulfur which may caused toxic.
Special Protective Equipments for Fire-Fighters
Fire fighters should be provide with air supplied respirator.
Wear self contained breathing apparatus(SCBA)
6. Accidental release measures
Personal precautions Wear suitable protective clothing and gloves in handling.
Environment precautions Comply with local and state regulations for container disposal
Notify authorities if product enters sewers or public waters.
Methods for cleaning and recovery Sweep or shovel spills into appropriate container for disposal
then washing with water.

7.Handling and storage


Handling Avoid all unnecessary exposure.
Keep container closed and dry when not in use.
Observe the usual precautionary measure required for chemicals
with dust-explosive properties

Storage Stable at room temperature(-10-60℃)


Avoid wide temperature variance.
Containers need to be regularly checked avoiding damaged or leaking

8.Exposure controls/personal protection


Protective Measures Avoid contact with eyes and skin
Skin protection Coveralls, gloves, apron, boots as require to minimize skin contact.
Eye protection Chemical goggles or safety glasses.
Respiratory protection Dust or mist respirator should be used when handling.(S73)
Ingestion Do not eat, drink or smoke around chemicals.
Industrial hygiene Wash hands before breaks and at end of work and use
skin -protecting ointment
Attention This product is sold solely for use by industrial institution

9. Physical and chemical properties


Appearance Granules
Colour Black
Order Odorless
pH value(2g/L, water) 6.0-7.5
Melting point over 350c
Boiling point (@760mm/Hg) Not applicable
Flash point Not applicable
Flammability Stable
Auto-ignition Temperature >230℃
Oxidizing Property Stable
Solubility (g/l) 180g/l at room temperature

10.Stability and reactivity


Chemical Stability Stable
Conditions to be avoided Heat, flame, the other ignition source
Substances to be avoided Strong oxidizing agents
Dangerous degradation product None known with normal product
Oxidizing Property Stable
11. Toxicological information
Acute oral toxicity LD50 (g/kg)
Irritant effect on skin Non-irritant (rabbit)
Irritant effect on eyes Non-irritant (rabbit eye)
Sensitization In the guinea-pig the product has a sensitizing effect(OECD 406)
Carcinogenicity >5,000mg/kg (rat)

12. Ecological information


LC50(mg/kg) No data available
BOD5 No data available
COD No data available
Material Contain Based on the substances in section 2
Metal content is below the limits of the association of
ecology and toxicology for dyestuff industry
13. Disposal considerations
Disposal Dispose in accordance with local national regulations

14. Transport information


General information None hazardous product
ADR None hazardous substance
RID None hazardous substance
ADNR None hazardous substance
IMDG None hazardous substance
IATA_C None hazardous substance
IATA_P None hazardous substance
Other information Keep separated from foodstuffs

15.Regulatory information
Symbol(s) None
R phrases R42/43 May cause sensitization by inhalation and skin contact
S phrases S22 Do not breathe dust
S24 Avoid contact with skin
S73 Wear suitable gloves
16. Other information
This information is based on our present state of knowledge.
It should not therefore be construed as guaranteeing specific properties of the products described
or their suitable for a particular application
The end of document

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