2

NCERT LINE BY LINE QUESTIONS

(1.) How many moles of ethane are required to produce 22gCO 2 after combustion)
(a.) 15 g (b.) 30 g
(c.) 7.5 g (d.) 21 g

(2.) The number of moles of oxygen present in 1 L of air under standard condition is (air contains
21%oxygen) [Page: 23]
(a.) 9.3 L (b.) 0.0093 L
(c.) 0.021 L (d.) 2.21 L

(3.) A bivalent metal has an atomic mass of 28. The molecular mass of its chloride is
(a.) 127 (b.) 63.5
(c.) 99 (d.) 91.5

(4.) Higher the number of moles, higher will be number of molecules as 1 mole contains 6.023 ×1023
number of molecules. What is the number of moles of carbon atoms in 2.2 g of CO 2 .
(a.) 0.6 (b.) 0.2
(c.) 0.05 (d.) 0.02

(5.) If the density of a solution is 1.27g / mL , the mass of 2.5mL solution in significant figures is
(a.) 3.175g (b.) 3175 × 10−3 g
(c.) 3.2g (d.) 31.75g

(6.) Which of the following is a mixture).

(a.) Gasoline (b.) Distilled water
(c.) Bronze (d.) Both (a) a (c)

(7.) Consider the following statements:

(I) Mass of 0.25 moles of H 2SO 4 is 24.5 g.(II) The order of number of molecules in 100mL each is
H 2 < NH 3 < CO 2 .
(III) The volume occupied by 1 mole atom of a diatomic gas at STP is 11.2 mL.
Correct statements are
(a.) Only I (b.) Only I a II
(c.) Only I & III (d.) All of these

(8.) Two students performed the same experiment separately and each one of them recorded two readings of
mass which are given below. Correct reading of mass is 3.0 g. On the basis of given data, mark the
correct option out of the following statements.
Student Readings
A 3.01 2.99
B 3.05 2.95
(a.) Results of both the students are neither (b.) Result of student A is both precise and

12
 accurate nor precise. accurate.
(c.) Result of student B is precise but not accurate. (d.) Result of student B is both precise and
accurate.

(9.) Two elements P and Q combine to form a compound X. Atomic mass of P is 14 and Q is 1. Percentage
of P in the compound is 82.35%. What will be the empirical formula of the compound X?
(a.) PQ (b.) P2Q
(c.) PQ 2 (d.) PQ3

(10.) Which of the following reactions is not correct according to the law of conservation of mass.
1
(a.) H 2 ( g ) + O 2 ( g ) → H 2 O (1) (b.) C3 H8 ( g ) + O 2 ( g ) → CO 2 ( g ) + H 2 O ( g )
2
1
(c.) SO 2 ( g ) + O 2 ( g ) → SO3 ( g ) (d.) CH 4 ( g ) + 2O 2 ( g ) → CO 2 ( g ) + 2H 2 O ( g )
2

(11.) Specific heat of metal is 0.30 and its chloride contains 83% of chlorine. What is exact atomic weight of
the metal)
(a.) 21.8l (b.) 23.4l
(c.) 22.08 (d.) 21.08

(12.) Match the following

(Column‐I) (Column‐II)
P. One g‐atom of nitrogen (i) 23 / N A g
Q. One mole of water (ii) 98 / N A g
R. One atom of sodium (iii) 18 g
S. One molecule of H 2SO 4 (iv) 14 g

(a.) P‐ iii, Q‐i, R‐ii, S‐ iv (b.) P‐ iv, Q‐iii, R‐ i, S - ii

(c.) P‐ iv, Q‐ iii, S‐ ii, R‐i (d.) P‐ i, Q‐ii, R‐ iv, S‐ iii

(13.) The density of a given object is 8.96g / cm3 . The volume of this object weighing 179.2 g in L is
(a.) 20 L (b.) 10 L
(c.) 0.02 L (d.) 0.01 L

(14.) Number of grams of oxygen in 16.l g of Na 2SO 4 ⋅10H 2O is

(a.) 20.8 g (b.) 22.4 g
(c.) 11.2 g (d.) 12 g

(15.) An alkaloid contains 17.28% nitrogen and its molecular mass is 162. The nitrogen atoms present in one
molecule of alkaloid is
(a.) 5 (b.) 4
(c.) 3 (d.) 2

(16.) The number of atoms present in one mole of an element is equal to Avogadro number. Which of the
following element contains the greatest number of atoms
(a.) 4 g C (b.) 46 g Na

13
(c.) 0.40 g Ca (d.) 12 g He

(17.) The relative abundance of various isotopes of silicon

= =
is as Si 28 92.23%,Si 29
4.67 and Si30 = 3.10%
The average atomic mass of silicon is
(a.) 29.l (b.) 28. 1
(c.) 28.5 (d.) 31.2

(18.) When 2.112g of KClO3 was heated, 1.212 g of KC1 and 0.9gO 2 were produced. The results illustrate:
(a.) The law of multiple proportion (b.) The law of definite proportion
(c.) The law of conservation of mass (d.) All of these

(19.) Which of the following is not a chemical property

(a.) Acidity (b.) Flammability
(c.) Basic nature (d.) Boiling point

(20.) Which statements are correct for Dalton’s atomic Theory?

(I) Matter consists of indivisible atoms.
(II) Compounds are formed when atoms of different elements combine in different ratio.
(III) Chemical reactions involve reorganisation of atoms.
(a.) I only (b.) I & II only
(c.) I a III only (d.) All of these

(21.) The number of atoms in 27 mg of water in terms of Avogadro number ( N A ) is

(a.) 4.5N A (b.) 4.5 × 10−3 N A
(c.) 1.5 × 10−3 N A (d.) 1.5N A

(22.) An organic compound has molecular weight 194. If this compound contains 36.08o%0 N , then number
of nitrogen molecules in this compound is
(a.) 4 (b.) 5
(c.) 6 (d.) 3

(23.) Two elements A and B have atomic weights 12 and 16. They form four compounds W, X, Y and Z in
which A is present in same amount while element B is present in the ratio 1:2:3:4. If compound W has
24 paris by weight of A and 32 parts of B, then compound X has 24 parts by weight of A and
(a.) 64 parts of B (b.) 32 parts of B
(c.) 14 parts of B (d.) 56 parts of B

(24.) Match the following:

(i ) 88g CO2 (a ) 0.25 mol

( ii ) 6.022 × 1023 molecules of H 2O (b) 2 mol
( iii ) 5.6 L of at STP (c) 1 mol
( iv ) 96 g O2 (d) 3 mol

(a.) i‐A, ii‐D, iii‐C, iv‐B (b.) i‐B, ii‐C, iii‐A, iv‐D
(c.) i‐ A, ii‐C, iii‐D, iv‐B (d.) i‐B, ii‐D, iii‐A, iv‐C

14
(25.) The crystalline salt Na 2SO 4 ⋅ xH 2O on heating loses 55.9% of its weight. The formula of the salt
is[Page: 2O]
(a.) Na 2SO 4 ⋅ 7H 2O (b.) Na 2SO 4 ⋅ 5H 2O
(c.) Na 2SO 4 ⋅10H 2O (d.) Na 2SO 4 ⋅ H 2O

(26.) The density of a gas x is four times that of gas y. The ratio of these molecular masses ( M x : M y ) will
be
(a.) 4: 1 (b.) 1:4
(c.) 2: 1 (d.) 1:2

(27.) What is the molarity of H 2SO 4 solution that has density 1.84g / mL and 89% by weight?
(a.) 17.14 M (b.) 16.7 M
(c.) 18.4 M (d.) 8.9 M

(28.) 1cc.N 2O at NTP contains.

