CLASS: 12th NEET SUBJECT: CHEMISTRY DPP

COORDINATION COMPOUNDS & d-BLOCK COMPOUNDS

1. The oxidation state of Mo in its oxido-complex 10. Among the following metal carbonyls,
species [Mo2O 4(C 2H 4) 2(H 2O) 2] 2–
is the C-O bond order is lowest in.
(1) +2 (2) +3 (3) +4 (4) +5 (1) [Mn(CO)6 ]+
2. What is the charge on the complex (2) [Fe(CO)5 ]
[Cr(C 2O4 )2(H2 O)2] formed by Cr(III) (3) [Cr(CO)6 ]
(1) +3 (2) +1 (3) +2 (4) –1 (4) [V(CO)6] –
3. In which of the following complex the nickel 11. Which of the following are bidentate
metal is in highest oxidation state? monovalent anion ligands ?
(1) Ni(CO)4 (a) Acetylacetonato
(2) K2NiF6 (b) Oxalato ion
(3) [Ni(NH 3)6](BF 4 )2 (c) Dimethylglyoximato
(4) K4 [Ni(CN)6 ] Select the correct answer :-
4. A complex of platinum, ammonia and chloride (1) (a) only
produces four ions per molecule in the solution. (2) (a) and (c) only
The structure consistent with the observation (3) (c) only
is – (4) (b) and (c) only
(1) [Pt(NH3)4]Cl4 (2) [Pt(NH3)2 Cl4 ] 12. Diethylenetriamine is :-
(3) [Pt(NH3)5Cl]Cl3 (4) [Pt(NH3)4Cl2]Cl2 (1) Chelating agent
5. How many moles of AgCl would be obtained, (2) Tridentate neutral molecule
when Co(NH3 )5 Cl 3 is treated with excess of (3) Tridentate monoanion
AgNO 3 ? (4) (1) and (2) both
(1) 1 mol (2) 2 mol 13. Total number of isomers in [Pt(NH 3) 2 (CN)2 ]
(3) 3 mol (4) No ppt is formed is :-
6. The oxidation number of Co in the complex ion (1) 2 (2) 4 (3) 6 (4) 8
3+ 14. Which of the following name is impossible :
NH
(en)2Co Co(en)2
OH (1) Potassium tetrafluoridoxido chromate (VI)
(1) +2 (2) +3 (3) +4 (4) +6 (2) Barium tetrafluoridochromate (II)
–4
7. The donor sites of [EDTA] are (3) Dichlorobis (urea) copper (II)
(1) O atoms only (4) All the impossible
(2) N atoms only 15. The formula of sodium nitroprusside is
(3) Two N atoms and four O atoms (1) Na4 [Fe(CN)5 NO2 ]
(4) Three N atoms and Three O atoms (2) Na2 [Fe(CN)5 NO+]
8. Among the following, metal carbonyls, the (3) NaFe[Fe(CN)6 ]
C-O bond is strongest in : (4) Na2 [Fe(CN)6 NO2 ]
(1) [Mn(CO)6 ]+ (2) [Cr(CO)6 ] 16. The formula of complex tris (ethylenediamine)
– 2–
(3) [V(CO)6] (4) [Ti(CO)6] cobalt (III) sulphate is :
9. The bond length in CO is 1.128Å. What will (1) [Co(en)2 SO4 ]
be the bond length of CO in Fe(CO)5 ? (2) [Co(en)3 SO4 ]
(1) 1.158Å (2) 1.128Å (3) [Co(en)3] 2SO 4
(3) 1.078Å (4) 1.118Å (4) [Co(en)3 ]2(SO4) 3
17. Which of following pairs of name and formula 24. A compound is made by mixing cobalt (III)
of complexes, is not correct ? nitrite and potassium nitrite solution in the ratio
(1) Tetraamminecopper(II)sulphate................ of 1 : 3. The aqueous solution of the compound
[Cu(NH3 )4 ]SO4 showed 4 particles per molecule whereas molar
(2) Diamminesilver(I)chloride..[Ag(NH3 )2 ]Cl conductivity reaveals the presence of six
