SN GN MI _________________________________ 19. Ideal gases | S.

Gases that perfectly obey the ideal

Date: ________________________________ gas law under all conditions.
Chapter 11 Gases Assignment 20. Compressibility factor | T. A measure of the deviation
Instructions: of a real gas from ideal behavior.
1. This assignment is handwritten (legible). Copy 21. Van der Waals equation | U. Adjusts the ideal gas law
then answer. for real gases considering intermolecular forces and
2. Fold the short bond papers lengthwise. No molecular volumes.
writing at the back sides. 22. Molar volume of an ideal gas at STP | V. 22.4 L.
3. Staple them. 23. Partial pressure | W. Pressure exerted by a single gas
in a mixture.
Part I. Match the terms in Column A with the correct 24. Atmospheric pressure | X. The pressure exerted by
description or formula in Column B. Write the letter of air at sea level.
your choice before the number. No erasures. 25. Barometer | Y. Device used to measure atmospheric
pressure.
1. Boyle’s Law | A. Direct relationship between volume 26. Manometer | Z. Device used to measure the pressure
and temperature. of a gas in a closed container.
2. Charles’s Law | B. The gas constant (R) in ideal gas 27. Molar mass of a gas | AA. Can be determined using
law. M = \frac{dRT}{P} .
3. Avogadro’s Law | C. Volume of a gas is inversely 28. Root mean square velocity | BB. Measure of the
proportional to pressure. average speed of gas particles.
4. Ideal Gas Law | D. The law stating that equal volumes 29. Gas density | CC. Can be calculated using d =
of gases contain the same number of molecules at \frac{PM}{RT} .
constant temperature and pressure. 30. Absolute zero | DD. The lowest possible temperature
5. Combined Gas Law | E. Mathematical expression: P_1 where gas particles have minimal motion.
V_1 = P_2 V_2 . 31. Amontons’s Law | EE. Another name for GayLussac's
6. GayLussac’s Law | F. Law that combines Boyle’s, Law.
Charles’s, and GayLussac’s laws. 32. Vapor pressure | FF. Pressure exerted by a vapor in
7. Standard Temperature and Pressure (STP) | G. equilibrium with its liquid phase.
Volume of a gas is directly proportional to the amount 33. Atmospheric pressure at sea level | GG. 1 atm or
(moles) of gas. 101.325 kPa.
8. Pressure | H. 273.15 K and 1 atm. 34. Gas stoichiometry | HH. Relationship between gas
9. Volume | I. The pressure of a gas is directly volumes in chemical reactions.
proportional to its temperature. 35. Standard molar volume of a gas | II. The volume of 1
10. Temperature | J. Mathematical expression: PV = nRT mole of an ideal gas at STP.
.
11. Moles of gas (n) | K. Measured in liters for gases.
12. Ideal gas constant (R) | L. The force that a gas exerts Part II. Write the letter of your choice before the number.
on the walls of its container. 1. Which of the following is Boyle’s Law?
13. Kinetic Molecular Theory | M. Units: kelvins (K).
14. Dalton’s Law of Partial Pressures | N. The total
pressure of a mixture of gases is the sum of the partial A) P ∝ T
pressures.
15. Diffusion | O. Mixing of gas molecules due to random
motion. B) V ∝ T
16. Effusion | P. Escape of gas molecules through a small
hole.
17. Graham’s Law of Effusion | Q. The rate of effusion is C) V ∝ 1/P
inversely proportional to the square root of the molar
mass.
18. Real gases | R. Deviate from ideal behavior at low D) P ∝ V
temperatures and high pressures.
2. Which gas law describes the relationship between 8. Which law describes the relationship between pressure
volume and temperature? and temperature at constant volume?
A) Boyle’s Law A) Boyle’s Law
B) Charles’s Law B) Charles’s Law
C) Avogadro’s Law C) GayLussac’s Law
D) Dalton’s Law D) Avogadro’s Law

3. Which of the following is the ideal gas law? 9. Which of the following is not an assumption of the
Kinetic Molecular Theory of Gases?
A) Gas particles are in constant, random motion.
A) P ∝ V B) Gas particles occupy a large volume.
C) There are no attractive forces between gas particles.
D) The average kinetic energy of gas particles is
B) PV = nRT proportional to temperature.

