History of Semiconductors Diffusion Engineering: B. Lojek
History of Semiconductors Diffusion Engineering: B. Lojek
.. INTRODUCTION
CHRONOLOGY OF SEMICONDUCTORS
semiconductors by the late thirties and integrated
circuits at the end of the fifties, they did not
know that they were going to change the lives of
. DIFFUSION E N G I “ G
SEMICONDUCTOR DIFFUSION
ENGINEERING AT Bell Telephone
future generations. Very few people at that time
recognized the significance of perhaps the most
important invention of the century. Nobody
. Laboratories (BTL)
PROBLEMS WlTH APPLICATION OF
noticed that the key people behind the inventions
were frequently frustrated and disappointed.
. S H W Y SEMICONDUCTOR
DIFFUSION “SISTOR AT
Tom Longo, and Dave Talbert?
In the beginning of the sixties the editors of
. FAIRCHILD
FIRST INTEGRATED CIRCUIT AT
“1958-1959 Robert Noyce, Jean Hoerni, lack
.
Kilby, and Kurt Lehovec all took part in
TEXAS INSTRUMENTS developing the integrated circuit”.
FIRST INTEGRATED CIRCUIT AT
. SYLVANIA
COMMERCIALLYAVAILABLE
PROLOGUE
On July I , 1948 The New York Times on page Fig. 1. Inventors of integrated circuit as they
48 in “News of Radio” section printed an were recognized in the early sixties.
announcement of NBC that it would broadcast
Waltz Time on Friday nights. The same section In Jack Kilby’s speech to The 2000 Nobel Prize
contains a brief report about a new invention, “a Committee the names reduced to just Robert
device called a transistor, which has several Noyce despite the fact that Hoerni and Lehovec
applications in radio where a vacuum tube ideas were so much more practical than Kilby’s
ordinaril.1; is employed. ’’ that even Texas Instrument adopted them.
210
The monumental result, the integrated circuit, many young scientists, on the contrary to low
was a result of the creativity of high-maintenance appreciation of diffusion engineering today.
employees. Diffusion and thermal processing play a less
important role in state of the art semiconductor
manufacturing than thej. did fifty years ago. At
I dedicate this work to the memory of William B. that time the technique of diffusing impurities
Shocklev. from a gaseous state into the semiconductor
When I am feeling down at work I always crystal opened up the possibilities of device
remember Shock1e.v. In ntj, entire life I have not performance never before possible.
met a more creative and resilient person than This presentation describes the history of
William Shocklev. diffusion in semiconductors from the beginning
He created not only Silicon Valley and a new of the fifties, when Carl Frosch and Lincoln
industry, but he changed the wa.v we live on this Derick at BTL forgot to close a hydrogen valve
plan&. For erample, ifthe atomic bomb had not and by mistake discovered the wet oxidation of
been invented, the life of the majariry ofpeople silicon; through the first days of November 1959,
would not be affected. However, I cannot when planar, four transistors setireset flip-flop
imagine my life without the transistor, even circuit began to work; until 1961 when
though I d 0 not use a mobile phone. Electrnglas manufactured the fust commercially
The fundamental theory of the PN junction as available diffusion furnace for the semiconductor
used today was formulated by Shockley in a very industry. Contrary to the commnn myth
short period of time. Shockley became the most integrated circuits did not take the world by
respected and hated man bv the age of fort).. storm, but had a slow growth through the
What was the source of his genius or what some beginning of the sixties. The development of the
call evilgenius? My answer is that Shocklev was first integrated circuit was certainly far from a
a man that Nature rarelyprodures and who only mainstream activity of the semiconductor
appears on Erath at intervals of centuries. companies.
Interestingly enough, the majorit). of those who
sharply criticize Shocklev put into their resumes
or biographies a note that they worked with and
were trained by W. Shockley.
It is too sad that Shockley never shared in the
rewards that so many Silicon Valley pioneers
reaped.
INTRODUCTION
211
1945 William Shockley become coordinator ofthe containing impurities. Silicon transistors were
-
Solid State Phvsics Research Proeram at BTL.
~~
less exoensive to oroduce and onerated at
higher temperature than germanium transistors.
1947 Point Contact Transistor [Bardeen, Brittain]
December - L. Derick and C. Frosch
1948 Junction Transistor [Shockley] discovered masking properties of Si02against
the diffusion of impurities.
June -BTL Press Conference revealing the
transistor invention. 1955 C. Frosch and L Derick released BTL Report
“The Oxidation of Silicon to Prevent Surface
1950 Diffusion from Solid Source used to form a PN Erosion During High Temperature
junction [ Dunlap, General Electric]. Operations”, BTL Memorandum #55-ll>Z,
June 14, 1955.
