AIITS 2325 HCT V JEEA Paper 2 OFFLINE

FIITJEE
ALL INDIA INTEGRATED TEST SERIES

JEE (Advanced)-2025
HALF COURSE TEST – V
PAPER –2
TEST DATE: 10-08-2024
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 51 questions.
 Each subject (PCM) has 17 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-B & Section-C.
Section – A (01 – 04, 18 – 21, 35 – 38): This section contains TWELVE (12) questions. Each question has
FOUR options. ONLY ONE of these four options is the correct answer.
Section – A (05 –07, 22 – 24, 39 – 41): This section contains NINE (09) questions. Each question has FOUR
options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – B (08 – 13, 25 – 30, 42 – 47): This section contains EIGHTEEN (18) numerical based questions.
The answer to each question is a NON-NEGATIVE INTEGER VALUE.
Section – C (14 –17, 31 – 34, 48 – 51): This section contains SIX (06) paragraphs. Based on each
paragraph, there are TWO (02) questions of numerical answer type. The answer to each question is a
NUMERICAL VALUE (XXXXX.XX). If the numerical value has more than two decimal places,
truncate/round-off the value to TWO decimal places.
MARKING SCHEME
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 If three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 Question is unanswered;
Negative Marks : 0 In all other cases.
Section – C: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 Question is unanswered;
Negative Marks : 0 In all other cases.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AIITS-HCT-V (Paper-2)-PCM-JEE(Advanced)/2025 2
Physics PART – I
SECTION – A
(One Options Correct Type)
This section contains FOUR (04) questions. Each question has FOUR options (A), (B), (C) and (D).
ONLY ONE of these four options is the correct answer.
1. For the situation shown in the figure, water flows on Free Surface
the surface of a fixed plate. The velocity of water as a
function of distance 'y' is given as:
2
y y 
U =    2    . Determine the magnitude of the
 h  h  
shear stress that the water applies at the base of the
plate. Coefficient of viscosity is .
 2
(A) (B)
h h
4 
(C) (D)
h h
2. From a uniform semicircular thin disc of radius R, a semicircular

portion of radius Rl2 is removed and placed in a new position as
shown in figure. Taking 0 as origin and x and y axis as shown in
figure, centre of mass of new setup is at
R 4R R 2R
(A) , (B) ,
4 3 4 3
R R R R
(C) , (D) ,
4  4 3
3. A bulb hangs from a bracket whose three arms each have one
end fixed in the wall, the other ends meeting at a point. The two
upper arms form an isosceles triangle with an angle of 60°
between the arms. The plane of this triangle is at right angles to
the third arm, which makes an angle of 30° with the wall. The bulb
and shade weight 1 N. The force in the arm AC is
1
(A) 3 2 N (B) N
2 3
1
(C) N (D) 2 3 N
3 2
4. A uniform square plate is placed on a horizontal floor. When it is

given an angular velocity  about a vertical axis through one of
its corners as shown in figure-I, it takes time t1 to come to a
complete stop. Now the same square plate is given the same
angular velocity to rotate about another vertical axis through its
centre as shown in figure-II. How long will it take to come to a
complete stop now?
(A) t1/2 (B) 2t1/3
(C) 3t1/2 (D) 2t1
3 AIITS-HCT-V (Paper-2)-PCM-JEE(Advanced)/2025
SECTION – A
(One or More than one correct type)
This section contains THREE (03) questions. Each question has FOUR options (A), (B), (C) and (D). ONE
OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
5. Two identical solid cones float in water as shown in figure.

Cone A has height h1 immersed in water while Cone B
has height h2 lying outside the water. Relative density of
both cone is 1/3.
(A) Value of h1/h2 will be (2)1/3
(B) Value of h1/h2 will be 1
(C) If cone A is further suppressed by small distance x and released, it will execute SHM. The
2 
 2R 
time period of oscillation would be  3  3 2  .
 g 
(D) If cone A is further suppressed by small distance x and released, it will execute SHM. The
4 
 R
time period of oscillation would be  3  3 2   .
 g
6. Water jet is projected at an angle to the horizontal. At the point of

projection, the area of the jet is S1 and at the highest point, the
area of the jet is S2. The initial velocity of projection is u.
(A) The angle of projection is cos1(S1/S2)
2u2 S1 S2
(B) The range on the level ground is 1  12
g S2 S2
2u2  S12 
(C) The maximum height reached from the ground is  1  
g  S22 
(D) The rate of volume flow is S2u
7. The ends of a long bar are maintained at different temperatures and
there is no loss of heat from the sides of the bar due to conduction
or radiation. The graph of temperature against distance of the bar
when it has attained steady state is shown here. The graph shows.
(A) the temperature gradient is not uniform.