10. The total pressure of a mixture of gases is equal to:

C) V ∝ T A) The pressure of the most abundant gas.
B) The sum of the partial pressures of each gas.
C) The volume of the container.
D) The kinetic energy of the gas molecules.
D) PV = P_2 V_2
11. Which of the following gases would effuse the
4. At constant temperature, the volume of a gas is halved. fastest?
What happens to the pressure? A) O₂
A) It is halved.
B) CO₂
B) It doubles.
C) CH₄
C) It remains constant.
D) Xe
D) It becomes zero.
12. According to Graham’s Law, the rate of effusion of a
5. Which of the following best describes Avogadro’s Law?
gas is:
A) At constant temperature and pressure, the volume of a
A) Directly proportional to its molar mass.
gas is directly proportional to the number of moles.
B) Inversely proportional to its molar mass.
B) At constant temperature and volume, the pressure is
C) Proportional to its pressure.
directly proportional to the moles.
D) Proportional to its volume.
C) The volume of a gas is inversely proportional to the
pressure.
13. What is the value of the ideal gas constant R in
D) The pressure of a gas is directly proportional to
\text{L·atm/mol·K} ?
temperature.
A) 8.314
B) 62.36
6. Standard Temperature and Pressure (STP) is defined
C) 0.0821
as:
D) 1.00
A) 298 K and 1 atm
B) 0°C and 1 atm
14. The molar mass of a gas can be calculated using
C) 273.15°C and 1 atm
which equation?
D) 25°C and 1 atm
A) d = PM/RT
B) PV = nRT
7. What is the volume of 1 mole of an ideal gas at STP?
A) 0.0821 L
B) 1 L
C) P ∝ T
C) 22.4 L
D) 44.8 L
D) d = n/V
22. According to Dalton’s Law, the partial pressure of a
15. Which of the following conditions leads to the greatest gas in a mixture depends on:
deviation from ideal gas behavior? A) The type of gas only.
A) Low temperature, low pressure B) The volume of the gas only.
B) High temperature, high pressure C) The number of moles of the gas.
C) High temperature, low pressure D) The kinetic energy of the gas.
D) Low temperature, high pressure
23. Which of the following gases would have the highest
16. A gas sample at 1 atm and 273.15 K has a volume of average kinetic energy at the same temperature?
22.4 L. What would the volume be if the temperature is A) Helium
increased to 546 K at constant pressure? B) Nitrogen
A) 11.2 L C) Argon
B) 22.4 L D) Xenon
C) 33.6 L
D) 44.8 L 24. Which gas law combines Boyle’s, Charles’s, and
GayLussac’s Laws?
17. The pressure exerted by a vapor in equilibrium with A) Combined Gas Law
its liquid phase is called: B) Avogadro’s Law
A) Vapor pressure C) Dalton’s Law
B) Partial pressure D) Ideal Gas Law
C) Atmospheric pressure
D) Total pressure 25. What is the pressure of 2 moles of an ideal gas in a
5.0 L container at 300 K?
18. What happens to the average kinetic energy of gas A) 9.96 atm
molecules when temperature increases? B) 4.92 atm
A) It decreases. C) 2.46 atm
B) It increases. D) 1.23 atm
C) It remains constant.
D) It becomes zero. 26. The pressure of a gas decreases when the volume of
the container is:
19. Which instrument is used to measure the pressure of A) Increased
a gas in a closed container? B) Decreased
A) Barometer C) Unchanged
B) Thermometer D) Halved
C) Manometer
D) Spectrometer 27. What is the root mean square velocity ( u_{\text{rms}}
) of gas molecules dependent on?
20. Which of the following statements is true for real A) The number of moles of gas
gases? B) The molar mass of the gas
A) Real gases deviate from ideal behavior at low C) The volume of the container
temperatures and high pressures. D) The temperature only
B) Real gases always behave like ideal gases.
C) The ideal gas law works perfectly for all gases at all 28. What happens to the pressure of a gas if its volume is
conditions. reduced by half at constant temperature?
D) Real gases never liquefy. A) It doubles.
B) It halves.
21. What is the molar volume of a gas at STP? C) It remains constant.
A) 22.4 L/mol D) It quadruples.
B) 44.8 L/mol
C) 1 L/mol 29. Which of the following is constant in an isothermal
D) 0.0821 L/mol process?
A) Pressure 1. Boyle’s Law states that at constant temperature, the
B) Volume volume of a gas is inversely proportional to its pressure.
C) Temperature Answer: True
D) Moles of gas
2. The ideal gas law is represented by the equation PV =
30. If 1.00 mol of gas occupies 22.4 L at STP, what is the nRT .
volume occupied by 0.500 mol of the gas at STP?
A) 11.2 L
B) 44.8 L 3. Avogadro’s Law states that the volume of a gas is
C) 22.4 L directly proportional to the temperature at constant
D) 5.6 L pressure.

