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Statistical Mechanics
Quantum mechanics and its maths
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Statistical Mechanics
Quantum mechanics and its maths
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UNUT=]V__ Bory STATISTICAL MECHANICS ToT a eee tn Stebrbenl Mechanics Wwe care tert Bey the Weratt behav Agihent Aan deo en Agen ts Pruecls te netetent 4, te proposes 5 ee. Hemnelves ne fhe partetes Ss STATE TH CAL DIST RIA UTIONs:- ne \ gee nécder so ad AA fl energy 6 ae-ft o + Perea N Shbeshienk Mecherits aelermenes the moot prrbeble “a Tr vole o cenbaeen Gorouet f foforl, Pury E + He Ayton fh ditnecbuded among the ae a +f povbictet, fry Ab Hheermet 2qew. af absolve. cae ee: Th by ry thebsherl mecloroes, wales tefabe.s 2. Axed Arr hey. prvtecles ane beeey by eet af Pl ge ote a torre &, md fo on.‘ Pa peviveles Aviom orange € © ~ ~” ' mC) = = pO Fce) . phone ne ae ne af ohates 4 aoorty 6 ' Fee) 6 ddtncbutiom fonction prbabitety of yy , plote : a fre obisdrah whom f ony tran - wu os inv ity a € & Erde ceo Pompei | 0 The dist rcb uhm frunetin {@ 4 Affr a dufferert type 4 pratelie. lle done 4 ae@ Oy maton, Ponticls'.- They ane volenital ara - Bat guarct ble pantrca (ae ffroeently few ape fom Orch ie dp be soit misab ) Fey Ae Wieg Ma welt Beth» Bethe wan” = (ht) For Example! qos DEbibuban ‘o im Mokcules, & Bosons = Thy ome colenberl ond ren-dekn Us habla ches, “Tho, toe ow rte AP 2 o 123, Be hey Ct ae bese E Ens as iit hi bnbrw ene ee 6 ee me @) Fewmcone Thong ae, tderteenl Ancf won dhibrngninbebie jee Ue Agar odd 7” yt. re ee ie Va, Bz, sf> - as 7 Fermc- Dine Pu bibuhiw pometoen (Fre). Fry Example elichons , prefens, neubrns ete MAX WELL-ROLTZ MANN SATS ne Sia (OO atc UR aa toeles nck os molecules of Bm Meetaeliae zs Csatenk obey Maxwell Boltzmann Séntistes ,@ The Maxwete-Buttowenm 6 dvlncbuben prnchen Hotes trat He owerare noc) the peattcts Fann (e) ma Atte of energy € In o ar at absolute Pomp eae - [fnece) = Ae HT! —@ VW cam (h, tHe yale of conatant A ape gw the wn t a Yor the ini pa aves bh ih, marr plvzebvew comnabant + a Wwowe poscteoy kk 6 Botta comnspont ard k= haoxb Tk =0-62 a1 w/e] MopecuLag Energies OF AN IDEAL GAS’— PUREE Beinn Cintrotces anced Ie tee amo leenkeo of aw wdexl fe Comer a Sia +t ewleak eg gy ee at ee (rmokee wes 4 am der, #7) ane bo ffeil My tre boat, bo one, igi (Seles oa find to afi Max welt Olzmannr Abefiatees. The ne. of no leewles, Point eel j ye neme = ae) fte) © Gos molecnles M-6 obebupics | 50 = ft = form ce) “ace = HO finn Ce) . fic) = 40 Tins Dupe fr. > "Ce = [qeo]nae iT —O Ss, pe vo. of PS ae toving omer oe hefveer¢ te G+de & (een a NCE) de =[4©) dé ]xre skt__@ To and Ce) d és To fr peeide one * abates dre —<. bo € and Etde. Since a wmoleente Pp phere aes p v Sia as- p = fame =P aha € At & memmiin6 MT inet orionectiue apace there ocerdinate axes one pr, by. pe as Be om Hae &, No 4 mementumn Atades in Moment nage 5 mal fy the vebune of & et tras ae ee. yp thiceress ab le = vet f Afbental abel Un mon, qer)ap 4 ee xy, qerdap = men ‘lei cas ae orth (dp) ov, HW) ae ans Axp> db e = Bh>ap eran] ROY
