Scribd
Upload
66 views11 pages

Benzene Test

I am fazia to sab theck hai sir

Uploaded by

kingbaloch33634
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
66 views11 pages

Benzene Test

I am fazia to sab theck hai sir

Uploaded by

kingbaloch33634
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 11

XII - PM.

PE Chemistry Class Test - 01 (2023-24)


XII Chemistry Class Test-01
1. Benzene can be oxidized by:
⚪ KMnO4

⚪ O2

⚪ O3
⚫ Both B and C

2. Which of the following on oxidation with KMnO4 yields benzoic acid?

⚫ All of these

3. Electrophile in Friedal-Craft’s alkylation of benzene is:


⚪ Carbanion
⚫ Carbocation
⚪ Acylium ion
⚪ Arenium ion
4. Which of the following compound is least reactive towards electrophilic substitution reaction?
⚪

5. Bond order and resonating structures of benzene are respectively:


⚪ 2, 2
⚪ 2, 3
⚫ 1.5, 2
⚪ 1.5, 3

6. Number of sigma bonds in benzene involving sp2-sp2 overlapping are:

⚪ 3
⚫ 6
⚪ 12
⚪ 15
7. Number of sp2 hybrid carbon atoms in styrene are:

⚪ 3
⚪ 6
⚪ 7
⚫ 8

8. Which conditions can convert benzene into toluene?


⚫ CH3Cl / AlCl3

⚪ Cl2 / FeCl3

⚪ CH3COCl / AlCl3

⚪ CH3CH2Cl / AlCl3

9. Aromatic compounds give smoky flame because of:


⚪ High percentage of H
⚫ High percentage of C
⚪ Delocalisation
⚪ Saturation

10. Benzene is ________ molecule:


⚪ Tetrahedral
⚫ Planar
⚪ Trigonal
⚪ Square planar

11. Preparation of benzene from phenol is:


⚫ Reduction
⚪ Oxidation
⚪ Addition
⚪ Dehydrogenation

12. The true statement about benzene is:


⚪ Because of unsaturation benzene easily undergoes addition reactions
⚪ There are two types of C-C bonds in benzene molecule
⚫ There is a cyclic delocalisation of pi-electrons in benzene
⚪ Mono substitution of benzene gives three isomeric products

13. Benzene contains double bonds but does not give addition reactions because:
⚪ Double bonds in benzene ring are strong
⚪ Double bonds change their position rapidly
⚫ Resonance lowers the energy of benzene molecule and leads to greater stabilization
⚪ Benzene has cumulative double bonds

14. Nitration mixture is:


⚪ 1:1 of conc.HNO3 and conc.HCl
⚫ 1:1 of conc.HNO3 and conc.H2SO4
⚪ 1:1 of conc.HNO2 and conc.H2SO4

⚪ 1:1 of conc.H2SO4 and conc.HCl

15. Benzene reacts with _____ to yield acetophenone:


⚫ CH3COCl+AlCl3

⚪ C6H5COCl+AlCl3
⚪ R-COCl+AlCl3
⚪ C2H5COCl+AlCl3

16. What is the electrophile in the nitration of benzene?


⚫

⚪ NO+
⚪ NO
⚪

17. With which one of the following reagents benzene do not undergo substitution reaction?
⚪ Fuming sulphuric acid
⚪ Nitration mixture
⚫ Chlorine in presence of light
⚪ Acyl halide in presence of AlCl3

18. Deactivating groups on benzene ring:


⚫ Decrease electron density at ortho and para positions
⚪ Increase electron density at meta position
⚪ Decrease electron density at meta position
⚪ Both A and B

19. Amongst the following compounds which can be most easily sulphonated?
⚪ Benzene
⚪ Nitrobenzene
⚫ Toluene
⚪ Chlorobenzene

20. Which of the following will undergo meta-substitution on monochlorination?


⚪ Ethoxy benzene
⚪ Chlorobenzene
⚫ Nitrobenzene
⚪ Phenol

21. The final product of the nitration of toluene is:


⚪ o-nitrotoluene
⚪ m-nitrotoluene
⚪ 2,4-dinitrotoluene
⚫ 2,4,6-trinitrotoluene

22. Which of the following can be easily nitrated?


⚪ Benzene
⚫ Phenol
⚪ Nitrobenzene
⚪ Chlorobenzene

23. Which of the following groups would enhance the reactivity of electrophilic aromatic substitution?
⚪ –CN
⚪ –CHO
⚫ –NHCOR
⚪ –NO2

24. Among the following compounds (I-III) the correct order of reaction with electrophile is:

⚪ II>III>I
⚪ III<I<II
⚪ I>II>III
⚫ I>III>II

25. The ortho/para-directing group among the following is:


⚪ -COOH
⚪ –CN
⚪ -COCH3
⚫ -NHCOCH3

26.