(B) the bar has uniform cross-sectional area
(C) the cross-sectional area of the bar increases as the distance from the hot end increases.
(D) the cross-sectional area of the bar decreases as the distance from the hot end increases.
SECTION – B
(Numerical Answer Type)
This section contains SIX (06) Numerical based questions. The answer to each question is a NON-
NEGATIVE INTEGER VALUE.
8. A steel wire of length 1m, mass 0.1 kg and uniform cross-section 1 mm2 is fixed rigidly at both
ends that there is no tension in the wire initially. The temperature of the wire is lowered by 20°C
and vibrations are set up in the wire such that three antinodes are formed between the ends. An
observer moving at 70 m/s towards the wire observes the frequency of emitted sound to be 40
Hz. If Young's modulus of steel is n × 1011 N/m2, then nearest integer of n will be ____. Given that
the coefficient of linear expansion of steel = 1.21 x 105 K1 and the velocity of and velocity of
sound in air is 330 m/s.
1
9. Given graph is vs velocity graph. If the time interval
acceleration
during which velocity changes from 2m/s to 4m/s is given by t
seconds. Then find the value of 2t.
10. In a soap film experiment an originally semicircle shaped thread

of radius 10 cm can be deformed to two semicircles with a force
of 0.01 N exerted at the middle of the thread. Calculate the
surface tension (in 10-2 N/m).
11. Two blocks of masses m1 = 1 kg and m2 = 2 kg are

connected by a spring of constant k = 100 N/m and
placed over a plank as shown. The coefficient of friction
between m2 and plank is 0.5 and there is no friction
between m1 and plank. Initially the whole system is at
rest. The plank is now pulled to right with constant
acceleration a = 2 m/s2. Find the amplitude (in cm) of
oscillation of block m1 relative to plank.
12. A cone of radius R and height H, is hanging inside a liquid of density ρ by

means of a string as shown in the figure. The force, due to the liquid acting
4 R2 gH
on the slant surface of the cone is , then value of N will be _____
N
(Neglect atmosphere pressure)
13. A uniform steel wire hangs from the ceiling and elongates due to its own weight. The
ratio of elongation of the upper quarter of the wire to the elongation of the lower
quarter of the wire is
SECTION – C
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions of
numerical answer type. The answer to each question is a NUMERICAL VALUE (XXXXX.XX). If the
numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Paragraph for Question Nos. 14 and 15
A metal block is placed in a room which is at 10°C for long time. Now it is heated by an electric
heater of power 500 W till its temperature becomes 50°C. Its initial rate of rise of temperature is
2.5°C/sec. The heater is switched off and now a heater of 100W is required to maintain the
temperature of the block at 50°C. (Assume Newtons Law of cooling to be valid)
14. What is the heat capacity of the block in J/C?
15. What is the rate of cooling (in C/s) of block at 50°C if the 100W heater is also switched off?
A small ball of mass 1 kg is kept in circular path of radius 1m in fixed

concentric smooth horizontal ring of radius R. Angular speed of the ball in
the circular motion is 1 rad/s. At a certain moment the string, which kept
the ball in the circular path breaks and the ball goes off tangentially to the
wall of rigid, fixed ring and bounces off elastically and again hits the ring
and bounces off. The seventh collision takes place exactly at the position
of the first collision.
16. Total impulse imparted to the ring by the ball in first three collision will be ______
17. Value of radius of the ring R will be______
Chemistry PART – II
SECTION – A
18. A buffer solution 0.04 M Na2HPO4 and 0.02 M Na3PO4 is prepared. The electrolytic oxidation of 1
millimole of the organic compound RNHOH is carried out in 100 mL of the buffer. The reaction is:
 RNO2  4 H   4e 
RNHOH  H 2O 
The approximate pH of solution after the oxidation is complete is:
[Given: for H3 PO4 , pKa1  2.2; pKa2  7.20; pKa3  12 ]
(A) 6.90 (B) 7.20
(C) 7.5 (D) None of these
19. Which of the following reaction is not a disproportionation reaction?

2   
(A) Br2  CO3  H 2 O 
 Br  BrO3  HCO3
 
(B) P4  OH  H 2O 
 PH 3  H 2 PO2
(C) H 2 S  SO2 
 S  H 2O
(D) H 2O2 
 H 2O  O2
20. van der Waal’s gas equation can be reduced to virial equation (in terms of volume) such that
B C
Z  A   .....
vm vm 2
Where A = first virial coefficient, B = second virial coefficient,
C = third virial coefficient.
2
The third virial coefficient of He(g) is 625 cm 2 /mol  .
What volume is available for 10 moles He(g) atoms present in 50L vessel?
(A) 49.75L (B) 49.25L
(C) 25L (D) 50L
21. Which of the following pairs of compounds is a ring chain isomer?