W. Shockley published Magnum Opus
“Electron and Holes in Semiconductors” (D. Theory of Interaction between Defects in Ge
Van Nostrand Company, Inc., Princeton,N.l. and Si [H. Reiss, S.S. Fuller, F.J. Morin, BTL.
1950).
June - W. Shockley resigned from BTL
195 1 September bell Telephone Laboratories and
Western Electric Company organized the In late 1955 Amold Beckman paid $25,W.W
”First Symposium on Transistor Technology”. to license patent rights from Western Electric.
Centralab Division of Globe Union purchased
license and lack Kilby attended meeting. 1956 February - A. Beckman announced the
formation of Shockley Semiconductor
Texas Instruments renamed from Geophysical Laboratories .
Service Inc. founded in 1920.
June - April - Bell Telephone Laboratories and
1952 Semiconductor Diffusion Equation Solution Western Electric Company organized the
[Van Roosbroeck, BTL]. “Third Symposium on TransistorTechnology”
with Sony’s engineer Iwahe and first Shockley
April - Bell Telephone Laboratories and Semiconductor Lab employees Happ, Valdes
Western Electric Company organized the and Noyce in audience.
“Second Symposium on Transistor
Technology”. The U.S. Amy, Navy and Air Charles Kittel published “Introduction to Solid
Force chose about two hundred people, the State Physics”, (John Wiley & Sons, Inc., New
BTL selected the rest mainly from licensees of York, 1956).
transistor patents.
“Zone refining” invented by William Pfann in November I - Bardeen, Brattain and Shxkley
1950-51 disclosed. Teal and Buehler described won the Nobel price for physics.
in detail crystal pulling apparatus.
Attendees include among others December 16 -Work of C.J. Frosch and L.
representatives from IBM, GE, TI, Derick “Surface protection and Selective
GlobeUnion and fourteen foreign (all NATO Masking during Diffusion in Silicon” is cited
countries) companies. in letter from A.T. David of Western Electric
to W. Shockley. Shockleyattachedtotheletter
Single crystal silicon is fabricated at BTL. routing list that is initialed by Noyce, Moore,
Hoerni, and Last.
1954 Diffusion from Gaseous Compounds [Fuller,
Ditzenberger, Frosch, G . L. Pearson BTL]. 1957 Vic Jones, one of the first Shockley
Semicondcutors Laboratories employee
April 26 - BTL announced its Solar Battery. resigns.
March -G.C. Dacey, C.A. Lee, W. Shockley J. Andrus and W.L. Bond of BTL disclosed
developed Mesa Diffusion Transistor. photoresist patterning of transistor
(“Photoengraving in Transistor
First commercial silicon transistor (Texas Manufacturing”, News abstracts of
Instruments). On May I O , 1954, Texas Electrochemical Soc. Semiconductor
Instruments announced the commercial Symposium, Washington, D.C. 1957).
availability of the grown-junction silicon
transistors. These first silicon transistors were lune 10 - Meeting between Beckman,
constructed by cutting a rectangular bar from a Shockley and seven scientists results in an
silicon crystal that was grown from a melt agreement that Shockley will remain director
of the company and a new position would be Western Electric announced 2N560
created to whom everybody else would report. transistor.
(Shockley would move to the Spinko Data Sheet for Fairchild NPN 2N696
building). released.
August - Smoot Horsley and his technician in September 12 -Jack Kilby demonstrated at
Shockley Semicondcutor produced first 72 TI phase shift oscillator assembled from
working four-layer diodes. grown-junction transistor and capacitors cut
from diffused power transistors metallized on
September 18 - seventonel’ alias “Eight both sides
Traitors” resigned from Shockley Laboratories.
November I 2 -ground breaking for new
September 19 -The “Eight” signed agreement Fairchild facility at 545 Whishman Rd. in
with Fairchild Camera & Instrument Mountain View. Total number of employees
Corporation. at Fairchild Semiconductor reach 150.
213
based on his patent notebook entry from formulated point defect (vacancy) mechanism
January of diffusion in Silicon.
August 18-21 -at WESCON 1959 show in January 31 -1. Hoerni, S. Roberts, 1. Last,
San Francisco, Robert Noyce asked Jay Last and Isy Haas resigned from Fairchild and
to initiate development of integrated circuit at formed Amelco as a part of Teledyne.
Fairchild. The main motivation behind this
decision was strong publicity campaign David F. Allison and Lionel Kattner form
generated by Texas Instruments. Signetics.
Summer - Shockley Semiconductor renamed Molectro -with Robert Widlar and Dave
to Shockley Transistor Corporation. Talbert.
1960 Spring - Fairchild’s operators collectively E. Kleiner left Fairchild and joined Amelco
burnt their hairnets and protested the wearing as industry consultant.
of smocks.
