Calculation of the Vapor pressure of n-pentane using Soave-Redlich-Kwong and Antoine's equations by A.K.

Coker

Soave-Redlich-Kwong equations:
U sin g SRK equation in cu
RT a SRK T 
P  RT 2  a SRK
v  b SRK  v v  bSRK  f V  V 3  V 
P 

RT
a 
a SRK T  a c,SRK  1 fSRK 1  Tr1 2 
2
P
 a  b RT  PbSRK
2
b  SRK SRK
 P
a b
0.42748R 2 Tc2 c  SRK SRK
a c,SRK  P
Pc

Q
a 2
 3b 
, R
fSRK  0.480 1.574 0.176 2
9

If Q and R are real (alway

0.08664RTc
bSRK 
Pc
and

The Antoine equation: R 2  Q3 , then the cubic equ

B Calculate these roots as fol

ln Pr* A 
Tr  C
 R 
 arc cos  
 Q3 
 

  a
V1  2 Q cos   
3 3
 R  Q , then the cubic equ

Calculate these roots as fol

 R 
 arc cos  
where the constants A, B and C depend on the acentric factor  Q3 
 

 0.252 Pc= 33.69 bar Tc= 469.7 K

  a
R= 83.14 cm3-bar/mol-K T= 309.2 K V1  2 Q cos   
 3 3
Tr= 0.658293
f      2 
0.865471296 V= 23532.5 cm3/mol V2  2 Q cos  
 3 
P= 1.05 bar
a c,SRK     2 
19349776.38 cm6-bar/mol2 V3  2 Q cos  
 3 
(Source : Pr ess, W.H., et. al
bSRK  100.4264273 cm3/mol
The art of Scientific Compu

a SRK T  26184024.42 cm6-bar/mol2

P= 3.32247E-07

Antoine's Equation

0.6 Tr 0.7

A4.0434  2.1456f  0.43477f 2  0.38481f 3  0.050479f 4
B4.3755 1.2981f  0.53208f 2  0.44506f 3  0.074005f 4
C0.0708033  0.240584f  0.0801510f 2  0.00990303f 3  0.000160472f 4

0.7 Tr 0.84

R=
A4.4401  2.2128f  0.53518f 2  0.17368f 3  0.018512f 4
 A4.4401  2.2128f  0.53518f 2  0.17368f 3  0.018512f 4
B 5.0075 1.2494f  0.78155f 2  0.32010f 3  0.047601f 4
C0.124652  0.273702f  0.0750076f 2  0.0137818f 3  0.00145038f 4

0.84 Tr 1.0

A4.8817  2.5164f  0.53557f 2  0.09639f 3  0.012108f 4

B 5.8938 1.6311f  0.91992f 2  0.24694f 3  0.034344f 4
C0.206497  0.281653f  0.0716095f 2  0.0174537 f 3  0.00236311f 4

0.6 Tr 0.7 0.7 Tr 0.84 0.84 Tr 1.0

A  5.795834984 6.056549

B 5.347417839 5.684212

C  -0.0838888 -0.06579

Pr= 0.029787214 0.029098 Pr= 0.02978721

P= 1.004 bar 0.9803 bar P= 1.0035 bar

% dev= 4.6 %

The vapor pressure, Pv of n  pen tan e from Eq. 4  16:

B
log Pv A   Clog T  DT  ET 2
T

A 33.3292, B  2.4227 x103 , C  9.2354

The vapor pressure, Pv of n  pen tan e from Eq. 4  16:

B
log Pv A   Clog T  DT  ET 2
T

A 33.3292, B  2.4227 x103 , C  9.2354

D 9.0199x10 11 , E 4.105 x10 6 143.42  T(K)  469.65

(Source : Co ker, A.K., Vol. 1, Ludwig 's Applied Pr ocess designfor chemical & Petrochemical plants,
pp109, Elsevier, 2007)

A= 33.3292
B= -2422.7
C= -9.2354
D= 9.0199E-11
E= 0.000004105

log Pv= 2.887917703

Pv= 772.5341793 mm Hg
1.016 bar

% dev between SRK and calculated Pv value from Vol. 1 Ludwig's Applied Process design for Chemical & Petrochemical plants pp. 109.