(3) Potassiumhexacyanidoferrate(III)..K4[Fe(CN)6] electrical charges. The formula of the
(4) Potassiumamminepentachloridoplatinate(IV) compound is
.......... K[PtCl5 (NH3)]
(1) Co(NO2)3 .2KNO2
18. Complex ion [CuCl2(NH2CoNH2] is named as
(2) Co(NO2)3 .3KNO2
(1) dichloro bis (urea) copper (II)
(3) K3[Co(NO2 )6 ]
(2) bis (urea) dichloro copper (II)
(4) K[Co(NO2)4 ]
(3) dichloro bis (urea) copper (I)
25. Which of the following shows maximum molar
(4) bis (urea) dichloro copper (I)
conductance
19. Trioxalatoaluminate (III) and tetrafluoro-
borate(III) ions are : (1) [Co(NH3 )6]Cl3
(1) [Al(C2 O4)3], [BF 4]3– (2) [Co(NH3)3Cl3 ]
(2) [Al(C2 O4)3 ]3+,[BF 4 ]3+ (3) [Co(NH3)4Cl2]Cl
(3) [Al(C2O4 )3]3– , [BF4 ]– (4) [Co(NH3 )5Cl]Cl2
2– 2–
(4) [Al(C2 O4 )3] , [BF4 ] 26. A Coordination complex has the formula
20. Calculate the EAN of central atom in the PtCl 4 .2KCl. Electrical conductance
following complexes: measurements indicate the presence of three
(i) [Cr(CO)6 ] ion in one formula unit. Treatment with AgNO3
(ii) [Fe( 5-C5 H5 )2 ] produces no precipitate of AgCl. What is the
21. In sodium nitroprusside, The oxidation number coordination no. of Pt in this complex
coordination No. and effective atomic number
(1) 5 (2) 6 (3) 4 (4) 3
of iron are respectively:
(1) +3, 6, 36 (2) +2, 6, 36 27. Which of the following complexes produces
(3) +3, 3, 36 (4) 6, +3, 35 three moles of Silver chloride when its one mole
22. In Tollen's reagent [Ag(NH3)2]+1. The oxidation is treated with excess of Silver nitrate:
number coordination number and effective (1) [Cr(H2 O)3 Cl3 ]
atomic number of central metal ion are
(2) [Cr(H2O)4 Cl2]Cl
respectively
[Atomic number of Ag = 47] (3) [Cr(H2O)5 Cl]Cl 2
(1) +1, 2, 50 (2) +1, 2, 51 (4) [Cr(H2O)6]Cl3
(3) +2, 1, 50 (4) +1, 1, 50 28. Concentrated H 2 SO 4 will not dehydrate the
23. The effective atomic no. of Co(CO)4 is 35 and following complex:
hense is less stable. It attains stability by: (1) [Cr(H2 O)5Cl]Cl2 .H2 O
(1) oxidation of Co (2) [Cr(H2O)4Cl2]Cl.2H2 O
(2) Reduction of Co
(3) [Cr(H2O)6]Cl6
(3) dimerization
(4) All of these
(4) (2) & (3) both
29. On adding AgNO 3 solution to a solution of 35. Which of the following cannot show linkage
[Pt(NH 3 ) 3 Cl 3 ]Cl. The percentage of total Isomerism :-
chloride ion precipitated is– (1) NO2 (2) SCN
(1) 100 (2) 75 (3) 50 (4) 25
(3) CN (4) NH3
30. One mole of the complex compound
36. The complexes [Pt(NH 3 ) 4 ][PtCl 6 ] and
Co(NH 3 ) 5 Cl 3 gives 3 moles of ion on
[Pt(NH3)4 Cl2] [PtCl4] are :-
dissolution in water. One mole of the same
(1) Linkage isomers
complex reacts with two moles of AgNO 3
solution to yield two moles of AgCl(s). The (2) Optical isomers
structure of the complex is– (3) Co-ordination isomers
(1) [Co(NH3)4Cl]Cl2.NH3 (4) Ionisation isomers