1.32 1.8
(a.) ×1023 electrons (b.) ×1022 atoms
224 224
6.02 (d.) All of these
(c.) ×1023 molecules
22400

(29.) 1 volume of hydrogen always combines with 1 volume of chloride to form 2 volumes of HC1. This
statement illustrates
(a.) Law of Definite Proportion (b.) Law of Conservation of Mass
(c.) Gay‐Lussac’s Law (d.) None of these

(30.) Four students weigh a sample of 2 g twice, which of the following is most accurate? The observations
are given in the table.
Student Measurement
A 1.95 1.95
B 1.98 2.00
C 2.01 1.99
D 2.05 2.04
(a.) A (b.) B
(c.) C (d.) D

(31.) The percentage of mass of Al in KAl ( SO 4 )2 ⋅12H 2O is

(a.) 4.74% (b.) 12.59%
(c.) 5.69% (d.) 11.21%

(32.) Consider the following statements:

(I) Atoms of H, O, N and C have identical properties but different mass.
(II) Matter is divisible into atoms which are further indivisible.
(III) Dalton’s atomic theory supports law of conservation of mass.
Which are correct according to Dalton’s atomic theory?

15
(a.) (i) & (ii) (b.) (ii) & (iii)
(c.) (i), (ii) & (iii) (d.) None of these

(33.) Match Column I with Column II.

Column I Column II
A Heterogeneous Mixture ( i ) Camphor
B Homogenous Mixture ( ii ) Mercury
C Element ( iii ) Rain
D Compound ( iv ) Soil
(a.) A‐(iii), B‐(ii), C‐(i), D‐(iv) (b.) A‐(iv), B‐(iii), C‐(ii), D‐(i)
(c.) A‐(i), B‐(iv)2 C‐(ii), D‐(iii) (d.) A‐ (ii), B‐(i), C‐ (iii), D‐ (iv)

(34.) Which of the following has maximum number of molecules?

(a.) 10gH 2 (b.) 22gCO 2
(c.) 5gH 2O (d.) 18gC6 H12O6

(35.) A compound contains 4.07% hydrogen, 24.27% C and 71.65% C1 . Its molar mass is 98.96 g. The
molecular formula is
(a.) CH 2Cl (b.) C2 H 4Cl2
(c.) C2 H 2Cl2 (d.) CH 3C1
(36.) A solution is prepared by adding 2.5 g of a substance in 47.5 g of water. The mass percent ofsolute is
(a.) 2.5% (b.) 2.15%
(c.) 5% (d.) 7.25%

(37.) The density (in g/mL) of a 3.60 M sulphuric acid solution that is 29oo %H 2SO 4 by mass will be
(a.) 1.45 (b.) 1.64
(c.) 1.88 (d.) 1.22

(38.) How many grams of a dibasic acid with molecular weight 200 should be present in 200 mL of solution
with 0.2 N)
(a.) 1 g (b.) 2 g
(c.) 3 g (d.) 4 g

(39.) Consider the following statements: (I) Molarity is defined in mol/L.(II) Molarity is the number of
moles of solute present in 1 kg of solution.(III) For making 0.2 M solution we require 0.2moles of
NaOH dissolved in 1 L solution. Which of these are incorrect)
(a.) I & III only (b.) II only
(c.) I & II only (d.) All of these

(40.) A chemist wants to prepare 500 mL of 1 mole solution of H 2SO 4 . Density of H 2SO 4 is 1.075g / cm3 .
The quantity of H 2SO 4 needed to prepare is
(a.) 47.97 (b.) 52.67
(c.) 58.9 (d.) 62. 1

16
(41.) If 500 mL of 95 M solution is diluted to 2,500 mL, what will be the molarity of the solution obtained)
(a.) 1.5 M (b.) 1.66 M
(c.) 1M (d.) 1.59 M

(42.) If the concentration of glucose ( C6 H12O6 ) in blood is 0.6g / L , what will be the molarity of glucose in
blood ?
(a.) 3.3 M (b.) 0.0033 M
(c.) 0.005 M (d.) 0.5 M

(43.) Match the following:

( i ) 58.5 g NaCl in 1 L solution (a ) 1% w / w
( ii ) 58.5 g NaCl in 1 kg water (b) 1m
( iii ) 1g NaCl in 99 g water (c) 1M
( iv ) 1g NaCl in 100 mL solution (d) 1% w / v

(44.) Which of the following is dependent on temperature ?

(a.) Molality (b.) Molarity
(c.) Mole fraction (d.) Weight percentage

(45.) What is the mass percentage of C in carbon monoxide ?

(a.) 0.044% (b.) 27.27%
(c.) 3.4% (d.) 42.85%

(46.) The density of 3 molar solution of NaOH is 1.1109 / mL . The molarity of the solution is
(a.) 3.21 M (b.) 2.97 M
(c.) 2M (d.) 1.l M

(47.) A H 2SO 4 solution has a molarity of 11.24 and molality of 94. Calculate the density of solution
(a.) 1.22 (b.) 1.124
(c.) 0.94 (d.) 1.115

(48.) What will be the molality of the solution containing 9.125 g of HCl in 500 g of water)
(a.) 0.l m (b.) 1m
(c.) 0.5 m (d.) 1m

(49.) The density of 2 M aqueous solution of NaOH is 1.28g / cm3 . The molality of solution is (Given that
molecular mass of NaOH = 40gmo1−1 )
(a.) 1.32 m (b.) 1.20 m
(c.) 1.56 m (d.) 1.67 m

(50.) Answer the following with correct significant figure.

10.10 + 11.231 + 8.01 + 2.3
(a.) 31.64l (b.) 31.6

17
 (c.) 31.5 (d.) 31.64

Topic wise Practice Questions

TOPIC 1: Measurement, Significant Figures and Laws of Chemical Combination

1. Which has highest weight?
1) 1 m3 of water 2) A normal adult man3) 10 litre of Hg 4) All have same weight
2. Arrange the numbers in increasing no. of significant figures. 0.002600, 2.6000, 2.6, 0.260
1) 2.6 < 0.260 < 0.002600 < 2.6000 2) 2.6000 < 2.6 < 0.002600 < 0.260
3) 0.260 < 2.6 < 0.002600 < 2.6000 4) 0.002600 < 0.260 < 2.6 < 2.6000
3. In which of the following number all zeros are significant?
1) 0.0005 2) 0.0500 3) 50.000 4) 0.0050
4. Which of the following is the best example of law of conservation of mass?
1) 12 g of carbon combines with 32 g of oxygen to form 44 g of CO 2 .
2) When 12 g of carbon is heated in a vacuum there is no change in mass.
3) A sample of air increases in volume when heated at constant pressure but its mass remains unaltered.
4) The weight of a piece of platinum is the same before and after heating in air.
5. The percentage of copper and oxygen in samples of CuO obtained by different methods were found to
be the same. This illustrates the law of
1) constant proportions 2) conservation of mass 3) multiple proportions 4) reciprocal proportions
6. One of the following combination which illustrates the law of reciprocal proportions?
1) N 2 O 3 , N 2 O 4 , N 2 O 5 2) NaCl, NaBr, NaI 3) CS 2 , CO 2 , SO 2 4) PH 3 , P 2 O 3 , P 2 O 5
7. The molecular weight of O 2 and SO 2 are 32 and 64 respectively. At 15°C and 150 mm Hg pressure, one
litre of O 2 contains ‘N’ molecules. The number of molecules in two litres of SO 2 under the same
conditions of temperature and pressure will be :
1) N/2 2) 1 N 3) 2 N 4) 4 N
8. 10 dm3 of N 2 gas and 10 dm3 of gas X at the same temperature contain the same number of molecules,
the gas X is
1) CO 2 2) CO 3) H 2 4) NO