% dev= 3.3 %
U sin g SRK equation in cubic form of the molar volume, V is :
RT 2  a SRK  bSRK RT  PbSRK
2
 a SRK bSRK
f V  V 3  V  V 0
P  P  P

RT
a 
P
 a  b RT  PbSRK
2

b  SRK SRK 
 P 
a b
c  SRK SRK
P

Q
a 2
 3b 
, R
2a 3
 9ab  27c 
9 54

If Q and R are real (always true when a, b and c are real)

and

R 2  Q3 , then the cubic equation has three real roots of V

Calculate these roots as follows :

 R 
 arc cos  
 Q3 
 

  a
V1  2 Q cos   
3 3
R  Q , then the cubic equation has three real roots of V

Calculate these roots as follows :

 R 
 arc cos  
 Q3 
 

  a
V1  2 Q cos   
 3 3
   2  a
V2  2 Q cos  
 3  3
   2  a
V3  2 Q cos  
 3  3
(Source : Pr ess, W.H., et. al., Numerical Re cipes in Fortran in Fortran 77 
The art of Scientific Computing, 2nd ed., Cambridge University Pr ess, pp179,1992)

83.14 cm3-bar/mol.K
Constants
a= -24482.8
b= 2.2E+07
c= -3E+09
Q= 5.9E+07
R= -5E+11
there are three real roots

theta= 3.063763
sqrt(Q)= 7688.375
a/3= -8160.92

The three real roots are:

V1= 129.7 cm3/mol

V2= 23532.5 cm3/mol
V3= 820.6 cm3/mol

The liquid molar volume129.7

is V1c=m3/mol
The vapor molar volume
23532.5
is Vcm
2= /mol
3

Calculation of fugacity coefficients for liquid and vapor phases:

For liquid phase:

Compressibility fact 0.0053

h= 0.7743
 Fugacity coefficient 0.9215

For vapor phase:

Compressibility fact 0.9612

h= 0.0043
Fugacity coefficient 0.9623

ants pp. 109.

Calculation of the Vapor pressure n-hexane using Soave-Redlich-Kwong and Antoine's equations by A.K. Coker

Soave-Redlich-Kwong equations:

RT a SRK T 
P 
v  b SRK  v v  bSRK 

a SRK T  a c,SRK  1 fSRK 1  Tr1 2 

2

0.42748R 2 Tc2
a c,SRK 
Pc

fSRK  0.480 1.574 0.1762

0.08664RTc
bSRK 
Pc

The Antoine equation:

B
ln Pr* A 
Tr  C
where the constants A, B and C depend on the acentric factor

 0.301 Pc= 30.25 bar Tc= 507.6 K

R= 83.14 cm3-bar/mol-K T= 341.9 K
Tr= 0.673562
f  
0.937828224 V= 27130 cm3/mol
P= 1.005991 bar
a c,SRK 
25168288.81 cm6-bar/mol2

bSRK  120.8717189 cm3/mol

a SRK T  34343706.91 cm6-bar/mol2

P= 1E-06

Antoine's Equation

0.6 Tr 0.7

A4.0434  2.1456f  0.43477f 2  0.38481f 3  0.050479f 4

B4.3755 1.2981f  0.53208f 2  0.44506 f 3  0.074005f 4

C0.0708033  0.240584 f  0.0801510 f 2  0.00990303f 3  0.000160472f 4

0.7 Tr 0.84

A4.4401  2.2128f  0.53518f 2  0.17368f 3  0.018512f 4
 A4.4401  2.2128f  0.53518f 2  0.17368f 3  0.018512f 4
B 5.0075 1.2494f  0.78155f 2  0.32010f 3  0.047601f 4
C0.124652  0.273702f  0.0750076f 2  0.0137818f 3  0.00145038f 4