(2) [Co(NH3)5 Cl].Cl2 37. [Co(NH 3 )5 NO 2 ] Cl 2 and [Co(NH 3 )5 ONO]Cl 2

are related to each other as :-
(3) [Co(NH3 )3Cl].2NH3
(1) Geometrical isomers
(4) [Co(NH3)4Cl2 ]Cl.NH3
(2) Linkage isomers
31. Select the correct statement for the complexes
(3) Coordination isomers
[Cr(H2O)6]Cl 3 and [Cr(H2O)5 Cl]Cl2.H2 O
(4) ionisation isomers
(1) There can be differentiated by amount.
38. The no. of geometrical isomers of
(2) There can be diffrentiated by electrical [Co(NH3 )3(NO3)3 ] are :-
conducting measurement method. (1) 0 (2) 2 (3) 3 (4) 4
(3) There can be diffrentiated by heating with 39. Consider the following statement and arrange
conc. H2 SO4 . in the order of true/false as given in the
codes :-
(4) All of these
32. Select incorrect match for [M(H 2 O) 6 ] 2+ (a) [Cr(NH3 )6 ][Cr(CN)6] and [Cr(NH3 )4(CN)2 ]
complex. [Cr(NH3)2(CN)4] are coordination isomers:-

(b) [Cr(Py) 2 (H 2 O) 2 Cl 2 ]Cl and

Electronic
Metal ions CFSE [Cr(Py)2(H2O)Cl3]H2O are ionisation isomer
configuration
1 Mn 2
t 32g e 2g 0 0 (c) [Pt(NH3)4Br2]Cl2 and [Pt(NH3)4Cl2] Br2 are
2 V 2
t 32g e 0g 1.2 linkage isomers
0

3 Ni2 t 62g e 2g 1.6 0 (d) [PtCl2(NH3 )2] exihibits optical isomerism

4 Ti 2 t 22g e 0g 0.8 0 (1) TTFT (2) FTFT (3) TTFF (4) TFFF
33. Which of the following is non-conducting? 40. Which of following isomers of [M(NH3 )2Cl2 ]
(1) CoCl3.6NH3 (2) CoCl3.5NH3 would react with silver oxalate (Ag 2C2 O4 ) :-
(3) CoCl3.4NH3 (4) CoCl3.3NH3
H3N Cl H3N Cl
34. Following sidwick's rule of EAN, Co(CO)x will M M
(1) (2)
be: H3N Cl Cl H 3N
(1) Co(CO)4 (2) Co(CO)3
(3) Both (4) None
(3) Co(CO)6 (4) Co(CO)10
41. Which of the following complex will follow 45. Three arrangements are shown for the complex
EAN rule ? [Co(en)(NH 3 ) 2 Cl 2 ] + pick up the correct
(1) [Mn(Co)5 ] statement:-

(2) [Mn(Co)6 ] Cl Cl Cl
Cl NH3
(3) [Fe(Co)5 ] NH3
Co en
(I) (II) Co en (III) en Co
(4) [Co(Co)4 ] H3 N
NH3
NH3
42. Identify the geometrical isomers of the NH3
Cl Cl
following:-
(1) II and III are optical isomers
Cl (2) I & III are optical isomers
en Cl en en Cl
Cl
(3) I & II one geometrical isomers
en en
(4) II & III are geometrical isomers
Cl en en Cl en Cl 46. Which kind of isomerism is exhibited by
Cl
(I) (iv) octahedral [Co(NH 3 )4 Br2 ]Cl ?
(II) (III)
(1) Geometrical & ionization
(1) I with III (2) Geometrical & optical
(2) II with IV (3) Optical & ionization
(3) I with II (4) Geometrical only

