SR Iit Star Model - A&apex - Jee Main PTM-12 (Pt-12-Syllabus) Mock Test QP (23-10-24)

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APEX & STAR MODEL-A PTM-12_MOCK TEST

Time:3HRS Max. Marks: 300M

PHYSICS MAX.MARKS: 100


SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options A), B), C) and D)
for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. A proton moving with one tenth of velocity of light has a certain de Broglie wavelength
of  . An alpha particle having certain kinetic energy has the same de-Broglie wavelength
 . The ratio of kinetic energy of proton and that of alpha particle is:
A) 4 : 1 B) 1 : 4 C) 1 : 2 D) 2 : 1
2. An electron accelerated through a potential difference V1 has de-Broglie wavelength of
 . When the potential is changed to V2 , its de-Broglie wavelength increases by 50%.
V 
The value of  1  is equal to
 V2 
9 3
A) 3 B) C) D) 4
4 2

3. An electron (mass m) with an initial velocity v  v0 i  v0  0 is moving in an electric
 h
field E   E0 i where E 0 is constant. If at t  0 de Broglie wavelength is 0  , then
mv0
its de Broglie wavelength after time t is given by
 eE t  0
A) 0 B) 0  1  0  C) 0t D)
 mv0   eE0t 
1  
 mv0 

Page | 1
4. A electron with speed v and a photon with speed c have the same de-Broglie
wavelength. If the same de-Broglie wavelength. If the kinetic energy and momentum of
electron are Ee and pe and that of photon are E ph and p ph respectively. Which of the

following is correct?
Ee 2c Ee v pe 2c pe v
A)  B)  C)  D) 
E ph v E ph 2c p ph v p ph 2c

5. Consider two separate ideal gases of electrons and protons having same number of
particles. The temperature of both the gases are same. The ratio of the uncertainty in
determining the position of an electron to that of a proton is proportional to
3
2
m  me mp mp
A)  p  B) C) D)
 me  mp me me

m
6. Particle A of mass m A  moving along the x  axis with velocity v0 collides
2
m
elastically with another particle B at rest having mass mB  . If both particles move
3
along the x -axis after the collision, the change  in de-Broglie wavelength of particle
A, in terms of its de-Broglie wavelength  0  before collision is
3 5
A)   0 B)   0 C)   20 D)   40
2 2
m
7. A particle A of mass m and initial velocity v collides with a particle B of mass
2
which is at rest. The collision is head on, an elastic. The ratio of the de-Broglie
wavelengths  A to B after the collision is
A 2 A 1 A 1 A
A)  B)  C)  D) 2
B 3 B 2 B 3 B

Page | 2
8. Given below are two statements:

Statement-I: Figure shows the variation of stopping potential with frequency  v  for the
h
two photosensitive materials M1 and M 2 . The slope gives value of ,
e
where h is Planck’s constant, e is the charge of electron.
Statement-II: M 2 will emit photoelectrons of greater kinetic energy for the incident
radiation having same frequency.
In the light of the above statements, choose the most appropriate answer
from the options given below.
A) Statement – I is correct and Statement-II is incorrect
B) Statement – I is incorrect but Statement – II is correct
C) Both Statement – I and Statement –II are incorrect
D) Both Statement – I and Statement – II are correct
9. Which figure shows the correct variation of applied potential difference V  with
photoelectric current  I  at two different intensities of light  I1  I 2  of same
wavelengths:

A) B)

C) D)

Page | 3
10. A metallic surface is illuminated with radiation of wavelength  , the stopping potential is
V0 . If the same surface is illuminated with radiation of wavelength 2 , the stopping
V0
potential becomes . The threshold wavelength for this metallic surface will be.
4
 3
A) B) 4 C)  D) 3
4 2
 R
11. Which of the following figure represents the variation of ln   with ln A (If R  radius
 R0 
of a nucleus and A  its mass number)?

