CLASS – XII Time – 3hrs
MM – 70
SUBJECT – CHEMISTRY
Note:-
Section A - Multiple-Choice Questions (MCQs)/ Assertion-Reasoning
Section B - 5 very short questions - 2 marks per question- 10 marks
Section C - 7 short question- 3 marks each - 21 marks
Section D - 3 long questions- 5 marks each - 20 marks
Section E - 2 case based questions - 4 marks each - 12 marks.
SECTION A
Q1. The standard reduction potentials of X, Y, Z (b) 6 × 96500 C
metals are 0.52, -3.03, -1.18 respectively. The
order of reducing power of the corresponding (c) 2 × 96500 C
metals is:
(d) 1 × 96500 C
(a) Y > Z > X
Q4. Osmotic pressure of a solution is 0.0821 atm
(b) X > Y > Z at a temperature of 300 K. The concentration in
moles/lit will be:
(c) Z > Y > X
(a) 0.33
(d) Z > X > Y
(b) 0.666
2+
Q2. The standard reduction potentials of Cu /Cu
and Cu2+/Cu+ are 0.337 and 0.153 respectively. (c) 0.0033
The standard electrode potential of Cu+/Cu half- (d) 3
cell is
Q5. The solution that forms maximum boiling
(a) 0.184 V azeotropes is
(b) 0.827 V (a) Carbon disulphide – Acetone
(c) 0.521V (b) Benzene - Toluene
(d) 0.490 V (c) Acetone – Chloroform
Q3. How many coulombs of electricity is required (d) n-Hexane – n-Hectane
to reduce 1 mole of Cr2O72- in acidic medium?
Q6. KH value for Ar(g), CO2 (g), HCHO (g) and
(a) 4 × 96500 C CH4 (g) are 40.39, 1.67, 1.83×10–5 and
0.413 respectively. Arrange these gases in the (a) C6H5Cl
order of their increasing solubility. (b) CH2=CHCl
(a) HCHO < CH4 < CO2 < Ar (c) ClCH2CH=CH2
(b) HCHO < CO2 < CH4 < Ar (d) CH3CH=CHCl
(c) Ar < CO2 < CH4 < HCHO
(d) Ar < CH4 < CO2 < HCHO Q12. For a reaction P + Q → 2 R + S , the incorrect
statement is
Q7. Which of the following is used for
denaturation of commercial alcohol? (a) Rate of disappearance of P = Rate of
appearance of S
(a) Copper sulphate
(b) Rate of disappearance of Q = 2 x Rate of
(b) Pyridine appearance of R
(c) Methyl alcohol (c) Rate of disappearance of Q = Rate of
disappearance of P
(d) All of the above
(d) Rate of disappearance of Q = 1⁄2 x Rate of
Q8. Rate of dehydration of alcohols follows the appearance of R
order:
Q13. A first order reaction has a rate constant
(a) 2° > 1° > CH3OH > 3° 1.15 × 10-3s-1. Time taken for 5 g of this reactant
(b) 3° > 2° > 1° > CH3OH to reduce to 3 g is
(c) 2° > 3° > 1° > CH3OH
(d) CH3OH > 1° > 2° > 3° (a) 444 s
Q9. Which is the correct IUPAC name for (b) 400 s
(c) 528 s
(d) 669 s
Q14. Which of the following influences the
reaction rate performed in a solution?
(a) Methylchlorobenzene (a) Temperature
(b) Toluene (b) Activation energy
(c) 1-Chloro-4-methylbenzene (c) Catalyst
(d) 1-Methyl-4-chlorobenzene (d) All of the above
Q10. Which of the following is most reactive Directions: These questions consist of two
towards aqueous NaOH? statements, each printed as Assertion and
Reason. While answering these questions, you
(a) C6H5Cl are required to choose any one of the following
(b) C6H5CH2Cl four responses.
(c) C6H5Br (a) If both Assertion and Reason are correct and
(d) BrC6H4Br the Reason is a correct explanation of the
Assertion.
Q11. Which of the following is most reactive (b) If both Assertion and Reason are correct but
towards nucleophilic substitution reaction? Reason is not a correct explanation of the
Assertion. Q16. Assertion : If a liquid solute more volatile
(c) If the Assertion is correct but Reason is than the solvent is added to the solvent, the
incorrect. vapour pressure of the solution may increase i.e.,
(d) If both the Assertion and Reason are incorrect. ps > po.
Reason : In the presence of a more volatile liquid
Q15. Assertion : Molarity of a solution in liquid solute, only the solute will form the vapours and
state changes with temperature. solvent will not.