(4) None of these 47. Which of the following has an optical isomer ?
(1) [Co(en)(NH3 )2 ]2+
43. Which of the following compounds show
(2) [Co(H2O) 4 (en)]3+
optical isomerism ?
(3) [Co(en)2 (NH3) 2] 3+
+
(a) Cis-[Co(NH3)4Cl2 ]
(4) [Co(NH3 )3 Cl]+
+
(b) trans-[Co(en)2 Cl2 ] 48. Which of the folloing pairs represents linkage
+
(c) cis-[Co(en)2Cl2 ] isomers ?
(d) [Co(en)3 ]3+ (1) [Pd(PPh3)2 (NCS)2] and [Pd(PPh3)2(SCN)2 ]
(2) [Co(NH3 )5NO3 ]SO4 and [Co(NH3)5SO4] NO3
(1) a & b
(3) [PtCl2(NH3)4 ]Br2 and [PtBr2 (NH3)4 ]Cl2
(2) b & c
(4) [Cu(NH3)4][PtCl4 ] and [Pt (NH3 )4] [CuCl4 ]
(3) c & d
49. Select the correct statement from the following?
(4) a, b & d (1) [Sc(H 2 O) 6 ] 3+ and [Ti(H 2 O) 6 ] 3+ both are
44. Which of the following isomerism is/are not colourless
shown by the complex [CoCl2(OH)2(NH3)2]Br? (2) [Co(NH3 )4 Br2]Cl show ionization isomers
(1) Ionization and geometrical isomers
(3) [Pd(NO 2 ) 2 (NH 3 ) 2 ] is square planar and
(2) Linkage
shows geometrical as well as linkage
(3) Gemetrical isomers
(4) Optical (4) Both (2) and (3) are correct
50. [Fe(en)2 (H 2 O)2 ] 2+ + en complex (x). The 57. Complex
correct statement about the complex (x) it is (a) Na2[Fe(CN)5NO]
(1) a low spin complex (b) [Fe(H2O)5NO]SO4
(c) K4[Fe(CN)6]
(2) diamagnetic
Which of the following statement are wrong ?
(3) shows geometrical isomerism
(1) (a) is used in detation of S 2–
(4) (1) and (2) both (2) complex part of each compound in
51. Which kind of isomerism is shown by the octahedral
complex [Co(NH3 )5 (ONO)]SO4 ? (3) (c) is used in detection of Fe3+
1. Ionization isomerism (4) O.S. of Fe in (a) and (b) is +1
2. Linkage isomerism 58. [Pt(NH3 )(NH2 OH)(NO2)(Py)]+ will form how
3. Geometrical isomerism many geometrical isomers :-
4. Optical isomerism (1) 2 (2) 3 (3) 0 (4) 5
(1) 1, 2, 3, & 4 are correct 59. Isomerism exhibited by [Cr(NH3 )2 (H2O)2Cl2 ]+
(2) 1, 3, & 4 are correct only are:-
(3) 1 & 2 are correct only (1) Ionisation, optical
(4) 2, 3 & 4 are correct only
(2) Hydrate, optical
52. Which of the following complexes show
(3) Geometrical, optical
geometrical as well as optical isomerism ?
(i) [Cr(ox) 3 ]3– (4) Coordinate, geometrical
(ii) [Rh(en)2 Cl2 ]+ 60. Which of the following is true for the complex
(iii) [Co(NH3)2Cl2 (en)]+ Co(NO2)(Cl)2.5NH3 (Co is in + 3 oxidation state)
Select the correct code (1) It shows ionisation isomerism
(1) (i) only (2) (i) & (ii) only (2) It is inner orbital complex
(3) (ii) & (iii) only (4) (i), (ii), & (iii) (3) It is diamagnetic
53. The total No. of possible isomers of the
(4) All
compound [CuII(NH3)4 ][PtII Cl4 ] are :-
61. The total No. of isomers possible for the
(1) 3 (2) 5 (3) 4 (4) 6
complex [Co(en)2 Cl2] is :-
54. [Co(en)3] 3+ ion is expected to show :-
(1) Two optically active isomers (1) 2 (2) 3 (3) 4 (4) 5
2+
(2) Two optically inactive isomers 62. The complex [Pt(NH3)4] has structure :-
(3) four optically active isomers; cis, d & from (1) Square planer
and trans d & form
(2) Tetrahedral
(4) None
55. The number of geometrical isomers for (3) Pyramidal
octahedral [Co(NH 3 ) 2 Cl 4 ] – , square planar (4) Pentagonal
[AuCl2Br2 ]– respectviely are :-
63. Which of the following is not correctly matched ?
(1) 4, 2 (2) 2, 2
(1) [MnCl 4]–2 tetrahedral, zero CFSE
(3) 3, 2 (4) 2, 3
56. How many isomers are possible for the complex (2) [Pt(NH3)(Br),(Cl)(Py)] tetrahedral, EAN = 36
ion [Cr(NH3 )3 Cl3 ? (3) [Fe(CO)2 (NO)2]tetrahedral, EAN = 36
(1) 3 (2) 2 (3) 4 (4) 5 (4) [Co(CO)4]– tetrahedral, C–O B.L. larger than CO
64. In complexes more stability is shown by:-
CoCl3.6NH3
(1) [Fe(H2O)6]3+ a se
Inc
r eas
cre e
(3) De
3–
(2) [Fe(CN)6] CoCl3.4NH3 Increase CoCl3.5NH3
3–
(3) [Fe(C2O4)3]
CoCl3.6NH3
(4) [FeCl6]3– Inc
se r eas
rea e
65. When MnO2 is fused with KOH, a coloured (4) Inc