0.84 Tr 1.0

A4.8817  2.5164f  0.53557f 2  0.09639f 3  0.012108f 4
B 5.8938 1.6311f  0.91992f 2  0.24694f 3  0.034344f 4
C0.206497  0.281653f  0.0716095f 2  0.0174537f 3  0.00236311f 4

0.6 Tr 0.7 0.7 Tr 0.84 0.84 Tr 1.0

A  5.951572906

B 5.434775114

C  -0.09259147

Pr= 0.03327071 Pr= 0.033271

P= 1.006438966 P= 1.006439 bar

% dev= 0.04 %

The vapor pressure, Pv of n  hexa n e from Eq.4  16:

B
log Pv A   Clog T  DT  ET 2
T

A 69.7378, B  3.6278 x103 , C  2.3927 x10

The vapor pressure, Pv of n  hexa n e from Eq.4  16:

B
log Pv A   Clog T  DT  ET 2
T

A 69.7378, B  3.6278 x103 , C  2.3927 x10

D 1.281x10 2 , E  1.6844 x10 13 177.84  T(K)  507.43

(Source : Co ker, A.K., Vol. 1, Ludwig 's Applied Pr ocess designfor chemical & Petrochemical plants,
pp109, Elsevier, 2007)

A= 69.7378
B= -3627.8
C= -23.927
D= 0.01281
E= -1.6844E-13

log Pv= 2.878230311

Pv= 755.4927675 mm Hg
0.9941 bar

% dev between SRK and calculated Pv value from Vol. 1 Ludwig's Applied Process design for Chemical & Petrochemical plants pp. 109.

% dev= 1.2 %
U sin g SRK equation in cubic form of the molar volume, V is :
RT 2  a SRK  bSRK RT  PbSRK
2
 a SRK bSRK
f V  V 3  V  V 0
P  P  P

RT
a 
P
 a  b RT  PbSRK
2

b  SRK SRK 
 P 
a b
c  SRK SRK
P

Q
a 2
 3b 
, R
2a 3
 9ab  27c 
9 54

If Q and R are real (always true when a, b and c are real)

and

R 2  Q3 , then the cubic equation has three real roots of V

Calculate these roots as follows :

 R 
 arc cos  
 Q3 
 

  a
V1  2 Q cos   
 3 3
Calculate these roots as follows :

 R 
 arc cos  
 Q3 
 

  a
V1  2 Q cos   
 3 3
   2  a
V2  2 Q cos  
 3  3
   2  a
V3  2 Q cos  
 3  3
(Source : Pr ess, W.H., et. al., Numerical Re cipes in Fortran in Fortran 77 
The art of Scientific Computing, 2nd ed., Cambridge University Pr ess, pp179,1992)
R= 83.14 cm3-bar/mol.K

Constants
a= -28256.3
b= 3.1E+07
c= -4E+09
Q= 7.8E+07
R= -7E+11
there are three real roots

theta= 3.062151
sqrt(Q)= 8858.709
a/3= -9418.76

The three real roots are:

V1= 156.9 cm3/mol

V2= 27130 cm3/mol
V3= 969.4 cm3/mol

The liquid molar volume156.9

is V1c=m3/mol
The vapor molar volume
27130
is Vcm
2= /mol
3

Calculation of fugacity coefficients for liquid and vapor phases:

For liquid phase:

 Compressibility fact 0.0056
h= 0.7704
Fugacity coefficient 0.9535

For vapor phase:

Compressibility fact 0.9601

h= 0.0045
Fugacity coefficient 0.9612

al plants pp. 109.

