KHALLAL-SHINDE CHEMISTRY CLASSES

Time: 60 min Some Basic concepts in chemistry Marks: 180

1. The reaction, 2C + O2 –– 2CO2 is carried out 11. 0.2 moles of HCl and 0.1 mole of calcium
by taking 24 g carbon and 96 g O2. Which one chloride were dissolved in water to have 500 ml
is limiting reagent: of solution. The molarity of 𝐶𝑙 − ions is:
a) C b) O2 a) 0.04 M b) 0.4 M
c) CO2 d) None c) 0.8 M d) 0.08 M
2. 4.48 litre of methane at NT.P. correspond to 12. To a 4 L of 0.2 M solution of NaOH, 2L of 0.5 M
a) 1.2 x 1022 molecules of methane NaOH are added. The molarity of the resulting
b) 0.5 mole of methane solution is
c) 3.2 g of methane a) 0.9 M b) 0.3 M
d) 0.1 mole of methane c) 1.8M d) 0.18 M.
3. If 3.01 x 10 molecules are removed from 98 mg
20 13. 250 ml of 6 M HCl and 650 ml of 3 M HCl were
of H2SO4, then the number of moles of H2SO4 mixed together. What volume of water is to be
left are- added so that the molarity of the final solution
a) 0.166 x 10-3 b) 0.50 x 10-3 is 3M ?
c) 1.66 x 10-3 d) 9.95 x 10-2 a) 300 ml b) 1150 ml
4. An oxide of a metal (M) contains 40% by mass of c) 250 ml d) 135 ml
oxygen. Metal (m) has atomic mass of 24. The 14. 1.2 g of Mg (At. mass 24) will produce MgO equal to
emperical formula of the oxide is – a) 0.05 mol (b) 40 g
a) M2O b) MO c) 40 mg (d) 4 g
c) M2O3 d) M3O4 15. The formula which represents the simple ratio of
5. A mixture containing 100 g H2 and 100 g O2 is atoms in a compound is called –
ignited so that water is formed according to the a) Molecular formula (b) Structure formula
reaction, 2H2 + O2  2H2O ; How much water c) Empirical formula (d) Rational formula
will formed –
16. 5.6 litre of a gas at N.TP.weighs equal to 8g the
a) 112.5 g b) 50 g
c) 25 g d) 200 g vapour density of gas is -
6. 0.5 mole of H2SO4 is mixed with 0.2 mole of
(a) 32 (b) 16 (c) 8 (d) 40.
Ca(OH)2. The maximum number of moles of 17. The law of conservation of mass holds good for all of
CaSO4 formed is the following except –
a) 0.2 b) 0.5 (a) All chemical reactions (b) Nuclear reactions
c) 0.4 d) 1.5 (c) Endothermic reacbons. (d) Exothermic reactions.
7. Two elements X (at mass 16) and Y (at mass 14 18. How many grams are contained in 1 gram –
) combine to form compound A, B and C. The atom of Na ?
ratio of different masses of Y which combine (a) 13 g (b) 23 g
with a fixed mass of X in A, B and C is 1 : 3 : 5. 1
If 32 parts by mass of X combines with 84 parts (c) 1 g (d) g
23
by mass of Y in B, then in C 16 parts by mass X 19. Number of HCl molecules present in 10 mL of
will combine with 0.1 N HCl solution
a) 14 parths by mass of Y (a) 6.022 x 1023 (b) 6.022 x 1022
b) 42 parts by mass of Y (c) 6.022 x 1021 (d) 6.022 x 1020
c) 70 parts by mass of Y 20. If 32 g of O2 contain 6.022 x 1023 molecules at
d) 84 parts by mass of Y NTP then 32 g of S, under the same conditions,
8. An aqueous solution of 6.3 g of oxalic acid will contain ,
dihydrate is made upto 250 ml. The volume of 0 (a) 6.022 x 1023 S (b) 3.011 x 1023 S
.1 N NaOH required to completely neutralise 10 (c) 12.044 x 10 23 S (d) 1 x 1023 S
ml of this solution is 21. How many molecule are present in 12 L of liquid
a) 40 ml b) 20 ml CCl4 ? The density of the liquid is 1.59 g cm-3
c) 10 ml d) 4 ml (a) 7.44 x 1026 (b) 0.744 x l026
9. 6.02 × 10 molecules of urea are present in 100
20 (c) 1.59 x 10 26 (d) 15.9 x 1026
ml of its solution. The concentration of urea 22. The vapour density of a gas is given by:
solution is : (a) VD = mol. wt. / 2
a) 0.02 M b) 0.01 M
c) 0.001 M d) 0.1M wt. of N molecules of gas
10. A litre of public water contains 5 mg of chlorine. (b) VD 
wt. of N molecules fo H2
The concentration of chlorine in ppm is