A) B) C) D)
12. The radius R of a nucleus of mass number A can be estimated by the formula
1
R  1.3 1010  A 3 m. It follows that the mass density of a nucleus is of the order of;
M prot .  M neut .  1.67  10 27 kg 

A) 103 kgm3 B) 1010 kgm3 C) 1024 kgm3 D) 1017 kgm3


13. An unstable heavy nucleus at rest breaks into two nuclei with move away with velocities
in the ration of 8 : 27. The ratio of the radii of the nuclei (assumed to be spherical) is:
A) 8 : 27 B) 2 : 3 C) 3 : 2 D) 4 : 9
27
14. If radius of the 13 Al nucleus is estimated to be 3.6 fermi then the radius of 125
52 Te nucleus

be nearly
A) 8 fermi B) 6 fermi C) 5 fermi D) 4 fermi
12
15. If M 0 is the mass of isotope 5 B, M P and M n are the masses of proton and neutron, then
nuclear binding energy of isotope is:
A)  5M P  7 M n  M 0  C 2 B)  M 0  5M P  C 2

C)  M 0  12 M n  C 2 D)  M 0  5M P  7 M n  C 2

Page | 4
16. Which of the following nuclear fragments corresponding to nuclear fission between
neutron  n  and uranium isotope 
1
0
235
92 U  is correct
144 89
A) 56 Ba 36 Kr  410 n B) 140
56
94
Xe 38 Sr  310 n
153
C) 51 Sb 99 1
41 Nb  30 n D) 144
56 Ba 89 1
36 Kr  30 n

17. In a nuclear fission reaction of an isotope of mass M , three similar daughter nuclei of
same mass are formed. The speed of a daughter nuclei in terms of mass defect M will
be:
2cM Mc 2 2 M 3M
A) B) C) c D) c
M 3 M M
238 234
18. 92 A 90 B 24 D  Q In he given nuclear reaction, the approximate amount of energy
released will be:
238
[Given, mass of 92 A  238.05079  931.5 MeV / c 2 , mass of
234
90 B  234.04363  931.5 MeV / c2 , mass of 42 D  4.00260  931.5MeV / c 2 ]
A) 3.82 MeV B) 5.9 MeV C) 2.12 MeV D) 4.25 MeV
19. The mass of proton, neutron and helium nucleus are respectively 1.0073 u , 1.0087 u and
4.0015 u . The binding energy of helium nucleus is:
A) 14.2 MeV B) 56.8 MeV C) 28.4 MeV D) 7.1 MeV
20. If the binding energy per nucleon in 73 Li and 42 He nuclei are 5.60 MeV and 7.06 MeV

respectively, then in the reaction p 73 Li  242 He energy of proton must be


A) 28.24 MeV B) 17.28 MeV C) 1.46 MeV D) 39.2 MeV

Page | 5
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the
numerical value has more than two decimal places, Truncate/Round-off the value of Two
decimal places. Answer to each question will be evaluated according to the following marking
scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.

21. The surface of a metal is illuminated alternately with photons of energies E1  4eV and
E2  2.5eV respectively. The ratio of maximum speeds of the photoelectrons emitted in
the two cases in 2. The work function of the metal in (eV) is ________
22. When the wavelength of radiation falling on a metal is changed from 500 nm to 200 nm,
the maximum kinetic energy of the photoelectrons becomes three times larger. The work
function of the metal is close to P  0.61 eV . Find P .
23. When radiation of wavelength  is used to illuminate a metallic surface, the stopping
potential is V . When the same surface is illuminated with radiation of wavelength 3 ,
V
the stopping potential is . If the threshold wavelength for the metallic surface is n
4
then value of n will be _______
24. When photon of energy 4.0 eV strikes the surface of a metal A , the ejected
photoelectrons have maximum kinetic energy TAeV and de-Broglie wavelength  A. The
maximum kinetic energy of photoelectrons liberated from another metal B by photon of
energy 4.50 eV is TB  TA  1.5 eV . If the de-Broglie wavelength of these
photoelectrons B  2 A , then the work function of meal B is 2PeV , Find P.
25. A beam of electromagnetic radiation of intensity 6.4  105W / cm 2 is comprised of
wavelength,   310 nm. It falls normally on a metal (work function   2eV ) of surface
of 1cm2 . If one in 103 photons ejects an electron, total number of electrons ejected in 1 s
is 10 x .  hc  1240 eVnm, 1eV  1.6 19
J  , then x is _______

Page | 6
CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options A), B), C) and D)
for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

26. The chemical reaction, 2 AgCl s   H 2 g   2 HCl aq   2 Ag  s  taking place in a galvanic

cell (under standard conduction is represented by the notation.