Calculation of the Vapor pressure of methyl chloride using Soave-Redlich-Kwong and Antoine's equations by A.K. Coker

Soave-Redlich-Kwong equations:
U sin g SRK equation in cubi
RT a SRK T 
P  RT 2  a SRK 
v  b SRK  v v  bSRK  f V  V 3  V 
P 

RT
a 
a SRK T  a c,SRK  1 fSRK 1  Tr1 2 
2
P
 a  b RT  PbSRK
2

b  SRK SRK 
 P 
a b
0.42748R 2 Tc2 c  SRK SRK
a c,SRK  P
Pc

Q
a 2
 3b 
, R
2
fSRK  0.480 1.574 0.176 2
9

If Q and R are real (always

0.08664RTc
bSRK 
Pc
and

The Antoine equation: R 2  Q3 , then the cubic equa

B Calculate these roots as follo

ln Pr* A 
Tr  C
 R 
 arc cos  
 Q3 
 

  a
V1  2 Q cos   
3 3
 R  Q , then the cubic equa

Calculate these roots as follo

 R 
 arc cos  
where the constants A, B and C depend on the acentric factor  Q3 
 

 0.153 Pc= 66.8 bar Tc= 416.3 K

  a
R= 83.14 cm3-bar/mol-K T= 249.1 K V1  2 Q cos   
 3 3
Tr= 0.598367
f      2  a
0.716702016 V= 18790.7 cm3/mol V2  2 Q cos  
 3  3
P= 1.075531 bar
a c,SRK     2  a
7666059.759 cm6-bar/mol2 V3  2 Q cos  
 3  3
(Source : Pr ess, W.H., et. al.,
bSRK  44.89091031 cm3/mol
The art of Scientific Computi

a SRK T  10356453.91 cm6-bar/mol2

P= 2.32607E-06

Antoine's Equation

0.6 Tr 0.7

A4.0434  2.1456f  0.43477f 2  0.38481f 3  0.050479f 4
B4.3755 1.2981f  0.53208f 2  0.44506f 3  0.074005f 4
C0.0708033  0.240584f  0.0801510f 2  0.00990303f 3  0.000160472f 4

0.7 Tr 0.84

R=
A4.4401  2.2128f  0.53518f  0.17368f  0.018512f
2 3 4
 A4.4401  2.2128f  0.53518f 2  0.17368f 3  0.018512f 4
B 5.0075 1.2494f  0.78155f 2  0.32010f 3  0.047601f 4
C0.124652  0.273702f  0.0750076f 2  0.0137818f 3  0.00145038f 4

0.84 Tr 1.0

A4.8817  2.5164f  0.53557f 2  0.09639f 3  0.012108f 4
B 5.8938 1.6311f  0.91992f 2  0.24694f 3  0.034344f 4
C0.206497  0.281653f  0.0716095f 2  0.0174537f 3  0.00236311f 4

0.6 Tr 0.7 0.7 Tr 0.84 0.84 Tr 1.0

A  5.486177199 5.810171 4.8817

B 5.176861096 5.606778 5.8938

C  -0.0641413 -0.03844 0.206497

Pr= 0.014932259 0.014947 0.087071 Pr= 0.014947

P= 0.9985 bar 0.997 bar 0.998 P= 0.9985 bar

% dev= 7.2 %

The vapor pressure, Pv of Methyl chloride from Eq. 4  16:

B
log Pv A   Clog T  DT  ET 2
T
The vapor pressure, Pv of Methyl chloride from Eq. 4  16:

B
log Pv A   Clog T  DT  ET 2
T

A 25.7264, B  1.7503x10 3 , C  6.7151

D  1.295610  9 , E 4.4341x10  6 175.43  T(K)  416.25
(Source : Co ker, A.K., Vol. 1, Ludwig 's Applied Pr ocess designfor chemical & Petrochemical plants,
pp109, Elsevier, 2007)

A= 25.7264
B= -1750.3
C= -6.7151
D= -1.2956E-09
E= 4.4341E-06

log Pv= 2.883154573

Pv= 764.107694 mm Hg
1.005 bar

% dev between SRK and calculated Pv value from Vol. 1 Ludwig's Applied Process design for Chemical & Petrochemical plants pp. 109.