TOPIC 2: Mole Concept

9. What is the mass of 1 molecule of CO?
1) 2.325 × 10-23 2) 4.65 × 10-23 3) 3.732 × 10-23 4) 2.895 × 10-23
10. How many atoms are contained in one mole of sucrose (C 12 H 22 O 11 )?
1) 20 × 6.02 × 1023 atoms/mol 2) 45 × 6.02 × 1023 atoms/mol
23
3) 5 × 6.02 × 10 atoms/mol 4) None of these
11. Molecular mass is defined as the
1) mass of one atom compared with the mass of one molecule
2) mass of one atom compared with the mass of one atom of hydrogen
3) mass of one molecule of any substance compared with the mass of one atom of C-12
4) None of the above
12. Two containers P and Q of equal volume (1 litre each) contain 6 g of O 2 and SO 2 respectively at 300 K
and 1 atmosphere, then
1) number of molecules in P is less than that in Q.
2) number of molecules in P and Q is same.
3) number of molecules in Q is less than that in P.
4) either 1) or 2).

18
13. A sample of AlF 3 contains 3.0 × 1024 F- ions. The number of formula unit of this sample are
1) 9 × 1024 2) 3 × 1024 3) 0.75 × 1024 4) 1.0 × 1024
14. Which one of the following is the lightest?
1) 0.2 mole of hydrogen gas
2) 6.023 × 1022 molecules of nitrogen
3) 0.1 g of silver
4) 0.1 mole of oxygen gas
15. The average atomic mass of neon based on following data is:
Isotope Relative abundance
20
Ne 0.9051
21
Ne 0.0027
22
Ne 0.0922
1) 0.33 u 2) 20.187 u 3) 6.729 u 4) 18.058 u
16. The ratio of number of oxygen atoms (O) in 16.0 g ozone (O 3 ), 28.0 g carbon monoxide (CO) and 16.0
oxygen (O 2 ) is (Atomic mass : C = 12, O = 16 and Avogadro’s constant NA = 6.023 × 1023 mol-1)
1) 3 : 1 : 2 2) 1 : 1 : 2 3) 3 : 1 : 1 4) 1 : 1 : 1
17. A mixture of CH 4 , N 2 and O 2 is enclosed in a container of 1 litre capacity at 0°C. Total pressure of
gaseous mixture is 2660 mm Hg. If the ratio of partial pressures of the gases is 1 : 4 : 2 respectively, the
number of moles of oxygen present in the vessel is:
1)1/ 22.4 2) 1.0 3) 0.1 4) none of these
18. The number of gram molecules of oxygen in 6.02 ×10 CO molecules is
24

1) 10 g molecules 2) 5 g molecules 3) 1 g molecules 4) 0.5 g molelcules

19. The number of molecules in 16 g of methane is
16 16
1) 3.0 ×1023 2) × 1023 3) 6.023 ×1023 4) ×1023
6.02 3.0
20. 25.4 g of I 2 and 14.2 g of Cl 2 are made to react completely to yield a mixture of ICl and ICl 3 . Calculate
moles of ICl and ICl 3 formed
1) 0.1, 0.1 2) 0.2, 0.2 3) 0.1, 0.2 4) 0.2, 0.1
21. If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass
unit, the mass of one mole of a substance will
1) decrease twice 2) increase two fold
3) remain unchanged 4) be a function of the molecular mass of the substance
22. Number of moles of MnO4- required to oxidize one mole of ferrous oxalate completely in acidic
medium will be
1) 0.6 moles 2) 0.4 moles 3) 7.5 moles 4) 0.2 moles
23. The number of moles of oxygen in one litre of air containing 21% oxygen by volume, under standard
conditions are
1) 0.0093 mole 2) 0.21 mole 3) 2.10 mole 4) 0.186 mole
24. Haemoglobin contains 0.334% of iron by weight. The molecular weight of haemoglobin is
approximately 67200. The number of iron atoms (at. wt. of Fe is 56) present in one molecule of
haemoglobin are
1) 1 2) 6 3) 4 4) 2
25. How many moles of P 4 O 6 and P 4 O 10 will be produced by the combustion of 12.4 g of phosphorous
(atomic mass 31) in 12.8 g of oxygen, leaving no P 4 or O 2 ?
1) 0.1 and 0.3 mol 2) 0.15 mol and 0.25 mol 3) 0.05 mol each 4) 0.1 mol each

TOPIC 3: Atomic, Molecular Masses, Equivalent Masses and Expression of

Concentration
26. Number of atoms in 558.5g Fe (at. wt. of Fe = 55.85 g mol-1) is
1) twice that in 60 g carbon 2) 6.023 × 1022
3) half that in 8 g He 4) 558.5 × 6.023 × 1023
27. The percentage weight of Zn in white vitriol [ZnSO 4 .7H 2 O] is approximately equal to (Zn = 65, S = 32,
O = 16and H = 1)

19
 1) 33.65 % 2) 32.56 % 3) 23.65 % 4) 22.65 %
28. The vapour density of a mixture containing NO 2 and N 2 O 4 is 27.6 . Mole fraction of NO 2 in the
mixture is
1) 0.2 2) 0.4 3) 0.6 4) 0.8
29. The number of molecules in 8.96 litre of a gas at 0º C and 1 atm. pressure is approximately
1) 6.023 × 1023 2) 12.04 × 1023 3) 18.06 × 1023 4) 24.08 × 1022
30. Suppose two elements X and Y combine to form two compounds XY 2 and X 3 Y 2 when 0.1 mole of
former weighs 10 g while 0.05 mol of the latter weights 9 g. The atomic masses of X and Y are
respectively
1) 60 & 40 2) 30 & 40 3) 40 & 30 4) 40 & 60
31. 4 g of a hydrated crystal of formula A.xH 2 O has 0.8 g of water. If the molar mass of the anhydrous
crystal 1) is 144 g mol-1, The value of x is
1) 4 2) 1 3) 2 4) 3
32. 6.02 ×10 molecules of urea are present in 100 mL of its solution. The concentration of solution is
20