1962 Electroglas Inc started marketing the first
Furnace Loading Push and Pull Mechanism generation of diffusion fumaces developed by
[Clevite Corporation]. Leach with strong support from Hoerni.
5‘ XK,
management highly publicized, he noted “It was
very interesting because people like to speak of
c ,’ FURNACE
teamwork when they talk about research. The CiSTyIcE UDNG TUBE
solar cell just sort of happened and had none of
the aspects of team work.” A photograph af the actual system schematically
shown in Fig. 3 s shown in Fig. 5.
The Apparatus used for diffusion from gaseous
compounds experiments in Bell Telephone In the mid fifties the first generation of top bench
Laboratories at the beginning 1950’s is shown in furnaces was improved and heating coils were
Fig, 3. added to the system. A very simple on-off
Most of the works reported by C.S. Fuller, J.A. controller and bubbler were added to the system.
Ditzenberger and C.J. Frosh were done in this Temperature was sensed by a thermocouple
system. The essential components are elongated inserted into a cavity in the middle of the wafer
fused quartz tubes with an inner diameter boat. All gas distribution was accomplished
approximately 25 mm extending through high through the quartz tubing and quartz valves. No
temperature controlled “glo-bar” furnace. The specialized gases for semiconductor industry
‘Glo-bar” furnace provides a constant existed at that time.
temperature zone approximately 100 mm long.
The semiconductor samples are placed vertically
215
Fig. 4. Diffusion furnace used at Bell Telephone Laboratories during early fifties. In this type of furnace
Carl Frosch and Lincoln Derick discovered by accident the oxidation of silicon.
MFNSION
Fig. 5. Oxidation system used by Carl J. Frosch and Lincoln Derick at BTL in early 1950's
216
Pitting of the semiconductor surface
during the diffusion process when non-
oxidizing gases were used. The surface
pitting resulted in non-uniform junction
depth.
217
Dunlap at the GE Research Labs. However, GE
did not follow up on the diffusion work except
for John Saby who extended this basic
technology to create a “control device” in 1951
which later become known as the alloy junction
transistor. (Fig. 8)
218
Almost at.the same time when Lee demonstrated through mask with size 50 x 150 pm to the base
his transistor, M. Tanenhaum and D.E Thomas region. An Aluminum layer was alloyed through
demonstrated silicon NPN transistor with the the emitter layer.
base and emitter regions produced by Alloying a film of gold with a small amount of
simultaneously diffusing impurities of antimony formed the contact to the emitter.
Aluminum and Antimony. Alloying of gold-antimony layer to the silicon
bulk formed the collector contact. The tungsten
AI LJYBNUS
ALUWNUM point pressure contacts were used to create an
EWnER GSOOLD-ANTIMONY electrical connection to the bulk.
The laboratory works of Lee and Tanenbaum
resulted in a transistor that was not easy to
manufacture. However, very good transistor
performance with diffused layers put into
question the main deterrent to the application of
diffusion to transistor technology - t h e drastic
decrease of lifetime (especially for silicon) when
the sample was exposed to the high temperatures
required for diffusion.
t COLLECTOR
I - T Y P E 1 H ) I G W N WrFERl
'P
219
The L.E. Martin of BTL in Laureldale, PA An Aluminum contact to the ring base is
further advanced Tanenbaum’s silicon transistor evaporated through the mask and alloyed. The
with several refinements in fabrication silver is alloyed to the N-type emitter layer. The
techniques. These refinements included an individual transistor dies were bonded to the
independent emitter and base diffusion and high gold plated heater. Thermocompression bonding
vacuum evaporation technique for producing the of gold wires was used to wire electrical
ohmic contacts with thermocompression bonding contacts.
of attached lead wires. Martin’s design of the transistor enabled for the
L. Martin designed the silicon NPN transistor fust time production of a large number of
with mesa “ringdot” structure shown in Fig. 17 transistors simultaneously. However, the 2N560
which was manufactured by Western Electric as did not use photoresit masks. The metal
2N560 for military logic application. “shadowing masks” were used for:
The base diffusion was performed in an open a) emitter diffusion,
tube used in Frosch and Derick experiments b) base contact
with the galium sesquioxide (Ga203) as the c) emitter contact
diffusion source in wet hydrogen atmosphere. The aligned (at that time so called “indexed”)
The surface concentration of the diffusion layer mask was used to etch the mesa structure.
was approximately 10’’ cni3 with thickness Fig. 19 shows a slice of silicon with transistors
approximately 0.5 p m ready for assembly.
Fig. 17 Beveled section of 2N560 ringdot mesa Fig. 19. Wafer with transistors 2N560 ready for
silicon transistor. assembly.