% dev= 7%
U sin g SRK equation in cubic form of the molar volume, V is :
RT 2  a SRK  bSRK RT  PbSRK
2
 a SRK bSRK
f V  V 3  V  V 0
P  P  P

RT
a 
P
 a  b RT  PbSRK
2

b  SRK SRK 
 P 
a b
c  SRK SRK
P

Q
a 2
 3b 
, R
2a 3
 9ab  27c 
9 54

If Q and R are real (always true when a, b and c are real)

and

R 2  Q3 , then the cubic equation has three real roots of V

Calculate these roots as follows :

 R 
 arc cos  
 Q3 
 

  a
V1  2 Q cos   
3 3
R  Q , then the cubic equation has three real roots of V

Calculate these roots as follows :

 R 
 arc cos  
 Q3 
 

  a
V1  2 Q cos   
 3 3
   2  a
V2  2 Q cos  
 3  3
   2  a
V3  2 Q cos  
 3  3
(Source : Pr ess, W.H., et. al., Numerical Re cipes in Fortran in Fortran 77 
The art of Scientific Computing, 2nd ed., Cambridge University Pr ess, pp179,1992)

83.14 cm3-bar/mol.K
Constants
a= -19255.8
b= 8762731
c= -4E+08
Q= 3.8E+07
R= -2E+11
there are three real roots

theta= 3.092237
sqrt(Q)= 6186.872
a/3= -6418.59

The three real roots are:

V1= 56.3 cm3/mol

V2= 18790.7 cm3/mol
V3= 408.8 cm3/mol

The liquid molar volume is V1= 56.3 cm3/mol

The vapor molar volume is V2= 18790.7 cm3/mol

Calculation of fugacity coefficients for liquid and vapor phases:

For liquid phase:

Compressibility factor Z = 0.0029

h= 0.7974
 Fugacity coefficient for liquid = 0.9147

For vapor phase:

Compressibility factor Z = 0.9758

h= 0.0024
Fugacity coefficient for liquid = 0.9763

plants pp. 109.