A) pt s  | H 2 g ,1bar |1M KCl aq  | AgCl s  | Ag  s 

B) pt s  | H 2 g ,1bar |1M HCl aq  |1M Agaq  | Ag s 

C) pt s  | H 2 g ,1bar |1M HCl aq  | AgCl s  | Ag  s 

D) pt s  | H 2 g ,1bar |1M HCl aq  | Ag  s  | AgCl s 

27. Choose the correct representation of conducto-metric titration of fermic acid with
potassium hydroxide.

A) VKOH B) VKOH

C) VKOH D) VKOH

Page | 7
28. The molar conductivity of a conductivity cell filled with 5 moles of 10ml KNO3 solution
is  m1 and that of 10 moles another identical cell having 40ml KNO3 solution is m2 .
The conductivities of both solutions are same, the relation between m2 and m1 is?
m1
A) m2  2m1 B) m2  C) m2  m1 D) m2  4m1
2

29. The equation that is incorrect is?


A)   0m     0m     0m     0m 
BaCl2 CaBr2 BaBr2 CaCl2

B)   0m     0m     0m     0m 
BaCl2 CaCl2 BaBr2 CaBr2

C)   0m     0m     0m   2   0m 
BaSO4 BaCl2 Na2 SO4 NaCl

 
D) 0m
HF
   0m 
NaCl
   0m 
HCl
   0m 
NaF

30. Consider the statements S1 and S2


Statement 1 : Specific conductance increases with increase in concentration of a weak
acid.
Statement 2 : Molar conductance decreases with decrease in concentration of a weak
acid the correct option among the following is?
A) Both S1 and S2 are correct
B) Both S1 and S2 are wrong
C) S1 is correct and S2 is wrong
D) S1 is wrong and S2 is correct

31. The limiting molar conductivities of AgNO3 , and H 2 SO4 are 13, 42 and 86 msm 2 mol 1
respectively the limiting molar conductivity of Ag 2 SO4 at same temperature is ________

mSm2 mol 1 .
A) 14 B) 28 C) 21 D) 24
Page | 8
32. For the cell, Zn s  | Zn  NO3  2 aq  || AgNO3 aq  | Ag s  . When the concentrations of Zn2 and

Ar  are decimolar each, the expression of G in J mol 1 is?


0
[ F is Faraday constant, R is gas constant, T is temperature Ecell  1.56V ]
A) 2.303 RT  1.56 F B) 3.12 F
C) 2.303 RT  3.12 F D) 2.303 RT  1.56 F

33. Consider the following cell reaction.


2 Fe s   O2 g   4 H g   2 Feaq2   2 H 2O l 

At  Fe2   103 M , P O2   0.1atm and pH  3, the cell potential at 25C is

( E 0  1.67V )
A) 1.47 V B) 1.77 V C) 1.87 V D) 1.57 V

34. 0.2 Faradays of electricity is passed through a solution of AgNO3 , the mass of silver
deposited on Cathode with current efficiency of 80% is ? (At wt of As=108)
A) 21.6 g B) 10.8 g C) 17.28 g D) 1.728 g

35. When 1.93 ampere current was passed for 16 min and 40 sec into nitrobenzene in acidic
medium, the amount of p -aminophenol produced is ?
A) 0.545g B) 5.45 g C) 1.23 g D) 12.3 g

36. When an electric current of 1.0 ampere is passed through acidified water, the volume of
O2 collected at STP in 965 seconds is?
A) 112ml B) 56ml C) 28ml D) 224ml

Page | 9
37. A current is passed through 2 voltmeters connected in series. The first voltmeter contains
XSO4 aq  and second has Y2 SO4 aq  . The relative atomic masses of X and Y are in the

ratio of 2 : 1. The simple ratio of mass of ‘ X ’ liberated to the mass of ‘ Y ’ is p : q . Find


p  q?
A) 5 B) 3 C) 2 D) 6

38. For NaCl aq  solution which of the following quantities go to zero as NaCl concentration

goes to zero? (Ignore the conductivity of the solvent)


A)  m B) K C) m Na  D) m Cl 
   

39. 1 molar solution of NaCl is filled in different conductivity cells. The order of equivalent
conductance of NaCl solution is?
Cell-1 Cell-2 Cell-3
A: 5cm2 6cm2 10cm2
l: 2cm 3cm 4 cm
(A=Area of cross section , l =distance between two electrodes.
A) Cell-1 > Cell-2 > Cell-3 B) Cell-1=Cell-2=Cell-3
C) Cell-1< Cell-2< Cell-3 D) Cell-2>Cell-1>Cell-3
40. Given below two statements.
Statement-1: The E 0 value of Ce 4 / Ce3 is positive.
Statement-2 : Ce is more stable in Ce4 state than in Ce3 state.
In light of the above statements choose the most appropriate answer from the following.
A) Both Statement-1 and Statement-2 are correct
B) Statement-1 is incorrect but statement -2 is correct
C) Both statement-1 and statement-2 are incorrect
D) Statement -1 is correct but statement – 2 is incorrect