-
Fig. 18 Cross-section of 2N560 ringdot mesa
silicon transistor.
220
Several of Shockley's former employees
publicized that Shockley had an exceptional
ability to simplify and solve problems of physics,
and, also, exceptional ability to find good and
talented people. History clearly proved, that this
myth is not hue as he hired several employees of
questionable integrity.
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221
While at BTL Shockley did not need to be Shockley, however, was not interested in any
worried about any facility issues, tooling or legal dispute and no legal action was initiated.
payroll. In Palo Alto the mesa transistor was still Eventually, other very capable employees of
in the early stages of development with no Shockley’s joined the “Eight” at Fairchild.
equipment suitable for production available. Between them, for example, D. Allison. “Tom”
Shockley underestimated the problems of start C.T. Sah .
up organization and he concentrated mostly on
the scientific aspects of company. Shockley never understood the reasoning of the
The four-layer diode was the key to W. group of “eight traitors,” although he never gave
Shockley’s plan to revolutionize phone systems. up, he also never fully recovered from this set
It was great device in theory, but not in practice back. He moved his interests back to science and
- at least not at the time when mesa transistor Shockley Semiconductor Laboratories
was still not completed. The four-layer diode is disappeared.
basically a combination of P and N type layers
of semiconductors. The four-layer diode could Shockley accepted a professorship at Stanford
replace both rectifier and transistors necessary to and at the time when the nation was going
connect long distance phone calls. through desegregation he picked the work of his
big idol - Alexander G. Bell, who was, beside
The disillusioned group of Shockley’s young the telephone, also interested in eugenics and
scientists, with the strong ego and desire to prove served as a honorary chair of World Eugenics
themselves were running into more frequent Conference in 1921. Nobody really proved that
conflicts with Shockley. It was almost Shockley was wrong with his eugenics opinions,
predictable that once they had more confidence however, also nobody joined him in support. He
and more knowledge about transistors they gave to his detractors easy ammunition against
would quit. They had access to all the him and it was not too difficult for incoming’
information kom BTL “Diffusion Conferences”, “politically correct” society to minimize his
and they were aware of the latest work on oxide contribution to mankind.
masking and resist “photoengraving.” There is a
memo dated December 16, 1956 describing the
latest BTL development work. Shockley attached DIFFUSION TRANSISTOR AT
a routing list to the memo and Robert Noyce, FAIRCHILD (2N696 and 2N697)
Gordon Moore, Jean Hoemi, and Jay Last
initialed the list. On November 6, 1958 The Fairchild “eight”
formed several transistors design teams. One,
After a night of wrestling between Robert under Gordon Moore, to develop NPN’s, and
Noyce, who originally did not want to leave second under Jean Hoemi, who was working for
Shockley, and G. Moore, R. Shelton, .I.Blank, J. Moore, to develop PNP’s.
Last, E. Kleiner, V. Grinich, and J. Hoemi all Jean Hoemi and David Allison developed the
eight scientists quit Shockley Semiconductor diffusion processes in diffusion furnaces they
Laboratories. designed with Cecil ‘‘Art’’ Lasch, Jr. Former
Paramount Pictures consultant and Shockley
Everybody who worked at Shockley Semiconductor Laboratory chemist, Gordon E.
Semiconductor Laboratories have described their Moore, managed all the early diffusion work at
personal experiences and portrayed all the Fairchild.
negatives of Shockley’s personality. The side The group extended BTL’s research work on
that was not heard was from Shockley himself. diffusion at Shockley Labs and then refined the
process at Fairchild to enable the production of
Historical documents only suggest what type of commercially manufactured transistors.
transistor Shockley originally intended to design. Transistor technology used by transistor
When the “Eight” left Shockley, the Beckman companies on the east coast was relatively well
Company’s legal department wanted to file a evolved in 1957. However, the mesa structure
suit and stop them from using information and silicon diffusion technology was still a
acquired during their association with Shockley. novelty. By the end of 1957 only Bell Telephone
(Fig. 22) Labs and Shockley Labs had some experience
with this device. From all other transistor
manufacturers, only Motorola hired a Western
222
Electric engineer to start the Mesa Transistor was used to control the temperature of the single
PrOgEUn. zone. The tube was equipped with a quartz
network of pipes, quartz valves, and flow meters.