‘X’ group present on benzene ring is:


⚪ –Cl
⚫ –NO2
⚪ –OH
⚪ –NH2

27. In electrophilic substitution reactions of halobenzene, halogens act as:


⚪ Activating and ortho, para directors
⚪ Deactivating and meta directors
⚪ Activating and meta directors
⚫ Deactivating and ortho, para directors
28.

Product ‘B’ is:


⚪ o-nitrotoluene
⚪ p-nitrotolune
⚫ m-nitrotoluene
⚪ Both A and B

29. Electrophile in chlorination of benzene is:


⚪ Chloride ion
⚪ Chlorine free radical
⚫ Chloronium ion
⚪ Chlorine molecule

30. Benzene is highly stable compound due to:


⚪ Cyclic structure
⚪ Planar shape
⚫ Delocalized pi – bonds
⚪ Strong sigma - bonds

31. Chlorination of benzene in presence of Lewis acid catalyst (FeCl3 or AlCl3) gives:

⚪ Benzene hexachloride
⚫ Chlorobenzene
⚪ Hexachlorocyclohexane
⚪ Both A and C

32. Conversion of benzene into cyclohexane is an example of:


⚫ Addition reaction
⚪ Oxidation reaction
⚪ Electrophilic substitution reaction
⚪ None of these

33. Reaction of benzene with acetyl chloride in presence of AlCl3 is called as:

⚪ Halogenation
⚪ Friedal-Craft’s alkylation
⚫ Friedal-Craft’s acylation
⚪ Addition reaction

34. According to Huckle rule, aromatic compounds possess 4n+2𝝿 electrons. Here value of ‘n’ can be:

⚪ 1,2,3………
⚫ 0,1,2,3……
⚪ 2,4,6………
⚪ 4,8,12….

35. Alkylation of ammonia produces:


⚪
Mixture of 1o, 2o and 3o amines
⚪
Mixture of 2o and 3o amines
⚫
Mixture of 1o, 2o, 3o amines and quaternary ammonium salt
⚪
Mixture of 2o, 3o amines and quaternary ammonium salt

36.

Predict final product of the given reaction:


⚪ Benzene
⚫ Phenol
⚪ Benzene diazonium chloride
⚪ Benzoquinone

37. Reduction of which of the following compound produces primary amine?


⚪ CH3-CN
⚪ CH3CH2NO2

⚪ CH3-CH2-CO-NH2
⚫ All of these

38.
. Y in the given reaction is:
⚪ CH3-NH2
⚪ CH3-CH2-NH2
⚫ CH3-CH2-CH2-NH2

39. Ethylamine can be obtained from methyl cynide by:


⚪ Hydrolysis
⚫ Reduction
⚪ Oxidation
⚪ Substitution

40. Shiff’s base is produced by reaction of:


⚪ o
1 -amine with alcohol
⚫ o
1 -amine with aldehyde
⚪ o
1 -amine with acid amide
⚪ o
1 -amine with acid halide

41. Most basic among following is:


⚪ NH3

⚫ CH3-NH2
⚪

42. Reaction of primary amine with acid halide produces:


⚪ Acid amide
⚫ N-substituted amide
⚪ N, N-disubstituted amide
⚪ All of these

43. Which of the following is a diazonium salt?


⚪

44. When propanamide (CH3CH2-CO-NH2) is treated with bromine (Br2) in presence of KOH _____ is
produced.
⚪ CH3-NH2

⚫ CH3CH2-NH2

⚪ CH3-CH2-CH2-NH2

⚪ CH3-CH2-CH2-CH2-NH2

45. Nitriles cannot be reduced by:


⚪ LiAlH4
⚪ Ni/H2

⚫ NaBH4

⚪ None of these

46. When acetamide is converted to methylamine, reaction is known as:


⚪ Reduction
⚪ Hoffman reaction
⚫ Hoffman degradation
⚪ Oxidation

47. Which of the following is true for the basicity of amines?


⚪ Alkylamines are generally less basic than arylamines because N is sp hybridised
⚪ Arylamines are generally more basic than alkylamines due to aryl group
⚫ Arylamines are generally less basic than alkylamines due to delocalisation of lone pair of electrons in the
benzene ring
⚪ Arylamines are generally less basic than alkylamines because lone pair of electrons on N in the
arylamines are not delocalized in the benzene ring

48. The reaction of ammonia with a large excess of CH3Cl will give mainly:

⚪ (CH3)3N
⚫
(CH3)4N+Cl-

⚪ CH3NH2
⚪ (CH3)2NH

49. CH3CH2CN and CH3CONH2 on reduction with LiAlH4 give:

⚪ Ethanamine and Methanamine respectively


⚪ Methanamine and Ethanamine respectively
⚪ Ethanamine and Ethanamine respectively
⚫ Propanamine and Ethanamine respectively

50. No intermolecular hydrogen bonding is observed in:


⚪ o
1 -amine
⚪ o
2 -amine
⚫ o
3 -amine
⚪ All amines possess strong hydrogen bonding

You might also like