Reason : The volume of a solution changes with
change in temperature.
SECTION B
Q17. What is the significance of Henry’s Law constant KH ?
Q18. Depict the galvanic cell in which the cell reaction is : Cu + 2Ag+ → 2Ag + Cu2+.
Q19. Write the rate equation for the reaction 2A + B → C if the order of the reaction is zero.
Q20. Why does iodoform have appreciable antiseptic properties?
Q21. Suggest a reagent for conversion of ethanol to ethanal.
SECTION C
Q22. Explain the solubility rule “like dissolves like” in terms of intermolecular forces that exist in solutions.
Q23. Write the Nernst equation for the cell reaction in the Daniell cell. How will the E cell be affected when
concentration of Zn2+ ions is increased ?
Q24. Why is molecularity applicable only for elementary reactions and order is applicable for elementary as
well as complex reactions?
Q25. Which of the following compounds (a) and (b) will not react with a mixture of NaBr and H 2SO4.
Explain why?
Q26. Draw other resonance structures related to the following structure and find out whether the
functional group present in the molecule is ortho, para directing or meta directing.
Q27. Write the structures of the isomers of alcohols with molecular formula C4H10O. Which of these
exhibits optical activity?
Q29. Explain why alcohols and ethers of comparable molecular mass have different boiling points?
SECTION D
Q30. Why are aryl halides less reactive towards nucleophilic substitution reactions than alkyl
halides? How can we enhance the reactivity of aryl halides?
Q31. What is Nernst equation ? write the Nernst equation for the reaction.
2Cr(s) + 3Cd2+ (aq) → 2Cr3+ (aq) + 3Cd (s)
Q32. Define the following modes of expressing the concentration of a solution. Which of these modes are
independent of temperature and why?
(i) w/w (mass percentage)
(ii) V/V (volume percentage)
(iii) w/V (mass by volume percentage)
(iv) ppm. (parts per million)
(v) x (mole fraction)
(vi) M (Molarity)
(vii) m (Molality)
SECTION E
Q33. Read the passage given below and answer the following questions:
Few colligative properties are:
(a) relative lowering of vapour pressure: depends only on molar concentration of solute
(mole fraction) and independent of its nature.
(b) depression in freezing point: it is proportional to the molal concentration of solution.
(c) elevation of boiling point: it is proportional to the molal concentration of solute.
(d) osmotic pressure: it is proportional to the molar concentration of solute.
A solution of glucose is prepared with 0.052 g at glucose in 80.2 g of water. (Kf =
1.86 K kg mol-1 and Kb = 5.2 K kg mol-1)
The following questions are multiple choice questions. Choose the most appropriate answer:
(i) Molality of the given solution is
(a) 0.0052 m (b) 0.0036 m (c) 0.0006 m (d) 1.29 m
(ii) Boiling point for the solution will be
(a) 373.05 K (b) 373.15 K (c) 373.02 K (d) 372.98 K
(iii) The depression in freezing point of solution will be
(a) 0.0187 K (b) 0.035 K (c) 0.082 K (d) 0.067 K
(iv) Mole fraction of glucose in the given solution is
(a) 6.28 x 10-5 (b) 1.23 x 10-4 (c) 0.00625 (c) 0.000284
Q34. Read the passage given below and answer the following questions:
Although chlorobenzene is inert to nucleophilic substitution, however it gives quantitative yield
of phenol when heated with aq. NaOH at high temperature and under high pressure. As far as
electrophilic substitution in phenol is concerned the - OH group is an activating group, hence, its
presence enhances the electrophilic substitution at o- and p-positions.
The following questions are multiple choice questions. Choose the most appropriate
answer:
(i) Conversion of chlorobenzene into phenol involves
(a) modified SN1 mechanism
(b) modified SN2 mechanism
(c) both (a) and (b)
(d) elimination-addition mechanism.
(ii) Phenol undergoes electrophilic substitution more readily than benzene because
(a) the intermediate carbo cation is a resonance hybrid of more resonating structures than
that from benzene
(b) the intermediate is more stable as it has positive charge on oxygen, which can be better
accommodated than on carbon
(c) in one of the canonical structures, every atom (except hydrogen) has complete octet
(d) the -OH group is o, p-directing which like all other o, p-directing group, is activating
(iii) Phenol on treatment with excess of conc. HNO3 gives
(a) o-nitrophenol
(b) p-nitrophenol
(c) o-and p-nitrophenol
(d) 2, 4, 6-trinitrophenol
(iv) The major product of the following reaction is