compound is the product and the colour is :- CoCl3.4NH3 Decrease CoCl3.5NH3

(1) Mn2O4, black 69. The complex [Fe(H 2 O) 5NO] 2+ is formed in

(2) KMnO4, purple Brown ring test for nitrates select correct
(3) Mn2O3, brown statement for the complex ?
(4) K2 MnO4, green (1) Hybridisation of iron is sp3d2
66. Which of the following is not correctly mathced ? (2) Iron and nitrosyl has +1 oxidation state

(1) [Fe (CN)6]3–– d2sp3 and paramagnetic (3) It has magnetic moment of 3.87 B.M.

(2) Fe(CO)5 – dsp3 and diamagnetic (4) All are correct

70. Which are the correct statements
(3) [Fe(en)3]3+ – sp3d2 and paramagnetic
(1) [Ag(NH3)2]+ is linear with sp hybridised
(4) [ZnCl 2(PPH3)2]–sp3 and paramagnetic
Ag+ion
67. Which of the following is incorrectly matched (2) NiCl42– , VO34 and MnO 4 have tetrahedral
complex ?
geometry
(3) [Cu(NH3)4]2+ , [Pt(NH3)4]2+ and [Ni(CN)4]2–
Complex Oxidation Electronic
number configuration have dsp2 hybridisation of the metal ion
(4) All the correct
1 K3[Co(C2O4)3] +3 t62g ego
71. Which of the following is/are inner orbital
2 (NH4)2[CoF4] +2 t52g eg2 complex as well as paramagnetic with
3 Cis[Cr(en)2Cl2]Cl +3 t 3
eg o magnetic moment equal to 3.78 (approx) ?
2g
(1) [Co(OX)3]3– (2) [Cr(NH3)6]3+
4 [Mn(H2O)6]SO4 +2 t32g eg2
(3) [Fe(H2O)5NO]2+ (4) [Zn (NH3)6]2+
68. Which of the following diagrams is correctly 72. In nitroprusside ion, the iron and NO exist as
related to the conductivity of complex having FeII and NO+ rather than FeIII and NO. These
same condition in water ? forms can be differentated by :-
(1) Estimating the concentration of iron
CoCl3.6NH3
a se
De
cre
(2) Measuring the concentration of CN
cre ase
(1) De (3) Measuring the solid state magnetic moment
CoCl3.4NH3 Decrease CoCl3.5NH3
(4) Thermally decomposing the compound
73. Na2S + Na2[Fe(CN)5NO] Na4[Fe(CN)5NOS].
CoCl3.6NH3
De Oxidation number of Fe in reactant (complex)
se cre
rea ase
(2) Inc and product (complex) are :-
CoCl3.4NH3 Decrease CoCl3.5NH3
(1) 2, 1 (2) 2, 2 (3) 2, 3 (4) 3, 3
74. Which of the following are square planar 80. Which of the following is/are correct about
complexes ? [Cu(NH3)4]SO4 :
(i) [AuCl4]– (1) It is a Tetrahedral complex
(ii) [PtCl4]2– (2) It is paramagentic with one unpaired
(iii) [Mn(Br)4]2– electron in the d-subshell
(3) It gives white precipitate with BaCl2
(iv) [Cu(NH3)4]2+
(4) Its aqueous solution does not conduct
Select the correct answer using the codes given
electricity.
below :-
81. The hybridisation of [CoF 6]3–& [Co(C 2O4)3]3–
(1) i and ii only
are:-
(2) ii and iii only
(1) Both sp3d2
(3) ii and iv only (2) Both d2sp3
(4) i, ii, and iv only (3) sp3d 2 and d2sp 3
75. The crystal field-splitting for Cr 3+ ion in (4) d2sp 3 and sp3d 2
octahedral field changes for I , H2O, NH3, CN 82. A complex of certain metal has the magnetic
and the increasing order is :- moment of 4.91 BM. whereas another complex
(1) I < H2O < NH3 < CN of the same metal with same oxidation state has
zero magnetic moment. The metal Ion could be:-
(2) CN < I– < H2O < NH3
(1) Co2+ (2) Mn2+
(3) CN < NH3 < H2O < I
(3) Fe2+ (4) Fe3+
(4) NH3 < H2O < I < CN
83. [Sc(H2O)6]3+ ion is :-
76. Which of the following is a high spin complex?
(1) Coloured and paramagnetic
(1) [Co(NH3)6]3+ (2) [Fe(CN)6]4– (2) Colourless and paramagnetic
(3) [Ni(CN)4]2– (4) [FeF 6]3– (3) Colourless and diamagnetic
77. Which has maximum paramagnetic nature ? (4) Coloured & octahedral
2+ 2+
(1) [Cu(H2O)4] (2) [Cu(NH3)4]
84. Which of the following complex compounds
2+
(3) [Mn(H2O)6] (4) [Fe(CN)6]4– does not exhibits cis-trans isomerism ?
78. Which of the following order of CFSE is
(1) [PtCl2(NH3)2 ]
incorrect?
(2) [PdCl2BrI]
(1) [Cr(NO2)6]3– > [Cr(NH3)6]3+ > [Cr(H2O)6]3+
(2) [PtF4]2– > [PdF4]2– > [NiF4]2– (3) [Pt(NH3 )2 (Cl)(Br)]