The Fairchild “eight” made two important All systems resembled research laboratory
decisions regarding the mesa transistor: Kodak equipment rather than industrial manufacturing
photoresist was used for patterning structure and equipment.
both base and emitter were formed by difision. The wafers were pushed into and pulled out of
Although the photoresist patterning of the tubes manually. Cooling wafers usually took
semiconductors structures was developed at place in a cool zone within the diffusion tube and
BTL, Western Electric engineers considered this allowed the wafers to cool to a temperature
process as non-manufacturable and they suitable for handling. Programmed heating and
preferred the metal shadow masks. There was no cooling was not used because of the difficulty in
photoresist for semiconductor masking maintaining good temperature profiles.
operations generally. All the .work at BTL and The used gases were just emitted into
Fairchild was done with photoresist developed atmosphere by vents placed just above diffusion
by Eastman Kodak for panerning printed tube exhausts.
circuits. There was no “clean room etiquette” and the
chain smoker, Robert Noyce, frequently smoked
Initially, the “eight” had a big motivation. They in the Laboratory.
disagreed with Nobel Price winner and they
wanted to prove that they were right. They had at Jay Last who had a background in optics paired
the beginning a remarkable relationship. They with Robert Noyce and designed contact
knew all the tasks necessary to make the masking equipment that alligned masks to the
transistor: they divided them up and worked wafer flat. Fairchild I” diameter wafers had quite
together. At the start up each of “eight” did his a long “flat edge” (Fix. 23) so alligning the mask
part without a whole lot of formal supervision, to the end point of the flat and to the wafer
and they worked mostly with their hands. They crown was quite satisfactory.
did not even have a copy machine. They
depended completely on their own
resourcefulness and they were not worried about
Wall Street ratings.
223
I) Emitter region Process Flow: MESA PNP 2N697
2) Base and emitter contacts
3) Metal 1) 200 pm thick P-type Si substrate (0.7-1.3
The wafers were placed by the front side (resist) Ricm)
on the emulsion side of the masking plate and 2) Substrate etch and polish to thickness120
exposed for 60 sec by a mercury lamp. The P
exposed wafers were developed and baked. 3) Base Deposition
Source Sb203 at 650 O C , wafers zone
temperature 1120 OC, 250 cm'imin Nitrogen,
Process Flow: MESA NPN 2N696 deposition time 25 min
-
4) Base Drive-in (XI 6 pnQ
1) 200 pm thick N-type Si substrate (1-1.4 1200"C/ 15%hours, 250 c&min Oxygen
Rim) Thickness of oxide grown during drive-in -
2) Substrate etch and polish to thickness120 I
P
P 4) MASK-Emitter
3) Surface oxidation (wafer flat on quartz boat) 5) Wet etch oxide (oxide grown during base
1200°C/16hoursdry0~,- lOO008, diffusion)
4) Base Deposition 6) Emitter diffusion
Source Ga203 is inserted into furnace during Wafers are placed vertically into the quartz
surface oxidation, nitrogen flush 1200 "Ci boat
5minutes, 500 cm3/minNitrogen Wafer zone temperature 11230 O C , 400
-
5 ) Base Drive-in (XI 3.5 m) cm3/min Nitrogen, 3 cm3/min Oxygen, flush
1200 "C/ 30 minutes, YO crn'imin Nitrogen, time 5 minutes
10 cm3/min Hydrogen Wafers are inserted into processing tube
Flash - 1200 "Ci 3 minutes, 500 c d i m i n Additional 15 cm'imin Hydrogen (thin
Nitrogen oxide)
Base Deposition and Drive-in is performed E l 3 is added to the gasses (3 minutes)
in the same tube by switching gases 400 cm3/minOxygen (3 minutes)
6) MASK - Emitter Wafers are removed from the processing
Wet etch oxide, emitter region and back side tube
(17 OC HF, W F solution) 7) Front side of wafer is covered by wax and
Strip resist (acetone) glass plate
7) Emitter Deposition 8) Back side of wafer cleaned in HF
Wafers flat on quartz boat 9) Wafer backside sand paper scratch
P20s Source temperature 200 OC, Wafer IO) Evaporation of Nickel on the back side
zone temperature 1000 O C , 200 m3/min 11) Nickel diffusion
Hydrogen, deposition time 60 minutes Wafers flat on quartz boat
8) Evaporation ofNickel on back side Wafer zone temperature 11230 OC, 400
-
9) Emitter Diffusion (XI 2.6 pm)
e Wafers flat on quartz boat
Wafer zone temperature 1100 OC, 200
. cm3/min Oxygen, diffision time 11 minutes
Slow cool to 200 o c
12) MASK - Base and Emitter Contacts
cm3/minOxygen, diffusion time 45 minutes 13) Vacuum Evaporation of Aluminum and
10) MASK- Base and Emitter Contacts Phosphorus
1 1) Vacuum Evaporation of Aluminum 14) MASK-Metal
12) MASK-Metal 15) Metal etch
13) Metal etch 16) Metal alloy (-600 ' C i Smin, Argon, rapid
14) Metal alloy (-600 OC/ Smin, Argon, rapid cool)
cool) 17) Back grinding to thickness 60 pm
15) Backgrinding to thickness 60 pm 18) Nickel backside plating
16) Nickel backside plating 19) Apiezon wax deposition on front side
17) Wax deposition on front side through a glass through a glass screen covering mesa region
screen covering mesa region 20) Mesa etch ( - 15 pm)
18) M e s a e t c h ( - l S P ) 21) Wafer dicing
19) Wafer dicing 22) Thermocompression wire bonding
20) Thermocompression wire bonding
Both transistor projects were successful, but the Good luck strikes the Fairchild “eight” for the
NPN transistor was easier to manufacture, second time: Fairchild Camera received an
mainly because of contact to the base . To form important contract from Autonetics, a Division
an Aluminum ohmic contact to a moderately of North American Aviation, who was
doped Antimony base of a PNP transistor is developing the guidance control system of the
much more difficult than in the case of a Boron Minuteman missile.