Page | 10
41. The half-cell reactions for rusting of iron are: H+ + O2 + 2e–→ H2O; Eº = +1.23V,
Fe2+ + 2e–→ Fe ; Eº = – 0.44 V. ∆Gº (in kJ) for rusting of iron per mole of oxygen is:
A) – 76 B) – 320 C) – 640 D) – 176
42. Potassium chlorate is prepared by the electrolyte KCl in basic solution according to the
reaction, Cl   60 H   ClO3  3H 2O  6e 
A current of XA has to be passed for 10 h ours to produce 9 g of KClO3 . The value of ‘
X ’ is? (M.wt of KClO3  122.6, F  96500C )
A) 1.18 B) 2.18 C) 0.18 D) 0.59
43. 10Cl   aq.  2 MnO4  aq.  16 H   aq.  5Cl2  g   2 Mn 2  aq.  8 H 2O  l 

The value of E0 for this reaction is 0.15 V. What is the value of the equilibrium constant
(K) for this reaction?
A) 2.4  1025 B) 4.9  1012 C) 1.2  105 D) 3.4  102
44. For a lead storage battery pick the correct statements.
I. During charging the battery PbSO4 on anode converts into PbO2
II. During charging of battery PbSO4 on cathode is converted into PbO2
III. Lead storage battery consists of grid of lead packed with PbO2 as anode.
IV. Lead storage battery has ~ 38% solution of H 2 SO4 as electrolyte
Choose the correct options given below.
A) I, II, IV only B) II, III, IV only C) II, III only D) II, IV only
45. The reduction potential of the following cell: Pt, Cl
2
 2atm  / NaCl  0.2M solution  ,
0
E  1.36 V, is ____
A) 1.26V B) 1.18V C) 1.41V D) 1.65V

Page | 11
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the
numerical value has more than two decimal places, Truncate/Round-off the value of Two
decimal places. Answer to each question will be evaluated according to the following marking
scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
45. The specific conductance of 0.01 M nitrous acid solution is 6  104 S cm1 at 25C . The

dissociation constant of nitrous acid is _________ 104 . Consider limiting molar


conductivity of HNO3 as 300 Scm2 mol 1
47. The specific conductance of 0.01M KCl in a conductivity cell with cell constant
1.5cm1 is 0.001S cm1 , the resistance of the cell is _______ 102  .
48. By how many of the following actions, can the Ecell be increased (∆S = + ve) for the cell
reaction
A | A+ (aq) || Cl– | Cl2(g) | Pt
(a) By dilution of anodic solution.
(b) By dilution of cathodic soltuion.
(c) By decreasing temperature.
(d) By increasing pressure of Cl2 in cathodic compartment.
(e) By increasing the mass of anode (A(s)
(f) By increasing temperature

49.  Fe3+ + Ag. The equilibrium constant at 25oC for the
The reaction is Fe2+ + Ag+ 
reaction (Given: E o Ag  / Ag =0.80 volt and E o Fe3 / Fe2  =0.771volt) is ………(nearest integer)

50. The number of moles of solid KCl added to one liter contents of a standard silver – silver
ion electrode to convert it to standard Cl-1, AgCl/Ag, electrode [
E 0Ag + /Ag = 0.8V, K sp(AgCl)  1010 ] are

Page | 12
MATHS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options A), B), C) and D)
for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

51. The ratio of the 5th term from the beginning to the 5th term from the end in the binomial
10
 1 
 1  1


3
expansion of 2  1

is a   :1 then a  b is
36 b

 2  3 3 

A) 5 B) 8 C) 6 D) 7
n
52. If the coefficients of the three successive terms in the binomial expansion of 1  x  are

in the ratio 1: 7 : 42 , then, the last of these terms in the expansion is:
A) 6th B) 7th C) 8th D) 9th
20
2 10 2
53. Let  a  bx  cx    pi xi , a, b, c  N . If p1  20 and p2  210 , then 2  a  b  c  is
i 0

equal to
A) 18 B) 32 C) 72 D) 50
n
54. If some three consecutive coefficients in the binomial expansion of  x  1 in powers of
x are in the ratio 2 :15 : 70 , then the average of these three coefficients is a three digit
number abc. Then a  b  c is
A) 7 B) 19 C) 11 D) 13
55. The value of
 21
C1 10 C1    21 C2 10 C2    21 C3 10 C3    21 C4 10 C4   ...   21 C10 10 C10  is
A) 210  211  1 B) 210  210  1 C) 29  211  1 D) 211  210  1
6
2 
56. If the fourth term in the binomial expansion of   x log8 x   x  0  is 20  87 , then the
x 
product of possible values of x is
A) 8 2 B) 8 C) 83 D) 82