(3) [Ni(DMG)2] < [Ni(en)2]2+ (4) [Pt(NH3)3(Cl)]+

(4) [Co(EDTA)]– > [Co(en)3]3+ 85. Which of the following correct?
79. Which of the following is/are inner orbital (1) Ti(NO3)4 is coloured
complex as well as dimagnetic in nature :
(2) [Cr(NH3)6]Cl3 is colourless
(1) [Zn(NH3)6]2+ (2) [Ni(NH 3)6]2+
(3) K3[VF6] is colourless
(3) [Cr(NH 3)6]3+ (4) [Co(NH3)6]3+
[Atomic no. Cr=24, Mn=25, Fe=26, Co=27] (4) [Cu(NCCH3)4] [BF4] is colourless
86. Of the following complex ions. The one that 93. Co-ordination isomerism is possible in :
probably has the largest overall formation (1) [Ag(NH3)2][Ag(CN)2]
constant Kf is :- (2) [Pt(en)2][PtCl4]
3+ 3+
(1) [Co(NH3)6] (2) [Co(H2O)6] (3) [Pt(NH3)4][Pt(C2O4)2]
(3) [Co(NH3)2 (H2O)4]3+ (4) [Co(en)3]3+ (4) [Pt(NH3)4][PtCl6]

87. Which is not a -bonded complex ? 94. Which amongst the following metal carbonyls
are inner orbital complex with diamagnetic
(1) Zeise's salt
property
(2) ferrocene
(i) Ni(CO)4
(3) bis(benzene) chromium
(ii) Fe(CO)5
(4) Tetraethyl lead
(iii) V(CO)6
88. What is wrong about the compound (iv) Cr(CO)6
K[Pt( 2–C2H4)Cl3] Select the correct code :-
(1) It is called zeise's salt (1) I & II
(2) II, III & IV
(2) It is bonded complex
(3) II & IV
(3) Oxidation number of Pt is + 4
(3) I, II, & IV
(4) Four ligands surrounds the platinum atom
95. To an acidified dichromate solution, a pinch of
89. Which of the following order is not correct ? Na2O2 is added and shaken. What is observed:
(1) [Cr(NH3)6]+3 > [Mn(CN)6]–3 > [V(CO)6] spin m.m. (1) blue colour
(2) Orange colour changing to green
(2) [Co(CN)6]–3 > [Co(NH3)6]+3 > [Co(H2O)6]+3 value
(3) No evolution of oxygen
(3) [Ni(CO)4] > [Co(CO)4]– > [Fe(CO)4]–2 (4) Bluish - green precipitate
(M–C bond strength) 96. Pick out the incorrect statement:
(4) [Ni(NH3)4] < [Ni(en)(NH3)2] < [Ni(en)2]+2
+2 +2