CH2Cl Cl
H3C CH CH CH3 and
(A) (B) and
OH OH HO OH
CH3
CH3
CH2 =CH-CH 2 -OH and OH CH2CH3
(C) (D) and
CH3
SECTION – A
22. Which of the following can exist in syn and anti-form?

(A) Ph  N  N  OH (B) Ph  N  N  Ph
(C) Ph  CH  N  OH Ph
(D)
C N OH
Ph
23. Which of the following does/do not impart characteristic colour to the flame?
(A) MgSO4 (B) CaCl2
(C) Sr  NO3  2 (D) BeCl2
24. 
For a reaction, A  P, the plots of [A] and [P] with time at temperature T1 and T2 are given
below. If T2 >T1, the correct statement(s) is (are) (Assume ∆Ho and ∆So are independent of
T2
temperature and ratio of ln K at T1 to ln K at T2 is greater than . Here H, S, G and K are
T1
enthalpy, entropy, Gibbs energy and equilibrium constant respectively.)
10 10
T1
[P] / (mol L1 )
[A]/ (mol L1 )
T2
5 5
T2
T1
Time Time
o o
(A) ∆H < 0, ∆S < 0 (B) ∆Go < 0, ∆Ho > 0
(C) ∆Go < 0, ∆So < 0 (D) ∆Go < 0, ∆So > 0
SECTION – B
25. Number of hydrogens replaced by Deuterium in the given reaction are:

OH
-
D2 O/DO

Prolonged

26. Number of enols of the given compound are:

O
27. How many of the molecules/ions are odd electron species;

  
NO2 , NO3 , ClO2 , ClO3 , CH 3 , CH 3 , CH 3 , NO , OF2 , N 2 O5 , Cl2O7 , BH 3 , C3O2
 x
28. AB  g   AB2  g   A 2B 3  g  Kp1  atm 1
10

2AB 2  g   A 2B 4  g  Kp 2  8atm 1
These two equilibria simultaneously existing in a vessel at 298 K. If initially only AB and AB2 are
present in 3:5 mole ratio and total pressure at equilibrium is 5.5 atm with pressure of AB2 at
0.5 atm. then x is……
29. Solubility of K2 Zn3 Fe  CN6  is s mol/ltr and its Ksp  216xsy . Then value of x  y is……
2
30. How many of the following molecules/ions have centre of symmetry?

XeF6 ,XeF4 ,SF4 ,SF6 ,PCl5 ,CH4 , NH4 , SiF62 , I3 , IF7 , XeOF2 , ClF3 , PCl3F2
SECTION – C
We have seen that Light and other electromagnetic radiations have a dual nature i.e. wave and
particle nature. According to Lewis de Broglie old moving particles (microscopic and
macroscopic) have dual nature. He correlates the two characters in the form of an equation know
as de-Broglie equation after his name.
h
 from E = hv = me2
mv
1
K.E. = V.e. = mv2
2
where, h= Planck’s constant,  = wavelength, m = mass of moving particle and v = velocity
31. The ratio of velocities of CH4 and O2 molecules so that they are associated with d-Broglie waves
of equal wavelengths is__
32. The ratio of velocities of electron and proton if the wavelength associated with an electron
become equal to the wavelength associated with a proton is (me = 9.1 x 1028 gm, mp = 1.67 x
1024 gm)
A catalyst increases the rate of chemical reaction by providing an alternative reaction pathway
which lower activation energy than the reaction pathway in its absence. A catalyst is not
consumed and therefore does not appear in the chemical equation for the reaction. A
homogenous catalyst is in the same phase as the reactants whilst a heterogenous catalyst in a
different phase.
2+
The complex [Co(NH3)5F] reacts with water according to the question:
[Co(NH3 )5 ]2  H2O  [CO(NH3 )5 (H2 O)]3   F
Rate = K[complex]a[H+]b
The reaction is acid catalysed i.e. [H+] does not change during the reaction.
Thus rate = K’ [complex]a where, K’ = [H+]b
Complex [H+] T1/2 (hr) T3/4(hr)
0.1 0.01 1 2
0.2 0.02 0.5 1
33. From the above data, value of a is:
34. Overall order of reaction is:
Mathematics PART – III
SECTION – A
 7     3   7     3 
35. If x = sin   
  sin      sin     , Y = cos      cos      cos     ,
 12   12   12   12   12   12 
X Y
then  is ____
Y X
(A) 2 cot2 (B) 2 tan2
(C) 2 cot (D) 2 tan
cos   sin 
36. Find the general values of  for which the quadratic function (sin )x2 + (2cos)x + is
2
the square of a linear function
 