a) 5 × 10−4 b) 5 wt. of 1 mole of gas
(c) VD 
c) 50 d) 0.5 wt. of 1 mole fo H 2
(d) All
23. Which represents per cent by weight: 35. The solution A and B are 0.1 and 0.2 molar in a
wt. of solute substance. If 100 mL of A are mixed with 25 mL
(a)  100 of B and there is no change in volume, then the
wt. of solution
final molarity of the solution is -
wt. of solute
(b)  100 (a) 0.15 M (b) 0.18 M
volume of solution (c) 0.12 M (d) 0.30 M
volume of solute 36. The number of milli equivalents contained in 0.5
(c)  100
volume of solution litre of 0.2 N solution is -
(d) None (a) 0.1 (b) 100
24. 1.0 g of hydrogen contains 6 x 10 23 atoms. The (c) 0.01 (d) 1.0
atomic weight of helium is 4. It follows that the 37. If 250 mL of a solution contains 24.5 g H2SO4,
number of atoms in 1 g of He is: the molarity and normality respectively are -
(a) 14 x 6 x 1023 (b) 4 x 6 x 1023 (a) 1M, 2N (b) 1M, 0.5 M
(c) 0.5 M, 1 N (d) 2 M, 1 N
(c) 6 x 1023 (d) 12 x 1023
38. In a flask at a certain temperature there are 2 g
25. 0.44 g of a colourless oxide of nitrogen occupies H2 and 8g O2. The mole fraction of O2 in the
224 mL at STP. The compound is: given mixture is
(a) N2O (b) NO (a) 0.2 (b) 1 (c) 2 (d) 0.1
(c) N2O2 (d) NO2
39. The solution having lowest molar concentration
26. 100 mL of PH3 when decomposed produces is -
phosphorus and hydrogen. The change in (a) 1.0 N HCl (b) 0.4 N H2SO4
volume is: (c) 0.1 N Na2CO3 (d) None
(a) 50 mL increase
40. A solution contains one mole of alcohol and four
(b) 500 mL decrease
moles of water. What are the mole fractions of
(c) 900 mL decrease
water and alcohol -
(d) None
(a) 1/4 , 4/1 (b) 4/1 , 1/4
27. The vapour density of pure ozone would be: (c) 4/5, 1/5 (d) 1/5 , 4/5
(a) 48 (b) 32
41. An aqueous solution of urea containing 18 g
(c) 24 (d) 16
urea in 1500 cm3 of solution has a density of
28. An oxide of iodine (I = 127) contains 25.4 g of 1.052 g/cm3. If the molecular weight of urea is
iodine for 8 g of oxygen. Its formula could be: 60 , then the molality of solution is –
(a) I2O3 (b) I2O (a) 0.2 (b) 0.192
(c) I2O5 (d) I2O7 (c) 0.064 (d) 1.2
29. The empirical formula of a compound is CH. Its 42. H2O2 solution used for hair bleaching is sold as
molecular weight is 78. The molecular formula a solution of approximately 5.0 g H2O2 per 100
of the compound will be: mL of the solution. The molecular weight of is
(a) C2H2 (b) C3H3 34.7he molarity of this solution is approximately
(c) C4H4 (d) C6H6 –
30. The amount of KMnO4 required to prepare 100. (a) 3.0 (b) 1.5
mL of 0.1 N solution in alkaline medium –( Molar (c) 0.15 (d) 4.0
Mass = 158) 43. The correct expression relating molality (m),
(a) 1.58 g (b) 0.52 g molarity (M), density (d) and molar Mass (MB) of
(c) 3.16 g (d) 0.31 g solute is
31. How many grams of glucose be dissolved to M M
make one litre solution of 10 % glucose (a) M = (b) m =
d  MM B d  MM B
(a) l0 g (b) 180 g
(c) 100 g (d) 1.8 g d  MM B d - MM B
(c) m = (d) m =
32. The volume of 0.1 M H2SO4 required to M M
neutralise 30 mL of 2.0 M NaOH is – 44. Out of molarity (M), molality (m), formality (F)
(a) 100 mL (b) 300 mL and mole fraction (x) those independent of
(c) 400 mL (d) 200 mL temperature are -
33. 1.5 litre of a solution of normality N and 2.5 (a) M, m (b) F, x
litres of 2M HCl are mixed together. The (c) m, x (d) M, x
resultant solution had a normality 5. The value 45. 10 gram of glucose are dissolved in 150 gram of
of N is – water. The mass % of glucose is -
(a) 6 (b) 10 (a) 5 % (b) 6.25 %
(c) 8 (d) 4 (c) 93.75% (d) 15 %
34. 2.3 g of C2H5OH (mol. wt. 46) are dissolved in
500 mL of water. The molarity of the solution is
–
(a) 0.01 (b) 0.1
(c) 0.05 (d) 2.0