(Thermodynamic stability) (1) MnO 24 is quite strongly oxidizing and

90. Which of the following is correct for zeise's salt ? stable only in very strong alkalies. In dilute
(1) The complex ion is square planar alkali, neutral solutions, it
(2) The CMI, Pt is in + 2 oxidation state disproportionates.
(3) H2C=CH2 Molecule is perpendicular to the
(2) In acidic solutions, MnO 4 is reduced to
PtCl3 plane
(4) All of these Mn2+ and thus, KMnO4 is widely used as
91. Which amongst the following are oxidising agent
organometalic componds :- (3) KMnO4 does not acts as oxidising agent in
(i) Al2(CH3)6 (ii) K[PtCl3(C2H2)] (iii) N(CH3)3 alkaline medium
(1) i only (2) iii only
(4) KMnO4 is manufactured by the fusion of
(3) i, ii, and iii (4) i and ii only pyrolusite ore with KOH in presence of air
92. The number of bonds in cation of shwetzer or KNO 3 , followed by electrolytic
salt is :-
oxidation in acidic medium
(1) 8 (2) 12 (3) 14 (4) 16
97. When a small amount of KMnO4 is added to 104. Which of the following is an oxidising agent?
concentrated H2SO4, a green oily compound is (1) [Mn2(CO)10] (2) [Fe(CO)5]
obtained which is highly explosive in nature.
(3) [Mn(CO)5] (4) [Fe2(CO)9]
Compound may be :
(1)Mn2 O 3 (2) MnSO4 105. Species which represent maximum crystal field
(3) Mn2O 7 (4) MnO2 stablisation energy :-
98. The incorrect statement(s) about Cr2+ and Mn3+ (1) [Co(CN)6]–3 (2) [Co(C2O4)3]–3
is (are)
(3) [Ni(H 2O)6]+2 (4) Both (1) and (2)
[Atomic numbers of Cr = 24 and Mn = 25]
106. What is the crystal field stabalisation energy
(1) Cr2+ is a reducing agent
value of d 5 configuration for tetrahedral
(2) Mn3+ is an oxidizing agent
complex ?
(3) Both Cr2+ and Mn3+ exhibit d4 electronic
configuration (1) 0.4 (2) 0.0 (3) –2 (4) +2
2+
(4) When Cr is used as a reducing agent, the 107. Which of the following complex show
5
chromium ion attains d electronic maximum numbers of stereo isomers is :-
configuration
(1) PtCl3 (C 2 H 4 )
99. Chromyl chloride test is given by -
(1) CH 3Cl (2) AgCl –2
(2) CuBr2Cl 2
(3) Hg2Cl2 (4) NH4Cl
+3
100. Crystal field stablisation energy for high spin (3) Cr(NH 3 )2 (en) 2
d4 octahedral complex is :-
–3
(1) –1.8 (2) –0.6 (4) Co(C 2 O 4 )3
0 0
(3) –1.2 0
(4) –1.6 + P
108. A Pt complex of NH3 and chlorine produces
101. Select the incorrect statement on basis of
four ions per molecule in the solution is :-
following conversion :-
(1) [Pt(NH3)4Cl2]Cl 2 (2) [Pt(NH3)6]Cl 4
KOH H
X air
Y Z + X (3) [Pt(NH3)2]Cl 4 (4) [Pt(NH3)5Cl]Cl 3
Black Dark an oxidising
coloured green agent 109. The most stable complex ion is :-
ore
(1) [Fe(C 2O4)3]3– (2) [Fe(H2O)6]+3