1) 0.01 M 2) 0.001 M 3) 0.1 M 4) 0.02 M

33. A metallic chloride contain 47.22% metal. Calculate the equivalent weight of metal.
1) 39.68 2) 31.76 3) 36.35 4) 33.46
34. Sulphur forms the chlorides S 2 Cl 2 and SCl 2 . The equivalent mass of sulphur in SCl 2 is
1) 8 g/mol 2) 16 g/mol 3) 64.8 g/mol 4) 32 g/mol
35. If 0.20 g chloride of a certain metal, when dissolved in water and treated with excess of AgNO 3 , yields
0.50 g of AgCl, the equivalent mass of the metal is (Ag = 108, Cl = 35.5)
1) 21.90 2) 20.04 3) 40.08 4) 43.80
36. Equivalent mass of a metal M is 2.5 times that of oxygen. The minimum molecular mass of its oxide is
1) 28 2) 42 3) 56 4) 112
37. The same amount of a metal combines with 0.100 g of oxygen and with 1.000 g of a halogen. Hence,
the equivalent mass of halogen is
1) 9 2) 35.5 3) 80 4) 127
38. In the reaction NaOH + Al ( OH )3 → NaAlO 2 + H 2 O The equivalent mass of Al(OH) 3 is
1) 78 2) 26 3) 52 4) unpredictable
39. On reduction 1.644 g of hot iron oxide give 1.15 g of iron. Evaluate the equivalent weight of iron.
1) 18.62 2) 19.13 3) 18.95 4) 12.95
40. If a pure compound is composed of X 2 Y 3 molecules and consists of 60% of X by weight, the atomic
weight of Y is
1) 2.25 times atomic weight of X 2) 44% of atomic weight of X
3) 4.0 times the atomic weight of X 4) 25% of the atomic weight of X
41. Oxalic acid H 2 C 2 O 4 reacts with permanganate ion according to the balanced equation below. How
many mL of 0.0154 KMnO 4 solution are required to react with 25.0 mL of 0.0208 M H 2 C 2 O 4
solution? 5H 2 C2 O 4 ( aq ) + 2MnO 4− ( aq ) + 6H + ( aq ) → 2Mn 2+ ( aq ) + 10CO 2 ( g ) + 8H 2 O (1)
1) 13.5 mL (2) 18.5 mL (3) 33.8 mL (4) 84.4 mL
42. Percentage of Se in peroxidase anhydrase enzyme is 0.5% by weight (at. wt. of Se = 78.4) then
minimum molecular weight of peroxidase anhydrase enzyme is
1) 1.568 ×103 2) 15.68 3) 2.136 ×104 4) 1.568 ×104
43. Liquid benzene ( C6 H 6 ) burns in oxygen according to the equation
2C6 H 6 (1) + 15O 2 ( g ) → 12CO 2 ( g ) + 6H 2 O ( g )
How many litres of O 2 at STP are needed to complete the combustion of 39 g of liquid benzene?(Mol.
wt. of O 2 = 32, C 6 H 6 = 78)
1) 74 L 2) 11.2 L 3) 22.4 L 4) 84 L
44. The mass of BaCO 3 produced when excess CO2 is bubbled through a solution of 0.205 mol Ba(OH) 2 is
1) 81 g 2) 40.5 g 3) 20.25 g 4) 162 g
45. 12 L of H 2 and 11.2 L of Cl 2 are mixed and exploded. Find the composition by volume of mixture.
1) 11.2, 11.2, 22.4 2) 0.8, 0, 22.4 3) 0.8, 0.8, 22.4 4) 0.8, 11.2, 22.4

20
46. 10 moles SO 2 and 15 moles O 2 were allowed to react over a suitable catalyst. 8 moles of SO 3 were
formed. The remaining moles of SO 2 and O 2 respectively are -
1) 2 moles, 11 moles 2) 2 moles, 8 moles 3) 4 moles, 5 moles 4) 8 moles, 2 moles

47. How many moles of KI are required to produce 0.4 moles of K 2 HgI 4 ?
1) 0.4 2) 0.8 3) 3.2 4) 1.6
48. Under similar conditions of pressure and temperature, 40 mL of slightly moist hydrogen chloride gas is
mixed with 20mL of ammonia gas, the final volume of gas at the same temperature and pressure will be
1) 100 mL 2) 20 mL 3) 40 mL 4) 60 mL
49. What is the volume of CO 2 liberated (in litres) at 1 atmosphere and 0°C when 10 g of 100% pure
calcium carbonate is treated with excess dilute sulphuric acid?
(Atomic mass Ca : 40, C : 12, O : 16)
1) 0.224 2) 2.24 3) 22.4 4) 224
50. The volume of 0.1 N dibasic acid sufficient to neutralize 1 g of a base that furnishes 0.04 mole of OH–
in aqueous solution is :
1) 400 mL 2) 600 mL 3) 200 mL 4) 800 mL

51. The density of 3M solution of sodium chloride is 1.252 g mL-1. The molality of the solution will be :
(molar mass, NaCl = 58.5 g mol-1)
1) 260 m 2) 2.18 m 3) 2.79 m 4) 3.00 m
52. The amount of BaSO 4 formed upon mixing 100 mL of 20.8% BaCl 2 solution with 50 mL of 9.8%
H 2 SO 4 solution with 50 mL of 9.8% H 2 SO 4 solution will be:
(Ba = 137, Cl = 35.5, S = 32, H = 1 and O = 16)
1) 23.3 g 2) 11.65 g 3) 30.6 g 4) 33.2 g
53. The formula of an acid is HXO 2 . The mass of 0.0242 moles of the acid is 1.657 g. What is the atomic
mass of X?
1) 35.5 2) 28.1 3) 128 4) 19.0
54. A portable hydrogen generator utilizes the reaction between calcium hydride and water to produce
hydrogen. What mass of hydrogen can be produced by 70 g cartridge of calcium hydride ?
1) 6.7 g 2) 3.5 g 3) 4.5 g 4) 5.5 g
1
55. If 1 moles of oxygen combine with Al to form Al 2 O 3 the weight of Al used in the reaction is (Al = 27)
2
1) 27 g 2) 54 g 3) 49.5 g 4) 31 g
56. O 2 , N 2 are present in the ratio of 1 : 4 by weight. The ratio of number of molecules is :
1) 7 : 32 2) 1 : 4 3) 2 : 1 4) 4 : 1
57. 6.8 g H 2 O 2 present in 100 mL of its solution. What is the molarity of solution?
1) 1 M 2) 2 M 3) 3 M 4) 0.5 M
58. How many moles of magnesium phosphate, Mg 3 (PO 4 ) 2 will contain 0.25 mole of oxygen atoms?
1) 1.25 × 10-2 2) 2.5 × 10-2 3) 0.02 4) 3.125 × 10-2
59. How many moles of Al 2 (SO 4 ) 3 would be in 50 g of the substance ?
1) 0.083 mole 2) 0.952 mole 3) 0.481 mole 4) 0.140 mole
60. 25mL of a solution of barium hydroxide on titration with a 0.1 molar solution of hydrochloric acid gave
a litre value of 35mL. The molarity of barium hydroxide solution was
1) 0.14 2) 0.28 3) 0.35 4) 0.07
TOPIC 4: Empirical Formula, Molecular Formula and Chemical Stoichiometry
61. The empirical formula of a compound is CH 2 . One mole of this compound has a mass of 42 grams. Its
molecular formula is :
1) C 3 H 6 2) C 3 H 8 3) CH 2 4) C 2 H 2
62. An organic compound contains carbon, hydrogen and oxygen. Its elemental analysis gave C, 38.71%
and H, 9.67%. The empirical formula of the compound would be :
1) CH 3 O 2) CH 2 O 3) CHO 4) CH 4 O
63. In a compound C, H and N atoms are present in 9 : 1 : 3.5 by weight. Molecular weight of compound is
108. Molecular formula of compound is