doped base of NPN transistor. In addition, G. The 30 kg and 0.05 m’ computer was consuming
Moore as head of group had the power to choose 250 W of electric power, mainly for hundreds of
NPN as the first Fairchild transistor. Fairchild transistors used in computer designed
with discrete Transistor - Diode Logic.
It was not very difficult for Sherman Fairchild,
who was IBM’s largest shareholder and member Shortly after the contract was signed, Autonetics
of IBM’s board committee to get an order for a discovered that the Fairchild double diffused
1
hundred transistors at a price one hundred fifty mesa transistors had a reliability problem: an
dollars per piece. unpassivated base-collector junction was very
“.ll”..l...” .,.. __x
susceptible to electric breakdown.
225
Hoerni also attended the meeting of the
Electrochemical Society in 1958, where
Mohamed “John” Atalla of BTL presented a
paper about passivation of PN Junction by oxide.
226
the masterpiece idea struck one morning when be The company grew significantly and as always
was taking a shower. growth brings problems. Transfer from the
In the history of transistors and integrated development facility in Palo Alto to
circuits, here are only a few cases when well manufacturing facilities was slow and difficult.
planned and managed projects resulted in For example, in December 1960, Eugene Klemer
success. Transistor, Diffusion Technology, and asked Gordon Moore to solve a problem when
the Planar Process were not the result of the staff in Palo Alto were accusing people from
coordinated and supervised effort. They ware the Mountain View of taking Palo Alto's supplies of
result of personal individuality and creativity. paper and pencils.
The significant reduction of leakage cnnent of The photographs of planar transistors, showing
planar devices led Fairchild to new diode the contacts to the base and emitter is in Fig. 29,
manufacturing facility in San Rafael. The and decorated emitter and base diffusion layer is
Fairchild parts were superior to all other showed in Fig. 30, are both from the time when
manufacturers and the market demand the author did reverse engineering work on
skyrocketed. Fairchild management was Fairchild transistors.
preoccupied with manufacturing problems and
paid very little attention to development of future
products.
FIRSTINTEGRATEDCIRCUITAT
FAIRCHILD
227
component, therefore the concept of appropriate
device isolation was one of the principal
problems of integrated circuits. The second
problem, equally important for integrated
circuits, was the interconnection of individual
isolated components. Although none of these
issues were addressed in Texas Instruments
invention, the company launched a large
publicity campaign promoting the Kilby patent.
In response to this campaign, Robert Noyce
asked at WESCON 1959 (August 18-21) Jay
Last to start a development program with a goal
to create a Fairchild integrated circuit. Except for
this encounter, Noyce paid no attention to Jay's
work. The management of Fairchild
Semiconductor, a division of Fairchild Camera
and Instrument Corporation, was preoccupied
with exploiting the new exciting product - t h e
planar transistor, including a new plant in San
Rafael making diodes based on the Hoerni's
planar principle. The development of the first
planar integrated circuit was certainly not the
mainstream activity at the company.
228
Fig. 34 The world's first planar integrated
circuit designed and produced by Jay Last,
Lionel Kattner, and Isy Haas of Fairchild
Semiconductor. Functional units were
demonstrated in May 1960.
229
,..l.._".".. . . . . . . ........................
7.
8. -
Boron diffusion ( 6000 A oxide, -150
230
Fig. 35.RIS Flip Fop circuit produced with technology later used for Fairchild Micrlogic DTpL 900 series
231
’I?
would deteriorate the circuit perfomiance. The
fact that Noyce considered this type of device
isolation of some importance is supported by a
note Gordon Moore on December 12, 1962
added to the notebook where he wrote “I do
remember discussing this idea with RNN early
this year.”
