9

Chapter 3

Some Basic Concepts of

Chemistry

ASSIGNMENT

Single Choice Type Questions

1. Number of carbon atoms present in 22 g CO2 is

(1) 6.02 × 1023 (2) 3.01 × 1023

(3) 3.01 × 10–23 (4) 6.02 × 10–23

2. How many g of NaOH will be needed to prepare 500 ml of 0.4 M solution?

(1) 1 g (2) 8 g

(3) 4 g (4) 16 g

3. 4 L of water is added to 2 L of 6 M HCl. The molarity of the final solution is

(1) 4 M (2) 2 M

(3) 1 M (4) 0.5 M

4. Impure sample contains one mole of glucose (C6H12O6) and impurity. In this sample oxygen is present 50%
by mass, then what is the mass percentage of hydrogen in sample? (Assume impurity does not contain C, H
and O)

(1) 10% (2) 12.25%

(3) 8.5% (4) 6.25%

5. 90 mL of 21% (w/v) HNO3 is completely neutralised by 112 mL of x% (w/v) of KOH. The value of x is

(1) 21 (2) 18

(3) 15 (4) 12

6. 0.48 g of Br2 is reacted with 0.57 g of F2 to form a pale yellow liquid, BraFb. The correct relation between a and
b is (Atomic mass of Br = 80, F = 19)

(1) a = b (2) b = 3a

(3) b = 5a (4) a = 2b

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 10 JEE SCORE for Main-2024 Some Basic Concepts of Chemistry

7. 15 mL of 0.5 M H2O2 reacts with 10 mL of 0.5 M KMnO4 in excess of sulphuric acid, according to reaction

2KMnO4 + 3H2SO4 + 5H2O2 → K2SO4 + 2MnSO4 + 8H2O + 5O2

The volume of O2 produced at STP is

(1) 1.68 L (2) 99 mL

(3) 168 mL (4) 33.6 mL

8. What is the equivalent weight of acid in following reaction?

2KOH + H4P2O7 → K2H2P2O7 + 2H2O

(Atomic mass of P = 31)

(1) 178 (2) 89

(3) 59.33 (4) 44.5

9. Which of the following pairs of substances illustrate the law of multiple proportions?

(1) H2O and D2O (2) NaCl and NaBr

(3) CO and CO2 (4) MgO and Mg(OH)2

10. Maximum number of atoms are present in

(1) 2.45 g of H2SO4 (2) 1.6 g of SO2

(3) 1.1 g of N2O (4) 0.8 g of O2

11. What is the normality of 50 mL solution of 4.1 g of H 2SO3?

(1) 1 N (2) 2 N

(3) 0.5 N (4) 3 N

12. Which of the following has minimum weight of free SO 3?

(1) 107% oleum (2) 121% oleum

(3) 115% oleum (4) 102% oleum

13. An organic compound X contains 10% C by mass. The minimum molar mass of compound X is (in g/mol)

(1) 100 (2) 120

(3) 150 (4) 200

14. 100 mL of water is taken in a container at specific temperature (density 0.9 g/mL). When liquid A is added to
it, volume becomes 105 mL. The mass of final solution (if density of liquid A is 15 g/mL) is

(1) 125 g (2) 165 g

(3) 145 g (4) 155 g

15. 3 g of hydrocarbon on complete combustion produce 8.8 g of CO 2 and 5.4 g of H2O. Empirical formula of
hydrocarbon is

(1) CH4 (2) CH2

(3) CH (4) CH3

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Some Basic Concepts of Chemistry JEE SCORE for Main-2024 11

16. One gram, equimolar mixture of CaCO3 and NaHCO3 undergo complete thermal decomposition. The volume
of CO2 gas formed at STP is

(1) 1.8 L (2) 182.6 mL

(3) 200 mL (4) 560 mL
17. Student A, B, C and D were measuring volume of a liquid. Their reading of experiment is

Student Trial 1 (mL) Trial 2 (mL)

A 1.87 1.92

B 2.32 2.31

C 2.01 1.95

D 1.93 2.61

If true value of volume is 2.00 mL, then the most precise measurement is done by student
(1) A (2) B
(3) C (4) D
18. Equal mass of HCl and NaOH is present in 1 litre of solution. The correct statement is
(1) HCl is completely consumed but NaOH remain in the solution
(2) NaOH is completely consumed but HCl remain in the solution
(3) Both NaOH and HCl are completely consumed
(4) HCl is limiting reagent in this reaction
19. 14 g of nitrogen (N2) reacts with 6 g of hydrogen at STP and form ammonia (NH3). If volume of NH3 produced
at STP is 11.2 L, the percentage yield is
(1) 25 (2) 50
(3) 75 (4) 100
20. 120 g of a solute is present in an aqueous solution that has molality 2 m. If this solution is diluted with water
such that final solution have mass 4.12 kg and molality is 0.5 m, the mass of water added in the initial solution
is
(1) 1 kg (2) 2 kg
(3) 3 kg (4) 4 kg

Numerical Value Type Questions

21. CNG is an important transportation fuel. When 100 g CNG is mixed with 208 g oxygen in vehicles, it leads to
the formation of CO2 and H2O and produced large quantity of heat during this combustion, then the amount of
carbon dioxide, produced in grams is ______. [Nearest integer]
[Assume CNG to be methane]
22. Two elements A and B which form 0.15 moles of A2B and AB3 type compounds. If both A2B and AB3 weigh
equally, then the atomic weight of A is ______ times of atomic weight of B.

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 12 JEE SCORE for Main-2024 Some Basic Concepts of Chemistry

23. 250 mL of 0.5 M NaOH was added to 500 mL of 1 M HCI. The number of unreacted HCI molecules in the
solution after complete reaction is ______ × 1021. (Nearest integer) (NA = 6.022 × 1023)

24. If the concentration of glucose (C6H12O6) in blood is 0.72 g L–1, the molarity of glucose in blood is
______ × 10–3 M. (Nearest integer)
(Given : Atomic mass of C = 12, H = 1, O = 16 u)
25. A protein ‘A’ contains 0.30% of glycine (molecular weight 75). The minimum molar mass of the protein ‘A’ is
______ × 103 g mol–1. [Nearest integer]
26. Chlorophyll extracted from the crushed green leaves was dissolved in water to make 2 L solution of Mg of
concentration 48 ppm. The number of atoms of Mg in this solution is x × 10 20 atoms. The value of x is ______.
(Nearest integer)
(Given : Atomic mass of Mg is 24 g mol–1; NA = 6 × 1023 mol–1)

27. When 800 mL of 0.5 M nitric acid is heated in a beaker, its volume is reduced to half and 11.5 g of nitric acid
is evaporated. The molarity of the remaining nitric acid solution is x × 10 –2 M. (Nearest integer)
(Molar mass of nitric acid is 63 g mol–1)
28. In the given reaction,

X + Y + 3Z ⎯⎯→ XYZ3

if one mole of each of X and Y with 0.05 mol of Z gives compound XYZ 3. (Given : Atomic masses of X, Y and
Z are 10, 20 and 30 amu, respectively). The yield of XYZ3 is ______ g. (Nearest integer)
29. A metal oxide has the formula M2O3. This oxide reacts with hydrogen to produce M and H2O according to the
reaction (unbalanced) M2O3 + H2 → M + H2O. If 32 g of M2O3 required 1.2 g of hydrogen for complete reduction.
The atomic mass of metal M is (in gm/mol)
30. It requires 40 ml of 1 M HxA to react completely with 20 ml of 1 M Ca(OH)2. What is the value of x?

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