21
 1) C 2 H 6 N 2 2) C 3 H 4 N 3) C 6 H 8 N 2 4) C 9 H 12 N 3
64. A chloride of a metal (M) contains 65.5% of chlorine. 100 mL of vapour of the chloride of metal at STP
weighs 0.72 g. The molecular formula of the metal chloride is :
1) MCl 2) MCl 2 3) MCl 3 4) MCl 4

65. In the reaction 4NH 3 (g) + 5 O 2 (g) → 4 NO(g) + 6H 2 O(l) When 1 mole of ammonia and 1 mole of O2
are made to react to completion,
1) 1.0 mole of H 2 O is produced 2) 1.0 mole of NO will be produced
3) all the oxygen will be consumed 4) all the ammonia will be consumed
66. If potassium chlorate is 80% pure, then 48 g of oxygen would be produced from (atomic mass of K =39)
1) 153.12 g of KClO 3 2) 122.5 g of KClO 3
3) 245 g of KClO 3 4) 98 g of KClO 3
67. The empirical formula of an acid is CH 2 O 2 , the probable molecular formula of acid may be :
1) C3H 6 O 4 2) CH 2 O 3) CH 2 O 2 4) C 2 H 4 O 2
68. Which of the following is the correct empirical and molecular formulae of a compound, if the molecular
mass of a compound is 80 and compound contains 60% of C, 5% of H and 35% of N ?
1) C2H 2 N ; C 4 H 4 N 2 2) C 3 H 4 N 2 ; C 6 H 8 N 4
3) C 2 H 4 N 2 ; C 4 H 8 N 4 4) C 2 H 2 N ; C 2 H 2 N
69. 12 gm of Mg (atomic mass 24) will react completely with hydrochloric acid to give
1) One mol of H 2 2) 1/2 mol of H 2 3) 2/3 mol of O 2 4) both 1/2 mol of H 2 and 1/2 mol of O 2
70. Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using
diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is
1) 3 2) 4 3) 5 4) 6

NCERT LINE BY LINE QUESTIONS – ANSWERS

(1.) c (2.) b (3.) c (4.) c (5.) a
(6.) d (7.) c (8.) b (9.) d (10.) b
(11.) a (12.) b (13.) c (14.) c (15.) d
(16.) d (17.) b (18.) c (19.) d (20.) c
(21.) b (22.) b (23.) a (24.) b (25.) c
(26.) a (27.) b (28.) d (29.) c (30.) c
(31.) c (32.) b (33.) b (34.) a (35.) b
(36.) c (37.) d (38.) d (39.) b (40.) a
(41.) c (42.) b (43.) b (44.) b (45.) d
(46.) b (47.) a (48.) c (49.) d (50.) b
TOPIC WISE PRACTICE QUESTIONS-ANSWERS
1) 1 2) 1 3) 3 4) 1 5) 1 6) 3 7) 3 8) 2 9) 2 10) 2
11) 3 12) 3 13) 4 14) 3 15) 2 16) 2 17) 1 18) 2 19) 3 20) 1
21) 1 22) 2 23) 1 24) 3 25) 3 26) 1 27) 4 28) 4 29) 4 30) 3
31) 3 32) 1 33) 2 34) 2 35) 1 36) 3 37) 3 38) 2 39) 1 40) 2
41) 1 42) 4 43) 4 44) 2 45) 2 46) 1 47) 2 48) 2 49) 2 50) 1
51) 3 52) 1 53) 1 54) 1 55) 2 56) 1 57) 2 58) 4 59) 4 60) 4
61) 1 62) 1 63) 3 64) 3 65) 3 66) 1 67) 3 68) 1 69) 2 70) 4

22
 NCERT LINE BY LINE QUESTIONS-EXPLANATIONS
7
C2 H 6 + O 2 → 2CO 2 + 3H 2O
(1.) (c) 2
1 mole (i.e. 30 g) C2 H 6 gives 2 moles (i.e. 88 g) CO 2
30
So 22 g will be produced by = × 22 = 7.5g
88
21
(2.) (b) Volume of oxygen i n1Lair = L
100
21 1
Number of moles = × =0.0093
100 22.4

(3.) (c)
formula: MCl2
= Mass Atomic mass of M + 2 × Atomic mass of Cl
= 28 + 2 × 35.5 = 28 + 71 = 99
(4.) (c) Mass of
CO 2 = 12 + 16 × 2 = 44
Mass of C in 44gCO 2 = 12 g
12
Mass of C in 2.2gCO 2 = × 2.2 = 0.6 g
44
0.6
Moles of carbon= = 0.05
12
(5.)
Mass
(a) Density =
Volume
Mass = Density × Volume = 1.27 × 2.5 = 3.175
In multiplication and divisions, the result must be reported with no more signification figures as in the
measurement with the few significant figures. Thus, the answer is (a).
(6.) (d) Gasoline is a mixture of small hydrocarbons and bronze is a mixture of copper and tin. Distilled
water is a pure substance.
(7.) (c) Equal volume of all gases at STP contain equal number of molecules, hence II is incorrect.
(8.) (b) Because readings of student A are close to the actual reading(accuracy) and both measurements are
close to each other also (precise).
(9.) (d)
Element Percentage Moles Mole ratio Simplest Ratio
P 82.35 82.35 / 14 = 5.88 5.88 1
=1
5.88
Q 17.65 17.65 / 1 = 17.65 17.65 3
=3
5.88
Thus, the empirical formula = PQ3
(10.) (b) As in C3 H8 ( g ) + O 2 ( g ) → CO 2 ( g ) + H 2 O ( g ) reaction number of elements are not same, so mass
of reactants is not equal to mass of products. Hence, it does not follow law of conservation of mass.
(11.) (a) Percentage of chlorine = 83%
Percentage of metal = 100 − 83 = 17%

23
 17 × 35.5
Exact=
weight = 7.27
83
Specific heat of metal = 0.30
6.4
Approximate atomic weight = = 21.33
0.30
21.33
=
Valency = 2= .93 3
7.27
Atomic weight of metal = 3 × 7.27 =21.81
(12.) P. One g ‐atom of nitrogen means 14 g of nitrogen, i.e., .P → ( iv )
Q. One mole of water ( H 2O ) = 2 ×1 + 16 = 18 g
Q → ( iii )
R. One mole of sodium, i.e. 23 g = N A atoms thus mass of 1 atom of sodium = 23 / N A g
R → (i)
S. One mole of H 2 SO 4 = 2 ×1 + 32 + 16 × 4 = 98g = N A molecules
Thus, mass of 1 molecule = 98 / N A
S → (ii)
(13.)
Mass
(c) Density =
Volume
Mass
Volume =
Density
179.2g
Volume = 3
= 20cm3 = 0 ⋅ 02I ∼
8.96g / cm
(14.) (c) The molecular mass of Na2 SO4 ⋅10 H 2O is = 322g
In 322 g , mass of oxygen is = 16 × ( 4 + 10 ) = 224g
224
In 16.1g , mass of oxygen will be ×16=.1 224 × 0.05 = 11.2 g
322
17.28 ×162
(15.) (d) Weight oof N in= alkaloid = 27.9
100
27.9
Number of N atoms= = 2
14
Assertion-Reason Type Questions
4
(16.) (d) Number of mole in = C = 0.33
12
46
Number of mole in Na = = 2
23
0.40
Number of mole in= Ca = 0.01
40
12
Number of mole in He = = 3
4
Higher the number of moles, higher will be number of molecules (atoms).
(17.) (b) Average Atomic Mass
At.Mass1 × Abundance1 + At.Mass 2 × Abundance 2 + At.Mass3 + Abundance3
=
Abundance1 + Abundance 2 + Abundance3
28 × 92.23 + 29 × 4.67 + 30 × 3.10
=
92.23 + 4.67 + 3.10