Page | 13
2022 22
57. Let the number  22    2022  leave the remainder a when divided by 3 and  when
2
divided by 7. Then  2     is equal to

A) 36 B) 100 C) 16 D) 25
58. The smallest natural number n , such that the coefficient of x in the expansion of
n
 2 1 n
 x  3  is C23 is 2  k  . Then k is
 x 
A) 18 B) 20 C) 22 D) 19
n
 12 1

59. If the number of integral terms in the expansion of  3  5 8  is exactly 33, then the least
 
value of n is:
2 2 2 2
A) 17 B) 12 C) 16 D) 18
p q
60. If the coefficients of x and x 2 in 1  x  1  x  are 4 and 5 respectively, then

2 p  3q is equal to
A) 4 B) 3 C) 4 D) 3
10
 x 1 x 1 
61. The coefficient of x 5 in the binomial expansion of  2 1
 1
 where
 3 
 x  x 1 x  x2
3

x  0,1 is:
A) neither prime nor composite B) prime number
C) irrational number D) composite number
10 2 9

62. The coefficient of x19 in the product


1  x 1  x  1  x  x  is
x
A) 84 B) 126 C) 126 D) 84
10
 5
63. If the constant term in the expansion of  3 x 3  2 x 2  5  is 8k  l , where l is an odd
 x 
integer, then the value of k is equal to:
A) 4 B) 5 C) 3 D) 6
Page | 14
20
64. r
t 1
2
 1  r ! is equal to:

A)  21! 20  B)  20! 20  C)  20!19  D)  21! 21

65. Let   0,   0 be such that  3   2  4. If the maximum value of the term independent
10
 19 1
 
of x in the binomial expansion of   x   x 6  is k , then k is equal to:
 
A) 3520 B) 3360 C) 1760 D) 840
66. Let S be the set of all values of a1 for which the mean deviation about the mean of 100
consecutive positive integers a1 , a2 , a3 ,...a100 is 25. Then S is
A)  B)  C)  D) W
67. Let sets A and B have 5 elements each. Let the mean of the elements in sets A and B
be 5 and 8 respectively and the variance of the elements in sets A and B be 12 and 20
respectively. A new set C of 10 elements is formed by subtracting 3 from each element
of A and adding 2 to each element of B . Then the average of the mean and variance of
the elements of C is ________.
A) 20 B) 16 C) 19 D) 18
68. Let X   x  N :1  x  17 and Y  {ax  b : x  X and a, b  R, a  0} . If mean and
variance of elements of Y are 17 and 216 respectively then a  b is equal to:
A) 27 B) 13 C) 9 D) 7
n n 2
2
69. A data consists of n observations: x1 , x2 ,..., xn . If   x  1
i 1
i  9n and   x  1
i 1
i  5n

then the variance of this data is:


A) 7 B) 5 C) 4 D) 25
70. The mean of 5 observations is 5 and their variance is 124.If three of the observations are
k
1, 2 and 6; then the mean deviation from the mean of the data is , then k is
10
A) 24 B) 25 C) 28 D) 26

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SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the
numerical value has more than two decimal places, Truncate/Round-off the value of Two
decimal places. Answer to each question will be evaluated according to the following marking
scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.

71. The remainder on dividing 599 by 11 is ________.

72. Let the ratio of the fifth term from the beginning to the fifth term from the end in the
n
 1  1
binomial expansion of  4 2  4  , in the increasing powers of 4 be 4
6 : 1.If the
 3 3
 
sixth term from the beginning is 4
, then is equal to ________.
3 2
n
 6 
73. Let  be the constant term in the binomial expansion of  x  3/2  , n  15 . If the
 x 
sum of the coefficients of the remaining terms in the expansion is 649 and the coefficient
of x  n is  , then  is equal to ________.
2023
74. Suppose r 
r 0
2 2023
Cr   2023    22021 . Then the value of  is ________.

75. The sum of positive integers k such that the constant term in the binomial expansion of
12
 3 3  8
 2 x  k  x  0 is 2 .l , where l is an odd integer, is ________.
 x 

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