232
THE FIRST INTEGRATED CIRCUIT created N-type base layer. From this wafer he cut
AT TEXAS INSTRUMENTS a bar 1.6 mm wide and alloy contacts to the back
of this semiconductor bar to provide contacts to
Texas Instrument was very slow in introducing the bulk resistor. Aluminum evaporated through
diffusion to transistor manufacturing. According an appropriate mask was used to form an emitter
to Kilby in 1958 there was still no working alloyed region. The gold-alloyed contact was
silicon mesa transistor. formed to the Ntype base. Wax was applied by
hand to mask the mesa of the transistor and
Obviously, at the time when TI hired Jack Kilby, region forming a dishibuted RC network. Loose
the company had no program or plan to explore Gold wire was then thermally bonded to the
an integrated circuit. appropriate areas to complete the
There are plenty of stories describing how Jack interconnection.
Kilby developed his circuit during a mandatory The transistor used by Kilby was identical to Lee
vacation. In a recent interview Kilby said: and Shockley’s transistor developed in 1955 in
“After several interviews, I was hired by Willis BTL.
Adcock of TI. My duties were not precisely
defined, but it was understood that 1 would work
in the general area of microminaturization. Soon June 23. 1964 J. 5. KILBY 3,138,743
after starting at TI in May 1958, I realized that ul”IATmI7m -w:c ClRNm
since the company made transistors, resistors, Fli.6 I.D. 6. 19s I Sk..t&“i.
233
Texas Instruments had at that time more tactics were the reason why Texas Instruments
sophisticated devices. lost in legal litigation with Sprague and Fairchild
Fig. 42. Jack S. Kilby’s phase shift oscillator with germanium mesa transistor, hulk resistor, and istributed
RC network (Texas Instruments, August 1958).
234
THEFIRST~GRA'IEDCIR~AT The other major Lehovec invention had a very
SPRAGW ELEClWC COMPANY interesting background. Lehovec attended a
workshop at Princeton University in the end of
At the beginning of the fifties the manufacturers 1958. Torkel Wallmark of RCA presented in this
of transistors resided on the east coast. The
manufacturing of point contact and alloyed
germanium transistors was very similar to the
assembling of vacuum tubes. Vacuum company
tubes such as RCA, Westinghouse, General
Electric, Sylvania, Raytheon and others saw the
transistor as a similar product. The management
of vacuum tube companies had no knowledge of
semiconductors and.they were not able to extend
the design of the transistor beyond the
knowledge they bought with license rights from
Western Electric. Gradually all of them quit the
semiconductor business.
The Sprague Electric Company is an example of
a different business decay. Two man in charge of
the company, two brothers, struggled for control
of the company, each of them trying to put his
son into the company leadership. As could have
been predicted, neither of them achieved his
goal. However, this internal fighting drove the
company slowly out of business.
In this environment Research Director of
Sprague Kurt Lehovec launched the
semiconductor business in 1952.
Kurt Lehovec started his career in former
Czechoslovakia. At Charles University in Prague
as a member of a group of Prof. B. Gudden
(student of Prof. Pohl), Lehovec worked on
selenium rectifiers. Suddeutsche Apparate Fabrik
in Nuremberg sponsored research. During the
course of this research he noticed that thallium
diffused into selenium very rapidly and the
"blocking effect" ' o f the rectifier was
significantly improved.
After the war, the CIA transferred Kurt Lehovec
to the USA during operation "Paper Clip", and
he started work for the U.S. Signal Corps in Fort
Monmouth in New Jersey. There he worked on
the problems of light emission from solids.
In 1952 A.C. Sprague hired Lehovec with the
intention to bring the company into the
semiconductor business. One of the first major
improvements of transistor technology was the
introduction of new alloying -'*capillary
alloying" at the end of the fifties. This method
with the surface melt technique enabled the " .
.. ,. ._
. , ,~ .. m. e*
production of multiple junctions in a single slice .I_,.
I .',, L*2;s'~~.rL*
.. . '. , , ., . .. .:
of semiconductor. The method was superior to
the BTL and TI grown junction transistor
Fig. 43 Transcript from Kilby vs. Lehovec final
process, which could produce, only PNP or NPN
hearing march 16,1966
structures.
235
workshop a visionary paper about the next Sprague Electric Company in Concord, NH
generation of electronics. Wollmark presented a where UNICIRCUIT series was manufactured.
list of problems that needed to be solved before
integrated circuits could be designed. One of
these limitations was device isolation.
Lehovec, educated from his work on the surface
melt multiple junction devices found a solution -
PN junction isolation.
The engineering problem was solved; the bigger
problem remained to be overcome. At that time
nobody had heard anything about integrated
circuits, so only visionaries could have
appreciated the importance of Lehovec’s
invention. Sprague Company did not have
visionaries and they did not want to file a patent
application.