24
 2582.44 + 135.43 + 93 2810.87
= = = 28.1
100 100
(18.)
3
(c) As KClO3 ∆ → KCl + O 2
2
Mass of reactant = Mass of products
=
2.112 g (1.212 + 0.9 ) g
Thus, it illustrates the law of conservation of mass.
(19.) (d) Boiling point is a physical property as it does not require any chemical change.
(20.) (c) Compounds are formed when atoms of different elements combine in same ratio.
27 ×10−3
= = 1.5 ×10−3
(21.) (b) Moles 18
Number of molecules= 1.5 ×10−3 N A
Number of atoms = 1.5 ×10−3 N A ×=3 4.5 ×10−3 N A
36.08
(22.) =
(b) Mass o N in the compound ×194 = 70 amu = 5 N atoms
100
(23.) (a)
In W  A : B 1:1
In X A : B 1: 2
In Y A : B 1: 3
In Z A : B 1: 4
In compound W 24g of A combines with 32 g of B. Then in X24g of A will combine with 64 g of
B.
(24.) (i) → (B)
88
88g CO= 2 = 2mol
44
(ii) → (C)
6.022 ×103 molecules of any compound = 1 mol
(iii) → (A)
5.6 1
5.6L of 02= = = 0.25 mol
22.4 4
(iv) → (D)
96
96gO= 2 = 3 mol
32
∆
(25.) (c)
Na 2SO 4 ⋅ xH 2O  → Na 2SO 4 + xH 2O
Suppose the weight of the compound is (a)
55.9
a− ×a = 142
100
100a − 55.9a = 14200
44.1a = 14200
14200
=a = 322
44.1
142 + 18 x = 322 ⇒18 x = 180 , x = 10
M d
(26.) (a) x = x
My dy
M x 4d y
d x = 4d y ⇒ = =4 :1
My dy

25
(27.) (b) Mass of solute = 89 g
Mass of solution = 100 g
Volume of solution
Mass 1.00
= = = 54.34mL
Density 184
89 1000
=
Molarity × = 16.7M
98 54.34
(28.) (d) As 22.4 L at STP contain 1 mole, or 6.023 ×1023 molecules
6.023 ×1023
Thus, 1 cc i.e. 1 mL contain = molecules
22400
1 molecule of N 2O contains 3 atoms, thus
3 × 6.023 ×1023
Number of atoms in 1cc =
22400
1.8 ×1022
i.e. atoms Electrons in 1 molecule of N 2O = 7 + 7 + 8 = 22
224
Thus, electrons in 1 cc of N 2O
22 × 6.023 ×1023 1.32 ×1023
= =
22400 224
(29.) (c) According to Gay‐Lussac’s law gases combined or produced in a chemical reaction. They do so in a
simple ratio by volume.
(30.) (c) C is most accurate because his values are closer to the actual value.
(31.) (c) Molar mass of KAl ( SO 4 )2 ⋅12H 2O =
39 + 27 + 32 × 2 + 16 × 8 + 12 ×18 = 474g / mol
27
Percentage by mass of Al = ×100 = 5.69%
474
(32.) (b) Atoms of H, O, N and C have different properties and different masses.
(33.) (b)
10
H= = 5
(34.)
2
(a) Moles of 2
22
Moles of CO= 2 = 0.5
44
5
Moles of H 2O= = 0.278
18
18
Moles of C6 H12= O6 = 0.1
180
Higher the number of moles, higher will be the number of molecules.
(35.) (b)
Element % Composition Number of moles Simplest molar ratio Simplest whole number
C 24.27 24.27 / 12 = 2.02 2.02 1
=1
2.02
H 4.07 4.07 / 1 = 4.07 4.07 2
=2
2.02
Cl 71.65 71.65 / 35.5 = 2.02 2..02 1
=1
202
Thus, empirical formula = CH 2 Cl
Empirical formula mass = 12 + 2 + 35.5 = 49.5

26
 Molar mass of compound = 98.96
Molar mass 98.96
=n = = 2
Empiricalformula mass 49.5
formula (=
Thus, Molecular = CH 2Cl )2 C2 H 4Cl2
Mass of solute
= Mass percent ×100
(36.) (c) Mass of sotution
2.5 2.5
= ×100 = ×100 = 5%
47.5 + 2.5 50
(37.) (d) 3.60 M means 3.6 moles present in 1000 mL.
Mass of 3.6 moles of H 2SO=4 3.6 × 98g = 352.8g
Given that 29 g of H 2SO 4 is present in 100 g of solution.
100
352.8 g of H 2SO 4 present in × 352.89 = 1216g of solution
29
Mass 1216
=
Density = = 1.216g / mL
Volume 1000
200
(38.) (d) Equivalent weight = = 100
2
If x g acid is required
x 1000
0=.2 ×
100 200
100 × 200 × 0.2
= ⇒x = 4g
1000
(39.) (b) Molarity is the number of moles of solute present in l litre of solution.
Mass / Molarmass
= Molaliry ×1000
Mass of solvent ( g )
(40.) (a)
Mass / 98
1 ×1000
Volume × Density
Suppose the mass of solute is x.
x
1 ×1000
98 × ( 500 ×1.075 − x )
1000 x
1=
52 ,675 − 98 x
52675 = 1098x
52675
=x = 47.97g
1098
(41.) (c) M1V1 = M 2 V2
500×5 = M 2 × 2500
500×5
M2 = = 1M
2500
(42.) (b) 1 Litre of blood contains 0.6 g of glucose
= 0=
Moles of glucose .6 / 180 0.0033mol
0.0033
= = 0.0033mol / L
Thus, molarity
1
(43.) (ii) → (b)
1 mole present in lkg water = l
Molar solution (1 m)