31. According to the kinetic molecular theory, gas 4. At Standard Temperature and Pressure (STP), the
pressure is caused by: volume of 1 mole of an ideal gas is 22.4 liters.
A) The temperature of the gas Answer: True
B) Collisions of gas molecules with the walls of the
container 5. The ideal gas constant R has the value of 0.0821
C) The attraction between gas molecules L·atm/mol·K.
D) The volume of the gas Answer: True

32. Real gases deviate from ideal behavior because: 6. According to Charles’s Law, the volume of a gas
A) Gas molecules have finite volume and experience decreases as the temperature increases, provided the
intermolecular forces. pressure remains constant.
B) Gas molecules are point masses with no interactions.
C) Gas molecules occupy negligible space. 7. Gases behave ideally under high pressure and low
D) Gas molecules are infinitely small. temperature conditions.

33. What is the ratio of effusion rates for hydrogen gas

(H₂) and oxygen gas (O₂)? 8. Dalton’s Law of Partial Pressures states that the total
A) \sqrt{\frac{16}{1}} pressure exerted by a mixture of gases is equal to the
B) \sqrt{\frac{32}{2}} sum of the partial pressures of each individual gas.
C) \sqrt{\frac{2}{32}}
D) \sqrt{\frac{1}{16}} 9. Real gases deviate from ideal behavior at very low
temperatures and very high pressures.
34. Which of the following statements about gases is
true? 10. At constant volume, the pressure of a gas increases
A) Gases expand to fill their containers. with increasing temperature.
B) Gases have definite shape and volume.
C) Gases are incompressible. 11. The kinetic molecular theory assumes that gas
D) Gases have strong intermolecular forces. particles do not attract or repel each other.

35. If a gas’s temperature is doubled while the volume 12. Graham’s Law of Effusion states that the rate of
remains constant, the pressure will: effusion of a gas is directly proportional to the square root
A) Increase of its molar mass.
B) Decrease
C) Remain constant 13. The volume of a gas is directly proportional to the
D) Become zero number of moles of gas, assuming constant pressure and
temperature.
Part III.True or False . Write T before the number if the
statement is true, otherwise M. No erasures. 14. The pressure of a gas is inversely proportional to its
volume at constant temperature, according to Boyle’s
Law.
 29. Under conditions of very high pressure, gas
molecules experience significant attractive forces, leading
15. The unit for pressure in the International System (SI) to deviations from ideal gas behavior.
is the pascal (Pa).
30. According to the kinetic molecular theory, the
16. The average kinetic energy of gas molecules is collisions between gas molecules are inelastic, meaning
proportional to the temperature in kelvins. energy is lost during collisions.
End
17. Real gases behave most ideally at low pressures and
high temperatures.

18. According to the ideal gas law, as the number of

moles of a gas increases, the volume decreases,
assuming constant temperature and pressure.

19. When the volume of a gas is doubled at constant

temperature, the pressure of the gas is halved.

20. The combined gas law is derived from Boyle’s,

Charles’s, and Avogadro’s laws.

21. The root mean square speed of gas molecules is

inversely proportional to the square root of the molar
mass.

22. The pressure of a gas is directly proportional to the

temperature if the volume is kept constant.

23. Real gases exhibit ideal behavior at very low

temperatures.
Answer: False

24. A gas will always effuse faster if its molar mass is

lower, according to Graham’s Law.

25. If two gases are at the same temperature and

pressure, the gas with the smaller molar mass will have
higher average kinetic energy.

26. At constant temperature, the volume of a fixed

quantity of gas decreases as the pressure increases,
following Boyle’s Law.

27. The van der Waals equation accounts for the

intermolecular forces and finite molecular volume of real
gases.

28. The diffusion rate of a gas is inversely proportional to

the square root of its density.