After months, a persistent Lehovec finally
prevailed. His patent was approved and issued by
the Patent Office without a major objection.
Immediately after the patent was issued Texas
Instruments appealed causing the interference
Kilby vs. Lehovec (Fig. 43 ).
After an attorneys’ meeting, which counted a
double digit of TI’S attorneys and one attorney
for Lehovec, in the interference proceeding, the Fig. 45. Packaged Sprague integrated circuit
Patent Office held that Lehovec was entitled to (1962).
all claims.
Lehovec moved to Los Angeles and retired in
1978. He becomes a poet and play writer. He
remains a loner and enjoys lone walks during the
night paying no emphasis to his previous career
of physicist.
THEFIRsTlhTEGRATEDClRClJlTAT
SYLVANIA
236
At that time James Buie at Pacific November of the same year, Tom Longo
Semiconductor (later TRW Electronic presented a paper at the IRE group meeting
Components Group) developed logic that (PGED) in Washington. It was from that paper
became later known as transistor-transistor that Texas Instruments copied this device and
logic. introduced two years later as Texas Instrument
TTL series 5400 with only a single difference -
Tom Longo started his career at General different pin out.
Telephone Labs in 1958. GTL merged with Actually, Tom Longo visited TI after he
Sylvania Electric Products in Wohurn, MA. presented the paper. TI’S Howard Moos who
Sylvania was one of the original companies was in charge of the 5400 series development
licensing transistor technology from BTL and said to Tom: “we are not too far behind you.”
producing alloy transistors. Tom become However, TI added to Tom’s circuit a very
Director of R&D and managed advanced devices important feature. TI developed the new plastic
development. package. This was the reason why the very low
By 1959 the transistor technology was well priced logic series became the most popular
evolved and Tom’s group developed the fust family of logic circuits.
Sylvania mesa double diffused transistor. The
next project in 1960 was the first gjgahertz The case of Sylvania TTL is a typical example of
silicon planar epitaxial transistor. During this advances in integrated circuits. Except for Jean
project Sylvania developed an accurate masking Hoerni’s idea of the planar transistor, which
procedure, and in 1961 started development of stood out, most of the achievements of
integrated circuits. The established goal was to monolithic integrated circuits are results of
develop a gate with sub 10 nsec speed (at that contributions of many participants: James Buie
time competitors offer 70 nsec which was the sparked the idea, Thomas Longo make it
typical gate delay). functional and manufacturable, Texas
Tom Lnngo was the first to recognize that the Instruments lowered price make a product
old myth that the resistor is the cheapest favorable over the existing devices on the
electronic components was not true any longer in market.
monolithic circuits. He used a large number of
transistors in his logic gate: multi-emitter input Tom Longo left Sylvania in 1966 and moved to
transistor, fust inverter, level shifter, Darlington start IC business at Transitron where he
and cascade - totem pole. The gate speed was developed the first 16 hit bipolar RAM.In 1970
about 6 nsec. In comparison with Fairchild Longo joined Fairchild.
circuits the major difference was that Sylvania
transistors were small, with very tight
dimensional control.
237
COMMERCULLY AVAaABLE
FURNACES (1960-1965)
238
line voltage changes. They decided that instead Nevertheless, a change in the power requirement
of powering the heating elements directly by of the center zone changes the power of two
line voltage they would use a step down other zones.
transformer and use low voltage heating The insertion of the boat into the center zone
elements. caused an increase of temperature of the end
zones. When the center zone reaches the set
point temperature, the power applied to the end
zones decreased.
For long processing times this was not a very
significant problem.
This type of furnace was marketed by Thermco
Products as Pacesetter 1, and an early units were
shipped to Westinghouse in Canoga Park, CA,
Motorola in Phoenix, and Hughes
Semiconductors in Newport Beach.
As other vendors, Thermco was using the quartz
pipes and quartz valves to distribute gases. The
quartz assemble called ‘Quartz Jungle” was
produced by hay area Hank Schroder’s company.
The processing time was “controlled” by
mechanical “Green Labs” timer. One turn of
timer was 60 minutes, when the timer rings, “the
girls’’ adjusted the timer again.
Fig. 51. Fairchild’s one inch wafers in
Electroglas difksion furnace (1962).
239
variation of the line voltage and allowed the second biggest producer of equipment for
Thermco to guarantee temperature uniformity semiconductor manufacturing, started production
over 2 0 zone with +/- 0.25 OC in the range of of Thermco diffusion furnaces under a license
processing temperatures of 8OO-IZSO ‘C with strictly limited to just the Japanese market only.
virtually no drift.
The furnace was marketed under the name
Pacesetter I1 as a two stack model, and become
industry workhorse for many years processing 2”
and 3” wafers
240
CONCLUSIONS
241