 Characteristic Properties of Pure Species

Methane Molar Acentric Tc Pc Zc Vc Tn


mass factor K bar cm3/mol K

Methane 16.043 0.012 190.6 45.99 0.286 98.6 111.4

Ethane 33.07 0.1 305.3 48.72 0.279 145.5 184.6
Propane 44.097 0.152 369.8 42.48 0.276 200 231.1
n-Butane 58.123 0.2 425.1 37.96 0.274 255 272.7
n-Pentane 72.15 0.252 469.7 33.7 0.27 313 309.2
n-Hexane 86.177 0.301 507.6 30.25 0.266 371 341.9
n-Heptane 100.204 0.35 540.2 27.4 0.261 428 371.6
n-Octane 114.231 0.4 568.7 24.9 0.256 486 398.8
n-Nonane 128.258 0.444 594.6 22.9 0.252 544 424
n-Decane 142.285 0.492 617.7 21.1 0.247 600 447.3
Isobutane 58.123 0.181 408.1 36.48 0.282 262.7 261.4
Isooctane 114.231 0.302 544 25.68 0.266 468 372.4
Cyclopentane 70.134 0.196 511.8 45.02 0.273 258 322.4
Cyclohexane 84.161 0.21 553.6 40.73 0.273 308 353.9
Methylcyclopentane 84.161 0.23 532.8 37.85 0.272 319 345
Methycyclohexane 98.188 0.235 572.2 34.71 0.269 368 374.1
Ethylene 28.054 0.087 282.3 50.4 0.281 131 169.4
Propylene 42.081 0.14 365.6 46.65 0.289 188.4 225.5
 1-Butene 56.108 0.191 420 40.43 0.277 239.3 266.9
cis-2-Butene 56.108 0.205 435.6 42.43 0.273 233.8 276.9
trans-2-Butene 56.108 0.218 428.6 41 0.275 237.7 274
1-Hexene 84.161 0.28 504 31.4 0.265 354 336.3
Isobutylene 56.108 0.194 417.9 40 0.275 238.9 266.3
1,3-Butadiene 54.092 0.19 425.2 42.77 0.267 220.4 268.7
Cyclohexene 82.145 0.212 560.4 43.5 0.272 291 356.1
Acetylene 26.038 0.187 308.3 61.39 0.271 113 189.4
Benzene 78.114 0.21 562.2 48.98 0.271 259 353.2
Toulene 92.141 0.262 591.8 41.06 0.264 316 383.8
Ethylbenzene 106.167 0.303 617.2 36.06 0.263 374 409.4
Cumene 120.194 0.326 631.1 32.09 0.261 427 425.6
o-Xylene 106.167 0.31 630.3 37.34 0.263 369 417.6
m-Xylene 106.167 0.326 617.1 35.36 0.259 376 412.3
p-Xylene 106.167 0.322 616.2 35.11 0.26 379 411.5
Styrene 104.152 0.297 636 38.4 0.256 352 418.3
Naphtalene 128.174 0.302 748.4 40.51 0.269 413 491.2
Biphenyl 154.211 0.365 789.3 38.5 0.295 502 528.2
Formaldehyde 30.026 0.282 408 65.9 0.223 115 254.1
Acetaldehyde 44.053 0.291 466 55.5 0.221 154 294
Methyl acetate 74.079 0.331 506.6 47.5 0.257 228 350.2
Ethyl acetate 88.106 0.366 523.3 38.8 0.255 286 350.2
Acetone 58.08 0.307 508.2 47.01 0.233 209 329.4
Methyl ethyl ketone 72.107 0.323 535.5 41.5 0.249 267 352.8
 Diethyl ether 74.123 0.281 466.7 36.4 0.263 280 307.6
Methyl t-butyl ether 88.15 0.266 497.1 34.3 0.273 329 328.4
Methanol 32.042 0.564 512.6 80.97 0.224 118 337.9
Ethanol 46.069 0.645 513.9 61.48 0.24 167 351.4
1-Propanol 60.096 0.622 536.8 51.75 0.254 219 370.4
1-Butanol 74.123 0.594 563.1 44.23 0.26 275 390.8
1-Hexanol 102.177 0.579 611.4 35.1 0.263 381 430.6
2-Propanol 60.096 0.668 508.3 47.62 0.248 220 355.4
Phenol 94.113 0.444 694.3 61.3 0.243 229 455
Ethylene glycol 62.068 0.487 719.7 77 0.246 191 470.5
Acetic acid 60.053 0.467 592 57.86 0.211 179.7 391.1
n-Butyric acid 88.106 0.681 615.7 40.64 0.232 291.7 436.4
Benzoic acid 122.123 0.603 751 44.7 0.246 344 522.4
Acetonitrile 41.053 0.338 545.5 48.3 0.184 173 354.8
Methylamine 31.057 0.281 430.1 74.6 0.321 154 266.8
Ethylamine 45.084 0.285 456.2 56.2 0.307 207 289.7
Nitromethane 61.04 0.348 588.2 63.1 0.223 173 374.4
Carbon tetrachloride 153.822 0.193 556.4 45.6 0.272 276 349.8
Chloroform 119.377 0.222 536.4 54.72 0.293 239 334.3
Dichloromethane 84.932 0.199 510 60.8 0.265 185 312.9
Methyl chloride 50.488 0.153 416.3 66.8 0.276 143 249.1
Ethyl chloride 64.514 0.19 460.4 52.7 0.275 200 285.4
Chlorobenzene 112.558 0.25 632.4 45.2 0.265 308 404.9
Tetrafluoroethane 102.03 0.327 374.2 40.6 0.258 198 247.1
 Argon 39.948 0 150.9 48.98 0.291 74.6 87.3
Krypton 83.8 0 209.4 55.02 0.288 91.2 119.8
Xenon 131.3 0 289.7 58.4 0.286 118 165
Helium 4 4.003 -0.39 5.2 2.28 0.302 57.3 4.2
Hydrogen 2.016 -0.216 33.19 13.13 0.305 64.1 20.4
Oxygene 31.999 0.022 154.6 50.43 0.288 73.4 90.2
Nitrogen 28.014 0.038 126.2 34 0.289 89.2 77.3
Air 28.851 0.035 132.2 37.45 0.289 84.8
Chlorine 70.905 0.069 417.2 77.1 0.265 124 239.1
Carbon monoxide 28.01 0.048 132.9 34.99 0.299 93.4 81.7
Carbon dioxide 44.01 0.224 304.2 73.83 0.274 94
Carbon disulfide 76.143 0.111 552 79 0.275 160 319.4
Hydrogen sulfide 34.082 0.094 373.5 89.63 0.284 98.5 212.8
Sulfur dioxide 64.065 0.245 430.8 78.84 0.269 122 263.1
Sulfur trioxide 80.064 0.424 490.9 82.1 0.255 127 317.9
Nitiric oxide (NO) 30.006 0.583 180.2 64.8 0.251 58 121.4
Nitrous oxide (N2O) 44.013 0.141 309.6 72.45 0.274 97.4 184.7
Hydrogen chloride 36.461 0.132 324.7 83.1 0.249 81 188.2
Hydrogen cyanide 27.026 0.41 456.7 53.9 0.197 139 298.9
Water 18.015 0.345 647.1 220.55 0.229 55.9 373.2
Ammonia 17.031 0.253 405.7 112.8 0.242 72.5 239.7
Nitric acid 63.013 0.714 520 68.9 0.231 145 356.2
Sulfuric acid 98.08 924 64 0.147 177 610
 Tc critical temperature
Pc critical pressure
Vc critical volume
Zc critical compressibility factor
Tn normal boiling point.

