Kerboodle PH Calc Qs

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20 Acids, bases, and pH

OCR Chemistry A Application

Acids and bases

Specification reference
 5.1.3

Introduction
As well as practising classifying chemicals as acids and bases, this worksheet will
give you a greater appreciation of what pH is and how it can be calculated for a
strong acid.

Learning outcomes
After completing this worksheet you should be able to:
 classify a chemical as an acid, base, or alkali
 explain the difference between a strong and weak acid
 determine the concentration of H when the concentration of a strong acid is
given
 calculate the pH of a strong acid
 calculate the concentration of a strong acid when the pH is given.

Background
There are several different models to define acids and bases. The Brønsted–Lowry
model focuses on protons. A Brønsted–Lowry acid is a proton donor while a
Brønsted–Lowry base is proton acceptor.
The concentration of the acid is how many moles are in a given volume of solution.
The strength is a measure of how ionised the acid is in solution. A strong acid will
fully ionise in solution whereas a weak acid will partially ionise in solution.
pH is a measure of the concentration of hydrogen ions in solution. As the
concentration of hydrogen ions for a strong acid is very high, yet the concentration
of hydrogen ions for a strong alkali is very low a logarithmic scale must be used. So,
pH  log10[H].

© Oxford University Press 2017 http://www.oxfordsecondary.co.uk/acknowledgements


This resource sheet may have been changed from the original 1
20 Acids, bases, and pH
OCR Chemistry A Application

Questions
1 In the nitration of benzene the electrophile, is produced by reacting
concentrated sulfuric acid with concentrated nitric acid:

HNO3  2H2SO4  NO2  H3O 


a State and justify which chemical is the Brønsted–Lowry acid.

(2 marks)

b In the second step of the mechanism, explain how can be classified as


a Brønsted–Lowry base.

(2 marks)

c State the roll of sulfuric acid in this reaction.

(1 mark)

d Explain why the same concentration of sulfuric acid and nitric acid would
have a different pH.

(3 marks)

2 A 100 cm3 sample of 0.012 mol dm3 HCl solution was made in a volumetric flask.
a Explain how hydrochloric acid can be classified as a strong acid.

(2 marks)

b State the concentration of hydrogen ions.

(1 mark)

c Calculate the pH of the solution.

(1 mark)

© Oxford University Press 2017 http://www.oxfordsecondary.co.uk/acknowledgements


This resource sheet may have been changed from the original 2
20 Acids, bases, and pH
OCR Chemistry A Application

d Explain why the pH of a 0.012 mol dm3 of HNO3 solution is the same as the
pH of the HCl solution.

(3 marks)

3 Phosphoric acid is a strong acid.


a Write a balanced chemical equation to show the dissociation of phosphoric
acid when in solution.

(1 mark)

b Calculate the pH of a 0.1 mol dm3 solution of phosphoric acid.

(2 marks)

c Calculate the concentration of phosphoric acid which has a pH of 1.2.

(3 marks)

d Write a balanced chemical equation for the reaction between sodium


carbonate and phosphoric acid.

(2 marks)

© Oxford University Press 2017 http://www.oxfordsecondary.co.uk/acknowledgements


This resource sheet may have been changed from the original 3

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