27
 (iii) → (a)
1 g solute dissolved in 99 g water Mass of solute = 1 g
Mass of solution =+ 1 99 = 100 g
Mass of solute 1
= % of solute ×100 = ×100 = 1%
Mass of solution 100
(iv) → (d)
Mass of solute = 1
Mass of solution = 100 mL
1
w / v% = ×100 = 1%
100
(44.) (b) Molarity depends on temperature as it contains volume which is temperature dependent.
(45.) (d) 12gC is present in CO 2 (12 + 16 = 28 )
amount of C 12
0%0 = ×100 = ×100
amount of CO 28
= 42.85%
(46.) (b) 3 molar solution means 3 moles of NaOH in 1 kg solvent.
3 moles of NaOH =3 × 40 =120g
Mass of solution = 1000 + 120 = 1120 g
3
=
Molarity ×=1000 2.97M
1120 / 1.110
gram moles of H 2SO 4
=
(47.) (a) Molarity volume of solution
moles of H 2SO 4
11.24 =
1
Moles of H 2SO 4 = 11.24 moles
Amount of H 2SO= 4 11.24 × 98 = 1.10l kg
moles of H 2SO 4
Molality =
kg of solvent
11.24
= = 0.1195kg
Amount of solvent
94
= 1.101 + 0.1195 = 1.2205kg
Amount of solution
1.2205
= = 1.22
Density of solution
1
9.125
(48.) (c) Moles of = HCl = 0.25 mole
36.5
Moles of solute
= Molality ×1000
Mass of solvent
0.25
= ×1000 = 0.5m
500
1 d MB
= −
(49.) (d) m M 1000
1.28 40
= − = 0.64 − 0.04 = 0.60
2 1000
1 10
m = = = 1.67m
0.6 6
Assertion‐Reason Type questions
(50.) (b) 10. + 11. 231 + 8.01 + 2.3 = 31.641

28
 As the result cannot have more digits to the right of the decimal point than either of the original
numbers.
Thus, the answer should be reported as 31.6.

TOPIC WISE PRACTICE QUESTIONS - SOLUTIONS

1. 1) 1m of water = 106 cm3of water
3

106 cm3 ×1g cm3 ( density of H 2 O ) =

∴ Mass of 106 cm3 water = 1g cm3 ) =
106
= 6
10 g =3
kg 10 = 3
kg 1000kg
10
b) Weight of normal adult man = 65 kg
∴ weightof1m3 of water is highest.
c) Density of Hg = 13.6g cm-3
Volume of Hg = 10 L = 10 ×1000 = 104 cm3
∴ Weight of Hg = 13.6 ×104 = 136000g = 136kg
2. 1) 2.6 has two significant figures.
0.260 has three significant figures.
0.002600 has four significant figures.
2.6000 has five significant figures.
3. 3) If zero is used to locate the decimal point it is considered as a significant figure. In 50.000 all zero are
significant.
4. 1)
5. 1) According to law of constant proportions a pure chemical compound always contains same elements
combined together in the same definite proportion of weight.
6. 3) In law of reciprocal proportions, the two elements combining with the third element, must combine
with each other in the same ratio or multiple of that ratio S and O when combine with C is 2 : 1. Ratio of
S and O is SO 2 is 1 : 1
7. (3) According to Avogadro's law "equal volumes of all gases contain equal number of molecules under
similar conditions of temperature and pressure". Thus if 1 L of one gas contains N molecules, 2 L of any
other gas under the same conditions of temperature and pressure will contain 2N molecules.
8. (2) The number of molecules of N 2 and X are same. Hence they must have the same molecular weights.
∴ X is CO.
9. (2) Gram molecular weight of CO = 12 + 16 = 28 g
28
6.023 × 1023 molecules of CO weight 28 g 1 molecule of CO weighs = = 4.65 ×10−23 g
6.02 ×10 23

10. 2) Total atoms in 1 molecule of C12 H 22 O11 = 12 + 22 + 11 = 45

∴ total atoms in 1 mole of C12 H 22 O11 =45 × 6.02 ×10 atoms/mol
23

11. 3)
6 6
12. 3) 6g of O 2 contains × N A molecules whereas 6g of SO 2 contains × N A molecules.
32 64
13. 4) In, AlF 3 the number of F is 3 for one AlF 3 molecule
3F− = 1 formula unit of AlF3
3.0 ×1024 F− ≡ 1×1024 AlF3 units= 1.0 ×1024
14. 3) a) Weight of H2 = mole × molecular wt. = 0.2 × 2 = 0.4 g
b) 6.023 ×1023 = 1mole
22
Thus 6.023x10 =0.1 mole
weight of N 2 = 0.1x28=2.8g
c) Weight of silver = 0.1 g
d) Weight of oxygen = 32 × 0.1 = 3.2 g
15. 2) Average atomic mass of neon = 20 × 0.9051 + 21× 0.0027 + 22 × 0.0922 = 20.187u
16. 2)

29
 2
17. 1) Partial pressure of O 2 =× 2660 = 760mm Hg
7
At STP one mol of a gas occupies a volume of 22.4 L.
Hence, number of moles of O 2 in 1L = 1/22.4
18. 2) 6.02 × 1023 molecules of CO =1mole of CO
6.02 × 1024 CO molecules = 10 moles CO
= 10 g atoms of O = 5 g molecules of O2
19. (3) 16 g CH 4 is 1 mol. Hence number of molecules = Avogadro number = 6.023 × 1023
25.4
20. 1) Initial mole of=I 2 = 0.1mole
257
14.2
Initial mole of =
Cl2 = 0.2mole
71
I 2 + 2Cl2 → ICI + ICI3
Initially 0 0
After reaction 0.1 0.1
21. 1) Relative atomic mass
Mass of one atom of the element Mass of one atom of the element
= or ×12
1/12 part of the mass of one atom of Carbon − 12
th
mass of one atom of the C − 12
Now if we use 1/6 in place of 1/12 the formula becomes
Relative atomic mass = Mass of one atom of element /Mass of one atom of carbon ×6
∴ Relative atomic mass decrease twice
22. 2)

1) 21% of 1 litre is ⇒ 0.21 litre.

23.
22.4 litres = 1 mole at STP
0.21
∴ 0.21 litre = = 0.0093mol
22.4
24. 3) Mass of iron in 100 g haemoglobin = 0.334 g.
842
∴ In 67200g haemoglobin, mass of iron = = 1.4 ×10−21 g
6.023 ×1023
∴ The number of Fe atoms in one molecule of haemoglobin
672 × 0.334
= = 4
56
12.4
25. 3) Moles of= P4 = 0.1
4 × 31
12.8
Moles of = O 2 = 0.4
32
Let x moles of P 4 form P 4 O 6
Then, moles of O 2 required= x × 3 + ( 0.1 − x ) × 5 =0.4
(given) ⇒ x =
0.05

30
 558.5
26. 1) Fe (number of moles) == 10moles = 10N A atoms
55.85
No. of moles in 60 g of C = 60/12 = 5 moles = 5N A atoms
27. 4) Molecular weight of ZnSO 4 , 7H 2 O = 65 + 32 + ( 4 ×16 ) + 7 ( 2 ×1 + 16 )= 287
65
∴ percentage mass of zinc (Zn) = ×100 = 22.65%
287
28. 4) ( V.D )mix = X NO2 × ( V.D ) NO + X N2O4 × ( V.D ) N O
2 2 4