= (kt)™ re | eae] 1 ok (kt) pom Mae 2aNn (a = = Bl x(kr) 4 . ma ee “(ny x cy? Lf 3x (kT) a eeY a U Vy
gt (erp ee ee (om mm)? 3/2 x2 (1) es kT. p8Kr_ A Ba xo *6 fis = ee “a ' Kk aff on V. = mm nos wees 4 y Pe| C Mrs an a koe eer, BT i atest eet) PE s ay Aaa (¥). ete toe Oe ok Mee EB pee *Y 1 og. ) Aare ee ogg Shr Since OK mobewte: (Ca atorns, Atomce’ moss af Orygen i i Mey ae tett iy (Atere macs nck) Mons oh tee ype dens = 2x(6u =32u blu & fog malacuele (02°) = Mase 27 E32 X1€6 xo oy) Mass - ote vaolrcate (Or oe < = 53sf2 X[e Pts Soa) xf 113 i 3K7_, foRbse A mers Te Aix 273 ea a = S31 7 eh = = [2x1 = fa a Fins = Yim = [21 a5n? axle?(cB QUANTUM STATISTICS ‘ NaN aS ae rons Wert babi shics for Bosens ak Fer rue ms Besons !- 9 Bosom eve 9 wv Posty vod Apia Je 1,2,3,4 > These preteetes are aut emg cba mb fay Wale, ferchons pee > They dott fried Panllls aonchuiew paometple We mm vase velnchen ow ~. a bons in a abete. > Rey Awe a wre ieee Phetms, Grevihens, Prone eke x? Exampls |- Fen ance ns) ~ al im fe Vp, 3h sh a Jone * ad - manege ae /: ee “4 wetable a6 Pow Ly Meee eae me ane ae BS) alse ow a a pa. 3 Mae Aone ong amin foet
Exewaples'- eleeborvs, prolie tasaaa fe Gir esha thet fro beso ms ( tr Dmfnet 7H eo. + a bosons ) cam be tw & Ara le iste. 2... be im w svg le otnte. >systen rd dB | Corn Tot a, Byaterm two particles s ri \@ me two Atte Ya and y, 4 co pone ete Prices oe dhs Dera cept then Pm she fae Panel = Ale 2 Pree” tine } petbctis te bate et patcls = a oe may a ard no Her ehiver- at pestle Ae We = Yai) We (2) Geet peri botty ae Yo = YAO) Yel), Bb get ak lo Boone meek ey rae. ae lf a es ee mh (combi it 2 pee two- Wi ai (Vie Coke Ee 2 ee +a) ay ' ot)Nee rechinelnmaiy pha paroles betwaer bakes te Sp ws pwd Bi. Ye eet Yo(') # Ya!) Yo(2)] Peay Vile) + velar veCD] wihech Ab Baw 25 equ ), £° we ate | a onbnchonge “4 points aos ek close -% povehim Soe colt fre voave fumekr , pe ee) bey bosoms Aeeit: depres "eae, fenehins, ee a FJ yar yale) + vate) v.09] = New , tear hanna pre Pag bebwoem ata jae Pad 2 aa NAA ce SAY ly, (2) Yor) — Yat!) Yul? He [Male) Yo) — ol? J a Wie Sale] BoE [ nome re wo] aay j (Some As ean @) wok erro. Ae a ie@ PO Reo tay thad | ug inter ost mcs es Joe weve furetom We (05 We i Rae j~) thew wa ‘call pre Wave fooche Me = Samelne ewe wevebar fe Farmnwvens Love ery eth wove fonehins, (IY New | folee a Am oat ea able a ond to Oe 1 2), et. Wille. cles (Cowiert porbers ), be Bee eel IN aed VY = Yo) ya (2) Probabusty ae [You]> = FR Yu yor® = yalidyale) yer ody?) Fre bo besens ie al2) + Ya(2) ad Ez vaya] = 2 yale ©) a, 1) Yate) Me Yo* =/2 [Ya(1) Yate) xe fiat vata} = 2] Yarn Yat YoPOD Yu (2)) = 2 Yay Yueed
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