(A) 2n +  (2n + 1)  tan12, n  I (B) 2n   (2n + 1) + tan12, n  I
4 4
 
(C) n +  (2n  1) + tan12, n  I (D) n +  (2n + 1)  tan12, n  I
4 4
 1  1   1 
37. The coefficient of x 49 in the expansion of (x  1)  x    x   ...  x  49  si equal to
 2  22   2 
 1 
(A)  2  1   (B) +ve coefficient of x
 250 
 1 
(C) ve coefficient of x (D)  2  1  
 2 49 
38. If the standard deviation of the number 2, 3, a and 11 is 3. 5, then which of the following is true?
(A) 3a2  32a + 84 = 0 (B) 3a2  34a + 91 = 0
2
(C) 3a  23a + 44 = 0 (D) 3a2  26a + 55 = 0
SECTION – A
x x
39. Find the general solution of the equation, 2 + tan x. cot   + cot x. tan   = 0
2 2
(A) 2n + (2/3), n  I (B) n + (/3), n  I
(C) 2n  (2/3), n  I (D) n  (/3), n  I
40. Ten persons numbered 1,2,...,10 play a chess tournament, each player playing against every
other player exactly one game. It is known that no game ends in a draw. If w1, w2, ..., w10 are the
number of games won by players 1, 2, 3, ..., 10, respectively, and l1, l2, ..., l10 are the number of
games lost by the players 1, 2, ..., 10 respectively, then
(A)  
w i  Ii  45 (B) wi + li = 9
2 2 2 2
(C)  w  81   I
i i (D)  w  I
i i
m
 30  20  p p
41. If f(m) =   30  i 
i 0
 , where   
 m  i   q
C q , then
50
(A) maximum value of f(m) is C25 (B) f(m) is always divisible by 50 (1  m  49)
50
2
(C) f(0) + f(1) + ... + f(50) = 250 (D) The value of  f m  100 C50
m 0
SECTION – B
42. The sequence of a1, a2, a3 ... a98 satisfies the relation an+1 = an + 1 for n = 1, 2, 3, . . . 97 and has
49
the sum equal to 4949. Evaluate a
k 1
2k .
43. ABC is a triangle. 3 Circles with radii 1,4 and 9 as shown are drawn inside the triangle each touching
two sides and the incircle. Then the radius of the incircle of the △ABC is
44. How many ten digits whole number satisfy the following property they have 2 and 5 as digits, and
there are no consecutive 2's in the number? (i.e. any two 2’s are separated by at least one 5).
45. If the expression z5 = 32 can be factorized into linear and quadratic factors over real coefficients
as (z5 − 32) = (z − 2)(z2 – pz + 4)(z2 – qz + 4), where p > q, then the value of p2 + 2q is equal
to______
46. Find the general solution of the equation sin x + cos x = 0. Also find the sum of all solutions
in [0, 100].
47. How many different ways can 15 candy bars be distributed between Ram, Shyam, Ghanshyam
and Balram, if Ram cannot have more than 5 candy bars and Shyam must have at least two?
Assume all candy bars to be alike.
SECTION – C
Let S = S1  S2  S3, where S1 = {z  C : |z| < 4},

   z  1  3i  
S2 = z  C :lm    0  and S3 = {z  C : Re(z) > 0}
  1  3i  
48. Area of S is ________
49. Min|1  3i  z| is equal to __________
There are two sets, A and B each of which consists of three numbers in A.P. whose sum is 15. D
p 7
and d are their respective common differences such that D  d = 1, D > 0. If  , where p and
q 8
q are the product of the numbers in those sets A and B respectively.
50. Sum of the product of the numbers in set A taken two at a time is___
51. Sum of the product of the numbers in set B taken two at a time is___

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FIITJEE

ALL INDIA INTEGRATED TEST SERIES

2. From a uniform semicircular thin disc of radius R, a semicircular

4. A uniform square plate is placed on a horizontal floor. When it is

5. Two identical solid cones float in water as shown in figure.

6. Water jet is projected at an angle to the horizontal. At the point of

(A) the temperature gradient is not uniform.

10. In a soap film experiment an originally semicircle shaped thread

11. Two blocks of masses m1 = 1 kg and m2 = 2 kg are

12. A cone of radius R and height H, is hanging inside a liquid of density ρ by

14. What is the heat capacity of the block in J/C?

Paragraph for Question Nos. 16 and 17

A small ball of mass 1 kg is kept in circular path of radius 1m in fixed

17. Value of radius of the ring R will be______

19. Which of the following reaction is not a disproportionation reaction?

21. Which of the following pairs of compounds is a ring chain isomer?

22. Which of the following can exist in syn and anti-form?

25. Number of hydrogens replaced by Deuterium in the given reaction are:

26. Number of enols of the given compound are:

27. How many of the molecules/ions are odd electron species;

30. How many of the following molecules/ions have centre of symmetry?

Mathematics PART – III

Let S = S1  S2  S3, where S1 = {z  C : |z| < 4},

48. Area of S is ________

49. Min|1  3i  z| is equal to __________

Paragraph for Question Nos. 50 and 51

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