27.6 = x × 23 + (1 − x ) × 46 ( x = mole fraction of NO 2 ) ⇒ x = 0.8

29. 4) At S.T.P. 22.4 litre of gas contains 6.023 ×1023 molecules
6.023 ×1023 × 8.96
∴ molecules in 8.96 litre of gas = = 24.08 ×1022
22.4
wt 10
30. 3) Molecular weight of XY = 2 = = 100
moles 0.1
9
Molecular weight of X= 3 Y2 = 180
0.05
Let a and b be the atomic masses of X and Y respectively.
Then a + 2b = 100
3a + 2b = 180
∴ a = 40 and b = 30
31. 3) Q Given weight of hydrated crystal = 4 g
Weight of water = 0.8
∴ Weight of anhydrous salt = 4 – 0.8 = 3.2
Q 3.2 g anhydrous salt = 0.8 g of water
0.8
∴ 144 g anhydrous salt = = ×144 = 36 g of water
3.2
36
∴= x = 2
18
6.02 ×1020 ×1000 6.02 ×1021
32.=1) M = = 0.01M
100 × 6.023 ×1023 6.02 ×1023
33. 2)Suppose weight of metallic chloride = 100 g
Then weight of metal = 47.22 g
Weight of chlorine = 100 – 47.22 = 52.78 g
 Mass of Metal  47.22
∴ Equivalent weight of metal=   × 35.5 = × 35.5 = 31.76
 Mass of chloride  52.78
34. 2) The atomic weight of sulphur = 32
In SCl 2 valency of sulphur = 2
32
So equivalent mass of sulphur = = 16g / mol
2
E + Eq.mass of Cl− E + 35.5 0.2
35. 1) −1
= = ⇒ E = 21.90
Eq.mass of Ag + Eq.mass of Cl 108 + 35.5 0.5
36. 3) Equivalent mass of oxygen = 8;
Equivalent mass of metal = 2.5 × 8 = 20
For mininum molecular mass, the oxide must contain
one mol atom of oxygen i.e., 16 g or two equivalents.
Mass of two equivalents of metal = 2 × 20 = 40 g.
Hence, molar mass of the metal oxide = 40 + 16 = 56 g
37. 3) 0.1 g of oxygen ≡ 1 g of halogen.

31
 1
Hence equivalent mass of halogen = = × 8= 80
0.1
(Equivalent mass of O = 8)
38. 2) 1equivalent of NaOH ≡ 1 equivalent of Al ( OH )3
78
∴ 40g of NaOH ≡ g of Al ( OH )3
3
39. Weight of iron oxide = 1.644 g
Weight of iron after reduction = 1.15 g
weight of displaced oxygen = 1.644 – 1.15 = 0.494 g
1.15
∴ Equivalent weight of iron = ×8 =18.62
0.494
Thus equivalent weight of metal is = 18.62.
60 40
40. 2) Mol of X in 60 g = and mol of Y in 40g =
Mx MY
n 2 60 M y 4
Also, x = = ⇒ Mg = M x = 44% of atomic weight of x
n y 3 M x 40 9
2
41. 1) mmol of H 2 C2 O 4 = 25 × 0.0208 = 0.52 ⇒ mmol of KMnO 4 required =× 0.52 =
0.208
5
0.208
⇒ volume of KMnO 4 required = =13.5mL
0.0154
42. 4) 0.5 g of Se = 100 g enzyme
100
78.4 g of Se = × 78.4 = 1.568 ×104 g enzyme
0.5
43. 4)
44. 2)

45. 2)

46. 1)

32
47. 2) 2KI + HgI 2 → K 2 HgI 4
Moles of KI required to produce 0.4 moles of K 2 HgI 4 =×
2 0.4 =0.8
48. 2)

49. 2)
50. 1) Applying law of equivalence
Equivalence of acid = Equivalence of base
0.1× v= 0.04 ×1
v =0.4L =0.4 ×1000 =400mL
51. 3) The relation between molarity (M) and molality (m) is
1 M 
d= M  + 2  , M2 = Mol. mass of solute On putting value
 m 1000 
 1 58.5 
= 3 +
1.252 
 m 1000 
on solving m = 2.79
52. 1)

Mass
53. 1) n =
Molar mass
1.657
0.0242= ⇒M= 68.47
M
1 + X + 32 = 68.47
X = 35.5
54. 1) CaH 2 + 2H 2 O → Ca ( OH )2 + 2H 2
2 × 2 × 70
=
Mass of H 2 = 6.67g
42
(Molar mass of CaH 2 = 42g )
3
55. 2) 2Al + O 2 → Al2 O3
2
According to equation 3/2mole of O 2 combines with 2 moleAl.
2 mole AI = 54g
56. 1) Let mass of O 2 = 1g
∴ Mass of N 2 = 4g
1
No. of molecules of O 2 =
32
4
No. of molecules of N 2 =
28
1 4 1 1
Ratio of no. of molecules = : : : = 7 : 32
32 28 32 7
57. 2) Weight of H 2 O 2 in 100mL of H 2 O 2 solution = 6.8g

33
 ∴ Weight of H 2 O 2 in 1000mL of its solution = 6.8 × 10 =68g
Molecular weight of H 2 O 2 = 34
68
Then, Molarity = = 2M
34
58. 4) 1 Mole of Mg 3 ( PO 4 )2 contains 8 mole of oxygen atoms
∴ 8 mole of oxygen atoms ≡ 1 mole of Mg 3 ( PO 4 )2
1
0.25 mole of oxygen atom ≡ × 0.25mole of Mg 3 ( PO 4 )2 =
3.125 ×10−2 mole of Mg 3 ( PO 4 )2
8
weight 50
59. 4)Number of moles = = = 0.14mole
mol.wt 342
60. 4) 25 × N = 0.1× 35; N = 0.14
Ba ( OH )2 is diacid base
N
Hence N = M × 2 or M =
2
M = 0.07M
61. 1) Empirical formula of compound = CH 2
Molecular mass of the compound = 42
∴
= = 3
n 42 /14
∴ Hence molecular formula = C3 H 6
62. 1)

Thus empirical formula is CH 3O

63. 3)

34
 0.72 × 22400
64. =
3) Molecular mass of metal = 161.28
chloride
100
Mass of chlorine in molar mass of chloride
65.5 ×161.28
= = 105.64g
100
Mole atoms of chlorine in one mole of chloride
105.64
= = 3
35.5
65. 3) According to stoichiometry they should react as follow
4NH 3 + 5O 2 → 4NO + 6H 2 O
4 mole of NH 3 requires 5 mole of O 2
5
1 mole of NH 3 requires = = 1.25 mole of O 2
4
Hence O 2 is consumed completely
66. 1)

67. 3) The acid with empirical formula CH 2 O 2 is formic acid, HCOOH.

68. 1) Let 100 g of compound be there
35
Number of moles of Nitrogen = = 2.5
14
5
Number of moles of Hydrogen= = 4.9
1.008
Since 2.5 is the smallest value division by it give ratio
N:H:C
1 : 1.96 : 1.96
=1:2:2
Empirical formula = C2 H 2 N
Empirical formula weight = 2 ×12 + 2 + 14 = 40
Molecular mass = 80
 80 
Molecular formulae = n ( C2 H 2 N ) = 2 ( C2 H 2 N )=
n =  C4 H 4 N 2
 40 
69. 2)

70. 4) The following reaction occurs:

6Fe 2+ + Cr2 O72− + 14H + → 6Fe3+ + 2Cr 3+ + 7H 2 O
From the above equation, we find that Mohr's salt
( FeSO4 . ( NH 2 )2 SO4 .6H 2O ) and dichromate reacts in 6 : 1 molar ratio.

35
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