(1) X may be MnO2 (3) [Fe(CN)6]4– (4) [Fe(CN)6]3–
(2) Y can be K2MnO4 110. Which of the following complex is example of
(3) Z can be KMnO4 strongest reducing agent ?
(4) None of these
(1) [Co(CN)6]–3 (2) [Co(CN)6]–4
102. When KMnO 4 reacts with KBr in acidic
(3) [Ag(CN)2]–1 (4) [Cu(CN)4]–3
medium then oxidation state of Mn changes
from +7 to :- 111. Pair of compound which is planar :-
(1) +2 (2) +4 (3) +3 (4) +6 (1) [Ni(CN)4]–4, [PtCl4]–2
103. Crystal field stabalisation energy for complex (2) [NiCl4]–4, [Ni(CN)4]–2
[Co(CN)6]–3 will be :- (3) [PtCl4]–2, [Ni(CO)4]
(1) +2.4 0
+ 3P (2) –2.4 0
+ 2P (4) [Ni(CN)4]–2, [Rh(CO)2(PPh3)2]+
(3) –3.6 0
+ 3P (4) –1.8 0
+ 3P
112. Which of following is diamagnetic ? 116. Match the column
(1) [RhCl(CO)(PPh3)(NH3)] Column-I Column-II
(2) [RhF 6]–3 (A) [Co(NH3 )4 (H2 O)2 ]Cl2 (p) Geometrical
(3) [Ir(H2O)6]F 2 isomers
(B) [Pt(NH3)2 Cl2 ] (q) Paramagnetic
(4) [MoCl6]–3
(C) [Co(H2O)5Cl] Cl (r) Diamagnetic
113. The relationship between
(D) [Ni(H2 O)6 ]Cl2 (s) Metal ion
[Co(NH 2–CH 2–CH–CH2–NH2)2Cl2]+ and with + 2
CH3 oxidation state
117. Match the column
[Co(NH2–CH2–CH2–CH2–NH2]2Cl2]+ is
Column-I Column-II
(1) Linkage isomer
(A) [Ni(CO)4] (p) Tetrahedral
(2) Ligand isomers
(B) [Fe (NO)2(CO)2] (q) -back bonding
(3) Coordination isomer (C) [Ni (PF3)4] (r) diamagnetic
(4) Solvate isomers (D) [NiBr2(PPh3)2] (s) One of the ligand
is three e– donor
MATCH THE COLUMN
114. Match the pair of complexes given in Column-I 118. Column-I Column-II
the characteristic (s) given in Column-II
(A) [Cu(NH3)4]2+ (p) Outer orbital complex
Column-I Column-II
(B) [CuCl4]2– (q) Inner orbital complex
(1) (NH4 )2[NiCl4 ] and (P) Both show
(NH4) 2[Ni(CN)4 ] same electrical (C) K2[Cr(CN)4 (r) Magnetic moment
conductance. (NH3)(NO)] = 1.73 B.M.
(2) CoCl3.6NH3 and (Q) Both show (D) K4[Co(NO2)6] (s) Metal O.S. +2
PtCl4.5NH3 same EAN.
(t) During hybridisation
(3) [Pt(NH3)2 Cl2 ] and (R) Both show
d-orbital e– jumps
(NH4)2[PtCl4 ] same primary
valancies to higher energy
(4) K2[Fe(H2O) 6] and (S) Both gives orbital
K4 [FeCl6 ] white precipitate
119. match the complexes listed in column-I with
with AgNO3
characteristic (s) /type of hybridisation listed in
Solution
column-II :
115. Match the column Column-I Column-II
Column-I Column-II (A) [Co(en)3] 3+ (p) Sp3 d2 hybridisation
(A) [Pd(NH3 )2Cl2 ] (p) Geometrical
(B) [Co(ox) 3]3– (q) Diamagnetic
isomerism
(B) [Co(OX)3 ] 3–
(q) Diamagnetic (C) [Co(H2O)6]2+ (r) d2 sp3 hybridisation
(C) [Fe(H2 O)4 Cl2 ] (r) Inner orbital (D) [Co (NO2)6]4– (s) Paramagnetic
complex
–
(t) Chelating reagent
(D) [Co(NH3)2 (NO2) 4] (s) Paramagnetic