(Source:
Table 4-4 Generalized Antoine constant functions for the SRK equation

0.6 Tr 0.7

A4.0434  2.1456f  0.43477f 2  0.38481f 3  0.050479 f 4

B4.3755 1.2981f  0.53208f 2  0.44506 f 3  0.074005f 4
C0.0708033  0.240584 f  0.0801510 f 2  0.00990303f 3  0.000160472 f 4

0.7 Tr 0.84

B 5.0075 1.2494 f  0.78155f 2  0.32010 f 3  0.047601f 4

A4.4401  2.2128f  0.53518f 2  0.17368f 3  0.018512 f 4
C0.124652  0.273702 f  0.0750076 f 2  0.0137818f 3  0.00145038f 4

0.84 Tr 1.0

A4.8817  2.5164f  0.53557f 2  0.09639 f 3  0.012108f 4

B 5.8938 1.6311f  0.91992 f 2  0.24694 f 3  0.034344f 4
C0.206497  0.281653f  0.0716095f 2  0.0174537 f 3  0.00236311f 4

(Source: DeDoes, A. J, et. al., CEP, pp 39-44, Jan. 2007)

Table 4-5 Generalized Antoine constant functions for the PR equation

0.7 Tr 0.84

A4.8512  2.3617f  0.45894f 2  0.070461f 3  0.10809 f 4

B5.5675 1.3213f  0.80186 f 2  0.11081f 3  0.087503f 4
C0.145395  0.287367 f  0.0815004 f 2  0.0253619 f 3  0.00813261f 4

0.84 Tr 1.0

A5.3988  3.0095f  0.68621f 2  0.10190 f 3  0.0027322 f 4

B 6.7141  2.3263f  1.3630 f 2  0.35003f 3  0.035704f 4
C0.243432  0.260581f  0.0448442 f 2  0.00718139 f 3  0.00122297 f 4

(Source: DeDoes, A. J, et. al., CEP, pp 39-44, Jan. 2007)

Table 4-6 Transforming Antoine constants A', B' and C' from Table 4-5 to dimensional constants A, B and C for use with Eq. 4-

A A ln Pc
A A ln Pc The units of Pc must be absolute pressure. Vapor pressure P* in Eq. 4-22 will have the same units as P c
B BTc The units of Tc must be absolute temperature in K or oR
C CTc Temperature T in Eq. 4-22 will have the same units as Tc
C CTc  273.15 Temperature T in Eq..4-22 in oC and Tc in K
C CTc  459.56 Temperature T in Eq. 4-22 in oF and Tc in oR

(Source: De Does, A.J., et. al. CEP, pp 39-44, Jan. 2007)

A, B and C for use with Eq. 4-22
will have the same units as P c